Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Gamma ray spectroscopy”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Science Capabilities of the GLAST Burst Monitor

The Large Area Telescope (LAT) on GLAST will make pioneering observations of gamma-ray bursts in the energy range above about 20 MeV. The primary function of the GLAST Burst Monitor (GBM) is to extend the energy range for GRB observations down to about 10 keV, allowing time-resolved spectroscopy over an energy range of six decades or more for strong bursts. The GBM will also generate alerts for strong bursts outside the LAT field-of-view, permitting re-orientation of the spacecraft so that the LAT can observe prompt or delayed high-energy emission. Burst locations will be disseminated rapidly to ground observers. The GBM will also provide data suitable for a variety of other studies, including discovery of gamma-ray transient sources, monitoring of Soft Gamma Repeaters, and observations of solar flares.

Meegan, Charles↗
DOE OSTI2022

Role of Metal Selection in the Radiation Stability of Isostructural M-UiO-66 Metal–Organic Frameworks

Robust and versatile metal–organic frameworks (MOFs) have emerged as sophisticated scaffolds to meet the critical needs of the nuclear community, but their performance depends on their underexplored structural integrities in high- radiation fields. The contributions of selected metal nodes in the radiation stability of MOFs within the isostructural M-UiO-66 series (where M = Zr, Ce, Hf, Th, and Pu; Zr-UiO-66 experiments were executed in a previous work) have been determined. Ce-, Hf-, and Th-UiO-66 MOF samples were irradiated via gamma and He-ion methodologies to obtain doses up to 3 MGy and 85 MGy, respectively, the latter strikingly higher than that obtained in most other studies. Appreciable self-irradiation constituted the total absorbed doses, up to 31 MGy of the gamma-irradiated Pu-UiO-66 samples. Structural degradation was ascertained by powder X-ray diffraction, X-ray total scattering, vibrational spectroscopy, and, where possible, N 2 physisorption isotherms. Diffuse reflectance infrared Fourier transform spectroscopy provided atomic-level mechanistic insights to reveal that the node-linker connection was most susceptible to radiation damage. Density functional theory calculations were performed on cluster models to evaluate the binding energy of the linkers to each metal node. Here, while the isostructures disclosed the same breakdown signatures, distinct radiation sensitivity as a function of metal selection was evident and followed the trend Hf-UiO-66 ~ Zr-UiO-66 > Th-UiO-66 > Pu-UiO-66 > Ce-UiO-66. We anticipate that these endeavors will contribute to the rational design of radiation-resistant materials for targeted applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1974

Astronomy satellites in the U.S. program

The Orbiting Astronomical Observatory (OAO) series demonstrated that necessary thermal control systems and high pointing stability are feasible on astronomical satellites. A geosynchronous International Ultraviolet Explorer (IUE) is being planned by the US, UK, and ESRO for stellar spectroscopy. High Energy Astronomy Observatories, HEAO-A B, and C, will concentrate on stellar X-ray objects, cosmic ray physics, and gamma ray astronomy. A Shuttle-compatible Solar Maximum Mission (SMM) is planned for studying solar flares and flare related phenomena during the next solar maximum. Now in the instrumentation definition stage is the Large Space Telescope (LST), to provide higher resolution and sensitivity, larger wavelength range (from ultraviolet to far infrared), and higher time resolution than ground-based telescopes.

Aucremanne, M. J.↗
NASA NTRS2014

A Trio of Gamma-Ray Burst Supernovae: GRB 120729A, GRB 130215ASN 2013ez, and GRB 130831ASN 2013fu

We present optical and near-infrared (NIR) photometry for three gamma-ray burst supernovae (GRB-SNe): GRB 120729A, GRB 130215A/SN 2013ez, and GRB 130831A/SN 2013fu. For GRB 130215A/SN 2013ez, we also present optical spectroscopy at t - t Sub 0) = 16.1 d, which covers rest-frame 3000-6250 A. Based on Fe ii 5169 and Si ii 6355, our spectrum indicates an unusually low expansion velocity of approximately 4000-6350 km s-1, the lowest ever measured for a GRB-SN. Additionally, we determined the brightness and shape of each accompanying SN relative to a template supernova (SN 1998bw), which were used to estimate the amount of nickel produced via nucleosynthesis during each explosion. We find that our derived nickel masses are typical of other GRB-SNe, and greater than those of SNe Ibc that are not associated with GRBs. For GRB 130831A/SN 2013fu, we used our well-sampled R-band light curve (LC) to estimate the amount of ejecta mass and the kinetic energy of the SN, finding that these too are similar to other GRB-SNe. For GRB 130215A, we took advantage of contemporaneous optical/NIR observations to construct an optical/NIR bolometric LC of the afterglow. We fit the bolometric LC with the millisecond magnetar model of Zhang & Mészáros (2001, ApJ, 552, L35), which considers dipole radiation as a source of energy injection to the forward shock powering the optical/NIR afterglow. Using this model we derive an initial spin period of P = 12 ms and a magnetic field of B = 1.1 10(exp 15) G, which are commensurate with those found for proposed magnetar central engines of other long-duration GRBs.

trio↗
DOE OSTI2021

Configuration and impurity quantification of AmLi sources using radiography and gamma spectroscopy

This paper presents the non-destructive assay of two AmLi sources used for detector characterization and active interrogation at PNNL, identified as MRC-101 and MRC-103. First, a detailed description of the internal configuration of 2724-BT encapsulated MRC sources is established. X-ray radiographs of the AmLi sources are reported for the first time to verify the dimensions and orientation of the encapsulation. Notably, a density variation was observed as a contrast change across the height of the source cavities. Contrary to commonly made assumptions in literature, it is indirectly observed that the AmLi source/target material only occupies a portion of the source cavity. The intensity of the prompt gamma-rays resulting from the inelastic scatter of alpha particles on 7Li was used to calculate the mass ratios of LiH:AmO2. The gamma-ray spectra revealed the presence of numerous impurities in both source and target material (243Am, 237Np, 154Eu, 23Na, and 9Be). Neutron-gamma production ratios were applied to the intensity of the Doppler-broadened peaks from alpha-induced reactions with 7Li, 9Be, and 23Na to calculate neutron rates for both sources. A neutron/alpha production yield (derived in this work) was then related to the atomic concentration of these isotopes to find the approximate masses within each source. Ultimately, the AmLi source density was estimated with prompt gamma analysis based on partial source volumes as 0.45±0.08 g/cm^3.

DTRA, AmLi, neutron↗
NASA NTRS1990

Radiolysis of aqueous solutions of acetic acid in the presence of Na-montmorillonite

The gamma-irradiation of 0.8 mol dm-3 aqueous, oxygen-free acetic acid solutions was investigated in the presence or absence of Na-montmorillonite. H2, CH4, CO, CO2, and several polycarboxylic acids were formed in all systems. The primary characteristics observed in the latter system were: (1) Higher yield of the decomposition of acetic acid; (2) Lower yield of the formation of polycarboxylic acids; (3) No effect on the formation of methane; (4) Higher yield of the formation of carbon dioxide; and (5) The reduction of Fe3+ in the octahedral sites of Na-montmorillonite. A possible reaction scheme was proposed to account for the observed changes. The results are important in understanding heterogeneous processes in radiation catalysis and might be significant to prebiotic chemistry.

Non-NASA Center↗
NASA NTRS2010

Fermi GBM Observations of Terrestrial Gamma Flashes

In its first two years of operation, the Fermi Gamma Ray Burst Monitor (GBM) has observed more than 77 Terrestrial Gamma Flashes (TGFs). The thick Bismuth Germanate (BGO) detectors are excellent for TGF spectroscopy, having a high probability of recording the full energy of an incident photon, spanning a broad energy range from 150 keV to 40 MeV, and recording a large number of photons per TGF. Correlations between GBM TGF triggers and lightning sferics detected with the World-Wide Lightning Location Network indicate that TGFs and lightning are simultaneous to within tens of microseconds. The energy spectra of some TGFs have strong 511 keV positron annihilation lines, indicating that these TGFs contain a large fraction of positrons

Wilson-Hodge, Colleen A.↗
NASA NTRS1999

The Chandra X-Ray Observatory: Overview

The Chandra X-ray Observatory, formerly, the Advanced X-ray Astrophysics Facility (AXAF), has now joined the Hubble Space Telescope and the Compton Gamma-Ray Observatory, as the third of NASA's "Great Observatories". Chandra provides unprecedented arcsecond imaging and spectrometric imaging and high-resolution dispersive spectroscopy, to address a large range of topics in x-ray astronomy and astrophysics. Here we provide an overview of the Observatory, its operation, and initial results.

Weisskopf, M. C.↗
NASA NTRS2000

The Chandra X-Ray Observatory: First Year of Operation

The Chandra X-ray Observatory - formerly, the Advanced X-ray Astrophysics Facility (AXAF) - has now joined the Hubble Space Telescope and the Compton Gamma-Ray Observatory, as the third of NASA's "Great Observatories". Chandra provides unprecedented arcsecond imaging and spectrometric imaging and high-resolution dispersive spectroscopy, to address a large range of topics in x-ray astronomy and astrophysics. Here we provide an overview of the Observatory, its operation, and results obtained during its first year of operation.

Weisskopf, M. C.↗
DOE OSTI2020

Improved plutonium and americium photon branching ratios from microcalorimeter gamma spectroscopy

Photon branching ratios are critical input data for activities such as nuclear materials protection and accounting because they allow material compositions to be extracted from measurements of gamma-ray intensities. Uncertainties in these branching ratios are often a limiting source of uncertainty in composition determination. Here, we use high statistics, high resolution - (60–70 eV full-width-at-half-maximum at 100 keV) gamma-ray spectra acquired using microcalorimeter sensors to substantially reduce the uncertainties for 11 plutonium ( 238 Pu, 239 Pu, 241 Pu) and 241 Am branching ratios important for material control and accountability and nuclear forensics in the energy range of 125 keV to 208 keV. Lastly, we show a reduction in uncertainty of over a factor of three for one branching ratio and a factor of 2–3 for four branching ratios.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1988

Nuclear line spectroscopy of solar flares

A large nuclear-line-rich solar flare which occurred near the west limb on April 27, 1981 has been analyzed. Three intense and isolated gamma-ray lines observed have been identified as the deexcitation lines of Ne-20(1.634 MeV), C-12(4.438 MeV), and O-16(6.129 MeV). The elemental abundances of the ambient gas at the site of gamma-ray line production in the solar atmosphere deduced using the observations are found to be different from local Galactic abundances.

Forrest, D. J.↗
NASA NTRS2004

The Generation-X X-ray Observatory Vision Mission and Technology Study

The new frontier in astrophysics is the study of the birth and evolution of the first stars, galaxies and black holes in the early Universe. X-ray astronomy opens a window into these objects by studying the emission from black holes, supernova explosions and the gamma-ray burst afterglows of massive stars. However, such objects are beyond the grasp of current or near-future observatories. X-ray imaging and spectroscopy of such distant objects will require an X-ray telescope with large collecting area and high angular resolution. Our team has conceived the Generation-X Vision Mission based on an X-ray observatory with 100 sq m collecting area at 1 keV (1000 times larger than Chandra) and 0.1 arcsecond angular resolution (several times better than Chandra and 50 times better than the Constellation-X resolution goal). Such an observatory would be capable of detecting the earliest black holes and galaxies in the Universe, and will also study extremes of density, gravity, magnetic fields, and kinetic energy which cannot be created in laboratories. NASA has selected the Generation-X mission for study under its Vision Mission Program. We describe the studies being performed to develop the mission concept and define candidate technologies and performance requirements for Generation-X. The baseline Generation-X mission involves four 8m diameter X-ray telescopes operating at Sun-Earth L2. We trade against an alternate concept of a single 26m diameter telescope with focal plane instruments on a separate spacecraft. A telescope of this size will require either robotic or human-assisted in-flight assembly. The required effective area implies that extremely lightweight grazing incidence X-ray optics must be developed. To achieve the required aerial density of at least 100 times lower than in Chandra, we will study 0.1mm thick mirrors which have active on-orbit figure control. We discuss the suite of required detectors, including a large FOV high angular resolution imager, a cryogenic imaging spectrometer and a grating spectrometer. We outline the development roadmap to confront the many technological challenges far implementing the Generation-X mission.

Figueroa-Feliciano, Enectali↗
DOE OSTI2024

Connecting radiation-driven changes in structural, thermal, and mechanical properties in several medical device polymers

Stemming from security threats and shortages in supply, a recent push has emerged to develop alternatives to radioisotope Cobalt-60 gamma radiation for sterilization of polymeric medical products, including electron beam (e-beam) and X-ray machine-based sources. However, before large-scale implementation, the effects of these non-isotope-based methods must be thoroughly investigated from several perspectives, involving their potential detrimental effects on the structural, thermal, and mechanical properties of polymers in medical devices. This paper investigates such effects in commonly used medical device polymers, including polypropylene homopolymer (PPH), polyolefin elastomer (POE), low-density polyethylene (LDPE), acrylonitrile butadiene styrene (ABS), and chlorobutyl rubber (CIIR). To connect radiation-driven changes in polymer structural and thermal properties and corresponding changes in mechanical properties, several characterization techniques were utilized, including gel permeation chromatography (GPC), Fourier transform infrared spectroscopy (FTIR), dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC). We found that the tensile strength of X-ray irradiated PPH, as well as X-ray, e-beam, and gamma irradiated CIIR decreases due to chain scission, which is corroborated by GPC and DMA. The GPC results of LDPE suggest chain scission, but interestingly without a corresponding decline in tensile strength. By comparison, POE and ABS appear to undergo further crosslinking with increasing irradiation dose, which generally strengthens them. Importantly, in the vast majority of the cases, there were small to no changes in properties upon changing radiation technologies (at a given dose), i.e., no radiation source dependence. However, in a few specific cases, radiation method dependencies did arise, for instance, in terms of the molecular weight of PPH being significantly increased upon X-ray irradiation, while the melting temperature, glass transition temperature, and elongation at break reduced compared to gamma. Overall, this study provides valuable insight into radiation-driven chemical and structural changes in polymers that produce changes in physical and functional properties.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Investigation of defects in melt and solution grown perovskite CsPbBr 3 single crystals

Recently, there has been considerable interest in x-ray and gamma ray detectors with large volume and high energy resolution that operate at room temperature. To improve detector energy resolution, the carrier mobility-lifetime product needs to be increased, and the electronic trap state concentration needs to be minimized. Defect concentrations in the part per billion range can alter the charge transport and carrier recombination lifetime. In this work, thermally stimulated current spectroscopy measurements were systematically carried out in bulk halide perovskite single crystals of CsPbBr 3 over a temperature range of 80–320 K. The origins and trap parameters of CsPbBr 3 crystals from the solution growth and melt growth procedures were determined and compared. Trap concentrations were ranged from 1 × 10 11 to 1 × 10 16 cm –3 . Appreciable detector performance was observed for CsPbBr3 crystals with trap concentrations less than 1 × 10 14 cm –3 . The comparison of spectral responses of crystal samples grown using two different methods shows that, after purification, solution-grown crystals are comparable to melt-grown crystals in terms of low defect concentration and improved detector performance. Finally, for an improved mobility-lifetime product and enhanced spectral response to high energy radiation from fissile materials, trap states in either type of a crystal ingot must be reduced closer to 10 11 cm –3 .

36 MATERIALS SCIENCE↗
DOE OSTI2022

Gamma-Ray-Induced Formation of Uranyl Peroxide Cage Clusters

Aqueous solutions of lithium uranyl triperoxide, Li 4 [UO 2 (O 2 ) 3 ] (LiUT), were irradiated with gamma rays at room temperature and found to form the uranyl peroxide cage cluster, Li 24 [(UO 2 )(O 2 )(OH)] 24 (Li–U 24 ). Raman spectroscopy and 18 O labeling were used to identify the Raman-active vibrations of LiUT. With these assignments, the concentration of LiUT was tracked as a function of radiation dose. A discrepancy between monomer removal and cluster formation suggests that the reaction proceeds by the assembly of an intermediate. Non-negative matrix factorization was used to separate Raman spectra into components and resulted in the identification of a unique intermediate species. Much of the conversion appears to be driven by water radiolysis products, particularly the hydroxyl radical. Furthermore, this differs from the 18 O-labeled copper-catalyzed formation of U 24 , which progresses at a steady rate with no observation of intermediates. Li–U 24 in solution decomposes at high radiation doses resulting in a solid insoluble product similar to Na-compreignacite, Na 2 (UO 2 ) 6 O 4 (OH) 6 ·7H 2 O, which contains uranyl oxyhydroxy sheets.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1993

MeV Gamma Ray Detection Algorithms for Stacked Silicon Detectors

By making use of the signature of a gamma ray event as it appears in N = 5 to 20 lithium-drifted silicon detectors and applying smart selection algorithms, gamma rays in the energy range of 1 to 8 MeV can be detected with good efficiency and selectivity. Examples of the types of algorithms used for different energy regions include the simple sum mode, the sum-coincidence mode used in segmented detectors, unique variations on sum-coincidence for an N-dimensional vector event, and a new and extremely useful mode for double escape peak spectroscopy at pair-production energies. The latter algorithm yields a spectrum similar to that of the pair spectrometer, but without the need of the dual external segments for double escape coincidence, and without the large loss in efficiency of double escape events. Background events due to Compton scattering are largely suppressed. Monte Carlo calculations were used to model the gamma ray interactions in the silicon, in order to enable testing of a wide array of different algorithms on the event N-vectors for a large-N stack.

McMurray, Robert E. Jr.↗
NASA NTRS1985

Observations of the Geminga optical candidate

The present spectroscopy and photometry for the proposed optical counterpart of the X-ray source IE 0630 + 178, which is also a candidate for identification with the gamma-ray source 'Geminga', yields a spectrum that is featureless at the current S/N ratio and resists classification. The properties of the X-ray and optical objects, and the statistical circumstances of the identification process, do not support the association of optical, X-ray, and gamma-ray sources. The uniqueness of the X-ray source nevertheless suggests that its X-rays are thermal emission from the surface of a neutron star whose optical counterpart is an undetected blue star of B magnitude approximately 26.

Halpern, J. P.↗
DOE OSTI2020

Magnetic Microcalorimeter (MMC) Gamma-Ray Detectors with Ultra-High Energy Resolution. Comprehensive Technology Readiness Assessment

Magnetic Microcalorimeter (MMC) gamma ray detectors have demonstrated very high energy resolution of 38 eV FWHM for gamma ray energies below 100 keV. This is an order or magnitude better than conventional HPGe detector and can remove most line-overlap problems in NDA by gamma spectroscopy below ~130 keV. Unlike superconducting transition edge sensors (TESs), MMCs have a reproducible and almost perfectly linear response, which greatly simplifies adding spectra from different detector pixels and reduces systematic errors in quantitative assays. The instrument is currently at TRL-5 but could advance to TRL-6 by improving the signal processing software and using the system for the quantitative analysis of a safeguards sample provided by e.g. the IAEA. Making MMC detectors commercially viable and used more widely then depends on making the technology more reliable, specifically by increasing the device uniformity and yield, and by developing commercial software. This situation is often only half-jokingly referred to as the “valley of death” and could be addressed though the SBIR program. Our collaborators at STAR Cryoelectronics LLC are well qualified to further advance MMC development, and XIA LLC is well-positioned to develop the data acquisition system and write the software for MMC readout. In addition, the advance to TRL-6 would be desirable to increase the visibility and showcase the value of MMC spectrometers, e.g. by placing one of them into the Safeguards Analytical Laboratory (SAL) at the IAEA, whose NDA experts have recently started to show interest in cryogenic detector technology. As a result of this LCP, we also now have an instrument at LLNL that we will use for various applications of MMCs in nuclear safeguards and science. We are confident that as the number of high-profile results increases, so will the interest in and commercial viability of this technology.

42 ENGINEERING↗