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At least 397 records · Page 22

Interaction-based ion selectivity exhibited by self-assembled, cross-linked zwitterionic copolymer membranes

Significance The separation of ions is challenging yet crucial for providing access to safe water resources as well as recovering valuable ions from water and wastewater. Yet, membranes rarely exhibit selectivity between ions of similar charge and size. We demonstrate that membranes, prepared by a fully scalable method that uses self-assembling zwitterionic copolymers, exhibit exceptional selectivity between salt anions of similar size and charge. We show that this unusual capability is derived from selective zwitterion–ion interactions occurring within the nanochannels, similarly to biological ion channels. We further demonstrate these membranes exhibit Cl − /F − permselectivity more than twice the values reported in previous studies, with applications in treating groundwater streams to prevent fluorosis and in wastewater treatment.

Lounder, Samuel J.↗

GeoThermalCloud: Cloud Fusion of Big Data and Multi-Physics Models using Machine Learning for Discovery, Exploration, and Development of Hidden Geothermal Resources

The primary goals of this project are exploring hidden geothermal resources in the U.S.A. and designing profitable enhanced geothermal systems (EGS). Many processes and parameters control geothermal exploration and energy production from geothermal fields. Diverse datasets (e.g., geology, geochemistry, geophysics, satellite, airborne geophysics) are available to help characterize subsurface geothermal conditions. Sparse and multi-scale characteristics of these datasets prohibit properly leveraging these datasets for geothermal exploration and profitable EGS design. Recent advancements in machine learning (ML) promise to resolve these issues. The tremendous challenges and risks of geothermal exploration and production bring the demand for novel ML methods and tools that can (1) analyze large field datasets, (2) assimilate model simulations (large inputs and outputs), (3) process sparse datasets, (4) perform transfer learning (between sites with different exploratory levels), (5) extract hidden geothermal signatures in the field and simulation data, (6) label geothermal resources and processes, (7) identify high-value data acquisition targets, and (8) guide geothermal exploration and production by selecting optimal exploration, production, and drilling strategies. To address these necessities, ML-based geothermal resources exploration and enhanced geothermal systems (EGS) design tools have been developed. The exploration tool is called GeoThermalCloud and EGS design tool is called GeoDT-ML. GeoThermalCloud (https://github.com/SmartTensors/GeoThermalCloud.jl) utilizes a LANL unsupervised ML platform called SmartTensors (https://tensors.lanl.gov/) to automate data analyses and interpretations by extracting hidden signatures to identify geothermal prospects. Also, it enables the identification of critical measurements needed to identify geothermal resource signatures. Alternatively, GeoDT-ML (https://github.com/SmartTensors/GeoThermalCloud.jl/tree/master/EGS) is an ML-based alternative to GeoDT (https://github.com/GeoDesignTool/GeoDT.git), a fast, simplified multi-physics solver to evaluate EGS project designs in uncertain geologic systems. GeoDT-ML leverages recent advances in deep learning and high-performance computing. It is a faster and simpler version of GeoDT. To make this project a success, we used capabilities of LANL, PNNL, Google, Stanford, and Julia Computing. We analyzed eight datasets of the U.S.A. using GeothermalCloud and demonstrated potential highly prospective geothermal resources and identified key factors defining highly prospective sites. The first data set includes 44 locations in southwest New Mexico and 18 geological, hydrogeological, geophysical, geothermal, geochemical attributes. We defined low- and medium-temperature hydrothermal systems and discovered a new highly prospective site. The second data set analyzed 18 shallow water chemistry attributes at 14,342 locations in the Great Basin. It demarcated modestly, moderately, and highly prospective sites including key attributes for each type of prospectivity. The third data set analyzed Utah FORGE data including satellite (InSAR), geophysical (gravity, seismic), geochemical, and geothermal attributes. Here, we performed prospectivity analysis to identify future drilling locations using geological, geochemical, and geophysical attributes. Maps of temperature at depth and heat flow are constructed based on the available data. Prospectivity maps were generated, and drilling locations were proposed for future geothermal field exploration. The fourth data set analyzed 21 attributes at 120 locations in Tularosa Basin, New Mexico; data comes from past play fairway analyses in this region. ML analyses identified geothermal signatures associated with modestly, moderately, and highly hydrothermal systems. We also defined dominant attributes and spatial distribution of the geothermal signatures. The fifth, sixth, seventh, and eighth datasets include Tohatchi Springs, New Mexico, Hawaii, Brady site, Nevada, and EGS Collab, respectively. Moreover, we coupled GeothermalCloud and magnetotellurics data to pinpoint drilling locations for developing geothermal projects in the Tularosa Basin, New Mexico. GeothermalCloud found potential prospective locations for geothermal resources near White Sands Missile Range and McGregor Range at Fort Bliss. Magnetotellurics data determined the potential depth (~1800m) of geothermal prospects at McGregor Range based on apparent resistivity structures/layers in the subsurface. The McGregor Range consists of three resistivity layers and two resistivity structures. Magnetotellurics data also helps identify that the western portion of the McGregor Range has thick and low-resistivity earth materials. The low resistivity to the west is most likely for a fault system. Assuming temperature is consistent with a geothermal reservoir, the west-central part of the McGregor Range has the highest geothermal potential because of the increase in porosity and associated permeability attributed to the interpreted fault system. Also, we devised a coupling strategy between a process model and GeothermalCloud to characterize hydrogeological conditions and geothermal conditions, respectively. The process model characterizes hydrogeological and geothermal conditions on highly prospective geothermal sites provided by GeothermalCloud. We developed a physics-informed neural network (PINN) version of the Burns equation that can be easily coupled with GeothermalCloud. Furthermore, we performed an optimal design decision maximizing the economic value of an EGS power plant. This study optimized the range of well spacing between injection and production wells maximizing net present value in dollars (NPV). For this task, we used the GeoDT to simulate the Utah FORGE EGS development cycle from the initial well design to the end of production. Next, we accomplished another crucial task, which is predicting permeability of geothermal reservoirs. Predicting permeability of geothermal reservoirs is a non-trivial task because of huge computational runtime of simulation and lack of measurements. To avoid these limitations, we used easy-to-measure chemical concentrations in the subsurface as measurement data and convolutional neural network based ML model of a high-fidelity model. Next, we predicted permeability using Markov chain Monte Carlo simulation. We found that Markov chain Monte Carlo simulation predicts permeability with a high certainty if the prediction zone in the simulation area has chemical concentration data. Finally, we analyzed the DOE funded INGENIOUS and GeoDAWN projects data. For discovering hidden geothermal systems in the Great Basin, the INGENIOUS project accumulated old data, collected new data, and released them in 2022. The dataset includes a total of 24 geological, geophysical, and geochemical attributes. Data resolution and scale significantly vary prohibiting an appropriate usage. To avoid such limitations, we brought all data in the same resolution and scale by applying the inverse distance weighting interpolation technique for predicting data in unsampled locations. Subsequently, we analyzed LiDAR data of the GeoDAWN project. We received data in tiles format. The DOE’s overarching goal is to use ML on LiDAR data for finding favorable geological structures (e.g., step up faults in Brady, Nevada). To serve the purpose, we need to label favorable geologic structures that correspond to LiDAR data. We wrote an algorithm to label the LiDAR data with the favorable geologic structures.

15 GEOTHERMAL ENERGY↗

A modERN resource: identification of Drosophila transcription factor candidate target genes using RNAi

Transcription factors (TFs) play a key role in development and in cellular responses to the environment by activating or repressing the transcription of target genes in precise spatial and temporal patterns. In order to develop a catalog of target genes of Drosophila melanogaster TFs, the modERN consortium systematically knocked down the expression of TFs using RNAi in whole embryos followed by RNA-seq. We generated data for 45 TFs which have 18 different DNA-binding domains and are expressed in 15 of the 16 organ systems. The range of inactivation of the targeted TFs by RNAi ranged from log2fold change -3.52 to +0.49. The TFs also showed remarkable heterogeneity in the numbers of candidate target genes identified, with some generating thousands of candidates and others only tens. We present detailed analysis from five experiments, including those for three TFs that have been the focus of previous functional studies (ERR, sens, and zfh2) and two previously uncharacterized TFs (sens-2 and CG32006), as well as short vignettes for selected additional experiments to illustrate the utility of this resource. The RNA-seq datasets are available through the ENCODE DCC (http://encodeproject.org) and the Sequence Read Archive (SRA). TF and target gene expression patterns can be found here: https://insitu.fruitfly.org. These studies provide data that facilitate scientific inquiries into the functions of individual TFs in key developmental, metabolic, defensive, and homeostatic regulatory pathways, as well as provide a broader perspective on how individual TFs work together in local networks during embryogenesis.

59 BASIC BIOLOGICAL SCIENCES↗

Resource management on the flight deck

Several approaches to the training and selection of aircrew are presented including both industry and nonindustry perspectives. Human factor aspects of the problem are also examined with specific emphasis on the psychology of the flight deck situation.

Cooper, G. E.↗

Selection for optimal crew performance - Relative impact of selection and training

An empirical study supporting Helmreich's (1986) theoretical work on the distinct manner in which training and selection impact crew coordination is presented. Training is capable of changing attitudes, while selection screens for stable personality characteristics. Training appears least effective for leadership, an area strongly influenced by personality. Selection is least effective for influencing attitudes about personal vulnerability to stress, which appear to be trained in resource management programs. Because personality correlates with attitudes before and after training, it is felt that selection may be necessary even with a leadership-oriented training cirriculum.

Chidester, Thomas R.↗

Low-Temperature Geothermal Play Fairway Analysis for the Denver Basin: Preprint

This project is part of a national initiative to showcase the benefits of incorporating low-temperature geothermal resource assessment into the deployment of geothermal heating and cooling (GHC), combined heat and power (CHP), and geothermal direct use (GDU) technologies. The initiative was established to accelerate the country's decarbonization efforts by identifying potential for low-temperature geothermal resource utilization (< 150 Degrees Celsius, i.e., GHC, CHP, and GDU) in selected sedimentary basins with numerous population centers. The Play Fairway Analysis (PFA) methodologies in this study were adapted from previous PFA investigations of sedimentary basin geothermal play types (SBGPTs) that evaluated the potential for low-temperature resources (< 150 Degrees Celsius). Workflows, relevant datasets, python code, common and composite geological criteria maps are utilized to develop low-temperature geothermal resource favorability maps for the Denver Basin, a sedimentary basin spanning Colorado, Nebraska, and Wyoming. The replication of these methodologies in other SBGPTs can evaluate potential for low-temperature resources. To facilitate future assessment of low-temperature geothermal resources in SBGPTs, this project provides PFA workflows, data, tools, and favorability maps that will ultimately support the utilization of low-temperature geothermal resources in sedimentary basins.

Denver Basin↗

Resource and environmental surveys from space with the thematic mapper in the 1980's

The selection of observation of vegetation is the primary optimization objective of the thematic mapper. The following are aspects of plans for the thematic mapper: (1) to include an appropriately modified first generation MSS in the thematic mapper mission; (2) to provide assured coverage for a minimum of six years to give agencies and other users an opportunity to justify the necessary commitment of resources for the transition into a completely valid operational phase; (3) to provide for global, direct data read-out, without the necessity for on-board data storage or dependence on foreign receiving stations; (4) to recognize the operational character of the thematic mapper after successful completion of its experimental evaluation; and (5) to combine future experimental packages with compatible orbits as part of the operational LANDSAT follow-on payloads.

Source record↗

Selective simulation and selective sensor interpretation in monitoring

An approach to selective processing in monitoring is described. The approach is designed to provide informative feedback on whether a system is performing nominally in the current operating context without exceeding available resources for prediction and interpretation. At the center of the approach to selective sensor interpretation and simulation is a causal model of the system being monitored. The architecture of the monitoring system, called PREMON, is described as well as how causal models of physical systems are represented and simulated.

Doyle, Richard J.↗

Sharpening Nanofiltration: Strategies for Enhanced Membrane Selectivity

Nanofiltration plays an increasingly large role in many industrial applications, such as water treatment (e.g., desalination, water softening, and fluoride removal) and resource recovery (e.g., alkaline earth metals). Energy consumption and benefits of nanofiltration processes are directly determined by the selectivity of the nanofiltration membranes, which is largely governed by pore-size distribution and Donnan effects. During operation, the separation performance of unmodified nanofiltration membranes will also be impacted (deleteriously) upon unavoidable membrane fouling. Many efforts, therefore, have been directed toward enhancing the selectivity of nanofiltration membranes, which can be classified into membrane fabrication method improvement and process intensification. Finally, this review summarizes recent developments in the field and provides guidance for potential future approaches to improve the selectivity of nanofiltration membranes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Investigation using data from ERTS-1 to develop and implement utilization of living marine resources

The author has identified the following significant results. This 15-month ERTS-1 investigation produced correlations between satellite, aircraft, menhaden fisheries, and environmental sea truth data from the Mississippi Sound. Selected oceanographic, meteorological, and biological parameters were used as indirect indicators of the menhaden resource. Synoptic and near real time sea truth, fishery, satellite imagery, aircraft acquired multispectral, photo and thermal IR information were acquired as data inputs. Computer programs were developed to manipulate these data according to user requirements. Preliminary results indicate a correlation between backscattered light with chlorophyll concentration and water transparency in turbid waters. Eight empirical menhaden distribution models were constructed from combinations of four fisheries-significant oceanographic parameters: water depth, transparency, color, and surface salinity. The models demonstrated their potential for management utilization in areas of resource assessment, prediction, and monitoring.

Stevenson, W. H.↗

ML-ACCEPT: Machine-Learning-enhanced Automated Circuit Configuration and Evaluation of Power Converters

This project, ML-ACCEPT, took a significant step toward achieving the first objective of the DIFFERENTIATE program: to help engineers to more rapidly and cost-effectively consider a wider range of more novel concepts before selecting an engineering-optimal architecture for high-fidelity detailed design and evaluation. Compared to existing methods, the ML-ACCEPT project investigated innovative technologies to make the design of power converters more cost-effective and time-efficient by i) integrating recent breakthroughs in ML, power electronics, simulation software, and optimization to research, develop, and developed a suite of ML-enhanced hypothesis generation tools for power converter design; and ii) facilitating the integration of the proposed software tools into existing power-converter design work-flows. Some existing tools for power-converter design have a certain level of intelligence to aid the design process, but to our knowledge none of them has ML-enhanced capability of automating the electrical circuit design process by selecting, configuring, and tailoring the individual components that enable available resources (e.g., high-voltage DC power) to be converted to the desired output (e.g., lower-voltage DC power with a desired voltage ripple), subject to application-specific (e.g., plasma generation and automotive applications) thermal and packaging considerations. The state-of-the-art circuit design of power converters is still heavily reliant on human experts to select the optimal topology and search for design parameters with human’s experience and intuitions, which can be very time-consuming, inefficient, and labor intensive. The team is composed of University of Michigan-Dearborn (UM-Dearborn), Lawrence Livermore National Laboratory (LLNL), Oak Ridge National Laboratory (ORNL), Modelon Inc., and lighthouse customers.

42 ENGINEERING↗

In-situ resource utilization in the design of advanced lunar facilities

Resource utilization will play an important role in the establishment and support of a permanently manned lunar base. At the University of Houston - College of Architecture and the Sasakawa International Center for Space Architecture, a study team recently investigated the potential use of lunar in-situ materials in the design of lunar facilities. The team identified seven potential lunar construction materials; concrete, sulfur concrete, cast basalt, sintered basalt, glass, fiberglass, and metals. Analysis and evaluation of these materials with respect to their physical properties, processes, energy requirements, resource efficiency, and overall advantages and disadvantages lead to the selection of basalt materials as the more likely construction material for initial use on a lunar base. Basalt materials can be formed out of in-situ lunar regolith, with minor material beneficiation, by a simple process of heating and controlled cooling. The team then conceptualized a construction system that combines lunar regolith sintering and casting to make pressurized structures out of lunar resources. The design uses a machine that simultaneously excavates and sinters the lunar regolith to create a cylindrical hole, which is then enclosed with cast basalt slabs, allowing the volume to be pressurized for use as a living or work environment. Cylinder depths of up to 4 to 6 m in the lunar mare or 10 to 12 m in the lunar highlands are possible. Advantages of this construction system include maximum resource utilization, relatively large habitable volumes, interior flexibility, and minimal construction equipment needs. Conclusions of this study indicate that there is significant potential for the use of basalt, a lunar resource derived construction material, as a low cost alternative to Earth-based materials. It remains to be determined when in lunar base phasing this construction method should be implemented.

Source record↗

Magnetic Nanoparticle Extraction of Lithium from Produced Waters: CRADA 483 [Abstract only]

In this project, we will synthesize, evaluate, and screen a set of new sorbents that have high capacity and selectivity for lithium. Sorbent performance will be evaluated by conducting Li extraction tests with produced water samples supplied by ConocoPhillips Company, Moselle Technologies, and Cascade Natural Resources. The best performing of these sorbents based on Li uptake capacity and selectivity will be produced as a magnetic nanoparticle and subjected to extended cycle testing in our laboratory bench-scale magnetic separator system. Moselle has acquired an exclusive license to the background IP associated with this magnetic nanoparticle mineral extraction technology and wishes to foster implementation of the technology in the oil & gas industry through this CRADA. Moselle will support PNNL in the design of a commercial-scale magnetic separator system tailored for lithium production. The goal is to collect sufficient information to support a decision by our industry partners to invest in a subsequent field demonstration at one of our partner’s field sites as a prerequisite to advancing this technology towards commercialization.

36 MATERIALS SCIENCE↗

Onboard Run-Time Goal Selection for Autonomous Operations

We describe an efficient, online goal selection algorithm for use onboard spacecraft and its use for selecting goals at runtime. Our focus is on the re-planning that must be performed in a timely manner on the embedded system where computational resources are limited. In particular, our algorithm generates near optimal solutions to problems with fully specified goal requests that oversubscribe available resources but have no temporal flexibility. By using a fast, incremental algorithm, goal selection can be postponed in a "just-in-time" fashion allowing requests to be changed or added at the last minute. This enables shorter response cycles and greater autonomy for the system under control.

Rabideau, Gregg↗

FORCE Update 2024

The Framework for Optimization of Resources and Economics (FORCE) tool suite is the U.S. Department of Energy’s Nuclear Integrated Energy Systems (IES) Program flagship tool suite for technoeconomic IES analysis of IES. This tool suite is useful for analysis designed to evaluate and improve the technoeconomics of energy production systems, particularly for systems including nuclear technology. In this report, we document the development activity for the FORCE tool suite to extend its capabilities as performed during fiscal year 2024. In addition to reliability and accessibility, capability is one of the three standards guiding the development of the FORCE tool suite and the software codes that are its constituent parts. Extending the capabilities of the FORCE tool suite allows analysis both within the IES program as well as industry, university, and laboratory partners to perform analysis with more accuracy, insight, and impactful narrative. Four areas of capability development were the focus of activity this year: economic parameter uncertainty quantification, multiresolution analysis, components-to-optimization workflow automation, and statespace construction workflows for real-time optimal control. In economic parameter uncertainty quantification, the ability of HERON to capture risk due to scenarios (weather and energy demand uncertainty) was expanded to also include uncertainties in financial parameters such as capital cost or operation and maintenance costs. By including these sources of uncertainty, which are sometimes very large compared with scenario uncertainty, HERON is better able to capture the risk posed by investment in various IES technology. Because of this, analysts can also consider the reduction in risks that can be realized by choice of some technologies. In multiresolution analysis, development activity extended on work completed previously. In fiscal year 2023, methods for decomposing time series signals, such as demand, solar and wind availability, and price profiles, were analyzed and down-selected to those most effective at splitting signals into different resolutions. These resolutions allow considering the influence of different energy demand and supply behaviors across different time scales. For example, energy demand might be divided into seasonal, weekly, and hourly profiles. In fiscal year 2024, this preliminary work was extended and implemented within the Risk Analysis Virtual Environment (RAVEN) risk and uncertainty analysis platform, which is used throughout the FORCE framework. This development of the “multi-resolution time series analysis” (MR-TSA) module in RAVEN allows training synthetic history generators on complex time series. These synthetic history generators can then be used in HERON for generating scenarios that represent possible market and weather scenarios that can be analyzed on different time scales. We envision completing this work in the future, implementing multiresolution dispatch optimization strategies that can make the most beneficial use of these stratified time histories. In components-to-optimization workflow development, workflows for translating user inputs of components into algorithms for algebraic optimization were selected and implemented. Similar algorithms within the Holistic Energy Resource Optimization Network (HERON) were separated from the main code base of HERON and gathered with the components-to-optimization workflows in the new Dispatch Optimization Variable Engine (DOVE) software library. This modularization allows FORCE users to analyze dispatch optimization and energy system duty cycles independently of HERON, which previously was a burdensome task. Additionally, these dispatch optimization algorithms, set up in an independent library, can now be used across all software applications within FORCE, especially including the real-time optimal control software Optimization of Real-time Capacity Allocation (ORCA). Allowing FORCE software to share dispatch optimization algorithms within a single library allows for improved software maintenance and reliability. In statespace characterization workflow development, alternative workflows for optimizing dispatch with additional technical accuracy was the focus, particularly to improve the real-time optimization decision making in ORCA. Using algorithms and workflows initially developed for the Feasible Actuator Range Modifier (FARM), workflows for determining the statespace representation of IES were identified and demonstrated. The resulting dispatch optimization required a more robust optimization algorithm than that originally used in HERON (and moved to DOVE), which required adding an alternate workflow to DOVE that can more accurately match the behavior of physical systems using a partial differential equation representation. In conclusion, capability developments in the FORCE tool suite in fiscal year 2024 have improved the ability of the FORCE tool suite to perform

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Assessing the Optimality of LinDist3Flow for Optimal Tap Selection of Step Voltage Regulators in Unbalanced Distribution Networks: Preprint

The adoption of distributed energy resources such as photovoltaics (PVs) has increased dramatically during the previous decade. The increased penetration of PVs into distribution networks (DNs) can cause voltage fluctuations that have to be mitigated. One of the key utility assets employed to this end are step-voltage regulators (SVRs). It is desirable to include tap selection of SVRs in optimal power flow (OPF) routines, a task that turns out to be challenging because the resultant OPF problem is nonconvex with added complexities stemming from accurate SVR modeling. While several convex relaxations based on semi-definite programming (SDP) have been presented in the literature for optimal tap selection, SDP based schemes do not scale well and are challenging to implement in large-scale planning or operational frameworks. This paper deals with the optimal tap selection (OPTS) problem for wye-connected SVRs using linear approximations of power flow equations. Specifically, the LinDist3Flow model is adopted and the effective SVR ratio is assumed to be continuous–enabling the formulation of a problem called LinDist3Flow-OPTS, which amounts to a linear program. The scalability and optimality gap of LinDist3Flow-OPTS are evaluated with respect to existing SDP-based and nonlinear programming techniques for optimal tap selection in three standard feeders, namely, the IEEE 13-bus, 123-bus, and 8500-node DNs. For all DNs considered, LinDist3Flow-OPTS achieves an optimality gap of approximately 1% or less while significantly lowering the computational burden.

linear approximations↗

Charging location selection of an incoming electric vehicle for large EV depot infrastructure

As the use of renewable energy resources increases within charging infrastructures, the risk that charging an additional load within the charging infrastructure will create a violation of the applicable grid code also increases. In an embodiment, a charging location is selected for an incoming load based on a load flow analysis, to thereby mitigate the risk of a violation. This selection process may also account for the charging schedule of the load and the capacity of available charging stations (e.g., fast charging vs. slow charging).

Hafiz, Faeza↗

An Overview of the Lunar Water ISRU Measurement Study (LWIMS)

NASA announced plans for the Artemis program, which would send crewed missions to the Moon by 2024 and achieve a sustainable lunar presence by 2028 [1]. To carry out sustained crewed surface operations, In-Situ Resource Utilization (ISRU), which would use lunar resources to produce mission consumables, will be critical. Water-bearing materials have been identified at both lunar poles and are often associated with Permanently Shadowed Regions (PSRs). These constitute a geological resource that may or may not be convertible to reserves with additional exploration. This water could provide both fuel and oxygen for refueling vehicles as well as life support consumables. However, the nature and extent of this resource is not well understood. Detection of water alone is not adequate for ISRU planning. For this reason, NASA chartered the Lunar Water ISRU Measurement Study (LWIMS). The goal of this study was to assess and define the type, amount, and fidelity of the measurements needed to select mining locations for lunar water ISRU and to define resource-related requirements for ISRU hardware development and architectures (mining operations, hardware emplacement, concept of operations).

Julie Kleinhenz↗