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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Coronal temperatures, heating, and energy flow in a polar region of the sun at solar maximum

The profiles of resonantly scattered Lyman-alpha coronal radiation have been used to determine the hydrogen kinetic temperature from 1.5 to 4 solar radius from the center of the polar region of the corona observed in 1980 at solar maximum. Hydrogen temperatures derived from the line profiles were found to decrease with height from 1.2 million K at r = 1.5 solar radii to 600,000 K at r = 4 solar radius. Comparison of the measured kinetic temperatures with predictions from a semiempirical two-fluid model showed evidence of a small amount of heating or a nonthermal contribution to the motions of coronal protons between 1.5 and 4 solar radius. The widths of the profiles confirmed an upper limit of 110 + or - 15 km/s on the rms magnitude of the line-of-sight component of velocities between 1.5 and 4 solar radius. Density measurements obtained in situ in the solar wind in the ecliptic were used to locate the sources of low speed and high-speed winds in the polar region. An eclipse photograph of the corona at solar maximum is provided.

Withbroe, G. L.↗
NASA NTRS1989

Effects of introducing a gas into the free-electron laser

The introduction of a gas into the wiggler section of a free electron laser (FEL) alters the phase velocity of the electromagnetic wave, and so changes the synchronism condition relating wavelength to wiggler parameters and beam energy. This provides a means for tuning the frequency of an oscillator, with the addition of 200 torr of hydrogen gas, the wavelength of a FEL operating in the near infrared without gas was reduced by 0.73 microns. The plasma generated from ionization of the hydrogen molecules by collisions with the electron beam diminished the oscillator gain, but this effect was eliminated by the addition of less than 0.1 percent of an electron attachment gas. Gain is also reduced by multiple scattering of the beam electrons, but this effect is not severe for a 1-m wiggler length. When hydrogen is used, a FEL with fixed wiggler parameters and electron energy can be tuned from the near infrared to about 1200 A, and, with helium, the wavelength can be reduced to 600 A.

Pantell, R. H.↗
NASA NTRS1993

Charge transfer and momentum exchange in exospheric D-H(+) and H-D(+) collisions

Mechanisms that control the escape of deuterium from planetary exospheres include the acceleration of D(+) in the polar wind, and the production of suprathermal D atoms through nonthermal collisions. In this paper we examine the effects of neutral-ion interactions involving deuterium and hydrogen on the velocity distribution of neutral D. A two-center scattering approximation is used as the basis for calculations of the differential cross sections for charge transfer and elastic scatter in collision of H with D(+) and of D with H(+) for ionosphere-exosphere collision energies below 10 e V. These data are used to derive temperature dependent rate coefficients for the charge transfer branches of these interactions, and to determine the effects of ion-neutral temperature differences on the rate of generation of suprathermal D through charge transfer and elastic scatter.

Hodges, R. R., Jr.↗
NASA NTRS1998

Molecular Processes in Comets

The research focused on molecular hydrogen and its response to ultraviolet radiation, photoelectron impact excitation and X-ray radiation and on the interpretation of the ultraviolet spectra of the Jupiter dayglow and auroras. A systematic effort was made to obtain reliable rate coefficients for rovibrational energy transfer of H2, particularly in collisions with hydrogen atoms. We carried out elaborate quantum-mechanical calculations of the scattering of H and H2 on what had been characterized as a reliable potential energy surface of the H3 molecular system. These calculations took into account reactive channels and rate coefficients for ortho-para transitions were obtained. Quantal calculations are too complex to be applied to all the possible rovibrational transitions and we turned to a semi-classical method. With it we calculated rate coefficients for transitions, reactive and non-reactive, for all the rovibrational levels. We carried out the calculations for three of the available H3 potential energy surfaces. We discovered an unexpected sensitivity of the rate coefficients for the non-reactive channels to the potential energy surface. This discovery stimulated more thorough investigations of the potential energy surface elsewhere and to the construction of a new surface. We have used it in further semi-classical calculations in work that will shortly be 2 completed and which, together with new quantum-mechanical calculations should comprise a set of reliable rate coefficients that can be used in discussions of H2 on the Jovian planets. We carried out a detailed study of the Jovian ultraviolet dayglow. There has been a long-running argument about the dayglow on Jupiter. There are two sources of excitation: fluorescence and photoelectron impact excitation. It had been argued that a third source "the electron glow" was needed to bring theory and observation into agreement. We believe we have shown conclusively that the third source is unnecessary. We have achieved a close quantitative agreement between the predicted spectrum arising from fluorescence and photoelectrons and the measured spectrum. We also demonstrated a method by which the presence of HD could be established observationary. Similar calculations were carried out of the ultraviolet spectra of the Jovian auroras. We again found close agreement. Indeed, the agreement was so detailed we were able to derive the temperature of the atmosphere. We found, contrary to the standard model of the time, a high temperature between 400 K and 600 K and established the presence of a significant temperature gradient. A large temperature gradient was indeed found by direct sampling with the Jupiter probe.

Dalgarno, A.↗
DOE OSTI2022

Pressure cells for in situ neutron total scattering: time and real-space resolution during deuterium absorption

In situ gas-loading sample holders for two-dimensionally arranged detectors in time-of-flight neutron total scattering experiments have been developed to investigate atomic arrangements during deuterium absorption using time and real-space resolution. A single-crystal sapphire container was developed that allows conditions of 473 K and 10 MPa hydrogen gas pressure. High-resolution transient measurements detected deuterium absorption by palladium that proceeded within a few seconds. A double-layered container with thick- and thin-walled vanadium allowed conditions of 423 K and 10 MPa hydrogen gas pressure. The deuterium occupation sites of a lanthanum–nickel–aluminium alloy are discussed in detail on the basis of real-space high-resolution data obtained from in situ neutron scattering measurements and reverse Monte Carlo structural modeling.

08 HYDROGEN↗
NASA NTRS1983

Tentative confirmation of an aurora on Uranus

There have been three recent reports of the detection of Lyman-alpha radiation (due to atomic hydrogen, H, at wavelength 1,216 A) from Uranus by means of the International Ultraviolet Explorer (IUE) satellite. The interpretations of these results differ. Two reports conclude that there is a strong aurora on Uranus, but the third concludes that the source is resonance scattering of solar Lyman-alpha. This paper reports the detection of emission features due to molecular hydrogen, H2, near 1,600 A. This detection is near the limit of the IUE sensitivity. If it is real, the detection of H2 emission strongly supports the conclusion that Uranus has an aurora comparable in strength with those of the inner two giant planets, Jupiter and Saturn. The first published IUE spectra of the Saturn aurora are also presented.

Caldwell, J.↗
DOE OSTI2024

Reversible hydrogen storage in multilayer graphane: Lattice dynamics, compressibility, and heat capacity studies

Multilayer graphane (hydride of graphite) is a crystalline hydrocarbon of composition CH, which can be synthesized from graphite and molecular hydrogen at pressures above 2GPa [V.E. Antonov et al. Carbon 100 (2016) 465]. Using X-ray diffraction, this compound was tentatively identified as the “graphane II” phase of 3D-graphane predicted by ab initio calculations [X.-D. Wen et al. PNAS 108 (2011) 6833] and consisting of layers of 2D-graphane in the “chair” conformation. When heated in a vacuum, the compound does not form any intermediate hydrocarbons and reversibly decomposes back into graphite and hydrogen at 770–920 K. In the present work, almost single-phase samples of graphite hydride and deuteride were synthesized at 7.4 GPa and 870 K. Their investigation by inelastic neutron scattering supplemented by ab initio calculations gave spectra g(E) of the phonon density of states with a gap of about 15 meV at approx. 100 meV, which is a unique identifier for the chair form of graphane. The equation of state V(P) of the hydride was studied at room temperature and hydrogen pressures up to 53 GPa by synchrotron X-ray diffraction in a diamond anvil cell. Further, the graphane II phase did not react with the surrounding hydrogen and did not undergo any phase transformations upon the compression and after heating to 1500 K at 53GPa. The high thermal and pressure stability of this exotic phase makes it an important part of the C–H system. The obtained g(E) spectra of graphite hydride and deuteride were used to calculate temperature dependences of their heat capacity. Measurements of the heat capacity at temperatures 120–673 K confirmed the good accuracy of these calculations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1997

Development of a Technique for Separating Raman Scattering Signals from Background Emission with Single-Shot Measurement Potential

A novel technique for extracting Q-branch Raman signals scattered by a diatomic species from the emission spectrum resulting from the irradiation of combustion products using a broadband excimer laser has been developed. This technique is based on the polarization characteristics of vibrational Raman scattering and can be used for both single-shot Raman extraction and time-averaged data collection. The Q-branch Raman signal has a unique set of polarization characteristics which depend on the direction of the scattering while fluorescence signals are unpolarized. For the present work, a calcite crystal is used to separate the horizonal component of a collected signal from the vertical component. The two components are then sent through a UV spectrometer and imaged onto an intensified CCD camera separately. The vertical component contains both the Raman signal and the interfering fluorescence signal. The horizontal component contains the fluorescence signal and a very weak component of the Raman signal; hence, the Raman scatter can be extracted by taking the difference between the two signals. The separation of the Raman scatter from interfering fluorescence signals is critically important to the interpretation of the Raman for cases in which a broadband ultraviolet (UV) laser is used as an excitation source in a hydrogen-oxygen flame and in all hydrocarbon flames. The present work provides a demonstration of the separation of the Raman scatter from the fluorescence background in real time.

Hartfield, Roy J., Jr.↗
NASA NTRS1985

Images of the earth's aurora and geocorona from the Dynamics Explorer mission

Several series of auroral and geocoronal images from th Dynamics Explorer Mission are presented and analyzed. It is found that the motion of the transpolar arc of a theta aurora is correlated with the y-component of the IMF; the arc motion is in the general direction of the y-component. In addition, a sequence of global images of a small auroral substorm shows the initial development of intense luminosities in a relatively small spatial region or 'bright spot' in the premidnight sector of the auroral oval and a subsequent appearance of an expanding area of lesser intensities at low latitudes and contiguous to the midnight boundary of the bright spot. Finally, a series of images of the geocorona in scattered solar Ly-alpha emissions is used to obtain a best-fit spherical model of atomic hydrogen densities in the earth's exosphere; a Chamberlain model provides an adequate fit to radial distances of 4.5 earth-radii, beyond which an exponential fit is used. The geocoronal tail is detected as an asymmetric increase in scattered Ly-alpha intensities in the antisolar direction.

Frank, L. A.↗
DOE OSTI2024

High-pressure synthesis and neutron scattering study of tantalum hydride TaH 1.23(5) and a tantalum polymorph with A15-type structure

A unique type of tantalum hydride was synthesized by exposing tantalum dihydride to the high hydrogen pressure of 9 GPa and a temperature of using toroid-type high-pressure chambers. The samples of this hydride were cooled down to 100 K, recovered to ambient pressure, and studied in a metastable state by hot extraction, powder x-ray and neutron diffraction, and inelastic neutron scattering. X-ray diffraction demonstrated that this hydride had an A15-type crystal structure of metal lattice (space group , Ta atoms at the 2a and 6c Wyckoff positions) and a lattice parameter of a = 5.150(5) Å at T = 85 K. The hydrogen content determined by hot extraction was H/Ta - 1.23(5). Hydrogen desorption during heating the sample in vacuum proceeded in two steps—first, Δ⁢H⁡/Ta=0.2 was desorbed at around -70 °⁢C, and then the rest of the hydrogen was desorbed between 100 ⁢°C and 390 ⁢°⁢C. The A⁢15-type metal lattice was preserved upon hydrogen removal, leaving a unique polymorph of tantalum. Neutron diffraction of A⁢15-TaH 1.23⁢(5) demonstrated that hydrogen atoms occupy the 24⁢k and 16⁢i Wyckoff sites in the crystal structure, and annealing at 250 K resulted in a decrease of the 24⁢k and an increase of the 16⁢i site occupancies. Inelastic neutron scattering revealed four vibrational modes in the fundamental band of A⁢15-TaH 1.23⁢(5) at 72, 135, 145, and 166 meV, the first three and the last one of which were tentatively assigned to the vibrations of H atoms at the 24⁢k and 16⁢i sites, respectively. No superconductivity was found in A⁢15-TaH 1.1 and hydrogen-free A15-Ta at temperatures down to 1.5 K.

36 MATERIALS SCIENCE↗
NASA NTRS1975

Approximate solutions of radiative transfer in dusty nebulae. I - Pure hydrogen nebulae

This is the first of a series of papers dealing with transfer of radiation in dusty nebulae. The formulae for the general problem are presented. This paper discusses nebulae containing dust and hydrogen. Approximate solutions, accurate to within 50 percent, are obtained for spherical nebulae containing purely absorbing dust. Less accurate solutions are presented for the general case of scattering and absorbing dust. The results are presented in a form convenient for calculating the required number of ionizing photons, the fractional ionization of hydrogen, and the fractions of ionizing photons absorbed by dust and gas in terms of size, hydrogen density, dust albedo, and optical depth. Explicit relations between these quantities are obtained for uniform nebulae. Simple integrals are presented for calculating the above quantities for spherically symmetric nebulae with nonuniform gas and dust distribution.

Petrosian, V.↗
NASA NTRS2003

Development of a High-Pressure Gaseous Burner for Calibrating Optical Diagnostic Techniques

In this work-in-progress report, we show the development of a unique high-pressure burner facility (up to 60 atm) that provides steady, reproducible premixed flames with high precision, while having the capability to use multiple fuel/oxidizer combinations. The highpressure facility has four optical access ports for applying different laser diagnostic techniques and will provide a standard reference flame for the development of a spectroscopic database in high-pressure/temperature conditions. Spontaneous Raman scattering (SRS) was the first diagnostic applied, and was used to successfully probe premixed hydrogen-air flames generated in the facility using a novel multi-jet micro-premixed array burner element. The SRS spectral data include contributions from H2, N2, O2, and H2O and were collected over a wide range of equivalence ratios ranging from 0.16 to 4.9 at an initial pressure of 10-atm via a spatially resolved point SRS measurement with a high-performance optical system. Temperatures in fuel-lean to stoichiometric conditions were determined from the ratio of the Stokes to anti-Stokes scattering of the Q-branch of N2, and those in fuel-rich conditions via the rotational temperature of H2. The SRS derived temperatures using both techniques were consistent and indicated that the flame temperature was approximately 500 K below that predicted by adiabatic equilibrium, indicating a large amount of heat-loss at the measurement zone. The integrated vibrational SRS signals show that SRS provides quantitative number density data in high-pressure H2-air flames.

Kojima, Jun↗
DOE OSTI2022

Total thermal neutron cross section measurements of hydrogen dense polymers from 0.0005–20 eV

Hydrogen dense polymers, specifically polyethylene, polystyrene, and Plexiglas, have served as neutron moderator and reflector materials in hundreds of separate critical benchmark experiments because of their low cost and abundance of hydrogen. In order to accurately model and simulate these critical benchmarks, the thermal scattering law (TSL) evaluation that governs how neutrons will thermalize must be well understood and rigorously validated. To support this validation, researchers at Rensselaer Polytechnic Institute performed total neutron cross section measurements for high-density polyethylene & polystyrene over the energy range 0.0005–20 eV and for Plexiglas G & Plexiglas G-UVT over the energy range 0.0005–3 eV. Comparisons were made between the measured cross section and that predicted by the ENDF/B-VIII.0 and Oak Ridge National Laboratory/European Spallation Source/Rensselaer Polytechnic Institute TSL evaluations for polyethylene, Plexiglas, and polystyrene, as available. These experiments represent the first total neutron cross section measurements for polystyrene.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

Micro-segregation phenomena and related spectroscopic signals in melt-grown β-Ga2O3 single crystals

One of the primary advantages of β-Ga2O3 over incumbent wide bandgap semiconductors is the ability to grow directly from the melt. Melt growth, using Czochralski or similar methods, results in impurities in the crystal which originate from the crucible, such as iridium and other transition metals like chromium. These impurities exhibit optoelectronic signatures useful for their identification and sensitive to the Fermi energy of a given crystal (i.e., signatures vary with the electrical conductivity of the matrix). In this work, we describe how laser Raman systems can be used to map and spatially correlate Cr3+ photoluminescence, electronic-coupled Raman scattering from Ir4+d–d internal transitions, and the Raman line attributed to hydrogenic shallow donors. Laser ablation inductively coupled plasma mass spectrometry directly measured spatially dependent relative metal concentrations and confirmed spectroscopic signals resulting from heterogeneities in impurity concentrations in β-Ga2O3 boules. Mapping of photoluminescence and Raman-related signatures is, thus, demonstrated as an effective and facile method for spatial measurement of chemical heterogeneities in both insulating and conductive melt-grown β-Ga2O3 crystals.

Dutton, Benjamin L. (ORCID:000000031272130X)↗
DOE OSTI2023

Exploring the gravitational structure of the proton with the dilepton final state using the CLAS12 detector at Jefferson Lab

The Gravitational Form Factors (GFFs) give access to the internal distributions of mass, pressure and shear force inside the proton. They were considered experimentally unmeasurable for decades due to the very weak gravitational interaction [1]. However, the Generalized Parton Distributions (GPDs), which describe the correlations between the longitudinal momentum and the transverse position of the partons inside the nucleon, have lately been related to the GFFs. For the first time, this relation gives the opportunity to extract GFFs experimentally. In this talk, I will present two ways to access GFFs using data taken in 2018 by the CLAS12 detector with a 10.6 GeV electron beam impinging on a liquid-hydrogen target. First, I will present the first measurement of the Timelike Compton Scattering reaction (the hard photoproduction of a lepton pair), that gives access to the quark GFFs via the angular asymmetry of the electron/positron pair [2]. I will then present the current effort to extract the near-threshold J/? photoproduction cross section using the same dataset. This later measurement is expected to provide direct insight on the gluons GFFs of the proton. [1] H. PAGELS. Energy-Momentum Structure Form Factors of Particles. Phys.Rev. 144 (1966) 1250-1260 [2] P. Chatagnon. First Measurement of Timelike Compton Scattering. Phys.Rev.Lett. 127 (2021) 26, 262501

Chatagnon, Pierre↗
NASA NTRS1976

Differential cross-section for positronium formation in electron-atomic hydrogen collisions

The L=0 and 1 partial wave amplitudes obtained by a two-state coupled static approximation with correlation with the L greater than or equal to 2 Born amplitudes were combined to obtain the differential cross section for positronium formation in electron-atomic hydrogen collisions. For positron energies of 0.64 and 0.75 ryd, minima at the scattering angles of 57 deg and 51 deg are found. Total cross sections for positronium formation for low and intermediate impact energies are given. Measurement of the differential cross section for the process positron + helium yields positronium + helium ion for the detection of possible minima is suggested.

Drachman, R. J.↗
NASA NTRS1991

High-speed laser anemometry based on spectrally resolved Rayleigh scattering

Laser anemometry in unseeded flows based on the measurement of the spectrum of Rayleigh scattered laser light is reviewed. The use of molecular scattering avoids the well known problems (particle lag, biasing effects, seed generation, seed injection) of seeded flows. The fundamental limits on velocity measurement accuracy are determined using maximum likelihood methods. Measurement of the Rayleigh spectrum with scanning Fabry-Perot interferometers is analyzed and accuracy limits are established for both single pass and multipass configurations. Multipass configurations have much higher selectivity and are needed for measurements where there is a large amount of excess noise caused by stray laser light. It is shown that Rayleigh scattering is particularly useful for supersonic and hypersonic flows. The results of the analysis are compared with measurements obtained with a Rayleigh scattering diagnostic developed for study of the exhaust plume of a small hydrogen-oxygen rocket, where the velocities are in the range of 1000 to 5000 m/sec.

Seasholtz, Richard G.↗
NASA NTRS1992

Interstellar dust from the Milky Way to the Magellanic Clouds

Interstellar dust in the Magellanic Clouds, with a weak or nearly absent 2175 A extinction feature, may be of interest in studies of galaxies in early stages of chemical evolution. To this inquiry, we extend the graphite-silicate grain model, introduced by Mathis, Rumpl, and Nordsieck and developed by Draine and Lee (1984) from the Milky Way to the Magellanic Clouds. We find that the empirical extinction curves in the Large and Small Magellanic Clouds can be reproduced by adjusting only the relative abundances of graphite and silicate grains, while leaving all other model properties fixed to those appropriate for the Galactic extinction curve. Using the graphite-silicate models, we calculate the absorption and scattering optical depths, the mass-density ratio of interstellar dust to neutral hydrogen, and the Kramers-Kronig relation for all three galaxies. We also present a fitting function for the three extinction curves, valid not only over the observed range of wavelengths but also over the full range as predicted by the models. All the quantities we derived here are independent of the dust-to-gas ratios in the Milky Way and the Magellanic Clouds, and can be applied to other galaxies if they contain Galactic or Magellanic-type dust.

Pei, Yichuan C.↗