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At least 397 records · Page 22

Digital alloy contact layers for perovskite solar cells

Thin film optoelectronic devices commonly require an individual material to perform multiple functions, but the physical properties of single-composition materials often cannot be tuned to optimize these diverse requirements. The electron selective contact layer in perovskite solar cells is a prime example. The material must simultaneously have optimal conduction band alignment, facilitate carrier extraction, prevent recombination, and provide a chemically stable interface with the notoriously volatile perovskite semiconductor. The pulse-by-pulse nature of the thin-film deposition method pulsed laser deposition (PLD) provides an opportunity to form material alloys where the chemical composition is controlled at the nanometer scale. These digital alloys may prove to be a powerful materials class to meet some of the multifunctional needs of thin film devices. Using PLD to make electron transport layers from ZnO and MgZnO targets, we demonstrate in this paper that digital alloy gradients can be tuned to significantly outperform either of the parent materials in perovskite solar cells.

36 MATERIALS SCIENCE↗

Providencia Island White Papers: Potential for Increasing the Physical Resilience of Distributed Energy Resources

Using technologies such as solar photovoltaics (PV) to provide power to a site during a large-scale grid outage can be an effective solution for enhancing resilience, if designed appropriately. This paper discusses storm-hardening strategies including wind-loading standards, secure racking systems, balance of electrical systems and pre-storm preparations.

24 POWER TRANSMISSION AND DISTRIBUTION↗

1H 1752 + 081: An eclipsing cataclysmic variable with a small accretion disk

We announce the discovery of an eclipsing nova-like cataclysmic variable (CV) as the optical counterpart to the HEAO 1 X-ray source 1H1752 + 081. This CV has an orbital period of 1.882801 hr, a high equivalent width of H-beta, and an average m(sub v) of 16.4 out of the eclipse. A geometric model is constructed from observations of the eclipse ingress and egress in many optical bandpasses. The broad-band emission originates primarily in two regions; the disk/accretion stream 'hot spot' and a compact central component, which may be a spot on the white dwarf surface, the entire white dwarf surface or the boundary layer between the accretion disk and the white dwarf surface. Based on the durations and offsets of the two eclipses we determined the mass ratio q = 2.5 +/- 0.6 and the angle of inclination i = 77 deg +/- 2 deg. If the central component is the entire white dwarf surface the masses of the stars are M(sub 1) = 0.80 +/- 0.06 solar masses and M(sub 2) = 0.32 +/- 0.06 solar masses. The disk is faint and small (R(sub D) = 0.25 +/- 0.05 r(sub L1), where r(sub L1) is the distance from the primary to the L(sub 1) point), compared to other eclipsing CVs. The small disk may result from the removal of angular momentum from the accretion disk by the magnetic field of the white dwarf; this CV may be a DQ Her type with a slowly rotating white dwarf. The emission-line velocities do not show the 'Z-wave' expected from the eclipse of a Keplerian accretion disk, nor do they have the correct phasing to originate near the white dwarf. The most likely origin of the line emission is the hot spot. The secondary star is visible at wavelengths greater than or equal to 6000 A during eclipse. We estimate a spectral type approximately M6 which, together with the observed m(sub 1) = 16.94 during eclipse, results in a distance estimate of 150 +/- 27 pc.

Silber, Andrew D.↗

Hubble space telescope Goddard High-Resolution Spectrograph observation of U Geminorum during quiescence: Evidence for a slowly rotating white dwarf

We have obtained a pair of consecutive far-ultraviolet Goddard High-Resolution Spectrograph (GHRS) exposures of the Si IV region of the dwarf nova U Geminorum in early quiescence, 8 days after its return to optical quiescence when the underlying white dwarf dominates the ultraviolet light of the system. Our GHRS observation revealed a fully resolved line profile for the resonance doublet of Si IV. If it is associated with the white dwarf photosphere, then our best synthetic fits are consistent with T (sub eff) = 35,000 K-38,000 K, log g = 8, a rotational velocity of 50 to 100 km per sec, with a modestly enhanced silicon abundance (1.3-2.3 times solar) and our results suggest that at least in U Gem and perhaps in other similar dwarf novae, the missing boundary layer cannot be explained by rapid rotation of the white dwarf. However, the gamma-velocity of the system remains uncertain. If the gamma-velocity is 43 km per sec (Friend et al. 1990), then a gravitational redshift of approximately 50-60 km per sec is implied for the white dwarf. If the gamma-velocity is 84 km per sec (Wade 1981), then a gravitational redshift of only 10-30 km per sec is indicated, which may imply that either the white dwarf has a low (0.5-0.6 of Solar Mass) mass or an extended atmosphere (corona) due to the outburst heating 8 days earlier. The implications of our line-fitting results for the structure and temperature of boundary layers in cataclysmic variables are discussed.

Sion, Edward M.↗

High-energy and ultra-high-energy neutrinos: A Snowmass white paper

Astrophysical neutrinos are excellent probes of astroparticle physics and high-energy physics. With energies far beyond solar, supernovae, atmospheric, and accelerator neutrinos, high-energy and ultra-high-energy neutrinos probe fundamental physics from the TeV scale to the EeV scale and beyond. They are sensitive to physics both within and beyond the Standard Model through their production mechanisms and in their propagation over cosmological distances. They carry unique information about their extreme non-thermal sources by giving insight into regions that are opaque to electromagnetic radiation. Here in this white paper describes the opportunities astrophysical neutrino observations offer for astrophysics and high-energy physics, today and in coming years.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Morphology of solar wind fluctuations and structure in the vicinity of the Sun from radio propagation measurements

Radio propagation measurements represent a powerful means for remote probing of electron density and solar wind speed in the acceleration region of the solar wind not yet explored by in situ measurements. Recent investigations based on radio propagation measurements have led to considerable progress in our knowledge of the general morphology of solar wind fluctuations and structure, especially in terms of their relationship to solar wind properties that have been observed directly by fields and particles measurements, and to coronal features observed in white-light measurements. The purpose of this paper is to present an overview of the latest results on quasi-stationary structure covering the large scale variation of solar wind speed over the streamer belt and coronal hole regions, coronal streamers (source of slow solar wind) and their associated small-scale electron density structure, plumes, density and fractional or relative density fluctuations, and the spectral characteristics of the electron density fluctuations. The radio propagation measurements not only reveal new information on the structure near the Sun, but also show that the structure appears to undergo substantial evolution on its way to 0.3 AU, the closest radial distance for which direct in situ spacecraft measurements are available.

Woo, R.↗

Spin Solar Cell Phenomenon on a Single-Molecule Magnet (SMM) Impacted CoFeB-Based Magnetic Tunnel Junctions

The single-molecule magnet (SMM) is demonstrated here to transform conventional magnetic tunnel junctions (MTJs), a memory device used in present-day computers, into solar cells. For the first time, we demonstrated an electronic spin-dependent solar cell effect on an SMM-transformed MTJ under illumination from unpolarized white light. We patterned cross-junction-shaped devices to form a CoFeB/MgO/CoFeB-based MTJ. The MgO barrier thickness at the intersection between the two exposed junction edges was less than the SMM extent, which enabled the SMM molecules to serve as channels to conduct spin-dependent transport. The SMM channels yielded a region of long-range magnetic ordering around these engineered molecular junctions. Our SMM possessed a hexanuclear [Mn 6 (μ 3 -O) 2 (H 2 N-sao) 6 (6-atha) 2 (EtOH) 6 ] [H 2 N-saoH = salicylamidoxime, 6-atha = 6-acetylthiohexanoate] complex and thioesters end groups to form bonds with metal films. SMM-doped MTJs were shown to exhibit a solar cell effect and yielded ≈80 mV open-circuit voltage and ≈10 mA/cm 2 saturation current density under illumination from one sun equivalent radiation dose. A room-temperature Kelvin Probe AFM (KPAFM) study provided direct evidence that the SMM transformed the electronic properties of the MTJ’s electrodes over a lateral area in excess of several thousand times larger in extent than the area spanned by the molecular junctions themselves. As a result, the decisive factor in observing this spin-photovoltaic effect is the formation of SMM spin channels between the two different ferromagnetic electrodes, which in turn is able to catalyze the long-range transformation in each electrode around the junction area.

14 SOLAR ENERGY↗

The 1980 rocket coronagraph measurements of the solar wind acceleration region

Spectroscopic measurements of temperatures, densities and flow velocities in the solar wind acceleration region provide critical empirical constraints on solar stellar wind theory. Preliminary results of an analysis of H I Lyman-alpha and white light measurements made on 16 February 1980 in a polar coronal region are reported. The hydrogen kinetic temperatures in the observed region were found to be nearly constant with T sub HI approximately equals 10 degrees K at heliocentric distances between 1.5 and 4 solar radii. The outflow velocities were found to be subsonic indicating that the critical point in the observed region was located at r approximately greater than 4 solar radii.

Withbroe, G. L.↗

Neptune's visual albedo variations over a solar cycle - A pre-Voyager look at ion-induced nucleation and cloud formation in Neptune's troposphere

A model of Neptune's troposphere and stratosphere is used to estimate the cosmic-ray-induced ionization on Neptune at sunspot maximum and minimum for a range of possible planetary magnetic field strengths. The impact of this ionization on aerosol formation and the effect of the aerosol layer on the planet's albedo are examined. The results suggest that the 'white haze' theory may explain observations of the variation of Neptune's visible albedo with solar cycle (Lockwood and Thompson, 1986).

Moses, Julianne I.↗

Hydrodynamic Simulations of Oxygen–Neon Classical Novae as Galactic 7 Li Producers and Potential Accretion-induced Collapse Progenitors*

Abstract We report on studies of classical nova (CN) explosions where we follow the evolution of thermonuclear runaways (TNRs) on oxygen–neon (ONe) white dwarfs (WDs). Using NOVA, a 1D hydrodynamic computer code, we accrete solar matter until the TNR is ongoing and then switch to a mixed composition. This approach is guided by the results of multidimensional studies of TNRs in WDs, which find that sufficient mixing with WD core material occurs after the TNR is well underway, and levels of enrichment of the CNONeMg elements are reached that agree with observations of CN ejecta abundances. Because the amount of accreted material is inversely proportional to the oxygen abundance, by first accreting solar matter, the amount of accreted material is larger than in those simulations with an initially enriched composition. We vary the mass of the WD (from 0.6 M ⊙ to 1.35 M ⊙ ) and the composition of the mixed materials. Our results show large enrichments of 7 Be in the ejected gases, implying that ONe CNe and CO CNe may be responsible for a significant fraction (∼100 M ⊙ ) of the Galactic 7 Li (∼1000 M ⊙ ). The production of 22 Na and 26 Al in CN explosions and the γ -ray emission predicted by our simulations are discussed. The WDs in all our simulations eject less material than they accrete and we predict that the WD is growing in mass as a consequence of the CN outburst. ONe CNe, therefore, may be an important channel for accretion-induced collapse events.

Starrfield, Sumner (ORCID:0000000213596312)↗

A review of the thermonuclear runaway model of a nova outburst

Kraft's (1963) model for a nova outburst caused by a thermonuclear runaway in the hydrogen-rich matter accreted onto the white dwarf in a binary system is reviewed. Hydrostatic and hydrodynamic studies of this phenomenon are summarized, analyses of shock ejection based on hydrodynamic computer codes are discussed, and one specific hydrodynamic code is outlined. Results obtained with this code are presented and evaluated for an initial model containing a white dwarf with a hydrogen-rich envelope of 0.0001 to 0.001 solar mass in hydrostatic and thermal equilibrium. It is shown that an implicit hydrodynamic computer code is required in order to study the thermonuclear-runaway phenomenon. The early evolution of three models with different intrinsic luminosities is illustrated, and enhancement of CNO nuclei at the bottom of the hydrogen-rich envelope is investigated. It is suggested that the concentration of C-13, N-15, and O-17 should be greatly enhanced in nova ejecta.

Sparks, W. M.↗

The masses of neutron stars - Observational constraints

The present state of empirical knowledge concerning neutron-star masses is reviewed on the basis of information obtained for the nine known X-ray pulsars in binary systems. Pulse profiles and other pulse parameters of these X-ray pulsars are examined, and allowable mass ranges are estimated for four X-ray pulsars in binary systems as well as for the binary pulsar PSR 1913+16. The approximate mass ranges obtained include 1.2 to 2.4 solar masses for 3U 0900-40, 0.7 to 4.3 solar masses for Cen X-3, 0.8 to 1.8 solar masses for SMC X-1, 0.0 to 2.3 solar masses for Her X-1, and either 1.4 to 1.8 solar masses or 0.0 to 1.8 solar masses for PSR 1913+16 if the companion is a normal white dwarf or some other type of star, respectively. Theoretical implications of these results are briefly considered.

Rappaport, S. A.↗

A quinone-assisted photoformation of energy-rich chemical bonds

In a study of biochemical means of solar energy conversion, ADP and inorganic phosphates were converted to ATP by white light in the nonaqueous solvent dimethylformamide in the presence of tetrachloro-p-quinone or ubiquinone. Conversion of ADP to ATP has been accomplished in aqueous suspension by the use of cell-like structures aggregated from poly(aspartic acid, glutamic acid, tyrosine). This is believed to occur through the formation of dopaquinone in the peptide structure during illumination. The way in which the quantitative yield of ATP has been influenced by pH and by added substances, such as FeCl2, was studied.

Fox, S. W.↗

LEO atomic oxygen effects on spacecraft materials: STS-5 results

Effects of low Earth orbit (LEO) atomic oxygen were measured on a variety of spacecraft materials which obtained exposure on STS-5. Material degradation dependency on temperature was found in one material. Of the five paints flown, only S13GLO was unaffected. Generally, the glossy paints became Lambertian and the diffuse coatings improved. Scanning electron microscope examinations indicated removal of urethane and epoxy paint binder materials. Reaction products were evident on the surfaces of Z302 paint and Mylar. Thin films showed thickness losses ranging from negligible loss in Teflon to considerable loss in Mylar and Kapton. Glossy films such as black Kapton and white Tedlar became diffused. Kevlar 29 rope lost tensile strength and silver solar cell interconnect material oxidized. Oxidation on the backside of an elevated specimen indicated that reflections of oxygen atoms were occurring and that reflecting surfaces, probably Kapton, were not fully accommodating the incident atoms.

Whitaker, A. F.↗

Solar corona synoptic observations from SOHO with an extreme ultraviolet imaging telescope

The major scientific objective of the EUV Imaging Telescope (EIT) is to study the evolution of coronal structure over a wide range of spatial and temporal scales and temperatures. A second strategic objective is to provide full disk synoptic maps of the global corona to aid in unifying SOHO (Solar and Heliospheric Observatory)/Cluster investigations. EIT will also provide images to support the planning of detailed spectroscopic investigations by the CDS (Coronal Diagnostic Spectrometer) and SUMER spectrometers in SOHO. EIT observations will be made in four narrow spectral bands, centered at 171 A (Fe 9), 195 A(Fe 12), 284 A (Fe 15), and 304 A (He 2) representing restricted temperature domains within a wide temperature range from 40,000 to 3,000,000 K. The results will be images of the solar atmosphere from the upper chromosphere and transition region to the active region corona. These maps, made at appropriate time intervals, will be used to study the fine structures in the solar corona and to relate their dynamic properties to the underlying chromosphere and photosphere. Dynamic events in the inner corona will be related to white light transients in the outer corona, and observations of the internal structure of coronal holes will be used to investigate origins of the solar wind.

Delaboudiniere, Jean-Pierre↗

Science objectives and performance of a radiometer and window design for atmospheric entry experiments

The Radiative Heating Experiment, RHE, aboard the Aeroassist Flight Experiment, AFE, (now cancelled) was to make in-situ measurements of the stagnation region shock layer radiation during an aerobraking maneuver from geosynchronous to low earth orbit. The measurements were to provide a data base to help develop and validate aerothermodynamic computational models. Although cancelled, much work was done to develop the science requirements and to successfully meet RHE technical challenges. This paper discusses the RHE scientific objectives and expected science performance of a small sapphire window for the RHE radiometers. The spectral range required was from 170 to 900 nm. The window size was based on radiometer sensitivity requirements including capability of on-orbit solar calibration.

Craig, Roger A.↗

Observations of hysteresis in solar cycle variations among seven solar activity indicators

We show that smoothed time series of 7 indices of solar activity exhibit significant solar cycle dependent differences in their relative variations during the past 20 years. In some cases these observed hysteresis patterns start to repeat over more than one solar cycle, giving evidence that this is a normal feature of solar variability. Among the indices we study, we find that the hysteresis effects are approximately simple phase shifts, and we quantify these phase shifts in terms of lag times behind the leading index, the International Sunspot Number. Our measured lag times range from less than one month to greater than four months and can be much larger than lag times estimated from short-term variations of these same activity indices during the emergence and decay of major active regions. We argue that hysteresis represents a real delay in the onset and decline of solar activity and is an important clue in the search for physical processes responsible for changing solar emission at various wavelengths.

Bachmann, Kurt T.↗