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At least 397 records · Page 22

A non-isothermal breakage-damage model for plastic-bonded granular materials incorporating temperature, pressure, and rate dependencies

Plastic-bonded granular materials (PBM) are widely used in industrial sectors, including building construction, abrasive applications, and defense applications such as plastic-bonded explosives. The mechanical behavior of PBM is highly nonlinear, irreversible, rate dependent, and temperature sensitive governed by various micromechanical attributions such as grain crushing and binder damage. This paper presents a thermodynamically consistent, microstructure-informed constitutive model to capture these characteristic behaviors of PBM. Key features of the model include a breakage internal variable to upscale the grain-scale information to the continuum level and to predict grain size evolution under mechanical loading. In addition, a damage internal state variable is introduced to account for the damage, deterioration, and debonding of the binder matrix upon loading. Temperature is taken as a fundamental external state variable to handle non-isothermal loading paths. The proposed model is able to capture with good accuracy several important aspects of the mechanical properties of PBM, such as pressure-dependent elasticity, pressure-dependent yield strength, brittle-to-ductile transition, temperature dependency, and rate dependency in the post-yielding regime. Furthermore, the model is validated against multiple published datasets obtained from confined and unconfined compression tests, covering various PBM compositions, confining pressures, temperatures, and strain rates.

Breakage↗

Overall chilled water system energy consumption modeling and optimization

The emergence of increasingly affordable variable-speed drive technology has changed the approach used to control chilled water systems equipped with these drives. The purpose of this research was to develop an integrated chilled water modeling technique that can determine the optimal system setpoints and estimate the energy saving potential of chiller system. The chiller system equipped with Variable Frequency Drives (VFDs) on cooling tower fans and condenser water pumps. To accomplish the objective, physical component models of the centrifugal chiller, cooling tower and condenser water pump were established with the goal of incorporating the system’s condenser water flow rate and cooling tower fan speeds as optimization variables. Furthermore, a cooling load prediction algorithm was developed using a multiple non-linear regression model to approximate the building’s cooling load subject to a range of environmental conditions. The inputs and outputs of the individual component models were linked to estimate how adjusting the cooling tower fan and condenser water pump speed would influence the system’s comprehensive performance. Here, the overall system model was then optimized using a generalized reduced gradient optimization algorithm to determine the potential energy savings through speed control with VFDs and to ascertain a control logic strategy for the building automation system to operate the heating and cooling system. A case-study was performed on a single chiller system at a museum and the model was calibrated according to logged data collected over four months. Results showed that for the system analyzed, the energy saving of optimizing the cooling tower fan system was found to be 12–15%, while the energy saving potential of optimizing the condenser water pump with the cooling tower fan was negligible. Additionally, comparing different cooling tower fan control strategies showed that a wet-bulb approach-based cooling tower control strategy was shown to have the highest correlation to the optimized fan speed with an R 2 of 0.924.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Performance Evaluation of AG-1 FC HEPA Filters and Medium in Nuclear Complex Facilities - 20434

High Efficiency Particulate Air (HEPA) filters are credited as the final barrier against the release of radioactive aerosol contamination in nearly every operating U. S. Department of Energy (DOE) and National Nuclear Security Agency (NNSA) nuclear facility. The Institute for Clean Energy Technology (ICET) at Mississippi State University maintains a research program that studies various aspects of these components of containment systems and seeks to answer key questions from across the industry. This programmatic overview will include results from recent and ongoing studies, including a study on filter design and performance envelope, degradation due to aging or fatigue, fire event impact on HEPA filters, and accelerated aging of medium and component parts. ICET has completed a study helping to define the threshold for combined elevated temperature and relative humidity resistance of separator style and separator-less style HEPA filters that are used in DOE complexes. The study provides experimental data that considers elevated temperature, elevated relative humidity (RH), and target differential pressure (dP) in an attempt to gain a better understanding or more comprehensive insight into the operating envelope of different configurations of ASME (American Society for Mechanical Engineers) AG-1 Section FC filters. Test variables including air temperature ranges of 48.88 deg. C, 54.44 deg. C, or 60 deg. C (120, 130, or 140 deg. F); air RH ranges including 60-70%, 80%, or 90+% with initial filter dP of either 497.68 Pa, 746.52 Pa, or 995.36 Pa (2 inches water column (in. w. c.), 3 in. w. c., or 4 in. w. c.) included for full bracketing of each set of conditions. A study examining the effects of aging and fatigue on nuclear grade HEPA filters and medium elucidates the physical properties of media along with testing of new and aged ASME AG-1 HEPA filters. In addition to performing autopsies of the tested, aged filters to help better understand the service life of their performance, newly designed accelerated aging chambers allow new medium to undergo accelerated aging and exposure treatments. Evaluation of degradation in physical properties and functionality requires a high population of aged filters of different ages, designs, manufacturers, and operational histories. The limited availability of this population and the impropriety of looking solely at formulations and components from past years requires experimental design that will provide foresight into future filter performance. This undertaking therefore involves not only properties analysis of aged medium from different operational histories, ages, designs, and manufacturers, but also prescience in analytical goals via accelerated aging studies of newly manufactured media. A more complete understanding of the mechanisms of degradation from past formulations as well as current and future formulations is possible. Accelerated Aging of newly manufactured media utilizes exposure treatments based on the Arrhenius equation to artificially age medium and therefore glimpse into the future. Evaluation of current media properties This testing allows for the comparison of performance and durability of new filters under upset or design basis conditions with aged filters that were in service under ambient conditions and other aged filters retained in storage. Susceptibility of HEPA filters to the effects of combustion byproducts, heat, and water is also being studied in an attempt to gain understanding on the prevention of filter failures during fire events in nuclear facilities. ICET seeks to determine the effect of filter performance due to smoke loading using characterized smoke from variable fuel compositions, geometries, and loads; the smoke capacity of various filters with different burning conditions, heat release rates and transport, as well as mass transport from the air stream will be studied in low flow containment systems. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Deformation and fracture characteristics of zirconium plate produced via ultrasonic additive manufacturing

Abstract The microstructural evolution, deformation modes, and fracture mechanisms of zirconium plate produced using ultrasonic additive manufacturing (UAM) are presented. In addition to conventional tensile testing techniques, digital image correlation captured highly variable strain accumulation in specimens loaded perpendicular or parallel to the build height (Z). When tested in parallel to Z, delamination at prior foil/foil interfaces creates strain localization noticeable in strain rate maps, whereas specimens loaded perpendicular to Z illustrate conventional strain hardening until necking accelerates delamination. Although bond strengths are statistically and spatially variable, in situ electron backscattering diffraction tests illustrate the ability for grains near interfaces to accommodate strain with twinning and slip modes consistent with conventionally produced zirconium alloys. Finally, mixtures of ductile and delamination-induced fracture highlight the interface-driven failure modes of UAM zirconium plate in the as-built condition. Graphic abstract

36 MATERIALS SCIENCE↗

Carbon sequestration and nitrogen and phosphorus accumulation in a freshwater, estuarine marsh: Effects of microtopography and nutrient loads

Wetlands are widely recognized as nutrient sinks for their ability to remove nutrients in runoff and retain them in soils. This is a valuable service, especially in agricultural watersheds, making nutrient removal one of the main goals in many wetland creation and restoration projects. However, incorporating nutrient management considerations requires site-level assessments, the scale at which wetland creation and restoration occur. Here we studied how carbon (C) sequestration, and nitrogen (N) and phosphorus (P) accumulation vary at different microtopographic levels and locations within a freshwater, estuarine marsh on the coast of Lake Erie. We further explored links between C sequestration, and N and P accumulation in recent years, and orthophosphate ($PO_{4}^{3-}$), ammonium ($NH_{4}^{+}$), and nitrate ($NO_{3}^{-}$) concentrations and loads. The rates of C sequestration and N accumulation were relatively lower at spots of intermediate depth and locations closer to the wetland’s main channel. P accumulation was highest at deep spots but did not differ among locations based on distance from the channel. Empirical models showed that nitrate load is the most important variable explaining the variability in C, N, and P sequestration/accumulation (r2 = 0.57, 0.61, and 0.32, respectively) and that the relationship between inorganic nutrient loads and accumulation was negative. Our findings suggest that including microtopographic relief features in wetland creation and design, especially deeper spots, is critical to enhancing wetland ecosystems’ C, N, and P sinking capacity. Also, that upstream nitrate management should be a priority to increase benefits from C sequestration and long-term N and P accumulation.

54 ENVIRONMENTAL SCIENCES↗

Bioinspired oxidation of benzyl alcohol: The role of environment and nuclearity of the catalyst evaluated by multivariate analysis

Inspired by copper-containing enzymes such as galactose oxidase and catechol oxidase, in which distinct coordination environments and nuclearities lead to specific catalytic activities, we summarize here the catalytic properties of dinuclear and mononuclear copper species towards benzyl alcohol oxidation using a multivariate statistical approach. Here, the new dinuclear [Cu 2 (μ-L 1 )(μ-pz)] 2+ (1) is compared against the mononuclear [CuL 2 Cl] (2), where (L 1 ) - and (L 2 ) - are the respective deprotonated forms of 2,6-bis((bis(pyridin-2-ylmethyl)amino)methyl)-4-methylphenol, and 3-((bis(pyridin-2-ylmethyl)amino)methyl)-2-hydroxy-5-methylbenzaldehyde and (pz) - is a pyrazolato bridge. Copper(II) perchlorate (CP) is used as control. The catalytic oxidation of benzyl alcohol is pursued, aiming to assess the role of the ligand environment and nuclearity. The multivariate statistical approach allows for the search of optimal catalytic conditions, considering variables such as catalyst load, hydrogen peroxide load, and time. Species 1, 2 and CP promoted selective production of benzaldehyde at different yields, with only negligible amounts of benzoic acid. Under normalized conditions, 2 showed superior catalytic activity. This species is 3.5-fold more active than the monometallic control CP, and points out to the need for an efficient ligand framework. Species 2 is 6-fold more active than the dinuclear 1, and indicates the favored nuclearity for the conversion of alcohols into aldehydes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Stable and Recyclable Photocatalysts of CsPbBr 3 @MSNs Nanocomposites for Photoinduced Electron Transfer RAFT Polymerization

All-inorganic metal halide perovskite CsPbX 3 (X = Cl, Br, I) nanocrystals (NCs) have demonstrated attractive optoelectronic characteristics. However, their photocatalytic properties are limited by their poor stability and easy recombination of photogenerated carriers. Herein, we introduced a CsPbBr 3 @MSNs nanocomposite (CsPbBr 3 NCs embedded in dendritic mesoporous silica nanospheres (MSNs)) as photocatalysts for photoinduced electron transfer reversible addition–fragmentation chain transfer (PET-RAFT) polymerization. In this study, the CsPbBr 3 nanocrystals (~8.1 nm; PLQY of 62 ± 2.1%) were embedded in dendritic MSNs using a nanoconfinement strategy. PET-RAFT polymerization was successfully initiated using the CsPbBr 3 @MSNs nanocomposite as the photocatalyst. Reaction variables, such as catalyst loading, monomer composition, and excitation light wavelengths, were varied to yield polymers with the desired control of molecular weight and dispersity as well as block copolymers with high chain-end fidelity. In addition, the perovskite-based photocatalysts could be readily separated and purified, which allowed effective and rapid recycling of the nanocomposites for multiple polymerization cycles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

GRAF-Plan for Vietnam

Evaluates the reserve requirements for power system balancing areas based on variability and uncertainty of load as well as wind and solar generation scenarios. The tool uses minute‐by‐minute site‐specific generation and load information, as well as information from generation and load forecasting algorithms used in the balancing areas. The Balancing‐Plan Tool can be used directly by utility planners and operators to aid in the integration of intermittent renewable resources. The tool provides reserve requirements of various kinds, such as day‐ahead, load following and regulation, as well as estimates the capacity of the generation fleet to provide the require reserves.

Campbell, Allison↗

TRIPOLI-4 neutronics calculations for IAEA-CRP benchmark of CEFR start-up tests using new libraries JEFF-3.3 and ENDF/B-VIII

Sodium-cooled Fast Reactors (SFR) are one of the promising Generation IV fast reactors. The China Experimental Fast Reactor (CEFR) is a 65 MWth pool-type SFR with a high neutron leakage core using high enriched uranium oxide fuel. The CEFR start-up tests in 2010 consist of series of neutronics experiments. Essential experimental data are available from the 2018 IAEA-CEFR-CRP benchmark document and useful for the validation of neutron transport codes and nuclear data libraries. The TRIPOLI-4 Monte Carlo transport code is a general-purpose neutronics code using continuous-energy nuclear data libraries. It has a rich validation database covering different computational and experimental benchmark data sets to assure the accuracy and credibility of numerical studies. Previous TRIPOLI-4 SFR core physics calculations used mainly MOX fuels. SFR control rod worth studies with TRIPOLI-4 were mainly on big-size cores. To test the modeling capability of TRIPOLI-4 on fuel loading patterns and on variable control rods positions for SFRs and to check recent nuclear data libraries, it is interesting to investigate the CEFR start-up tests in this work, including core states from subcritical to supercritical, control rods and rod group worth, point kinetics parameters, and radial foil activation measurements. TRIPOLI-4 calculation results using new data libraries JEFF-3.3, ENDF/B-VIII, and those of ENDF/B-VII.1 for different CEFR core states are reported here. By means of different options of TRIPOLI-4, control-rod SAs reactivity worth, point kinetics parameters, and radial {sup 237}Np(n,f) fission rate distribution were successfully evaluated. Both ENDF/B-VIII and JEFF-3.3 nuclear data libraries provided reliable results with a difference of 170 +/- 11 pcm in k{sub eff}.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Simulink Model of a New Energy EVG-005 5kW Hydropower Turbine

Simulink model for a New Energy 5kW hydropower turbine. ADCP data ("ds_streamwise_7_13.nc") and DC voltage, DC current, and rotor rotation observed from the New Energy EVG-005 Current Energy Converter (CEC) ("electrical_7_13_10ohms.nc") were collected at the Tanana River Test Site (TRTS) near Nenana Alaska. - Data was collected on July 13th, 2023 with a constant 10 ohms resistance applied with a DC load bank. - Simulink model is meant to resemble the electrical setup at the TRTS. - Model is initialized by running the "NewEnergy_2023_10hz.m" Matlab script. Then the Simulink model ("New_Energy_Model_PMSM.slx") can be run. - Results are processed with the "NewEnergy_2023_processing.m" Matlab code. The Matlab results are also saved in the "New_Energy_7_13_model_validation_results.mat" Matlab file. This can be directly loaded into the Matlab Workspace using the "Load()" command. - The timetable variables "electrical_model_downsampled" is the model results and the "electrical_limited" is the experimental data from the TRTS.

16 TIDAL AND WAVE POWER↗

Net-Zero Carbon Microgrids

The microgrid concept has been effective in creating aggregations of distributed energy resources—generation, storage and loads—for resiliency, in the form of energy security. The success of microgrids in bringing energy security to a wide range of customers—from individual residences to commercial and industrial installations to military bases—has been exemplified during power disruptions and extended outages due to extreme weather events, cybersecurity attacks, and equipment failures. Now microgrids have an opportunity to meet the challenges of climate change and contribute to a carbon-free power delivery system. The transition to net-zero starts within microgrids themselves. In fact, today’s microgrids are largely dominated by generators using fossil fuels, natural gas and diesel, with high greenhouse gas emissions. In short, the transition to net-zero means replacing fossil fueled generators with renewable generation in microgrids. This transition is extended by including new dispatchable generation technologies that are 100% carbon-free and that offer additional advantage of a more-dependable and sustainable source of energy and power. Basically, the decarbonization of microgrids requires three elements: 1) maximizing generation from renewable energy resources, 2) management of storage and flexible loads to balance the variability and intermittency of renewable energy resources, and 3) introducing new clean power sources, including hydrogen-based generation and small modular reactors. This report affirms a need for specific focus by governmental agencies at national, regional, and local levels to establish technology, policy, and investment in this area. The intention of the Net-Zero Microgrid (NZM) Program is to inform these constituencies with cross-cutting research and tools for the reduction of GHG in microgrids – to net-zero in the near term eventually to zero in the longer term. The NZM Program is committed to achieving decarbonization for resiliency and for providing clean energy at the local or distribution level, from remote communities to underserved communities, and large industrial and military facilities. The NZM Planning and Design Platform is a core tool to be developed as an early deliverable of the NZM Program because only a fully integrated microgrid-design approach will ensure maximum carbon reduction in energy production.

13 HYDRO ENERGY↗

Energy Performance of Awnings in Residential Buildings

Residential buildings consume approximately 20% of the total primary energy in the United States. More than 50% of this energy is spent in heating, cooling, and lighting these buildings. Solar heat gain is one of the largest and most variable sources of cooling load in these buildings, while it can also provide passive heating during the heating season. Shading devices can be used to control the amount of solar heat gain in buildings. Various studies have considered how different shading devices and their applications affect energy and occupant comfort in buildings. However, most of these studies were limited to planar shading devices such as roller shades, cellular shades, and blinds. Although some theoretical studies have been performed for awnings, the energy performance of awnings has rarely been studied via either energy simulation or field measurement. In this study, the authors evaluated the energy performance of typical operable awnings by using field data, aided by simulation. Awnings were installed on a real house, and measurements were performed to evaluate the thermal performance of the awning. The measured data were then used to develop a calibrated energy model and evaluate the awning’s energy performance. The annual simulation of the building model used showed that awnings left in the closed position from April to September can reduce annual HVAC energy consumption by 15% compared with a building without any shades. The validated model was used in US Department of Energy prototype buildings to evaluate awning energy performance in climate zones 1A through 4B via energy simulation. For these prototype buildings, energy savings of up to 1,034 kWh were achieved for a building with a conditioned floor area of 2,377 ft 2 .

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A Guide for Improved Resource Adequacy Assessments in Evolving Power Systems: Institutional and Technical Dimensions

This paper identifies and evaluates issues in traditional resource adequacy (RA) assessment practices, and how adjusting these practices may affect and depend on existing institutional arrangements for planning and procurement. The paper proposes a technical-institutional roadmap that would allow regulators in vertically-integrated jurisdictions and system planners and operators in restructured jurisdictions to revise RA practices across a range of components. First, we compile a critical review of current RA assessment practices based on (1) interviews with RA practitioners and (2) a review of recent technical literature. We find that (i) RA may need to expand beyond capacity adequacy to ensure energy adequacy – relevant for energy-limited resources such as storage – and potentially some form of ancillary service adequacy (e.g. enough ramping-up and ramping-down capability in the system); (ii) chronological hourly simulations for all hours in the year are the current best practice; (iii) metrics and models used do not reflect economic criteria in system operation and loss of load; and (iv) there is a need to improve representation of weather dependencies and weather data. Second, we review planning and RA reports for several private and public entities that plan generation and/or transmission infrastructure in the continental U.S. to look for existing practices involving resilience assessments. We find no systematic treatment of the costs of extreme weather and other hazards, the benefits of resilience, and resilience metrics in planning analyses and no systematic treatment of resilience metrics, methods, and outcomes for resource adequacy purposes. Third, we create a technical framework for probabilistic RA assessment and use it to study how key choices about how to model power system operations affect the values that are obtained for RA metrics. We find that (i) non-economic dispatch schemes that ignore economic objectives can lead to accurate RA assessments when coordinated with detailed operational strategies; (ii) multi-year data is critical to capture a wide variety of system conditions; (iii) not incorporating transmission limits into RA assessment could lead to substantial underestimation of traditional “expected value” RA metrics; and (iv) new RA metrics that capture event-specific shortfall characteristics should be used as supplements to traditional metrics. Finally, we examine RA assessments and use this information to propose a guide of evolving industry standards for resource adequacy assessments in resource planning and transmission planning. We report minimum, best, and frontier practices for temporal resolution of assessments, metrics and targets, weather data, load forecasting, characterization of variable renewable resources, characterization of transmission and market transactions, RA modeling and integration with planning processes, and capacity accreditation.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Wing optimization for space shuttle orbiter vehicles

The results were presented of a parametric study performed to determine the optimum wing geometry for a proposed space shuttle orbiter. The results of the study establish the minimum weight wing for a series of wing-fuselage combinations subject to constraints on aerodynamic heating, wing trailing edge sweep, and wing over-hang. The study consists of a generalized design evaluation which has the flexibility of arbitrarily varying those wing parameters which influence the vehicle system design and its performance. The study is structured to allow inputs of aerodynamic, weight, aerothermal, structural and material data in a general form so that the influence of these parameters on the design optimization process can be isolated and identified. This procedure displays the sensitivity of the system design of variations in wing geometry. The parameters of interest are varied in a prescribed fashion on a selected fuselage and the effect on the total vehicle weight is determined. The primary variables investigated are: wing loading, aspect ratio, leading edge sweep, thickness ratio, and taper ratio.

Surber, T. E.↗

Compiled data on the vascular aquatic plant program, 1975 - 1977

The performance of a single cell, facultative sewage lagoon was significantly improved with the introduction of vascular aquatic plants. Water hyacinth (Eichhornia crassipes) was the dominant plant from April to November; duckweed (Lemna spp.) and (Spirodela spp.) flourished from December to March. This 2 ha lagoon received approximately 475 cu m/day of untreated sewage and has a variable COD sub 5 loading rate of 22-30 kg/ha/day. During the first 14 months of operation with aquatic plants, the average influent BOD sub 5 was reduced by 95% from 110 mg/l to an average of 5 mg/l in the effluent. The average influent suspended solids were reduced by 90% from 97 mg/l to 10 mg/l in the effluent. Significant reductions in nitrogen and phosphorus were effected. The monthly kjeldahl nitrogen for influent and effluent averaged 12.0 and 3.4 mg/l, respectively, a reduction of 72%. The total phosphorus was reduced on an average of 56% from 3.7 mg/l influent to 1.6 mg/l effluent.

Wolverton, B. C.↗

Finite-element analysis of crack growth under monotonic and cyclic loading

An elastic-plastic (incremental) finite-element analysis, in conjunction with a crack-growth criterion, was used to study crack-growth behavior under monotonic and cyclic loading. The crack-growth criterion was based on crack-tip strain. Whenever the crack-tip strain equals or exceeds a critical strain value, the crack grows. The effects of element-mesh size, critical strain, strain hardening, and specimen type (tension or bending) on crack growth under monotonic loading were investigated. Crack growth under cyclic loading (constant amplitude and simple variable amplitude) were also studied. A combined hardening theory, which incorporates features of both isotropic and kinematic hardening under cyclic loading, was also developed for smooth yield surfaces and was used in the analysis.

Newman, J. C., Jr.↗

Acoustic test and analyses of three advanced turboprop models

Results of acoustic tests of three 62.2 cm (24.5 inch) diameter models of the prop-fan (a small diameter, highly loaded. Multi-bladed variable pitch advanced turboprop) are presented. Results show that there is little difference in the noise produced by unswept and slightly swept designs. However, the model designed for noise reduction produces substantially less noise at test conditions simulating 0.8 Mach number cruise speed or at conditions simulating takeoff and landing. In the near field at cruise conditions the acoustically designed. In the far field at takeoff and landing conditions the acoustically designed model is 5 db quieter than unswept or slightly swept designs. Correlation between noise measurement and theoretical predictions as well as comparisons between measured and predicted acoustic pressure pulses generated by the prop-fan blades are discussed. The general characteristics of the pulses are predicted. Shadowgraph measurements were obtained which showed the location of bow and trailing waves.

Brooks, B. M.↗

Acoustic measurements of three Prop-Fan models

Results of NASA sponsored acoustic tests of three 2 ft. diameter models of the Prop-Fan (a small diameter, highly loaded, many-bladed variable pitch advanced turboprop) are presented. The highly swept model designed for noise reduction produces substantially less near field noise at simulated 0.8 Mach number cruise conditions than the unswept or slightly swept models. It also produces less far field noise at conditions simulating takeoff and landing. The noise reduction mechanism is discussed. Correlation between harmonic noise measurements and theoretical predictions and between measured and predicted acoustic pressure pulses is good. Shadowgraph measurements which show the location of blade associated wave patterns were obtained. Predicted and measured wave locations show good general agreement. Full scale near and far field noise is predicted.

Brooks, B. M.↗