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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Collision induced disassociations of 2000 ev diatomic O, N, CO and NO positive molecular ions as function of reactant ion internal energy
Collective approach to thermodynamics of N- particle electron gas including transverse radiation, calculating internal energy and pressure of modes
An explicit numerical solution of the compressible Navier-Stokes equations is applied to the thermodynamic analysis of supercritical oxygen in the Apollo cryogenic storage system. The wave character is retained in the conservation equations which are written in the basic fluid variables for a two-dimensional Cartesian coordinate system. Control-volume cells are employed to simplify imposition of boundary conditions and to ensure strict observance of local and global conservation principles. Non-linear real-gas thermodynamic properties responsible for the pressure collapse phenomonon in supercritical fluids are represented by tabular and empirical functions relating pressure and temperature to density and internal energy. Wall boundary conditions are adjusted at one cell face to emit a prescribed mass flowrate. Scaling principles are invoked to achieve acceptable computer execution times for very low Mach number convection problems. Detailed simulations of thermal stratification and fluid mixing occurring under low acceleration in the Apollo 12 supercritical oxygen tank are presented which model the pressure decay associated with de-stratification induced by an ordinary vehicle maneuver and heater cycle operation.
The tables include entropy, enthalpy, internal energy, density, volume, speed of sound, specific heat, thermal conductivity, viscosity, thermal diffusivity, Prandtl number, and the dielectric constant for 65 isobars. Quantities of special utility in heat transfer and thermodynamic calculations are also included in the isobaric tables. In addition to the isobaric tables, tables for the saturated vapor and liquid are given, which include all of the above properties, plus the surface tension. Tables for the P-T of the freezing liquid, index of refraction, and the derived Joule-Thomson inversion curve are also presented.
Computer programs were developed which compute the thermodynamic properties of equilibrium air for use in either the time-dependent or shock-capturing computational methods. For the time-dependent method, tne NASA-ARC RGAS computer program was modified to allow internal energy and density to be used as the independent variables. In addition, simplified-curve fits for p = p(e,rho), a = a(e,rho), and T = T(p,rho) were devised to reduce computer time. For the shock-capturing method a simplified curve fit for h = h(p,rho) was made. These approximate curve fits may be particularly useful when employed on advanced computers such as the Illiac 4 or the CDC Star since they avoid the cumbersome table-lookup feature of the RGAS program.
Calculation of the thermodynamic properties of an atomic hydrogen-helium plasma for postulated conditions present in a stagnation shock layer of a spacecraft entering the atmosphere of Jupiter. These properties can be used to evaluate transport properties, to calculate convective heating, and to investigate nonequilibrium behavior. The calculations have been made for temperatures from 10,000 to 100,000 K, densities of 10 to the minus 7th and .00001 g cu cm, and three plasma compositions: pure hydrogen, 50% hydrogen/50% helium, and pure helium. The shock layer plasma consists of electrons, protons, atomic hydrogen, atomic helium, singly ionized helium, and doubly atomized helium. The thermodynamic properties which have been investigated are: pressure, average molecular weight, internal energy, enthalpy, entropy, specific heat, and isentropic speed of sound. A consistent model was used for the reduction of the ionization potential in the calculation of the partition functions.
Thermophysical properties data for oxygen at pressures below 5000 psia have been extrapolated to higher pressures (5,000-10,000 psia) in the temperature range 100-600 R. The tables include density, entropy, enthalpy, internal energy, speed of sound, specific heat, thermal conductivity, viscosity, thermal diffusivity, Prandtl number, and dielectric constant.
When graphite is used as ablation material in heat shields, very often a prominent carbon species vaporized into the stream is C3. The thermodynamic properties of the C3 molecule are, therefore, important in calculating transport phenomena in the ablation flow field. The nature of the C3 thermodynamic functions has been in doubt because of the uncertain contribution of the bending mode vibrations to the total internal energy of the molecule. An approach for overcoming these difficulties is considered. The results of the computations are presented in the form of graphs and approximating functions.
The sharp leading edge problem has been studied for both monatomic and diatomic gases using the Boltzmann equation with the Bhatnagar-Gross-Krook type models as the governing equation and the discrete ordinate method with a closed-boundary value approach as a tool. Plate length relative to the freestream mean free path is taken to be 52. The gas-surface interaction law is assumed to be diffuse reflection. The local distribution functions of molecular velocities and internal energies (for the diatomic gas) for the entire flowfield have been calculated for a freestream Mach number of 6.1. Comparisons are made between the calculated results and experimental data.
A preliminary evolutionary calculation was made for a stellar object of 0.001 solar mass composed of pure hydrogen. The star undergoes the gravitational contraction from an initial radius of 35 times the present radius of Jupiter (R sub Jup). The interior is assumed to be in convective equilibrium throughout the evolution. The evolution has been followed for 10 to the ninth power y at which time R = 2.8 R sub Jup and the central temperature is 18000 K. The log of the luminosity (in units of solar luminosity) and effective temperature due to the internal energy sources are log L/solar luminosity = -9.0 and log T sub e = 1.77.
Compressibility measurements and thermodynamic properties data for parahydrogen were extended to higher temperatures and pressures. Results of an experimental program are presented in the form of new pressure, volume and temperature data in the temperature range 23 to 300 K at pressures up to 800 bar. Also given are tables of thermodynamic properties on isobars to 1000 bar including density, internal energy, enthalpy, entropy, specific heats at constant volume and constant pressure, velocity of sound, and surface derivatives. The accuracy of the data is discussed and comparisons are made with previous data.
The internal energy, pressure, and compressibility of ground-state, spin-aligned atomic hydrogen, deuterium, and tritium are calculated assuming that all pair interactions occur via the atomic triplet (spin-aligned) potential. The conditions required to obtain atomic hydrogen and its isotopes in bulk are discussed; such a development would be of value in propulsion systems because of the light mass and energetic recombination of atomic hydrogen. Results show that atomic triplet hydrogen and deuterium remain gaseous at 0 K, and that tritium forms a liquid with a binding energy of approximately -0.75 K per atom at a molar volume of 130 cu cm per mole. The pair distribution function for these systems is calculated, and the predicted superfluid behavior of atomic triplet hydrogen and tritium is briefly discussed.
The solar system is considered along with the significance of meteorites as samples of the universe, the origin of planets, and earth's-eye view of the moon, previews of the lunar surface, aspects of impact cratering, lunar igneous processes, the mapping of the moon, the exploration of the moon in connection with the Apollo lunar landings, and the scientific payoff from the lunar samples. Studies of Mars, Venus, and the planets beyond are discussed, taking into account the Mariner Mars program, the Mariner orbiting mission, missions to Venus, the Mariner flight to Mercury, and the Pioneer missions. Attention is also given to the origin of the moon, implications of the moon's thermal history, similarities and differences in planetary evolution, and the role of internal energy in planetary development.
From the point of view of meteorology the most important differences between Jupiter and the earth are related to the fact that Jupiter has an appreciable internal energy source and probably lacks a solid surface. The composition and vertical structure of the Jovian atmosphere is considered along with the composition of Jovian cloud particles, turbulence in Jupiter's atmosphere, data on the horizontal structure and motions of the atmosphere, and questions related to the longevity of Jupiter's clouds. Attention is given to the barotropic characteristics of Jupiter's atmosphere, the radiation balance in the atmosphere of the earth and of Jupiter, and studies of the Great Red Spot.
Close encounters between two spherical galaxies of equal size and consisting of only one stellar population are calculated using models of elliptical galaxies constructed according to King's (1966) method. The mass loss and the change in internal energy are computed under the assumption that the stars do not change their velocity or density distributions during the encounters. The results for a specific case are compared with the calculations of Gallagher and Ostriker (1972), who employed the observed brightness distribution and the derived density distribution of the E1 galaxy NGC 3379. For models with one stellar population, the results suggest that the radius of a galactic halo would have to be at least 200 kpc for appreciable mass loss to occur over the history of a galaxy in a rich cluster. The calculations are then extended to include a halo population characterized by a high central velocity dispersion. In this case, it is found that the halo population of sufficiently large galaxies can be dispersed without appreciably affecting the main population. It is suggested that the missing mass of many clusters of galaxies may be located in an intergalactic sea of faint stars making up an envelope for the centrally located gE galaxies.
The evolution of the middle part of the primitive solar nebula is traced through seven stages: (1) a gravitational instability which clumps condensed material into bodies of appreciable size; (2) the formation of a larger body as a result of mutual collisions; (3) gravitational condensation of the gas in the nebula; (4) subsequent hydrodynamic collapse of the gas onto a heavy-element planetary core; (5) the attainment of a highly distended hydrostatic configuration and its subsequent slow gravitational contraction; (6) the formation of a gaseous disk around proto-Jupiter; and (7) the formation of the Galilean satellites (and Amalthea) within this disk. Different theories on the origin of the primitive solar nebula are reviewed, models of Jupiter are evaluated, and the origin and evolution of the planet are traced through the indicated stages. It is proposed that Jupiter's current excess luminosity is due mostly to a loss of internal energy generated during the initially more rapid contraction period and, to a lesser degree, to the planet's current release of gravitational energy. The question of when the icy constituent was added to the outer two Galilean satellites is considered.
The formation of the ethylene oxide molecular ion and its subsequent ion-molecule reactions leading to the products C2H5O(+) and C3H5O(+) have been studied using time-resolved photoionization mass spectroscopy, ion cyclotron resonance spectroscopy, and photoelectron spectroscopy. An examination of the effects of internal energy on reactivity shows that the ratio of C3H5O(+) to C2H5O(+) increases by an order of magnitude with a single quantum of vibrational energy. The formation of (C2H4O/+/)-asterisk in a collision-induced isomerization is found which yields a ring-opened structure by C-C bond cleavage. The relaxed ring-opened C2H4O(+) ion reacts with neutral ethylene oxide by CH2(+) transfer to yield an intermediate product ion C3H6O(+) which gives C3H5O(+) by loss of H.
Models of the interior of Uranus suggest that the abundances of such substances as CH4 are greatly enhanced with respect to solar abundances of heavy elements. Such enhancement leads to a new type of model atmosphere for Uranus, which agrees with observation if the internal energy flux is small (no more than 10%) compared with the absorbed solar energy. An important feature of the models is the presence of a cloud of CH4 droplets whose top is at a temperature of approximately 90 K and a pressure of about 4 atm. Above the cloud, the atmosphere is stable because of the rapid decrease in the thermal flux with depth. Being saturated, most of the observable gaseous CH4 is near the cloud; the CH4 abundance above the cloud, of the order of 5 km-am, is a very sensitive function of the cloud-top temperature.