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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 415 records · Page 23
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Liquid-Vapor Equilibrium of Multicomponent Cryogenic Systems

Liquid-vapor and solid-vapor equilibria at low to moderate pressures and low temperatures are important in many solar system environments, including the surface and clouds of Titan, the clouds of Uranus and Neptune, and the surfaces of Mars and Triton. The familiar cases of ideal behavior are limiting cases of a general thermodynamic representation for the vapor pressure of each component in a homogeneous multicomponent system. The fundamental connections of laboratory measurements to thermodynamic models are through the Gibbs-Duhem relation and the Gibbs-Helmholtz relation. Using laboratory measurements of the total pressure, temperature, and compositions of the liquid and vapor phases at equilibrium, the values of these parameters can be determined. The resulting model for vapor-liquid equilibrium can then conveniently and accurately be used to calculate pressures, compositions, condensation altitudes, and their dependencies on changing climatic conditions. A specific system being investigated is CH4-C2H6-N2, at conditions relevant to Titan's surface and atmosphere. Discussed are: the modeling of existing data on CH4-N2, with applications to the composition of Titan's condensate clouds; some new measurements on the CH4-C2H6 binary, using a high-precision static/volumetric system, and on the C2H6-N2 binary, using the volumetric system and a sensitive cryogenic flow calorimeter; and describe a new cryogenic phase-equilibrium vessel with which we are beginning a detailed, systematic study of the three constituent binaries and the ternary CH4-C2H6-N2 system at temperatures ranging from 80 to 105 K and pressures from 0.1 to 7 bar.

Thompson, W. Reid↗
NASA NTRS1988

Heavy hydrocarbon main injector technology

One of the key components of the Advanced Launch System (ALS) is a large liquid rocket, booster engine. To keep the overall vehicle size and cost down, this engine will probably use liquid oxygen (LOX) and a heavy hydrocarbon, such as RP-1, as propellants and operate at relatively high chamber pressures to increase overall performance. A technology program (Heavy Hydrocarbon Main Injector Technology) is being studied. The main objective of this effort is to develop a logic plan and supporting experimental data base to reduce the risk of developing a large scale (approximately 750,000 lb thrust), high performance main injector system. The overall approach and program plan, from initial analyses to large scale, two dimensional combustor design and test, and the current status of the program are discussed. Progress includes performance and stability analyses, cold flow tests of injector model, design and fabrication of subscale injectors and calorimeter combustors for performance, heat transfer, and dynamic stability tests, and preparation of hot fire test plans. Related, current, high pressure, LOX/RP-1 injector technology efforts are also briefly discussed.

Fisher, S. C.↗
NASA NTRS1990

Enhanced heat transfer rocket combustor technology component hot-fire test results

The evaluation of a method for enhancing combustor hot-gas wall heat extraction by using hot-fire tests of a rocket engine combustor calorimeter with hot-gas wall ribs is presented. The capability for enhanced heat extraction is required to increase available turbine drive energy for high chamber pressure operation, and therefore higher overall expander cycle engine performance. Determination of the rib effectiveness for incorporation into the design of a high-performance combustor for an advanced expander cycle combustor intended for use in an orbital transfer vehicle or advanced space engine, was the objective of these tests.

Brown, William S.↗
NASA NTRS1991

Characterizing water/rock interaction in simulated comet nuclei via calorimetry: Tool for in-situ science, laboratory analysis, and sample preservation

Although results from the Giotto and Vega spacecraft flybys of comet P/Halley indicate a complex chemistry for both the ices and dust in the nucleus, carbonaceous chondrite meteorites are still regarded as useful analogs for the rocky components. Carbonaceous chondrites mixed with water enable simulation of water/rock interactions which may occur in cometary nuclei. Three general types of interactions can be expected between water and minerals at sub-freezing temperatures: heterogeneous nucleation of ice by insoluble minerals; adsorption of water vapor by hygroscopic phases; and freezing and melting point depression of liquid water sustained by soluble minerals. Two series of experiments were performed in a differential scanning calorimeter (DSC) with homogenized powders of the following whole-rock meteorites and comparison samples: Allende (CV3), Murchison (CM2), Orgueil (CI), Holbrook (L6), and Pasamonte (eucrite) meteorites as well as on peridotite (PCC-1, USGS), saponite (Sap-Ca-1, CMS), montmorillonite (STx-1, CMS), and serpentine (Franciscan Formation, California). Results are briefly discussed.

Allton, Judith H.↗
NASA NTRS1989

The oxygen sensitivity/compatibility ranking of several materials by different test methods

Eleven materials were evaluated for oxygen compatibility using the following test methods: heat of combustion (ASTM D 2015), liquid oxygen impact (ASTM D 2512), pneumatic impact (ASTM G 74), gaseous mechanical impact (ASTM G 86), autogenous ignition temperature by pressurized differential scanning calorimeter, and the determination of the 50 percent reaction level in liquid oxygen using silicon carbide as a reaction enhancer. The eleven materials evaluated were: Teflon TFE, Vespel SP-21, Krytox 240AC, Viton PLV5010B, Fluorel E2160, Kel F 81, Fluorogold, Fluorogreen E-600, Rulon A, Garlock 8573, nylon 6/6.

Lockhart, Billy J.↗
NASA NTRS1991

Thermal conductivity of evacuated perlite at low temperatures as a function of load and load history

Perlite, a powdered insulation, is commonly used in large cryogenic storage dewars. When these dewars are thermally cycled, the perlite in the evacuated space between the inner and outer vessels of the dewar experiences a changing mechanical load due to thermal expansion and contraction of the inner vessel. Thermal conductivity data were obtained using a boil-off calorimeter. The apparent thermal conductivity of evacuated perlite increases strongly with applied load. Hysteretic behavior of the conductivity was observed when perlite was subjected to cyclic mechanical loading.

Dube, W. P.↗
NASA NTRS1991

An apparatus for the specific heat measurement of undercooled liquids

This paper describes a drop calorimeter with an electromagnetic levitator that was specifically built for enthalpy measurements of undercooled liquids, including high-melting-point metals. Design diagrams of this device and of a furnace for making a suspended drop are presented together with results of measurements on an aluminum sample.

Ohsaka, K.↗
NASA NTRS1991

Subscale LOX/hydrogen testing with a modular chamber and a swirl coaxial injector

To support basic injector and chamber technology, the response of a modular calorimeter chamber to an injector with swirl coaxial elements was investigated. The tests supported both the Advanced Launch System (ALS) and the Space Shuttle Main Engine programs. Original test plans included chamber pressures up to 2250 psia, the current ALS engine criteria, but hardware limitations forced conditions to be reduced. With four different chamber configurations, a variety of data was obtained with chamber pressures ranging from 1483 psia to 1679 psia and mixture ratios from 5.24 to 6.90. The swirl coaxial injector showed good chamber wall compatibility, despite misaligned elements, and its high performance was independent of fuel. Heating rates and wall temperatures were acceptable and close to predict profiles, and after scaling to a chamber pressure of 2250 psia, heating rates remained acceptable. In addition, a chamber spool made with the vacuum plasma spray process survived hot-fire testing with no detrimental effects.

Elam, Sandra K.↗
NASA NTRS1990

X-ray spectroscopic instrumentation for the 21st century

Several technologies being developed for high resolution X-ray spectroscopy are compared to determine the most suitable applications for each. Nondispersive cryogenic technology is considered by means of devices such as microcalorimeters and superconducting tunnel-junction detectors, and dispersive technologies are represented by crystal diffractors, transmission gratings and reflection gratings. Calorimeters and superconducting tunnel-junction conductors are found to be suitable for high energies while reflection gratings are more effective at lower energies. In general, however, the selected technology depends primarily on the particular implementation. Parameters such as launch capability, constraints, and scientific drivers are the guiding forces for selecting a particular device.

Kahn, Steven M.↗
NASA NTRS1990

A gamma-ray imaging telescope based on liquid xenon

A liquid-xenon time projection chamber (TPC) is discussed in terms of its utility as an imaging telescope for high energy astrophysics. The concept exploits the efficiency of xenon as an ionization and scintillation medium for imaging astrophysical gamma-ray sources. The design fundamentally follows the approach of an ionization calorimeter functioning as a TPC dedicated to 3D tracking. A schematic diagram of the instrument is presented, and the device measures the ionization signals - resulting from gamma-ray interactions with xenon - on collection electrodes. The liquid xenon instrument permits the identification of the direction of the Compton electron and thereby determines the location of the source. The energy region of 1-30 MeV is covered by the instrument, and source localization is possible for the entire range.

Aprile, Elena↗
NASA NTRS1992

Underground muons from the direction of Cygnus X-3

The flux of underground muons from the direction of the binary Cygnus X-3 was measured by the Soudan 2 proton decay detector. This time-projection calorimeter is located at a depth of 2200 m (water equivalent) in northern Minnesota at latitude 48 deg N, longitude 92 deg W. An analysis was then performed that compared both the total observed flux and the observed flux per transit with the number of events expected in the absence of a source. This expected number of events was determined by combining the detector acceptance as a function of time with detector acceptance as a function of the local spatial coordinates. These functions were evaluated by use of off-source events. The direction of Cygnus X-3 was defined as a 2 deg half-angle cone, centered on the nominal source coordinates. This definition is consistent with the expected appearance of a point source in the Soudan 2 detector after consideration of track reconstruction errors, multiple scattering in the rock, and possible systematic effects. Details of the analysis and the results are presented.

Marshak, M. L.↗
NASA NTRS1992

Heat generation during overcharge of Ni/H2 cells

Information is given in viewgraph form on the heat generation during overcharge of nickel hydrogen cells. The heat dissipated during various rates of charge and overcharge was measured, using a radiative type calorimeter. Measurements made during the charging of the cell indicated that the total heat was greatest for C/10 charge, compared with C/2 or C/4. The endothermic to exothermic transition occurred at 1.43 V for C/10 charge, and increased to 1.467 V at C/2 charge. The magnitude of the endothermic heat was only 3.7 percent of the total heat generated during charging. Experimentally measured values were compared against those calculated using a thermoneutral potential of 1.51 V. Although there was general agreement between the calculated and measured values, a significant difference existed in the instantaneous heat values for the initial stages of cell discharge. Heat dissipated during self-discharge appears to depend on the charge rate preceding open circuit stand.

Vaidyanathan, Hari↗
NASA NTRS1990

The NASA cosmic ray program for the 1990's and beyond

The interim report of the 1989 NASA Cosmic Ray Program Working Group is presented. The report summarizes the cosmic ray program for the 1990's, including the recently approved ACE, Astromag, HNC, POEMS, and SAMPEX missions, as well as other key elements of the program. New science themes and candidate missions are identified for the first part of the 21st century, including objectives that might be addressed as part of the Human Exploration Initiative. Among the suggested new thrusts for the 21st century are: an Interstellar Probe into the nearby interstellar medium; a Lunar-Based Calorimeter to measure the cosmic ray composition near 10 exp 16 eV; high-precision element and isotope spectroscopy of ultraheavy elements; and new, more sensitive studies of impulsive solar flare events.

Ahlen, S. P.↗
NASA NTRS1990

Calorimetric determination of thermal parameters for the Li/BrCl in SOCl2 (BCX) chemistry

The heat capacity of a Li-BCX DD-cell was found to be dependent on its state of charge by drop calorimetry measurements. The method of drop calorimetry involves measuring the energy (joules) gained or lost from a sample that is transferred from a bath at temperature A to one at temperature B. The thermoneutral potential is defined as the cell potential where the cell electrochemical reactions are neither exothermic nor endothermic. A Hart scientific calorimeter system, Model No. S77XX, designed for heat conduction calorimetry and drop calorimetry was used. Calorimetric analysis yielded a thermoneutral potential of 4.14 volts and a cell heat capacity dependent on the state of charge.

Darcy, Eric C.↗
NASA NTRS1992

Numerical analysis of the hot-gas-side and coolant-side heat transfer in liquid rocket engine combustors

The objective of this paper are to develop a multidisciplinary computational methodology to predict the hot-gas-side and coolant-side heat transfer and to use it in parametric studies to recommend optimized design of the coolant channels for a regeneratively cooled liquid rocket engine combustor. An integrated numerical model which incorporates CFD for the hot-gas thermal environment, and thermal analysis for the liner and coolant channels, was developed. This integrated CFD/thermal model was validated by comparing predicted heat fluxes with those of hot-firing test and industrial design methods for a 40 k calorimeter thrust chamber and the Space Shuttle Main Engine Main Combustion Chamber. Parametric studies were performed for the Advanced Main Combustion Chamber to find a strategy for a proposed combustion chamber coolant channel design.

Wang, Ten-See↗
NASA NTRS1992

Analysis of film cooling in rocket nozzles

Computational Fluid Dynamics (CFD) programs are customarily used to compute details of a flow field, such as velocity fields or species concentrations. Generally they are not used to determine the resulting conditions at a solid boundary such as wall shear stress or heat flux. However, determination of this information should be within the capability of a CFD code, as the code supposedly contains appropriate models for these wall conditions. Before such predictions from CFD analyses can be accepted, the credibility of the CFD codes upon which they are based must be established. This report details the progress made in constructing a CFD model to predict the heat transfer to the wall in a film cooled rocket nozzle. Specifically, the objective of this work is to use the NASA code FDNS to predict the heat transfer which will occur during the upcoming hot-firing of the Pratt & Whitney 40K subscale nozzle (1Q93). Toward this end, an M = 3 wall jet is considered, and the resulting heat transfer to the wall is computed. The values are compared against experimental data available in Reference 1. Also, FDNS's ability to compute heat flux in a reacting flow will be determined by comparing the code's predictions against calorimeter data from the hot firing of a 40K combustor. The process of modeling the flow of combusting gases through the Pratt & Whitney 40K subscale combustor and nozzle is outlined. What follows in this report is a brief description of the FDNS code, with special emphasis on how it handles solid wall boundary conditions. The test cases and some FDNS solution are presented next, along with comparison to experimental data. The process of modeling the flow through a chamber and a nozzle using the FDNS code will also be outlined.

Woodbury, Keith A.↗
NASA NTRS1993

Performance and heat transfer characteristics of a carbon monoxide/oxygen rocket engine

The combustion and heat transfer characteristics of a carbon monoxide and oxygen rocket engine were evaluated. The test hardware consisted of a calorimeter combustion chamber with a heat sink nozzle and an eighteen element concentric tube injector. Experimental results are given at chamber pressures of 1070 and 3070 kPa, and over a mixture ratio range of 0.3 to 1.0. Experimental C efficiency was between 95 and 96.5 percent. Heat transfer results are discussed both as a function of mixture ratio and axial distance in the chamber. They are also compared to a Nusselt number correlation for fully developed turbulent flow.

Linne, Diane L.↗