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At least 415 records · Page 23

Emission measures and structure of the transition region of a sunspot from emission lines in the far ultraviolet

Absolute intensities of emission lines in the wavelength range from 1200 A to 1817 A from the large sunspot in McMath region 12510 near the disk center are presented. The intensities are averaged across the umbra and penumbra of the sunspot. The observations were made with the NRL slit spectrograph on Skylab. Emission measures are derived from the measured intensities. Assuming a balance between the divergence of the conductive energy flux and the radiative energy losses, a self-consistent model of the lower transition region in the sunspot is constructed. The model gives a constant pressure of about 0.19 dyn/sq cm and a conductive flux which decreases approximately one order of magnitude between 200,000 and 40,000 K. The temperature gradient is relatively constant, increasing slowly with decreasing temperature

Cheng, C.-C.↗

The IR emission features - Emission from PAH molecules and amorphous carbon particles

Techniques for the assessment of the importance of the various forms of PAHs, and recent infrared observations concerning the PAH problem, are considered. Spectroscopic data suggest that the observed interstellar spectrum is due to both free molecule-sized PAHs producing the narrow features, and amorphous carbon particles contributing to the broad underlying components. Explanations for the multicomponent emission spectrum are discussed. A model of the emission mechanism for the example of chrysene is presented, and an exact treatment of the IR fluorescence from highly vibrationally excited large molecules shows that species containing 20-30 carbon atoms are responsible for the narrow features, although the spectra more closely resemble those of amorphous carbon particles. It is suggested that future emphasis should be placed on the spatial characteristics of the component spectra.

Allamandola, L. J.↗

On the wavelength dependence of apparent emissivity of asteroid microwave emissions - Ceres and Vesta

Observations of Ceres and Vesta demonstrate the need for modifying the physical parameters of the standard model procedure in treating single-wavelength observations. It is suggested that simultaneous IR and cm-wavelength data should be used in order to determine such properties as the surface dielectric characteristics, layer depth, and radio emissivity. If using the standard model, an emissivity of 0.8 should be adopted for wavelengths of longer than 1 cm.

Webster, William J., Jr.↗

Modelling of IR emission of interstellar clouds. I - Emission of isolated clouds and dust abundance variations

A model for the IR emission and extinction properties of small dust particles is used here to compute the IR emissions in the IRAS photometric bands for a set of isolated, spherical, and nonhomogeneous clouds heated by the local interstellar radiation field. It is predicted that the IR limb brightening (LB) in the IRAS photometric bands caused by selective absorption of UV photons of different energies in the cloud generally happens for central extinctions over 4 mag at 12 microns and greater than 10 mag at 100 microns and intermediate extinctions for the other IRAS bands. The surface brightness in the four IRAS bands is limited to about 0.4, 0.6, 3, and 10 MJy/sr at 12, 25, 60, and 100 microns respectively when no strong density discontinuity is present at the cloud edge.

Bernard, J. P.↗

Spectral imaging of the 3.3 and 11.3 micron emission bands in NGC 1333 - Discovery of spatially separate band emissions

Spectral images in the 3.3 and 11.3 micron IR emission band around the star SVS 3 in NGC 1333 indicate that the two bands have their origin in different locations, rendering them useless in estimates of the sizes of the molecules emitting the bands. This is in keeping with the emission bands' generation by a mixture of variously sized polycyclic aromatic hydrocarbons (PAHs) whose smallest species have been dehydrogenated in the vicinity of SVS 3. Hot bands and overtone/combination bands may account for the 3.4-micron band, rather than molecular side-groups of the PAHs.

Bregman, Jesse↗

Molecular line emission models of Herbig-Haro objects. II - HCO(+) emission

We present time-dependent models of the chemistry and temperature of interstellar molecular gas clumps that are exposed to the radiation from propagating stellar-jet shocks. The X-ray, EUV, and FUV radiation from the shock initiates ion chemistry and also heats the gas in the clumps. Using representative parameters, we show that, on the shock transit time between the clumps, the abundances of the ionized molecular species that are produced in the clumps can exceed the values determined from steady state models by several orders of magnitude. Collisional excitation by the heated gas can lead to measurable line emission from several ionized species; as in previous investigations of X-ray-irradiated molecular gas, we find that electron impacts contribute significantly to this process. We apply these results to the interpretation of the HCO(+) line emission that has already been detected in several Herbig-Haro objects. We demonstrate that this picture provides a natural explanation of the fact that the line intensity typically peaks ahead of the associated shock, as well as of the reported low line-center velocities and narrow line widths. We tabulate several diagnostic line intensities of HCO(+) and other molecular species that may be used to infer the physical conditions in the emitting gas.

Wolfire, Mark G.↗

Tropospheric Emission Spectrometer and Airborne Emission Spectrometer

The Tropospheric Emission Spectrometer (TES) is an instrument being developed for the NASA Earth Observing System Chemistry Platform. TES will measure the distribution of ozone and its precursors in the lower atmosphere. The Airborne Emission Spectrometer (AES) is an aircraft precursor to TES. Applicable descriptions are given of instrument design, technology challenges, implementation and operations for both.

TES AES Ozone Spectrometer Earth Observation↗

Simulations of NOx Emissions from Low Emissions Discrete Jet Injector Combustor Tests

An experimental and computational study was conducted to evaluate the performance and emissions characteristics of a candidate Lean Direct Injection (LDI) combustor configuration with a mix of simplex and airblast injectors. The National Combustion Code (NCC) was used to predict the experimentally measured EINOx emissions for test conditions representing low power, medium power, and high-power engine cycle conditions. Of the six cases modeled with the NCC using a reduced-kinetics finite-rate mechanism and lagrangian spray modeling, reasonable predictions of combustor exit temperature and EINOx were obtained at two high-power cycle conditions.

Ajmani, Kumud↗

Particle and Trace Gas Emissions Indices Measured During the 2021 Boeing ecoDemonstrator Emissions Ground Test

We present particle and trace gas emissions indices sampled on the ground at 30 meters behind the CFM LEAP-1B engines of the Boeing ecoDemonstrator 737-9 aircraft. Testing was carried out at Boeing Field in Seattle, WA, USA in Fall of 2021. Four different fuels were investigated including a 100% sustainable aviation fuel (SAF), a petroleum-based Jet A fuel, and two SAF blends. Total and non-volatile particle number concentrations were measured with a pair of condensation particle counters with one operating behind a custom-built thermal denuder heated to 350 degrees Celsius. Similarly, total and non-volatile particle number size distributions were measured with a pair of Scanning Mobility Particle Sizers (SMPSs). Non-volatile particle mass was estimated from particle light absorption techniques using an assumed mass absorption coefficient, while particle chemical speciation was measured by an Soot Particle Aerosol Mass Spectrometer (SP-AMS). A detailed list of instruments is given on the project website [1]. Overall, the results are consistent with expectations based on ICAO Emissions Databank certification data for the LEAP-1B with a stark reduction in non-volatile particle number and mass observed for the higher thrust conditions when the combustor was staged. The production of volatile particles under these conditions as well as experimental considerations related to background subtraction methods will be discussed.

Benjamin A. Nault↗

National Emission Standards for Hazardous Air Pollutants--Radionuclide Emissions Calendar Year 2014

This report is required to document compliance with 40 CFR 61 Subpart H. In 2014, the potential dose from radiological emissions to air, resulting from both current and past NNSS activities, was well below the 10 mrem/yr dose limit. Air sampling data collected at all air monitoring stations had average concentrations of radioactivity that were a fraction of the CL values. Concentrations ranged from 0.2% to a maximum of 8.9% of the allowed NESHAP limit. Because the nearest member of the public resides about 9 kilometers from potential release points on the NNSS, dose to the public would be only a small fraction of the value measured on the NNSS. The potential dose to the public from NLVF emissions was also very low at 0.0000086 mrem/yr, more than six orders of magnitude lower than the 10 mrem/yr limit.

Warren, Ronald W.↗

Proof of Concept Coded Aperture Miniature Mass Spectrometer Using a Cycloidal Sector Mass Analyzer, a Carbon Nanotube (CNT) Field Emission Electron Ionization Source, and an Array Detector

Despite many potential applications, miniature mass spectrometers have had limited adoption in the field due to the tradeoff between throughput and resolution that limits their performance relative to laboratory instruments. Recently, a solution to this tradeoff has been demonstrated by using spatially coded apertures in magnetic sector mass spectrometers, enabling throughput and signal-to-background improvements of greater than an order of magnitude with no loss of resolution. This paper describes a proof of concept demonstration of a cycloidal coded aperture miniature mass spectrometer (C-CAMMS) demonstrating use of spatially coded apertures in a cycloidal sector mass analyzer for the first time. C-CAMMS also incorporates a miniature carbon nanotube (CNT) field emission electron ionization source and a capacitive transimpedance amplifier (CTIA) ion array detector. Results confirm the cycloidal mass analyzer’s compatibility with aperture coding. A >10× increase in throughput was achieved without loss of resolution compared with a single slit instrument. Several areas where additional improvement can be realized are identified. .

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

First-principles Calculation of Resonant X-ray Emission Spectra Applied to ZnO

A framework for calculating the k-conserving component of K edge resonant x-ray emission spectroscopy measurements of anisotropic solids is presented. The crystalline band structure is calculated using a quasiparticle self-consistent GW implementation. Coherent spectra are calculated in the Kramers-Heisenberg formalism, and the effect of the experimental geometry in the dipole approximation is fully considered. Coherent spectra are calculated for ZnO and successfully compared to previously measured data.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Strong Field Electron Emission from Fixed in Space H{sub 2}{sup +} Ions

We have studied electron emission from the H{sub 2}{sup +} ion by a circularly polarized laser pulse (800 nm, 6x10{sup 14} W/cm{sup 2}). The electron momentum distribution in the body fixed frame of the molecule is experimentally obtained by a coincident detection of electrons and protons. The data are compared to a solution of the time-dependent Schroedinger equation in two dimensions. We find radial and angular distributions which are at odds with the quasistatic enhanced ionization model. The unexpected momentum distribution is traced back to a complex laser-driven electron dynamics inside the molecule influencing the instant of ionization and the initial momentum of the electron.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Particle emissions from mobile sources: Discussion of ultrafine particle emissions and definition

There is no universally agreed upon definition for ultrafine particles (UFP). Commonly used definitions for UFP are either particle number below 100 nm or total particle number, but without an agreed upon lower cut point. For example, a lower cut point of 3 nm compared to 10 nm could result in a substantially higher count. Another definition for UFP is total particle mass but without a commonly agreed upon aerodynamic diameter upper cut point, e.g., below 100 nm, 200 nm, 300 nm, etc. Yet another definition is lung deposited surface area weighted by lung deposition fraction, found mainly in the particle mobility diameter range from 20 to 400 nm. It is clear from these definitions that there are inconsistencies in the way UFP is used and defined in the literature. Sometimes these metrics are well correlated, sometimes not. In this paper we suggest three exposure metrics: UFP-N, UFP-M, and UFP-S, that we believe will add clarity. These metrics represent total number, mass, and surface area below 500 nm, respectively. For surface area and mass, the 500 nm cut point can be either aerodynamic or mobility diameter depending upon measurement methodology. For all metrics, this cut point captures nearly all of the primary particle emissions from mobile sources. Furthermore, UFP-N would include a lower cut point of 3–6 nm and would not require an upper size cut point because there is very little particle number above 500 nm or even above 100 nm. Thus, our definition of UFP-N is consistent with the current definition of ultrafine number except for, importantly, the specification of a lower cut point. These exposure metrics can help facilitate consistency in the characterization of both short- and long-term UFP ambient exposures and associated health effects in epidemiological studies.

42 ENGINEERING↗

A synchronized emissive probe for time-resolved plasma potential measurements of pulsed discharges

A pulsed emissive probe technique is presented for measuring the plasma potential of pulsed plasma discharges. The technique provides time-resolved data and features minimal disturbance of the plasma achieved by alternating probe heating with the generation of plasma. Time resolution of about 20 ns is demonstrated for high power impulse magnetron sputtering (HIPIMS) plasma of niobium in argon. Spatial resolution of about 1 mm is achieved by using a miniature tungsten filament mounted on a precision translational stage. Repeated measurements for the same discharge conditions show that the standard deviation of the measurements is about 1-2 V, corresponding to 4%-8% of the maximum plasma potential relative to ground. The principle is demonstrated for measurements at a distance of 30 mm from the target, for different radial positions, at an argon pressure of 0.3 Pa, a cathode voltage of -420 V, and a discharge current of about 60 A in the steady-state phase of the HIPIMS pulse.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗