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At least 415 records · Page 23

Effect of Anions on the Delithiation of [Li–Al] Layered Double Hydroxides: Thermodynamic Insights

The utilization of lithium aluminum [Li–Al] layered double hydroxides (LDHs) is explored for direct lithium extraction (DLE) from geothermal brines and minerals. Following extraction, the Li + ions need to be removed from the LDH structure and converted into LiOH or Li 2 CO 3 products, making them suitable for battery applications. The research investigates the delithiation of [Li–Al-X] LDHs (where X = Cl – , OH – , and SO 4 2– ), which were synthesized and dried under different conditions. Herein the study aims to understand how the choice of anions and drying conditions affects the delithiation process. To determine the stability of these [Li–Al] LDHs, high-temperature oxide melt solution calorimetry is employed. The results reveal that the stability of LDHs varies significantly based on postdrying conditions, anion choice, and the water content in the interlayer. The order of stability, as indicated by the enthalpy of formation values, is found to be OH-LDH-O > OH-LDH-A > SO 4 -LDH-O > SO4-LDH-A > Cl-LDH-O > Cl-LDH-A. This trend is attributed to the interactions among the interlayer species and the metal hydroxide layers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Observational Investigation of the Effect of Turbulence on Microphysics and Precipitation in Warm Marine Boundary Layer Clouds

Abstract Turbulence is omnipresent in the marine boundary layer (MBL) and several mechanisms have been proposed regarding its role on MBL cloud microphysics. In particular, past modeling studies suggested that increasing turbulence broaden the droplet size distribution (DSD) and leads to precipitation initiation, this suggested relationship has not been evaluated yet using long‐term observations. Here, comprehensive retrievals from long‐term ground‐based observations are used to explore the impact of turbulence on microphysics and precipitation in drizzling MBL clouds. Our analysis supports that broader DSD and larger droplets are observed with strong turbulence, but interestingly, the precipitation is reduced instead of being enhanced. This suppression mechanism is mainly due to the entrainment and mixing process in which the entrained dry air evaporates cloud water. This study provides observational evidence to show the complex effect of turbulence on MBL cloud properties and implies the potential influence of turbulence on the clouds lifetime.

54 ENVIRONMENTAL SCIENCES↗

OVERVIEW OF PARTICLE DEPOSITION MODELS FOR SPENT NUCLEAR FUEL STORAGE SYSTEMS

Deposition models were built to evaluate contaminant deposition on spent nuclear fuel (SNF) canisters. The primary contaminant of concern is chloride, which is dispersed in the atmosphere and then deposits onto the canisters. During dry storage, the primary degradation process is likely to be Chloride Induced Stress Corrosion Cracking (CISCC) at the heat-affected zones of the canister welds. It is known that stainless steel canisters are susceptible to CISCC; however, the rate of chloride deposition onto the canisters is poorly known, based on sparse field data from a small number of sites. The models presented in this study could be useful for determining the rate of deposition on the canisters and the likelihood of CISCC to help with SNF canister ageing management. The deposition models were developed with the commercial computational fluid dynamics (CFD) code STAR-CCM+. Various deposition mechanisms were considered and incorporated into the models, and a sensitivity study was conducted to determine the most important mechanisms for deposition within a SNF storage system. The models included both a vertical and horizontal configuration storage system: NAC International’s Modular, Advanced Generation, Nuclear All-purpose STORage System (MAGNASTOR®) and a NUHOMS® horizontal storage module respectively. The resulting canister deposition on the horizontal canister is visually compared with inspection data taken onsite at the Calvert Cliffs Nuclear Power Plant. These models are preliminary, and development of the models will continue. Future validation exercises are currently being planned, including the Canister Deposition Field Demonstration (CDFD) effort funded by U.S. Department of Energy office of Nuclear Energy office of Spent Fuel Waste Science and Technology. The goal of the modeling presented is to demonstrate a potential modeling technique that could be used to plan and inform SNF canister ageing management programs with predictive models for the timing and occurrence of canister CISCC.

Suffield, Sarah R.↗

An Analytic Formula for Entraining CAPE in Midlatitude Storm Environments

Abstract This article introduces an analytic formula for entraining convective available potential energy (ECAPE) with an entrainment rate that is determined directly from an environmental sounding, rather than prescribed by the formula user. Entrainment is connected to the background environment using an eddy diffusivity approximation for lateral mixing, updraft geometry assumptions, and mass continuity. These approximations result in a direct correspondence between the storm-relative flow and the updraft radius and an inverse scaling between the updraft radius squared and entrainment rate. The aforementioned concepts, combined with the assumption of adiabatic conservation of moist static energy, yield an explicit analytic equation for ECAPE that depends entirely on state variables in an atmospheric profile and a few constant parameters with values that are established in past literature. Using a simplified Bernoulli-like equation, the ECAPE formula is modified to account for updraft enhancement via kinetic energy extracted from the cloud’s background environment. CAPE and ECAPE can be viewed as predictors of the maximum vertical velocity w max in an updraft. Hence, these formulas are evaluated using w max from past numerical modeling studies. Both of the new formulas improve predictions of w max substantially over commonly used diagnostic parameters, including undiluted CAPE and ECAPE with a constant prescribed entrainment rate. The formula that incorporates environmental kinetic energy contribution to the updraft correctly predicts instances of exceedance of by w max , and provides a conceptual explanation for why such exceedance is rare among past simulations. These formulas are potentially useful in nowcasting and forecasting thunderstorms and as thunderstorm proxies in climate change studies. Significance Statement Substantial mixing occurs between the upward-moving air currents in thunderstorms (updrafts) and the surrounding comparatively dry environmental air, through a process called entrainment. Entrainment controls thunderstorm intensity via its diluting effect on the buoyancy of air within updrafts. A challenge to representing entrainment in forecasting and predictions of the intensity of updrafts in future climates is to determine how much entrainment will occur in a given thunderstorm environment without a computationally expensive high-resolution simulation. To address this gap, this article derives a new formula that computes entrainment from the properties of a single environmental profile. This formula is shown to predict updraft vertical velocity more accurately than past diagnostics, and can be used in forecasting and climate prediction to improve predictions of thunderstorm behavior and impacts.

54 ENVIRONMENTAL SCIENCES↗

Preparation of prepreg graphite tape with insoluble polymer

Powdered polymer is finely ground. Second polymer, soluble, is mixed with appropriate solvent. Milled polymer and graphite filaments are added to soluble polymer-solvent solution to create slurry. Slurry is dried, and when ready for processing, the soluble, binder-polymer is removed by heat during precure or cure cycle.

Yates, C. I.↗

Automated Array Assembly Task In-depth Study of Silicon Wafer Surface Texturizing

Several aspects of silicon wafer surface texturizing were studied. A low cost cleaning method that utilizes recycled Freon in an ultrasonic vapor degreaser to remove organic and inorganic contaminants from the surface of silicon wafers as received from silicon suppliers was investigated. The use of clean dry air and high throughout wafer batch drying techniques was shown to lower the cost of wafer drying. A two stage texturizing process was examined for suitability in large scale production. Also, an in-depth gettering study with the two stage texturizing process was performed for the enhancement of solar cell efficiency, minimization of current versus voltage curve dispersion, and improvement in process reproducibility. The 10% efficiency improvement goal was exceeded for the near term implementation of flat plate photovoltaic cost reduction.

Jones, G. T.↗

Thermally grown oxide and diffusions for automatic processing of integrated circuits

A totally automated facility for semiconductor oxidation and diffusion was developed using a state-of-the-art diffusion furnace and high temperature grown oxides. Major innovations include: (1) a process controller specifically for semiconductor processing; (2) an automatic loading system to accept wafers from an air track, insert them into a quartz carrier and then place the carrier on a paddle for insertion into the furnace; (3) automatic unloading of the wafers back onto the air track, and (4) boron diffusion using diborane with plus or minus 5 percent uniformity. Processes demonstrated include Wet and dry oxidation for general use and for gate oxide, boron diffusion, phosphorous diffusion, and sintering.

Kennedy, B. W.↗

Plasma-sprayed self-lubricating coatings

One of the most important criterion for acceptable commercial application of a multiple phase composition is uniformity and reproducibility. This means that the performance characteristics of the coat - e.g., its lubricating properties, bond strength to the substrate, and thermal properties - can be readily predicted to give a desired performance. The improvement of uniformity and reproducibility of the coats, the oxidation behavior at three temperature ranges, the effect of bond coat and the effect of preheat treatment as measured by adhesive strength tests, coating examination procedures, and physical property measurements were studied. The following modifications improved the uniformity and reproducibility: (1) changes and closer control in the particle size range of the raw materials used, (2) increasing the binder content from 3.2% to 4.1% (dried weight), and (3) analytical processing procedures using step by step checking to assure consistency.

Nakamura, H. H.↗

Intraseasonal and interannual oscillations in coupled ocean-atmosphere models

An investigation is presented of coupled ocean-atmosphere models' behavior in an environment where atmospheric wave speeds are substantially reduced from dry atmospheric values by such processes as condensation-moisture convergence. Modes are calculated for zonally periodic, unbounded ocean-atmosphere systems, emphasizing the importance of an inclusion of prognostic atmosphere equations in simple coupled ocean-atmosphere models with a view to simulations of intraseasonal variability and its possible interaction with interannual variability. The dynamics of low and high frequency modes are compared; both classes are sensitive to the degree to which surface wind anomalies are able to affect the evaporation rate.

Hirst, Anthony C.↗

Polymer Infiltration Studies

Progress was made on the preparation of carbon fiber composites using advanced polymer resins. Processes reported include powder towpreg process, weaving towpreg made from dry powder prepreg, composite from powder coated towpreg, and toughening of polyimide resin (PMR) composites by semi-interpenetrating networks. Several important areas of polymer infiltration into fiber bundles will be researched. Preparation to towpreg for textile preform weaving and braiding and for automated tow placement is a major goal, as are the continued development of prepregging technology and the various aspects of composite part fabrication.

Marchello, Joseph M.↗

Polymer infiltration studies

The preparation is reported of carbon fiber composites using advanced polymer resins. Current and ongoing research activities include: powder towpreg process; weaving, braiding and stitching dry powder prepreg; advanced tow placement; and customized ATP towpreg. The goal of these studies is to produce advanced composite materials for automated part fabrication using textile and robotics technology in the manufacture of subsonic and supersonic aircraft.

Marchello, Joseph M.↗

Atomic Oxygen Removes Varnish And Lacquer From Old Paintings

Dry and relatively nondestructive plasma process found effective in removing protective coats from old paintings. Process generates monatomic oxygen, which reacts with varnish, lacquer, polyurethane, acrylic, and other organic coating materials; reactions produce mostly carbon monoxide and water vapor, then simply pumped away by vacuum system in which plasma generated. Does not attack oxide-based pigments in underlying paint layers, and brush-stroke marks remain undisturbed.

Rutledge, Sharon K.↗

Design Status of the Capillary Brine Residual in Containment Water Recovery System

One of the goals of the AES Life Support System (LSS) Project is to achieve 98% water loop closure for long duration human exploration missions beyond low Earth orbit. To meet this objective, the AES LSS Project is developing technologies to recover water from wastewater brine; highly concentrated waste products generated from a primary water recovery system. The state of the art system used aboard the International Space Station (ISS) has the potential to recover up to 85% water from unine wastewater, leaving a significant amounts of water in the waste brine, the recovery of which is critical technology gap that must be filled in order to enable long duration human exploration. Recovering water from the urine wastewater brine is complicated by the concentration of solids as water is removed from the brine, and the concentration of the corrosive, toxic chemicals used to stabilize the urine which fouls and degrades water processing hardware, and poses a hazard to operators and crew. Brine Residual in Containment (BRIC) is focused on solids management through a process of "in-place" drying - the drying of brines within the container used for final disposal. Application of in-place drying has the potential to improve the safety and reliability of the system by reducing the exposure to curew and hardware to the problematic brine residual. Through a collaboration between the NASA Johnson Space Center and Portland Status University, a novel water recovery system was developed that utilizes containment geometry to support passive capillary flow and static phase separation allowing free surface evaporation to take place in a microgravity environment. A notional design for an ISS demonstration system was developed. This paper describes the testing performed to characterize the performance of the system as well as the status of the system level design.

Sargusingh, Miriam J.↗

Design Status of the Capillary Brine Residual in Containment Water Recovery System

One of the goals of the AES Life Support System (LSS) Project is to achieve 98% water loop closure for long duration human exploration missions beyond low Earth orbit. To meet this objective, the AES LSS Project is developing technologies to recover water from wastewater brine; highly concentrated waste products generated from a primary water recovery system. The state of the art system used aboard the International Space Station (ISS) has the potential to recover up to 85% water from unine wastewater, leaving a significant amounts of water in the waste brine, the recovery of which is a critical technology gap that must be filled in order to enable long duration human exploration. Recovering water from the urine wastewater brine is complicated by the concentration of solids as water is removed from the brine, and the concentration of the corrosive, toxic chemicals used to stabilize the urine which fouls and degrades water processing hardware, and poses a hazard to operators and crew. Brine Residual in Containment (BRIC) is focused on solids management through a process of "in-place" drying - the drying of brines within the container used for final disposal. Application of in-place drying has the potential to improve the safety and reliability of the system by reducing the exposure to crew and hardware to the problematic brine residual. Through a collaboration between the NASA Johnson Space Center and Portland Status University, a novel water recovery system was developed that utilizes containment geometry to support passive capillary flow and static phase separation allowing free surface evaporation to take place in a microgravity environment. A notional design for an ISS demonstration system was developed. This paper describes the concept for the system level design.

Callahan, Michael R.↗

Mechanical Properties and Interfacial Bonding of Overmolded Polymer Composite Lattice Structures

This study investigates the mechanical properties and interfacial bonding of Polyamide 12 filled with Glass Fiber (PA12/GF) lattice structures overmolded with Nylon 66 (PA66) and Thermoplastic Polyurethane (TPU). The PA12/GF lattices, designed in Gyroid, Isotruss, and Octahedral geometries, were produced using the Selective Laser Sintering (SLS) technique. The thermal characteristics of both the lattice and overmolding materials were analyzed using Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA). The mechanical performance and interfacial bonding were evaluated through mechanical testing and microstructural analysis. The results indicate that overmolding improved flexural strength and impact resistance of the PA12/GF lattices. For instance, the plain PA12/GF Isotruss lattice exhibited a flexural strength of 15.5 MPa. By overmolding it with TPU the flexural strength increased by up to 137%, while PA66-overmolding resulted in an increase of 371%, achieving a flexural strength of 73 MPa. In terms of impact resistance, TPU-overmolding improved performance significantly, with an increase of 1800% (Gyroid) compared to the plain lattice. Microstructural analysis revealed good adhesion at the interface, especially when both the lattice and overmolding materials were thoroughly dried prior to the overmolding process to minimize interfacial porosity. This study highlights the potential of using overmolding to enhance lattice structures performance, offering lightweight and cost-efficient solutions for automotive applications.

Talabi, Isaac [ORNL] (ORCID:0000000340215594)↗

Investigations into the burning-out of organic substances in the ceramic body

Pressed compacts were made of spray dried alumina containing water soluble polyvinyl alcohol or cellulose derivative binder. The burning out of organic binder on gradual heating was investigated by visual and microscopic observations of the cross section and by thermogravimetry. Burning out proceeds inward from the peripheries, gradually reducing the size of the black core, which first consists of a dark boundary layer and later turns uniformly black with a sharp boundary. A detailed mechanism of the burning out process between and within the spray dried granules is observed under the microscope. Oxygen atmosphere accelerates the burning out process.

Locher, C.↗