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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and product transport, catalyst siting, catalyst accessibility, catalyst stability, catalyst activity, co-catalyst proximity, composition of the chemical environment at and beyond the catalytic active site, chemical intermediate and transition-state conformations, thermodynamic affinity of molecular guests for MOF interior sites, framework charge and density of charge-compensating ions, pore hydrophobicity/hydrophilicity, pore and channel rigidity vs. flexibility, and other features and properties. Collectively and individually, these properties help define overall catalyst functional behaviour. Here, this review focuses on how porous, catalyst-containing MOFs capitalize on molecular-scale confinement, containment, isolation, environment modulation, energy delivery, and mobility to accomplish desired chemical transformations with potentially superior selectivity or other efficacy, especially in comparison to catalysts in homogeneous solution environments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Diffusion of Brønsted acidic dopants in conjugated polymers

Many semiconductor devices (e.g., light emitting diodes and photovoltaics) utilize heterojunctions of doped and undoped layers or depend on gradients of electronic doping to control charge transport. Understanding of the formation and stability of gradients in doping requires an understanding of diffusion of dopants and the complex changes in polymer properties that arise during doping. Conjugated polymers can be electrically doped by strong acids, but the details of the reaction mechanism and subsequent stability are not understood. Here, we show a clear kinetic isotope effect in the doping of thin films of poly(3-hexylthiophene) (P3HT) by bis(trifluoromethane)sulfonimide (HTFSI) from solution indicating that this doping process is limited by proton transfer to the polymer. Complementary X-ray photoelectron spectroscopy and dynamic secondary ion mass spectrometry (DSIMS) depth profiling of dopant concentrations show definitive evidence of dopant enrichment at the P3HT surface. These surface-limited concentration profiles suggest that diffusivity of dopants vary inversely with dopant concentration due to doping-induced changes to the structure of the conjugated polymer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Magneto-optical study of Nb thin films for superconducting qubits

Abstract Among the recognized sources of decoherence in superconducting qubits, the spatial inhomogeneity of the superconducting state and the possible presence of magnetic-flux vortices remain comparatively underexplored. Niobium is commonly used as a structural material in transmon qubits that host Josephson junctions, and excess dissipation anywhere in the transmon can become a bottleneck that limits overall quantum performance. The metal/substrate interfacial layer may simultaneously host pair-breaking loss channels (e.g. two-level systems) and control thermal transport, thereby affecting dissipation and temperature stability. Here, we use quantitative magneto-optical imaging of the magnetic-flux distribution to characterize the homogeneity of the superconducting state and the critical current density, j c , in niobium films fabricated under different sputtering conditions. The imaging reveals distinct flux-penetration regimes, ranging from a nearly ideal Bean critical state to strongly nonuniform thermo-magnetic dendritic avalanches. By fitting the measured magnetic-induction profiles, we extract j c and try to correlate it with film physical properties and with measured qubit internal quality factors. Our results indicate that the Nb/Si interlayer can be a significant contributor to decoherence and should be considered an important factor that must be optimized.

Datta, Amlan [Ames National Laboratory; Iowa State↗
DOE OSTI2025

Altermagnetic behavior in OsO 2 : Parallels with RuO 2

We investigate and compare the electronic structure of OsO 2 with the extensively studied RuO 2 . Calculations show that OsO 2 exhibits antiferromagnetism and spin splitting driven by crystal symmetry, a characteristic of altermagnetism and similar to RuO 2 . Examination of the Fermi surface, with and without spin-orbit coupling, reveals that OsO 2 has lower Fermi group velocities compared to RuO 2 , suggesting limited charge carrier mobility in OsO 2 . While this characteristic may constrain its performance in high-speed electronic transport applications, it may also enhance stability for spin-based information storage in spintronics. Additionally, comparison of the vibrational properties of these rutile oxide systems demonstrates dynamical stability, typical mass dependent behaviors, and favorable agreement with measured Raman data. The calculated phonon density of states for RuO 2 also agrees with our neutron scattering data. These observations substantiate the implications of the electronic and vibrational behaviors in OsO 2 and RuO 2 , encouraging further investigation of their potential for emerging technological applications.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Per- and polyfluoroalkyl substances (PFAS) in fish collected from the Rio Grande and reservoirs in northern New Mexico

Per- and polyfluoroalkyl substances (PFAS) are a group of industrial and commercial chemicals widely used throughout the world due to their beneficial chemical properties. Because of their widespread use, their chemical stability, and their ability to be transported over long distances through atmospheric deposition and movement through waterways, PFAS are found throughout most aquatic ecosystems; yet large sampling gaps exist among reservoir and river ecosystems in the desert southwest of the United States. In this study, we examine PFAS concentrations in the tissue of fish (catfish [channel and blue], common carp, smallmouth bass, northern pike, walleye, white crappie and white sucker) collected in northern New Mexico, including examining PFAS composition and concentration relative to trophic level distribution. We collected fish from two man-made reservoirs and from the Rio Grande. We then collected muscle and liver tissues from fish specimens, which were screened for 39 PFAS compounds. We detected PFAS compounds in most fish tissue sampled, including the biomagnification of PFAS compounds within liver samples, with PFOS concentrations ranged from 1.13 to 350.1 (64.4 average) times higher in the liver samples compared to muscle samples. Most PFAS concentrations within muscle samples were within the range of atmospheric transportation previously reported and average tissue concentrations of PFAS were calculated to be 2.02 ± 1.81 ng g -1 . Using stable isotopes as a predictor of trophic-foraging exposure and PFAS concentrations, we noted a correlation between enriched δ 15 N values, which had higher perfluorodecanoic acid concentrations.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1972

Night visual approaches: Pilot performance with and without a head-up display

Simulated night visual approaches were flown into two airports with and without a head up display (HUD) in a transport aircraft. The HUD featured pitch stabilized vertical scales which displayed the glide slope angle to the runway aim point and a horizontal bar which aided the pilot in his control of the aircraft flight path angle. One airport was located on flat terrain with numerous foreground lights, the second airport had no foreground lights and the terrain sloped up behind the airport. With the HUD glide slope tracking precision was equally good for either runway. With no HUD glide slope tracking was about three times worse with the flat airport and about eight times worse with the airport with no foreground lights and up-sloping terrain beyond the runway.

Palmer, E. A.↗
NASA NTRS1973

Initial flight and simulator evaluation of a head up display for standard and noise abatement visual approaches

A preliminary assessment was made of the adequacy of a simple head up display (HUD) for providing vertical guidance for flying noise abatement and standard visual approaches in a jet transport. The HUD featured gyro-stabilized approach angle scales which display the angle of declination to any point on the ground and a horizontal flight path bar which aids the pilot in his control of the aircraft flight path angle. Thirty-three standard and noise abatement approaches were flown in a Boeing 747 aircraft equipped with a head up display. The HUD was also simulated in a research simulator. The simulator was used to familiarize the pilots with the display and to determine the most suitable way to use the HUD for making high capture noise abatement approaches. Preliminary flight and simulator data are presented and problem areas that require further investigation are identified.

Bourquin, K.↗
NASA NTRS1981

Heat pipe solar receiver with thermal energy storage

An HPSR Stirling engine generator system featuring latent heat thermal energy storge, excellent thermal stability and self regulating, effective thermal transport at low system delta T is described. The system was supported by component technology testing of heat pipes and of thermal storage and energy transport models which define the expected performance of the system. Preliminary and detailed design efforts were completed and manufacturing of HPSR components has begun.

Zimmerman, W. F.↗
NASA NTRS1978

Advanced composite stabilizer for Boeing 737 aircraft

Activities related to development of an advanced composites stabilizer for the Boeing 737 commercial transport are reported. Activities include discussion of criteria and objectives, design loads, the fatigue spectrum definition to be used for all spectrum fatigue testing, fatigue analysis, manufacturing producibility studies, the ancillary test program, quality assurance, and manufacturing development.

Source record↗
NASA NTRS1978

Advanced composite stabilizer for Boeing 737 aircraft

Activities related to development of an advanced composites stabilizer for the Boeing 737 commercial transport are reported. Activities include discussion of the design and weight status, stiffness requirements, the finite element model, test programs, quality assurance, and manufacturing producibility studies. Design details of the graphite/epoxy components are virtually complete. Emphasis is placed on the metal and fiberglass trailing edge components. The bending and torsional stiffness properties are satisfactory for both stability/control and for flutter requirements. The finite element model input geometry is revised to reflect the latest changes to production drawings.

Source record↗
NASA NTRS1991

Optimal discrete-time dynamic output-feedback design - A w-domain approach

An alternative method for optimal digital control design is described in this paper. The method is based on the usage of the w-transform and has many attractive design features. One of these is its immediate connection with frequency loop-shaping techniques that are now popular and effective for multivariable control synthesis in continuous-time domain. Furthermore, any design algorithms originally developed for continuous-time systems can now be immediately extended to the discrete-time domain. The main results presented in this paper are the exact problem formulation and solution of an optimal discrete-time dynamic output-feedback design in the w-domain involving a quadratic performance index to random disturbances. In addition, necessary conditions for optimality are obtained for the numerical solution of the optimal output-feedback compensator design. A numerical example is presented illustrating its application to the design of a low-order dynamic compensator in a stability augmentation system of a commercial transport.

Ha, Cheolkeun↗
NASA NTRS1999

Point Defect Distributions in ZnSe Crystals: Effects of Gravity Vector Orientation during Physical Vapor Transport Growth

ZnSe crystals were grown by the physical vapor transport technique under horizontal and vertical (stabilized and destabilized) configurations. Secondary ion mass spectroscopy and photoluminescence measurements were performed on the ZnSe samples to map the distributions of [Si], [Fe], [Cu], [Al] and [Li or Na] impurities as well as Zn vacancy, [V(zn)]. The annealings of ZnSe under controlled Zn pressures were studied to correlate the measured photoluminescence emission intensity to the equilibrium Zn partial pressure. In the horizontal grown crystals the segregations of [Si], [Fe], [Al] and [V(zn)] along the gravity vector direction were observed whereas in the vertically stabilized grown crystal the segregations of these point defects were radially symmetrical. No apparent pattern was observed on the measured distributions in the vertically destabilized grown crystal. The observed segregations in the three growth configurations were interpreted based on the possible buoyancy-driven convection in the vapor phase.

Su, Ching-Hua↗
NASA NTRS1999

Point Defect Distributions in ZnSe Crystals: Effects of Gravity Vector Orientation During Physical Vapor Transport Growth

ZnSe crystals were grown by the physical vapor transport technique under horizontal and vertical (stabilized and destabilized) configurations. Secondary ion mass spectroscopy and photoluminescence measurements were performed on the grown ZnSe samples to map the distributions of [Si], [Fe], [Cu], [Al] and [Li or Na] impurities as well as Zn vacancy, [V (sub Zn)]. Annealings of ZnSe under controlled Zn pressures were studied to correlate the measured photoluminescence emission intensity to the equilibrium Zn partial pressure. In the horizontal grown crystals the segregations of [Si], [Fe], [Al] and [V (sub Zn)] were observed along the gravity vector direction whereas in the vertically stabilized grown crystal the segregation of these point defects was radially symmetrical. No apparent pattern was observed on the measured distributions in the vertically destabilized grown crystal. The observed segregations in the three growth configurations were interpreted based on the possible buoyancy-driven convection in the vapor phase.

Su, Ching-Hua↗
NASA NTRS2001

Constraints on Variability of Brightness and Surface Magnetism on Time Scales of Decades to Centuries in the Sun and Sun-Like Stars: A Source of Potential Terrestrial Climate Variability

These four points summarize our work to date. (1) Conciliation of solar and stellar photometric variability. Previous research by us and colleagues suggested that the Sun might at present be showing unusually low photometric variability compared to other sun-like stars. Those early results would question the suitability of the technique of using sun-like stars as proxies for solar irradiance change on time scales of decades to centuries. However, our results indicate the contrary: the Sun's observed short-term (seasonal) and longterm (year-to-year) brightness variations closely agree with observed brightness variations in stars of similar mass and age. (2) We have demonstrated an inverse correlation between the global temperature of the terrestrial lower troposphere, inferred from the NASA Microwave Sounding Unit (MSU) radiometers, and the total area of the Sun covered by coronal holes from January 1979 to present (up to May 2000). Variable fluxes of either solar charged particles or cosmic rays, or both, may influence the terrestrial tropospheric temperature. The geographical pattern of the correlation is consistent with our interpretation of an extra-terrestrial charged particle forcing. (3) Possible climate mechanism amplifying the impact of solar ultraviolet irradiance variations. The key points of our proposed climate hypersensitivity mechanism are: (a) The Sun is more variable in the UV (ultraviolet) than in the visible. However, the increased UV irradiance is mainly absorbed in the lower stratosphere/upper troposphere rather than at the surface. (b) Absorption in the stratosphere raises the temperature moderately around the vicinity of the tropopause, and tends to stabilize the atmosphere against vertical convective/diffusive transport, thus decreasing the flux of heat and moisture carried upward from surface. (c) The decrease in the upward convection of heat and moisture tends to raise the surface temperature because a drier upper atmosphere becomes less cloudy, which in turn allows more solar radiation to reach the Earth's surface. (4) Natural variability in an ocean-atmosphere climate model. We use a 14-region, 6-layer, global thermo-hydrodynamic ocean-atmosphere model to study natural climate variability. All the numerical experiments were performed with no change in the prescribed external boundary conditions (except for the seasonal cycle of the Sun's tilt angle). Therefore, the observed inter-annual variability is of an internal kind. The model results are helpful toward the understanding of the role of nonlinearity in climate change. We have demonstrated a range of possible climate behaviors using our newly developed ocean-atmosphere model. These include climate configurations with no interannual variability, with multi-year periodicities, with continuous chaos, or with chaotically occuring transitions between two discrete substrates. These possible modes of climate behavior are all possible for the real climate, as well as the model. We have shown that small temporary climate influences can trigger shifts both in the mean climate, and among these different types of behavior. Such shifts are not only theoretically plausible, as shown here and elsewhere; they are omnipresent in the climate record on time scales from several years to the age of the Earth. This has two apparently opposite implications for the possibility of anthropogenic global warming. First, any warming which might occur as a result of human influence would be only a fraction of the small-to-large unpredictable natural changes and changes which result from other external causes. On the other hand, small temporary influences such as human influence do have the potential of causing large permanent shifts in mean climate and interannual variability.

Baliunas, Sallie L.↗
NASA NTRS2002

An Experimental Investigation of Incompressible Richtmyer-Meshkov Instability

Richtmyer-Meshkov (RM) instability occurs when two different density fluids are impulsively accelerated in the direction normal to their nearly planar interface. The instability causes small perturbations on the interface to grow and eventually become a turbulent flow. It is closely related to Rayleigh-Taylor instability, which is the instability of a planar interface undergoing constant acceleration, such as caused by the suspension of a heavy fluid over a lighter one in the earth's gravitational field. Like the well-known Kelvin-Helmholtz instability, RM instability is a fundamental hydrodynamic instability which exhibits many of the nonlinear complexities that transform simple initial conditions into a complex turbulent flow. Furthermore, the simplicity of RM instability (in that it requires very few defining parameters), and the fact that it can be generated in a closed container, makes it an excellent test bed to study nonlinear stability theory as well as turbulent transport in a heterogeneous system. However, the fact that RM instability involves fluids of unequal densities which experience negligible gravitational force, except during the impulsive acceleration, requires RM instability experiments to be carried out under conditions of microgravity. This experimental study investigates the instability of an interface between incompressible, miscible liquids with an initial sinusoidal perturbation. The impulsive acceleration is generated by bouncing a rectangular tank containing two different density liquids off a retractable vertical spring. The initial perturbation is produced prior to release by oscillating the tank in the horizontal direction to produce a standing wave. The instability evolves in microgravity as the tank travels up and then down the vertical rails of a drop tower until hitting a shock absorber at the bottom. Planar Laser Induced Fluorescence (PLIF) is employed to visualize the flow. PLIF images are captured by a video camera that travels with the tank. Figure 1 is as sequence of images showing the development of the instability from the initial sinusoidal disturbance far into the nonlinear regime which is characterized by the appearance of mushroom structures resulting from the coalescence of baroclinic vorticity produced by the impulsive acceleration. At later times in this sequence the vortex cores are observed to become unstable showing the beginnings of the transition to turbulence in this flow. The amplitude of the growing disturbance after the impulsive acceleration is measured and found to agree well with theoretical predictions. The effects of Reynolds number (based on circulation) on the development of the vortices and the transition to turbulence are also determined.

Jacobs, J. W.↗
NASA NTRSDate not supplied

Secondary Volcanically-Induced Lunar Atmosphere and Lunar Volatiles: 3-D Modeling and Analysis

The fact that the Moon could have a transient secondary atmosphere due to volcanic outgassing has been known for some time, though typically such an atmosphere was believed to be extremely thin (~10-8 bar) [1]. But recent research by Needham and Kring (NK) [2] suggests that during the peak of volcanic activity ~3.5 Ga such a volcanically-outgassed atmosphere could reach ~10-2 bar of surface pressure. In similar research Wilson et al. [3] proposed a more conservative estimate, arguing that the thickness of such an atmosphere would depend on the intervals between major eruptions and may not exceed microbar densities. In either case a collisional atmosphere could be present, which would control transport of outgassed volatiles (such as H2O) and their deposition in polar regions, where they could be preserved until modern day frozen in permanently shadowed regions (PSR) or buried beneath the regolith. Here we study such a hypothetical atmosphere to investigate its stability, meteorological properties and the effect on transport of volatiles. We use the ROCKE-3D planetary 3-D General Circulation Model (GCM)[4]. The insolation and orbital parameters were set to conditions 3.5 Ga. The atmospheric composition, based on the list of outgassed species presented by NK in combination with our estimates for atmospheric escape, condensation and the results from our 1-D chemistry model, was chosen to be either CO-dominated or CO2-dominated (depending on atmospheric temperature). In this study we restricted ourselves to relatively "thick" lunar atmospheres of 1-10 mb, though we believe that our results will scale to thinner atmospheres as well. We present the results for ground and atmospheric temperature for modeled atmospheres over a wide parameter space. In particular we consider different atmospheric compositions (CO or CO2 dominated), a set of atmospheric pressures from 1 mb to 10 mb and a set of obliquities from 0o to 40o. We also present an experiment of a single major eruption [5] and show that in just 3 years ~80% of the outgassed water is deposited in polar regions. This demonstrates the efficiency of such an atmosphere in delivering volatiles. We argue that a secondary lunar atmosphere could play a significant role in forming volatile deposits currently observed in the polar regions of the Moon.

Lunar atmospheres↗