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At least 415 records · Page 23

Marine Sciences Laboratory Radionuclide Air Emissions

The U.S. Department of Energy Office of Science (DOE-SC) Pacific Northwest Site Office has oversight and stewardship duties associated with the Pacific Northwest National Laboratory Marine Sciences Laboratory (MSL), located on Battelle Land-Sequim. The facility has two buildings with the potential to emit low levels of radioactive materials. DOE-SC contracted for exclusive use of its radiological operations effective October 1, 2012. This report is prepared to document compliance with the Code of Federal Regulation, Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants , Subpart H, “National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities” and Washington Administrative Code Chapter 246-247, Radiation Protection–Air Emissions . Compliance is indicated by comparing the estimated effective dose equivalent (EDE) to the maximally exposed individual (MEI) with the 10 millirem per year (mrem/yr) U.S. Environmental Protection Agency (EPA) standard. The MSL has only fugitive emissions sources. Despite the fact that the regulations are intended for application to point source emissions, fugitive emissions are included with regard to complying with the EPA standard. The EDE to the MSL MEI due to routine operations in 2016 was 5.7E-04 mrem (5.7E-06 mSv). No non-routine emissions occurred in 2016. The MSL is in compliance with the federal and state 10 mrem/yr standard.

40 CFR 61 Subpart H↗

PNNL-Sequim Campus Radionuclide Air Emissions Report for Calendar Year 2023

The U.S. Department of Energy Office of Science (DOE-SC) Pacific Northwest Site Office has oversight and stewardship duties associated with the Pacific Northwest National Laboratory Sequim campus. Some research projects have the potential to emit low levels of radioactive materials. This report is prepared to document compliance with the Code of Federal Regulation, Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants, Subpart H, “National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities” and Washington Administrative Code Chapter 246-247, "Radiation Protection–Air Emissions." Compliance is indicated by comparing the estimated effective dose equivalent (EDE) to the maximally exposed individual (MEI) member of the public with the 10 millirem per year (mrem/yr) U.S. Environmental Protection Agency (EPA) standard. The PNNL-Sequim campus has only fugitive emissions sources.

40 CFR 61 Subpart H↗

Corrective Action Decision Document/Corrective Action Plan for Corrective Action Unit 413: Clean Slate II Plutonium Dispersion (TTR) Tonopah Test Range, Nevada. Revision 0

This Corrective Action Decision Document/Corrective Action Plan provides the rationale and supporting information for the selection and implementation of corrective actions at Corrective Action Unit (CAU) 413, Clean Slate II Plutonium Dispersion (TTR). CAU 413 is located on the Tonopah Test Range and includes one corrective action site, TA-23-02CS. CAU 413 consists of the release of radionuclides to the surface and shallow subsurface from the Clean Slate II (CSII) storage–transportation test conducted on May 31, 1963. The CSII test was a non-nuclear detonation of a nuclear device located inside a concrete bunker covered with 2 feet of soil. To facilitate site investigation and the evaluation of data quality objectives decisions, the releases at CAU 413 were divided into seven study groups: 1 Undisturbed Areas 2 Disturbed Areas 3 Sedimentation Areas 4 Former Staging Area 5 Buried Debris 6 Potential Source Material 7 Soil Mounds Corrective action investigation (CAI) activities, as set forth in the CAU 413 Corrective Action Investigation Plan, were performed from June 2015 through May 2016. Radionuclides detected in samples collected during the CAI were used to estimate total effective dose using the Construction Worker exposure scenario. Corrective action was required for areas where total effective dose exceeded, or was assumed to exceed, the radiological final action level (FAL) of 25 millirem per year. The results of the CAI and the assumptions made in the data quality objectives resulted in the following conclusions: The FAL is exceeded in surface soil in SG1, Undisturbed Areas; The FAL is assumed to be exceeded in SG5, Buried Debris, where contaminated debris and soil were buried after the CSII test; The FAL is not exceeded at SG2, SG3, SG4, SG6, or SG7. Because the FAL is exceeded at CAU 413, corrective action is required and corrective action alternatives (CAAs) must be evaluated. For CAU 413, three CAAs were evaluated: no further action, clean closure, and closure in place. The CAAs were evaluated on technical merit focusing on performance, reliability, feasibility, safety, and cost. Based on the evaluation of analytical data from the CAI, review of future and current operations at CAU 413, and the detailed and comparative analysis of CAAs, clean closure was selected as the preferred CAA for CAU 413 by the U.S. Air Force, Nevada Division of Environmental Protection, and U.S. Department of Energy at the CAA meeting held on August 24, 2016.

54 ENVIRONMENTAL SCIENCES↗

Nevada National Security Site Environmental Report 2017

The National Nuclear Security Administration Nevada Fields Office (NNSA/NFO) directs the facility management and program operations at the Nevada National Security Site (NNSS) North Las Vegas Facility (NLVF), and Remote Sensing Laboratory–Nellis (RSL-Nellis) in Nevada and directs selected operations at four sites outside of Nevada that include RSL-Andrews in Maryland, Livermore Operations in California, Los Alamos Operations in New Mexico, and the Special Technologies Laboratory in California. This report summarizes data and the compliance status of the NNSA/NFO environmental protection and monitoring programs for calendar year 2017 at the NNSS and at its two support facilities, the NLVF and RSL-Nellis. This report also addresses environmental restoration (ER) projects conducted by the Environmental Management Nevada Program Office at the Tonopah Test Range (TTR).

54 ENVIRONMENTAL SCIENCES↗

Mapping Environmental Contaminants at Ray Mine, AZ

Airborne Visible and InfraRed Imaging Spectrometer (AVIRIS) data was collected over Ray Mine as part of a demonstration project for the Environmental Protection Agency (EPA) through the Advanced Measurement Initiative (AMI). The overall goal of AMI is to accelerate adoption and application of advanced measurement technologies for cost effective environmental monitoring. The site was selected to demonstrate the benefit to EPA in using advanced remote sensing technologies for the detection of environmental contaminants due to the mineral extraction industry. The role of the Jet Propulsion Laboratory in this pilot study is to provide data as well as performing calibration, data analysis, and validation of the AVIRIS results. EPA is also interested in developing protocols that use commercial software to perform such work on other high priority EPA sites. Reflectance retrieval was performed using outputs generated by the MODTRAN radiative transfer model and field spectra collected for the purpose of calibration. We are presenting advanced applications of the ENVI software package using n-Dimensional Partial Unmixing to identify image-derived endmembers that best match target materials reference spectra from multiple spectral libraries. Upon identification of the image endmembers the Mixture Tuned Match Filter algorithm was applied to map the endmembers within each scene. Using this technique it was possible to map four different mineral classes that are associated with mine generated acid waste.

McCubbin, Ian↗

Application of Artificial Intelligence for Surface PM2.5 Estimations from Geostationary Satellite and Atmospheric Numerical Model Data

PM2.5, particulate matter (PM) with a diameter less than or equal to 2.5 μm, is emitted from anthropogenic fuel combustion and forest fires. Due to their small size, PM2.5 can penetrate into respiratory systems and cause or exacerbate serious illness. The US Environmental Protection Agency (EPA) regulates the levels of surface PM2.5 but surface monitoring has spatial and temporal limitations. The Aerosol Optical Depth (AOD) retrievals from the Geostationary Operational Environmental Satellite (GOES) missions and meteorological factors can be utilized as an alternative technique to estimate surface PM2.5 levels at a higher spatial and temporal resolution compared to surface monitors. Traditional estimation approaches rely on linear regression techniques and have limitations modeling the nonlinear relationship between the meteorological factors, AOD retrievals, and surface PM2.5. We compare different machine learning techniques and identify the best-suited model that can represent the nonlinearity between the factors affecting PM2.5 levels

Manisha Khatri↗

LLNL NESHAPs 2023 Annual Report

Lawrence Livermore National Security, LLC operates facilities at Lawrence Livermore National Laboratory (LLNL) in which radionuclides are handled and stored. These facilities are subject to the U.S. Environmental Protection Agency (EPA) National Emission Standards for Hazardous Air Pollutants (NESHAPs) in Code of Federal Regulations (CFR) Title 40, Part 61, Subpart H, which regulates radionuclide emissions to air from Department of Energy (DOE) facilities. Specifically, NESHAPs limits the emission of radionuclides to the ambient air to levels resulting in an annual effective dose equivalent of 10 mrem (100 µSv) to any member of the public. Using measured and calculated emissions, and building-specific and common parameters, LLNL personnel applied the EPA-approved computer code, CAP88-PC, Version 4.1.1.0, to calculate the dose to the maximally exposed individual member of the public for the Livermore Site and Site 300.

54 ENVIRONMENTAL SCIENCES↗

Rad-NESHAP Review of TA-21-257 Remediation Activities

Environmental Protection and Compliance (EPC) Division personnel reviewed the remediation work at Technical Area 21, Building 257 (TA-21-257) for compliance with Radionuclide NESHAP1 requirements. Remediation activities include removal of Building 257, the associated waste lines, and waste storage tanks. We used project data and the most recent CAP88 plume dispersion model to estimate the emissions source term and the resulting off-site dose to members of the public. Emissions monitoring requirements from this work are being met by measuring ambient air concentrations at public receptor locations using LANL’s Airnet system. All requirements under 40 CFR 61 Subpart H are being met for the currently planned scope of operations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Updated External Exposure Dose Coefficients

In 2018, the Environmental Protection Agency (EPA) updated and expanded the Federal Guidance Report (FGR) No. 12 to No. 15; tabulating age-specific external exposure effective dose rate coefficients for 1,252 radionuclides in the air, water, and soil (EPA 2018). However, the EPA discovered errors in the tables of dose coefficients for soil which led to the report being retracted for correction. This led to the adoption of “a uniform method of data-smoothing and extrapolation of monoenergetic organ doses at low energies across all exposure pathways; the originally-published dose coefficients utilized different methods for each media type” (EPA 2019). This resulted in all the external exposure dose coefficients being updated and FGR 15 being republished in August 2019 with corrected tables.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Marine Sciences Laboratory Radionuclide Air Emissions Report for Calendar Year 2017

The U.S. Department of Energy Office of Science (DOE-SC) Pacific Northwest Site Office has oversight and stewardship duties associated with the Pacific Northwest National Laboratory Marine Sciences Laboratory (MSL), located on Battelle Land-Sequim. The facility has two buildings with the potential to emit low levels of radioactive materials. This report is prepared to document compliance with the Code of Federal Regulation, Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants, Subpart H, “National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities” and Washington Administrative Code Chapter 246-247, Radiation Protection–Air Emissions. Compliance is indicated by comparing the estimated effective dose equivalent (EDE) to the maximally exposed individual (MEI) with the 10 millirem per year (mrem/yr) U.S. Environmental Protection Agency (EPA) standard. The MSL has only fugitive emissions sources. Despite the fact that the regulations are intended for application to point source emissions, fugitive emissions are included with regard to complying with the EPA standard. The EDE to the MSL MEI due to routine operations in 2017 was 1.6E-04 mrem (1.6E-06 mSv). No non-routine emissions occurred in 2017. The MSL is in compliance with the federal and state 10 mrem/yr standard.

40 CFR 61 Subpart H↗

Geographic Information Systems as an Opportunity for Public Engagement in Environmental Data Analysis for Nuclear Waste Management - 17505

For half a century, scientists across government agencies, industry, academia and other research organizations have been using geographic information system (GIS) tools to display data collected for a wide variety of programs. Recent technology advances have made it possible for the public to also use GIS tools to display data. Meanwhile, around the world, volunteers are increasingly participating in citizen science activities that involve collecting environmental observations and measurements. Considering themes of broad interest to which citizen science and GIS tools could be applied, integrated nuclear waste management represents a potential opportunity for public engagement in environmental data analysis. In the United States, the Department of Energy's (DOE's) goal is to develop solutions for the long-term, sustainable management of the nation's spent nuclear fuel (SNF) and high-level radioactive waste (HLW) from commercial electricity generation, as well as national defense activities. The DOE has been exploring options for an integrated waste management system to transport, store, and dispose of SNF and HLW. To support its efforts, DOE has been exploring ways to seek broad input from the public. Literature was reviewed to assess recent advances in GIS technology and citizen science that could contribute to public engagement in waste management planning. Results identified a variety of promising tools and applications that are readily accessible online, including QGIS and the U.S. Environmental Protection Agency's (EPA's) Real Time Geo-spatial Data Viewer (RETIGO). For example, interested members of the public could illustrate air quality, water quality, and other environmental data in GIS plots to visually represent local conditions over time. This paper highlights potential opportunities for those interested in citizen science and GIS tools as part of exploring options for public engagement in planning for an integrated waste management system. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Regulations for Bat Protection in Mexico's Wind Farms

Wind energy development has expanded the fastest globally among all renewable sources during the last 20 years. However, wind farms have documented adverse impacts on bats, including mortality from collisions with turbine blades and disruptions to habitat and behavior. As the world's sixth most attractive economy for renewables, with 70 operating wind farms, Mexico and its bats now face escalating threats from the country's burgeoning wind industry. Despite this rapid growth, few studies have analyzed Mexico's regulatory framework to prevent, evaluate, and mitigate wind farm effects on bats. In this study, we reviewed Mexican laws and treaties that facilitate wind farm permitting, construction, operation, and decommissioning, and searched for guidelines that specifically address bat conservation. We found eight international pacts that promote wind power adoption along with three relevant articles in Mexico's Constitution. The General Law of Ecological Balance and Environmental Protection proved most pertinent for impact management. Supplementary guidelines from the Ministry of Environment and Natural Resources offer general strategies for evaluating wind farm impacts on bats, but adherence remains voluntary. Given expanding wind power investments across Mexico, we highlight the need for more stringent national standards that require preventative and corrective measures to protect bat populations. Tighter legislation and enforcement offer pathways toward environmentally sustainable wind energy development in Mexico.

17 WIND ENERGY↗

Unraveling the Hsp70-ROS-autophagy axis in pentachlorophenol-challenged lung and liver epithelial cells

Pentachlorophenol (PCP) was extensively utilized as an organochlorine pesticide and wood preservative in the United States from the 1930s until the Environmental Protection Agency (EPA) imposed restrictions due to concerns about its toxicity and potential carcinogenic properties. Although it is no longer widely used, PCP remains a concern due to its environmental persistence and potential for long-term health effects. Significant occupational and environmental exposures have likely occurred, with the health and economic costs of PCP exposure potentially being substantial given its known toxicity. Notably, PCP exhibits rapid absorption through both the skin and respiratory system and has been shown to cause hepatotoxicity, developmental toxicity, immunotoxicity, irritation, and carcinogenicity in laboratory animal studies. PCP exposure induces oxidative stress, a key mechanism underlying its inflammatory and toxic effects, which can activate cellular stress responses including upregulation of heat shock protein 70 (Hsp70). Previous studies in lung and liver epithelial cells have shown that Hsp70 and oxidative stress play pivotal roles in triggering autophagy. This study establishes the critical role of the Hsp70-reactive oxygen species (ROS)-autophagy axis in regulating cellular responses to PCP exposure in human alveolar (A549) and liver carcinoma (HepG2) epithelial cells. Our research elucidated the molecular mechanisms underlying PCP's cellular effects, demonstrating that its exposure resulted in increased expression of autophagy-related proteins (Beclin-1, LC3B, ATG12, and ATG16), subunits of NADPH oxidase (NCF-1, NCF-2, NOX2, and Rac), and antioxidant proteins (SOD and GPx) in both lung and liver cell types. Notably, PCP augmented the interaction between Hsp70 and the autophagy regulator Beclin-1. Pretreatment with the ROS inhibitor N-acetylcysteine or Hsp70 knockdown markedly reversed PCP-induced responses. Our in-silico protein–protein docking analysis and molecular dynamics simulation studies revealed enhanced interactions and/or stable confirmations maintained throughout the simulations for TLR4-Hsp70 and Hsp70-Beclin-1 complexes in the presence of PCP. These findings provide a strong foundation for future studies, employing in vivo experimental models and human populations to identify promising targets for PCP-induced toxicity and cellular injury. As a result, these findings may have far-reaching implications for public health and environmental policy, ultimately leading to the identification of biomarkers and the development of more effective interventions for environmentally induced toxicity and diseases.

97 MATHEMATICS AND COMPUTING↗

Conversion Coatings for Aluminum Alloys by Chemical Vapor Deposition Mechanisms

With the rise of environmental awareness and the renewed importance of environmentally friendly processes, the United States Environmental Protection Agency has targeted surface pre-treatment processes based on chromates. Indeed, this process has been subject to regulations under the Clean Water Act as well as other environmental initiatives, and there is today a marked movement to phase the process out in the near future. Therefore, there is a clear need for new advances in coating technology that could provide practical options for replacing present industrial practices. Depending on the final application, such coatings might be required to be resistant to corrosion, act as chemically resistant coatings, or both. This research examined a chemical vapor deposition (CVD) mechanism to deposit uniform conversion coatings onto aluminum alloy substrates. Robust protocols based on solutions of aryl phosphate ester and multi-oxide conversion coating (submicron) films were successfully grown onto the aluminum alloy samples. These films were characterized by X-ray Photoelectron Spectroscopy (XPS). Preliminary results indicate the potential of this technology to replace aqueous-based chromate processes.

Reye, John T.↗

NESHAPs CY19 Report: Radionuclide Air Emission Report for 2019

Lawrence Livermore National Security, LLC operates facilities at Lawrence Livermore National Laboratory (LLNL) in which radionuclides are handled and stored. These facilities are subject to the U.S. Environmental Protection Agency (EPA) National Emission Standards for Hazardous Air Pollutants (NESHAPs) in Code of Federal Regulations (CFR) Title 40, Part 61, Subpart H, which regulates radionuclide emissions to air from Department of Energy (DOE) facilities. Specifically, NESHAPs limits the emission of radionuclides to the ambient air to levels resulting in an annual effective dose equivalent of 10 mrem (100 μSv) to any member of the public. Using measured and calculated emissions, and building-specific and common parameters, LLNL personnel applied the EPA-approved computer code, CAP88-PC, Version 4.0.1.17, to calculate the dose to the maximally exposed individual member of the public for the Livermore Site and Site 300. In 2019, LLNL maintained its compliance with 40 CFR 61, Subpart H. All radioactive air emissions resulted in calculated doses far below the annual 10 mrem (100 μSv) sitewide standard. The annual doses to the site-wide maximally exposed individual member of the public at the Livermore Site and Site 300 from planned and unplanned operations in 2019 are: Livermore Site: 4.3 x 10⁻³ mrem (4.3 x 10⁻² μSv); Site 300: 9.5 x 10⁻⁸ mrem (9.5 x 10⁻⁷ μSv).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Electrochemically recovered struvite matches conventional fertilizers in soil nutrient supply

Phosphorus (P) is an essential macronutrient for agriculture, yet global reliance on finite phosphorite reserves raises concerns about long-term food and nutrient security. Struvite (MgNH 4 PO 4 ·6H 2 O), a mineral recovered from municipal wastewater, represents a sustainable and circular source of P, but uncertainty remains regarding its nutrient availability relative to conventional fertilizers. This study evaluated the fertilizer value and environmental safety of electrochemically recovered struvite (RecoP) in comparison with diammonium phosphate (DAP), triple superphosphate (TSP), and rock phosphate (RockP). Nutrient availability, potential contaminant concentrations, and soil P and nitrogen (N) dynamics were assessed using standardized chemical analyses and an 8-week incubation experiment across three soils with contrasting soil types. RecoP contained 14.7% citrate-soluble P, significantly greater than RockP and comparable to DAP and TSP. Across all soils, RecoP increased both readily available and moderately labile P pools (p < 0.01), matching the performance of conventional fast-release fertilizers. Despite containing approximately half the total of DAP, RecoP stimulated nitrification rates that were 2.2 times greater than the control and exceeded those of TSP, suggesting that fertilizer-derived N bioavailability, rather than total N loading, governed microbial N transformation responses. Concentrations of potentially toxic elements in RecoP were consistently well below US Environmental Protection Agency regulatory limits thresholds. Collectively, these results indicate that RecoP functions as a readily available source of both P and N, comparable to widely used conventional fertilizers, while meeting environmental safety standards. RecoP therefore represents a viable component of sustainable nutrient management strategies that support P recycling and agricultural productivity.

Kharal, Sudarshan [Ohio Univ., Athens, OH (United ↗

Verification of EPA's " Preliminary remediation goals for radionuclides" (PRG) electronic calculator

The U.S. Environmental Protection Agency (EPA) requested an external, independent verification study of their “Preliminary Remediation Goals for Radionuclides” (PRG) electronic calculator. The calculator provides information on establishing PRGs for radionuclides at Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) sites with radioactive contamination (Verification Study Charge, Background). These risk-based PRGs set concentration limits using carcinogenic toxicity values under specific exposure conditions (PRG User’s Guide, Section 1). The purpose of this verification study is to ascertain that the computer codes has no inherit numerical problems with obtaining solutions as well as to ensure that the equations are programmed correctly.

97 MATHEMATICS AND COMPUTING↗