Results for “surface transformation” — Page 22

NASA NTRS1975

Molecular relaxations, molecular orientation, and the friction characteristics of polyimide films

The friction characteristics of polyimide films bonded to metallic substrates were studied from 25 to 500 C. These results were interpreted in terms of molecular orientation and thermomechanical data obtained by torsional braid analysis (TBA). A large friction transition was found to occur at 40 + or - 10 C in a dry argon atmosphere (10 ppm H2O). It was postulated that the mechanical stresses of sliding transform or reorder the molecules on the surface into a configuration conducive to easy shear, such as an extended chain. The molecular relaxation which occurs in this temperature region appears to give the molecules the necessary freedom for this reordering process to occur. The effects of velocity, reversibility, and thermal prehistory on the friction properties of polyimide were also studied.

Fusaro, R. L.↗

NASA NTRS1975

Molecular relaxations, molecular orientation and the friction characteristics of polyimide films

The friction characteristics of polyimide films bonded to metallic substrates were studied from 25 to 500 C. These results were interpreted in terms of molecular orientation and thermomechanical data obtained by torsional braid analysis (TBA). A large friction transition was found to occur at 40 plus or minus 10 C in a dry argon atmosphere (10 ppm H2O). It was postulated that the mechanical stresses of sliding transform or reorder the molecules on the surface into a configuration conducive to easy shear, such as an extended chain. The molecular relaxation which occurs in this temperature region appears to give the molecules the necessary freedom for this reordering process to occur. The effects of velocity, reversibility, and thermal prehistory on the friction properties of polyimide were also studied.

Fusaro, R. L.↗

NASA NTRS1980

Vector analogues of the Maggi-Rubinowicz theory of edge diffraction

The Maggi-Rubinowicz technique for scalar and electromagnetic fields is interpreted as a transformation of an integral over an open surface to a line integral around its rim. Maggi-Rubinowicz analogues are found for several vector physical optics representations. For diffraction from a circular aperture, a numerical comparison between these formulations shows the two methods are in agreement. To circumvent certain convergence difficulties in the Maggi-Rubinowicz integrals that occur as the observer approaches the shadow boundary, a variable mesh integration is used. For the examples considered, where the ratio of the aperture diameter to wavelength is about ten, the Maggi-Rubinowicz formulation yields an 8 to 10 fold decrease in computation time relative to the physical optics formulation.

Meneghini, R.↗

NASA NTRS1980

An alternating-direction-implicit algorithm for the unsteady potential equation in conservation form

An implicit finite difference scheme for an efficient computation of unsteady potential flow about airfoils is presented. The formulation uses density and velocity potential as dependent variables, and is cast in conservation form to assure the theoretically correct determination of shockwave location and speed. To enable boundary conditions to be imposed directly on the airfoil surface, a time varying sheared rectilinear coordinate transformation is employed. Calculated time history solutions on a pulsating airfoil are compared with the results of another unsteady transonic code. It is concluded that the method has excellent numerical stability and gives accurate solutions with sharply resolved shocks.

Chipman, R. R.↗

NASA NTRS1983

Hybrid C-H grids for turbomachinery cascades

The three basic types of grids available for two-dimensional cascade configurations are examined with respect to their relative advantages and disadvantages. Subsequently, a hybrid coordinate system is proposed such that it combines the major advantages of the C-type and the H-type meshes. The development of the hybrid grid system employs the patching of appropriate regions of these two basic mesh systems such that the transformed domain has a multi-block structure. Viewing the transformed domain as a three-dimensional surface enables the coordinates to be continuous across the boundaries of the patches in a natural manner.

Ghia, U.↗

NASA NTRS1985

Photovoltaics module interface: General purpose primers

The interfacial chemistry established between ethylene vinyl acetate (EVA) and the aluminized back surface of commercial solar cells was observed experimentally. The technique employed is called Fourier Transform Infrared (FTIR) spectroscopy, with the infrared signal being reflected back from the aluminum surface through the EVA film. Reflection infrared (IR) spectra are given and attention is drawn to the specific IR peak at 1080/cm which forms on hydrolytic aging of the EVA/aluminum system. With this fundamental finding, and the workable experimental techniques, candidate silane coupling agents are employed at the interface, and their effects on eliminating or slowing hydrolytic aging of the EVA/aluminum interface are monitored.

Boerio, J.↗

NASA NTRS1990

Flight control design considerations for STOVL powered-lift flight

Short Takeoff Vertical Landing (STOVL) aircraft rely on the propulsion system for the lift and control functions during slow speed flight. The propulsion system provides the entire lifting force and all of the control power for hovering flight at zero airspeed. STOVL designs such as the General Dynamics E-7D ejector configuration incorporate an integrated flight/propulsion control system to manage the aerodynamic and propulsive-lift control effectors and to reduce the pilot's workload for powered-lift flight. Desired flying qualities characteristics are implemented through the utilization of an explicit model following flight control system. With the model following control system, the pilot commands the desired response (e.g., throttle commands vertical velocity in hover, instead of power lever angle). Design considerations for developing a multivariable model-following flight control system are presented in this paper. When the regulator gains are defined in terms of generalized controls, the design problem becomes how to best transform the generalized controls to aerodynamic control surface, thrust and thrust vectoring commands.

Vincent, James H.↗

NASA NTRS1992

CAGI: Computer Aided Grid Interface. A work in progress

Progress realized in the development of a Computer Aided Grid Interface (CAGI) software system in integrating CAD/CAM geometric system output and/or Interactive Graphics Exchange Standard (IGES) files, geometry manipulations associated with grid generation, and robust grid generation methodologies is presented. CAGI is being developed in a modular fashion and will offer fast, efficient and economical response to geometry/grid preparation, allowing the ability to upgrade basic geometry in a step-by-step fashion interactively and under permanent visual control along with minimizing the differences between the actual hardware surface descriptions and corresponding numerical analog. The computer code GENIE is used as a basis. The Non-Uniform Rational B-Splines (NURBS) representation of sculptured surfaces is utilized for surface grid redistribution. The computer aided analysis system, PATRAN, is adapted as a CAD/CAM system. The progress realized in NURBS surface grid generation, the development of IGES transformer, and geometry adaption using PATRAN will be presented along with their applicability to grid generation associated with rocket propulsion applications.

Soni, Bharat K.↗

NASA NTRS1992

Tropospheric chemical models

The differences in atmospheric composition over the globe and the short- and long-term variations in this composition are the net effect of several atmospheric and biospheric processes: biospheric emissions, atmospheric circulation, atmospheric chemical transformations and finally deposition back to the surface. Accurate and realistic atmospheric chemistry and circulation models are essential to interpret the observed global distributions and trends of atmospheric species in terms of these underlying processes. Comparisons between model predictions and observations test current understanding of these processes and models used in conjunction with inverse methods allow deductions of the rates of these processes from the observations. With the planned inclusion of at least CO and CH4 observations on the Earth Observing System (EOS) satellites, together with the large global data set expected from in situ observations under the International Global Atmospheric Chemistry (IGAC) Project, the further development of global three-dimensional high-resolution atmospheric chemistry and circulation models in order to interpret this new data is a high-priority endeavor.

Prinn, R. G.↗

NASA NTRS2008

Saturn Magnetospheric Impact on Surface Molecular Chemistry and Astrobiological Potential of Enceladus

The active south polar surface of Enceladus is exposed to strong chemical processing by direct interaction with charged plasma and energetic particles in the local magnetospheric environment of this icy moon. Chemical oxidation activity is suggested by detection of H202 at the surface in this region and less directly by substantial presence of C02, CO, and N2 in the plume gases. Molecular composition of the uppermost surface, including ejecta from plume activity, is radiolytically transformed mostly by penetrating energetic electrons with lesser effects from more depleted populations of energetic protons. The main sources of molecular plasma ions and E-ring dust grains in the magnetospheric environment are the cryovolcanic plume emissions from Enceladus. These molecular ions and the dust grains are chemically processed by magnetospheric interactions that further impact surface chemistry on return to Enceladus. For example, H20 neutrals dominating the emitted plume gas return to the surface mostly as H30+ ions after magnetospheric processing. Surface oxidant loading is further increased by return of radiolytically processed ice grains from the E-ring. Plume frost deposition and micrometeoroid gardening protect some fraction of newly produced molecular species from destruction by further irradiation. The evident horizontal and vertical mobility of surface ices in the south polar region drive mixing of these processed materials into the moon interior with potential impacts on deep ice molecular chemistry and plume gas production. Similarly as suggested previously for Europa, the externally driven source of radiolytic oxidants could affect evolution of life in any subsurface liquid water environments of Enceladus.

Cooper, Paul D.↗

NASA NTRS2023

Measurements and Computations of Natural Transition on the NASA Juncture-Flow Model with a Symmetric Wing

Experiments were performed in the 14- by 22-Foot Subsonic Tunnel to assess natural transition on the symmetric-airfoil wings of the NASA Juncture-Flow Model. Infrared thermography was used to visualize the heating on the upper surface of both wings of the full-span model, and on the fuselage, for angles of incidence ranging from -10° to 10° at a fixed Reynolds number of 2.4E6 based on the chord length at the wing planform break. The fuselage boundary layer transitioned well upstream of the wing-root leading edge for all conditions. Transition fronts were identified by a steep rise in the surface temperature, and the transition coordinates were transformed from an image-based to a body-fixed system. Additionally, the state of the boundary layer was estimated at pressure ports distributed on the wings through observation of the pressure coefficient as a function of the angle of incidence. For increasing angles of incidence, the transition front was observed to advance upstream, in a mostly spanwise-uniform fashion, from near midchord at α = 0°; however, for increasingly negative angles of incidence, the transition front first receded and then advanced in a nonuniform jagged manner that is typically observed with stationary crossflow. The transition wedges first appeared inboard of the wing break and then spread outboard to near the tip by α = -6°. The upstream shift in transition at positive angles of incidence and the outboard progression of crossflow-dominated transition at increasingly negative angles of incidence are consistent with trends identified in a computational assessment of the boundary-layer transition based on both linear stability analysis and Reynolds-averaged-Navier-Stokes-based transition models. The stability results obtained from the Langley Stability and Transition Analysis Code were used to recalibrate a dual N-factor criterion, which allowed for the prediction of transition fronts that showed excellent agreement with the experiment. The Reynolds-averaged-Navier-Stokes-based models, from the NASA OVERFLOW 2.3 solver, that accounted for the crossflow instability showed mixed results in comparison with the experiment, with the helicity-based Langtry-Menter model performing the best. The experimental data, particularly the cases involving strong influence from both Tollmien-Schlichting and crossflow instabilities, will be valuable for the continued validation and improvement of transition models.

Boundary layer transition↗

NASA NTRS2023

Measurements and Computations of Natural Transition on the NASA Juncture-Flow Model with a Symmetric Wing

Experiments were performed in the 14- by 22-Foot Subsonic Tunnel to assess natural transition on the symmetric-airfoil wings of the NASA Juncture-Flow Model. Infrared thermography was used to visualize the heating on the upper surface of both wings of the full-span model, and on the fuselage, for angles of incidence ranging from -10° to 10° at a fixed Reynolds number of 2.4E6 based on the chord length at the wing planform break. The fuselage boundary layer transitioned well upstream of the wing-root leading edge for all conditions. Transition fronts were identified by a steep rise in the surface temperature, and the transition coordinates were transformed from an image-based to a body-fixed system. Additionally, the state of the boundary layer was estimated at pressure ports distributed on the wings through observation of the pressure coefficient as a function of the angle of incidence. For increasing angles of incidence, the transition front was observed to advance upstream, in a mostly spanwise-uniform fashion, from near midchord at α = 0°; however, for increasingly negative angles of incidence, the transition front first receded and then advanced in a nonuniform jagged manner that is typically observed with stationary crossflow. The transition wedges first appeared inboard of the wing break and then spread outboard to near the tip by α = -6°. The upstream shift in transition at positive angles of incidence and the outboard progression of crossflow-dominated transition at increasingly negative angles of incidence are consistent with trends identified in a computational assessment of the boundary-layer transition based on both linear stability analysis and Reynolds-averaged-Navier-Stokes-based transition models. The stability results obtained from the Langley Stability and Transition Analysis Code were used to recalibrate a dual N-factor criterion, which allowed for the prediction of transition fronts that showed excellent agreement with the experiment. The Reynolds-averaged-Navier-Stokes-based models, from the NASA OVERFLOW 2.3 solver, that accounted for the crossflow instability showed mixed results in comparison with the experiment, with the helicity-based Langtry-Menter model performing the best. The experimental data, particularly the cases involving strong influence from both Tollmien-Schlichting and crossflow instabilities, will be valuable for the continued validation and improvement of transition models.

boundary layer transition↗

NASA NTRS2023

Measurements and Computations of Natural Transition on the NASA Juncture-Flow Model with a Symmetric Wing

Experiments were performed in the 14- by 22-Foot Subsonic Tunnel to assess natural transition on the symmetric-airfoil wings of the NASA Juncture-Flow Model. Infrared thermography was used to visualize the heating on the upper surface of both wings of the full-span model, and on the fuselage, for angles of incidence ranging from -10° to 10° at a fixed Reynolds number of 2.4E6 based on the chord length at the wing planform break. The fuselage boundary layer transitioned well upstream of the wing-root leading edge for all conditions. Transition fronts were identified by a steep rise in the surface temperature, and the transition coordinates were transformed from an image-based to a body-fixed system. Additionally, the state of the boundary layer was estimated at pressure ports distributed on the wings through observation of the pressure coefficient as a function of the angle of incidence. For increasing angles of incidence, the transition front was observed to advance upstream, in a mostly spanwise-uniform fashion, from near midchord at α = 0°; however, for increasingly negative angles of incidence, the transition front first receded and then advanced in a nonuniform jagged manner that is typically observed with stationary crossflow. The transition wedges first appeared inboard of the wing break and then spread outboard to near the tip by α = -6°. The upstream shift in transition at positive angles of incidence and the outboard progression of crossflow-dominated transition at increasingly negative angles of incidence are consistent with trends identified in a computational assessment of the boundary-layer transition based on both linear stability analysis and Reynolds-averaged-Navier-Stokes-based transition models. The stability results obtained from the Langley Stability and Transition Analysis Code were used to recalibrate a dual N-factor criterion, which allowed for the prediction of transition fronts that showed excellent agreement with the experiment. The Reynolds-averaged-Navier-Stokes-based models, from the NASA OVERFLOW 2.3 solver, that accounted for the crossflow instability showed mixed results in comparison with the experiment, with the helicity-based Langtry-Menter model performing the best. The experimental data, particularly the cases involving strong influence from both Tollmien-Schlichting and crossflow instabilities, will be valuable for the continued validation and improvement of transition models.

boundary layer transition↗

DOE OSTI2023

Kinetically versus thermodynamically controlled factors governing elementary pathways of GaP(111) surface oxidation

GaP and related III-V semiconductors have attracted interest as high-efficiency photoelectrochemical electrodes for solar water splitting. However, their efficacy is linked to the presence, identity, and integrity of native surface oxides, which are structurally and chemically complex and evolve during operation. Using ambient pressure X-ray photoelectron spectroscopy (APXPS) coupled with ab initio simulations, we track key chemical motifs expressed during evolution of GaP(111) surface oxides, their associated reaction kinetics, and their correlations with electronic properties. We identify two distinct thermal regimes corresponding to kinetically and thermodynamically controlled oxidation. Below 600 K, exposure to O2 generates kinetically facile Ga-O-Ga configurations, whereas higher temperatures cause activated oxygen to insert into Ga–P bonds as part of a thermodynamically driven transformation into a complex, heterogeneous 3D network of surface POx (1≤x ≤ 4) groups and Ga2O3 species, the latter of which eventually dominates upon depletion of surface phosphorus. Here our study highlights the critical competition between kinetic and thermodynamic factors during GaP oxidation, yielding insights for fabricating stable III-P-based photoelectrodes with precisely engineered surface properties.

08 HYDROGEN↗

DOE OSTI2023

United States cool surfaces deployment plan

Solar-reflective building envelope surfaces, such as cool roofs and walls, can be especially helpful in disadvantaged communities that often have poorly insulated older homes, aging or absent air conditioning units, steep utility bills, polluted air, and high vulnerability and exposure to extreme heat. With support from the U.S. Department of Energy, our project seeks to dramatically increase the climate-appropriate deployment of cool surfaces across the United States with an emphasis on their application to disadvantaged communities. First, we sought to identify cool-surface deployment barriers, opportunities, and models by (a) reviewing the history of cool-surface deployment activities, (b) interviewing cool-surface stakeholders, (c) researching successful energy-efficiency/green building deployment models; and (d) interviewing the actors who have implemented these models. Second, we conducted a workshop to engage stakeholders in development of a deployment plan. Third, we asked several U.S. federal agencies (a) how cool surfaces and cool surface stakeholders could support their missions and (b) how agency activities could support cool-surface deployment. Fourth, we identified a set of transformative ideas that form the core of the deployment plan. Transformative ideas include but are not limited to initiatives to (a) launch an educational campaign to make the general public and building professionals aware of how cool roofs and walls exclude unwanted solar heat; (b) create a “Cool Roof Prize” stimulating the development of affordable, high-performance cool asphalt roofing shingles; (c) conduct high-profile, large-scale demonstration programs that bring cool surfaces to disadvantaged heat-vulnerable communities; and (d) support local, regional, and state climate action (heat mitigation) plans with cool surfaces.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

NASA NTRS1989

The effect of metal surface passivation on the Au-InP interaction

The effect of SiO2 encapsulation on reaction rates in the Au-InP system was studied. Scanning electron microscopy and x-ray photoelectron spectroscopy were used to investigate surface and/or interface morphologies and in-depth compositional profiles. It was found that the rate of dissolution of InP into Au and subsequent phase transformations are largely dependent on the condition of the free surface of the metalization. SiO2 capping of Au is reported for the first time to suppress the Au-InP reaction rate. The Au-InP interaction is shown to be quite similar to the Au-GaAs interaction despite differences in behavior of the group-V elements.

Fatemi, Navid S.↗

DOE OSTI2025

Selective Adsorption of Thiol-Containing Molecules on Copper Sulfide Surfaces via Molecule–Surface Disulfide Bridges

Recent results in the fields of nanoenhanced agriculture and expanding interest in prebiotic chemistry have placed increased emphasis on understanding the chemically selective interaction of small molecules with the surfaces of metal sulfides. Here, we present an integrated experimental and computational study of the interaction of thiol-containing molecules with copper sulfide (covellite) surfaces in aqueous media. In situ Fourier-transform infrared (FTIR) measurements and ex situ X-ray photoelectron spectroscopy (XPS) measurements show that molecules bearing free thiol groups, including glutathione and cysteine, bind strongly to CuS (covellite) nanoparticles and to CuS (001) single crystals, while control studies show that similar molecules lacking the free thiol group exhibit much less binding. Additional experiments show that these thiol-containing molecules interact transiently with CuO nanoparticle surfaces but are readily removed by rinsing. The FTIR and XPS experiments demonstrate that adsorption of molecular thiols to CuS surfaces occurs in a chemically selective manner. Further experimental studies and density functional calculations show that the preferred mode of binding is through the surface S atoms, forming a Solid–S–S–Molecule disulfide linkage. While the role of disulfide linkages in controlling structure and function of proteins and other biomolecules is widely known, the formation of surface disulfide linkages as a motif for covalent molecular binding at surfaces has not been established previously.

36 MATERIALS SCIENCE↗

DOE OSTI2025

Subsurface hydrogen, curvature, and strain: lessons from electro-reduction of benzaldehyde on nano-structured Pd catalysts

The unique ability of palladium (Pd) to absorb hydrogen and form a bulk hydride is vital for chemical transformations that involve hydrogenation reactions. Nano-structured Pd catalysts offer a promise of tuning these reaction rates by exploiting variations of reactant binding energies depending on the surface structure and morphological constraints that result in inhomogeneous strain. However, the interplay between the nano-structure of Pd and the ability of Pd to adsorb (and absorb) hydrogen as well as other reactive species needs to be better understood for a rational understanding of competitive chemical transformations at Pd surfaces. We consider the effects of the surface corrugation, strain, and subsurface Pd hydride on the reduction of benzaldehyde to benzyl alcohol in two qualitatively different samples – Pd nanoparticles and Pd gels formed by quasi-one-dimensional chains of these nanoparticles. Our electrochemical measurements and computational modelling suggest that surface concave sites, inherent to Pd gels, facilitate hydrogen transfer to the Pd subsurface region, thus weakening benzaldehyde binding to the surface. This effect is further modulated by the strain, depending on the local coordination environment on the corrugated surface. Furthermore, these findings demonstrate how structurally complex samples in the form of gels provide degrees of freedom for controlling the behavior of metal catalysts that are not available in isolated nanoparticles, which paves the way for new approaches in the design of catalytic materials and synthesis of metal hydrides.

Padavala, Sri Krishna Murthy [University of Minnes↗