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At least 415 records · Page 23
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NASA NTRS1993

High-resolution absorption cross section measurements of carbon monoxide at 20 K between 96.7 and 98.8 nanometers

Photoabsorption cross sections for five CO bands, at wavelengths between 96.7 and 98.8 nm, have been measured at high-resolution in a supersonic jet-cooled source at the Photon Factory synchrotron facility. New integrated cross sections are reported for the K-X, L(prime)-X, and L-X bands. Low-temperature spectra of the J-X and W-X bands, which were used in the determination of the absorbing CO column densities, are also presented. The rotational structures of the K-X, L(prime)-X, and L-X bands do not overlap in the low-temperature spectra, allowing for the first unambiguous determination of these band oscillator strengths. We also report revised room temperature measurements of integrated cross sections for the K-X, L(prime)-X, and L-X bands, in which distortions in the measured spectra due to insufficient instrumental resolution have been minimized; the revised room temperature integrated cross sections are consistent with the low-temperature results.

Stark, G.↗
NASA NTRS1993

A multi-transition study of carbon monoxide in the Orion A molecular cloud. II - C(O-18)

We present an analysis of density, temperature, and excitation conditions in a one half square degree region around BN/KL in Orion A using new C(O-l8) J = 1 yields 0 and J = 2 yields 1 data. This paper extends a previous study of Orion A, based on a multitransition analysis of (C-13)O, to the optically thinner C(O-18) species that traces better the dense inner regions of giant molecular clouds. From the C(O-18) maps we identify several condensations and are able to derive their size, linewidth, average density, mass, and virial mass.

Dutrey, A.↗
NASA NTRS1994

High-resolution oscillator strength measurements for the A(v') - X(0) bands of carbon monoxide with 11 less than or equal to v' less than or equal to 14

Band oscillator strengths (f-values) for four bands of the Fourth Positive system (A (1)Pi - Chi(sup 1) Sigma(+)) of CO have been determined from high-resolution (lambda/Delta lambda approximately equal to 150,000) absorption spectra. The bands, (14, 0) through (11, 0), are at wavelengths between 121 and 127 nm. Our f-values for the (11, 0) and (12, 0) bands support those of Chan, Cooper, & Brion (1993), which have been shown to be consistent with observations of CO in the clouds in the line of sight to zeta Oph. Our f-values for the (13, 0) and (14, 0) bands are the first directly measured values for these bands.

Smith, Peter L.↗
NASA NTRS1995

High-resolution absorption cross section measurements of supersonic jet-cooled carbon monoxide between 92.5 and 97.4 nanometers

High-resolution photoabsorption cross sections for eight CO bands, at wavelengths between 92.5 nm and 97.4 nm, have been measured in a supersonic jet-cooled source (approximately equals 20 K) at the Photon Factory synchrotron radiation facility. New integrated cross sections are reported for four bands between 92.5 nm and 94.2 nm. A low-temperature spectrum of the W(1)-X(0) band (95.6 nm), which was used to determine the absorbing CO column densities, is also presented. Additional jet-cooled cross section measurements were made on the L(0)-X(0), K(0)-X(0), and W(0)-X(0) bands (96.7-97.4 nm) which verify previously published results. A self-consistent set of band oscillator strengths is presented for the eight bands studied.

Yoshino, K.↗
NASA NTRS1994

Solid carbon monoxide in the Serpens dark cloud

The 4.67 micrometer absorption feature of solid CO is an important signature of grain mantles in molecular clouds. This paper presents new observations of solid CO absorption in the spectra of four infrared sources in and behind the Serpens dark cloud. We also present supplementary 2.0-2.5 micrometer spectra which clarify the nature of selected sources. Solid CO profiles are compared with models based on laboratory data. In common with previous studies of other clouds, we find that the observed profiles are consistent with the presence of two distinct phases of CO-bearing ice, one dominated either by CO itself or by CO mixed with absorption relative to that of the water-ice feature at 3.1 micrometers is unusually high in Serpens: we deduce column densities for CO and H2O in solid form and conclude that the mean CO abundance in dust is 40% of the H2O abundance, compared with values in the range 0%-30% typical of other molecular clouds. On the basis of its 2.0-2.5 micrometer spectrum and near-infrared colors, we deduce the infrared source CK 2 to be a K5-M0 III field star situated behind the Serpens cloud and suffering 40-50 mag of visual extinction. Assuming empirical correlations between extinction and total (gas + dust) CO column density, we estimate the CO depletion (i.e., the fraction of interstellar CO in the line of sight tied up in grains) to be approximately 40% in the intracloud medium of the Serpens cloud, comparable with previous estimates for the Taurus dark cloud, and much higher than that found in the environments of protostellar objects.

Chiar, J. E.↗
NASA NTRS1994

Interstellar carbon monoxide toward zeta Ophiuchi

Interstellar CO A-X bands in the spectrum of zeta Oph were recorded at high Sound-to-Noise (S/N) with grating G160M of the Goddard High Resolution Spectrograph on the Hubble Space Telescope. Isotopic fractionation of CO is severe: CO-12/CO-13 = 167, C(16)O/C(18)O approximately equal to 1550 and C(16)O/C(17)O is greater than 5900 are found where C-12/C-13 = 70, O-16/O-18 = 500, and O-16.O-17 = 2600 are observed or expected. Standard models of the zeta Oph cloud predict CO-12/CO-13 is less than or approximately 70. The higher observed ratio suggests that photodissociation of CO, not the isotopic charge exchange reaction ((13)C(+) + CO reversible reaction (12)C(+) + (13)(CO), is the dominant influence on the CO-12/CO-13 ratio.

Lambert, David L.↗
NASA NTRS1994

Intersystem transitions of interstellar carbon monoxide toward zeta Ophiuchi

Absorption from seven intersystem (triplet-singlet) transitions of interstellar (12)CO were detected in ultraviolet spectra of zeta Oph. The observed equivalent widths are approximately consistent with the transitions' predicted f-values and the (12) CO column density derived from the weakest of the observed A-X bands. These unsaturated intersystem transitions provide the opportunity to measure the (12)CO column density for heavily reddened (dense) sight lines. Laboratory measurements of oscillator strengths more precise than available ones will be needed to derive accurate column densities.

Federman, S. R.↗
NASA NTRS1993

Latitudinal distribution of carbon monoxide in the deep atmosphere of Venus

A large number of i.r. spectra of Venus was obtained using the Near-Infrared Mapping Spectrometer (NIMS) on the Galileo spacecraft, during the February 1990 encounter. Preliminary results show an apparent increase in the tropospheric CO volume mixing ratio (vmr) in the northern polar region. Other possible explanations of the observations are examined and rejected and an increase of the CO abundance north of 47 deg N of (35 +/- 15)% is inferred. Some possible causes of this enhancement are suggested.

Collard, A. D.↗
NASA NTRS1994

Relationship of ozone and carbon monoxide over North America

Observations at sites in eastern North America show a strong correlation between O3 and CO concentrations in summer, with a consistent slope DeltaO3/DeltaCO approximately = 0.3. Observations in the aged Denver plume at Niwot Ridge, Colorado, also show a strong correlation but with DeltaO3/DeltaCO = 0.15. These data offer a sensitive test for evaluating the ability of photochemical models to simulate production of O3 over North America and its export to the global atmosphere. Application to the Harvard/Goddard Institute for Space Studies three-dimensional, continental-scale model shows that the model gives a good simulation of the observed O3-CO correlations and of the associated DeltaO3/DeltaCO. This successful simulation lends support to model estimates of 6 Gmol/d for the net O3 production in the U.S. boundary layer in summer (corresponding to a net O3 production efficiency of 5.5, which is the number of O3 molecules produced per molecule of NOx consumed) and 70% for the fraction of the net production that is exported to the global atmosphere. Export of U.S. pollution appears to make a significant contribution to total tropospheric O3 over the northern hemisphere in summer. Simple interpretation of observed DeltaO3/DeltaCO as an O3/CO anthropogenic enhancement ratio is shown to underestimate substantially anthropogenic O3 production, because O3 and CO concentrations are negatively correlated in the absence of photochemistry. It is also shown that concurrent observations of DeltaO3/DeltaCO and DeltaO3/Delta(NO(y)-NO(x)) ratios can be used to impose lower and upper limits on the net O3 production efficiency.

Chin, Mian↗
NASA NTRS1994

Global circulation, thermal structure, and carbon monoxide distribution in Venus' mesosphere in 1991

Millimeter-wave observations of CO lines have provided a detailed picture of Venus' mesosphere dynamics in 1991 from simultaneous measurements of absolute wind velocities in two layers and of temperature and CO horizontal and vertical profiles at 75-115 km. Venus' circulation at 90-110 km was characterized in 1991 by the superposition of a zonal retrograde flow and a subsolar-to-antisolar flow of approximately equal velocities, increasing from about 40 +/- 15 m/sec at 95 km to 90 +/- 15 m/sec at 105 km altitude. The magnitude of the increase of the SS-AS flow is consistent with Venus thermosphere general circulation models (VTGCM). At 105 km, the data further indicate a cos(latitude) dependence of the zonal flow and marginally suggest the presence of a poleward meridional component of 35 +/- 30 m/sec. No obvious day-to-day variations of the circulation are evident in the data at the 20 m/sec level. Thermal profiles in the low-latitude region appear to be consistent with the Pioneer Venus nightside profile, except above 110 km, where they are somewhat colder. High-latitude warming is still found, but mid-latitudes appear to be colder than the equator. The atmosphere appears to be in cyclostrophic balance up to about 105 km. The horizontal distribution of CO on Venus' nightside is essentially uniform, both in latitude and in local time. This behavior agrees with VTGCM simulations in which the zonal flow velocity is prescribed to match the observations. Comparison with previous wind measurements indicates that the zonal flow experiences dramatic long-term variations. This variability, along with short-term fluctuations of the mesospheric zonal flow (evidenced by the variability in the O2 nightglow emissions), apparently controls the CO and O2 nightglow distributions. Gravity wave activity is a plausible mechanism that can drive these variations.

Lellouch, Emmanuel↗
NASA NTRS1995

Quantum yield for carbon monoxide production in the 248 nm photodissociation of carbonyl sulfide (OCS)

Tunable diode laser absorption spectroscopy has been coupled with excimer laser flash photolysis to measure the quantum yield for CO production from 248 nm photodissociation of carbonyl sulfide (OCS) relative to the well-known quantum yield for CO production from 248 nm photolysis of phosgene (Cl2CO2). The temporal resolution of the experiments was sufficient to distinguish CO formed directly by photodissociation from that formed by subsequent S((sup 3)P(sub J)) reaction with OCS. Under the experimental conditions employed, CO formation via the fast S((sup 1)D(sub 2)) + OCS reaction was minimal. Measurements at 297K and total pressures from 4 to 100 Torr N2 + N2O show the CO yield to be greater than 0.95 and most likely unity. This result suggests that the contribution of OCS as a precursor to the lower stratospheric sulfate aerosol layer is somewhat larger than previously thought.

Zhao, Z.↗
NASA NTRS1997

Relative Band Oscillator Strengths for Carbon Monoxide: Alpha (1)Pi-Chi (1)Sigma(+) Transitions

Band oscillator strengths for CO transitions between the electronic states A (l)Pi and X(1)Sigma(+) were measured via absorption with a synchrotron radiation source. When referenced to the well-characterized (5,0) band oscillator strength, our relative values for the (7,0) to (11,0) bands are most consistent with the recent experiments of Chan et al. and the theoretical predictions of Kirby & Cooper. Since the results from various laboratory techniques and theory now agree, analyses of interstellar CO based on absorption from A-X bands are no longer hindered by uncertainties in oscillator strength.

Federman, S. R.↗
NASA NTRS1998

Northern and Southern Hemisphere Ground-Based Infrared Spectroscopic Measurements of Tropospheric Carbon Monoxide and Ethane

Time series of CO and C2H, measurements have been derived from high-resolution infrared solar spectra recorded in Lauder, New Zealand (45.0 degrees S, 169.7 degrees E, altitude 0.37 km), and at the U.S. National Solar Observatory (31.9 degrees N, 11, 1.6 degrees W, altitude 2.09 km) on Kitt Peak. Lauder observations were obtained between July 1993 and November 1997, while the Kitt Peak measurements were recorded between May 1977 and December 1997. Both databases were analyzed with spectroscopic parameters that included significant improvements for C2H6 relative to previous studies. Target CO and C2H6 lines were selected to achieve similar vertical samplings based on averaging kernels. These calculations show that partial columns from layers extending from the surface to the mean tropopause and from the mean tropopause to 100 km are nearly independent. Retrievals based on a semiempirical application of the Rodgers optimal estimation technique are reported for the lower layer, which has a broad maximum in sensitivity in the upper troposphere. The Lauder CO and C2H, partial columns exhibit highly asymmetrical seasonal cycles with minima in austral autumn and sharp peaks in austral spring. The spring maxima are the result of tropical biomass burning emissions followed by deep convective vertical transport to the upper troposphere and long-range horizontal transport. Significant year-to-year variations are observed for both CO and C2H6, but the measured trends, (+0.37 +/- 0.57)% yr(exp -1) and (-0.64 +/- 0.79)% yr(exp -1), I sigma, respectively, indicate no significant long-term changes. The Kitt Peak data also exhibit CO and C2H6, seasonal variations in the lower layer with trends equal to (-0.27 +/- 0.17)% yr(exp -1) and (-1.20 +/- 0.35)% yr(exp -1), 1 sigma, respectively. Hence a decrease in the Kitt Peak tropospheric C2H6 column has been detected, though the CO trend is not significant. Both measurement sets are compared with previous observations, reported trends, and three-dimensional model calculations.

Rinsland, Curtis P.↗
NASA NTRS1999

Carbon Monoxide Distributions and Atmosphere Transports over Southern Africa

Sources and transports of CO as measured by the Measurement of Air Pollution from Space (MAPS) over a substantial sector of the southern hemisphere between South America and southern Africa are described by air parcel trajectories based upon European Center for Medium Range Weather Forecasts (ECMWF) model data fields. Observations, made by NASA Shuttle astronauts during the October 1994 mission, of vegetation fires suggest a direct relationship between in situ biomass burning, at least over South America and southern Africa, and coincident tropospheric measurements of CO. Results of this paper indicate that the transport of CO from the surface to the levels of maximum MAPS sensitivity (about 450 hPa) over these regions is not of a direct nature due largely to the well stratified atmospheric environment. The atmospheric transport of CO from biomass burning within this region is found to occur over intercontinental scales over numbers of days to more than a week. Three distinct synoptic circulation and transport classes are found to have occurred over southern Africa during the October 1994 MAPS experiment: (1) transport from South America and Africa to southern Africa associated with elevated MAPS measured CO (> 150 ppbv); (2) weakening anticyclonic transport from South America associated with moderate CO (< 150 ppbv and > 105 ppbv); and (3) transport from the high southern latitudes associated with low CO (<105 ppbv).

Garstang, Michael↗
NASA NTRS1998

Northern and Southern Hemisphere Ground-Based Infrared Spectroscopic Measurements of Tropospheric Carbon Monoxide and Ethane

Time series of CO and C2H6 measurements have been derived from high resolution infrared solar spectra recorded in Lauder, New Zealand (45.0 deg S, 169.7 deg E, altitude 0.37 km) and at the U. S. National Solar Observatory (31.90 deg N, 111.6 deg W, altitude 2.09 km) on Kitt Peak. Lauder observations were obtained between July 1993 and November 1997 while the Kitt Peak measurements were recorded between May 1977 and December 1997. Both databases were analyzed with spectroscopic parameters that included significant improvements for C2H6 relative to previous studies. Target CO and C2H6 lines were selected to achieve similar vertical samplings based on averaging kernels. These calculations show that partial columns from layers extending from the surface to the mean tropopause and from the mean tropopause to 100 km are nearly independent. Retrievals based on a semiempirical application of the Rodgers optimal estimation technique are reported for the lower layer, which has a broad maximum in sensitivity in the upper troposphere. The Lauder CO and C2H6 partial columns exhibit highly asymmetrical seasonal cycles with minima in austral autumn and sharp peaks in austral spring. The spring maxima are the result of tropical biomass burning emissions followed by deep convective vertical transport to the upper troposphere and long-range horizontal transport. Significant year-to-year variations are observed for both CO and C2H6, but the measured trends, (+0.37 +/- 0.57)%/ yr and (-0.64 +/- 0.79)%/ yr, 1 sigma, respectively, indicate no significant long-term changes. The Kitt Peak data also exhibit CO and C2H6 seasonal variations in the lower layer with trends equal to (-0.27 +/- 0.17)%/ yr and (-1.20 +/- 0.35)%/ yr, 1 sigma, respectively. Hence, a decrease in the Kitt Peak tropospheric C2H6 column has been detected, though the CO trend is not significant. Both measurement sets are compared with previous observations, reported trends, and three-dimensional model calculations.

Rinsland, Curtis P.↗
NASA NTRS2003

Cosmic: Carbon Monoxide And Soot In Microgravity Inverse Combustion

Almost seventy percent of fire related deaths are caused by the inhalation of toxins such as CO and soot that are produced when fires become underventilated.(1) Although studies have established the importance of CO formation during underventilated burning,(2) the formation processes of CO (and soot) in underventilated fires are not well understood. The goal of the COSMIC project is to study the formation processes of CO and soot in underventilated flames. A potential way to study CO and soot production in underventilated flames is the use of inverse diffusion flames (IDFs). An IDF forms between a central air jet and a surrounding fuel jet. IDFs are related to underventilated flames because they may allow CO and soot to escape unoxidized. Experiments and numerical simulations of laminar IDFs of CH4 and C2H4 were conducted in 1-g and micro-g to study CO and soot formation. Laminar flames were studied because turbulent models of underventilated fires are uncertain. Microgravity was used to alter CO and soot pathways. A IDF literature survey, providing background and establishing motivation for this research, was presented at the 5th IWMC.(3) Experimental results from 1-g C2H4 IDFs and comparisons with simulations, demonstrating similarities between IDFs and underventilated fires, were presented at the 6th IWMC.(4) This paper will present experimental results from micro-g and 1-g IDFs of CH4 and C2H4 as well as comparisons with simulations, further supporting the relation between IDFs and underventilated flames.

Mikofski, M. A.↗
NASA NTRS2006

Oscillator Strengths and Predissociation Widths for Rydberg Transitions in Carbon Monoxide

CO is used as a probe of astronomical environments ranging from planetary atmospheres and comets to interstellar clouds and the envelopes surrounding stars near the end of their lives. One of the processes controlling the CO abundance and the ratio of its isotopomers is photodissociation. Accurate oscillator strengths for Rydberg transitions are needed for modeling this process. Absorption bands were analyzed by synthesizing the profiles with codes developed independently in Meudon and Toledo. Each synthetic spectrum was adjusted to match the experimental one in a non-linear least-squares fitting procedure with the band oscillator strength, the line width (instrumental and predissociation.

Federman, Steven R.↗