Design of semiconductor ternary quantum dots with optimal optoelectronic function
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FLASH is a multiphysics multiscale adaptive mesh refinement (AMR) code originally designed for simulation of reactive flows often found in Astrophysics. With its wide user base and flexible applications configuration capability, FLASH has a dual task of maintaining scalability and portability in all its solvers. The scalability of fully explicit solvers in the code is tied very closely to that of the underlying mesh. Others such as the Poisson solver based on a multigrid method have more complex scaling behavior. Multigrid methods suffer from processor starvation and dominating communication costs at coarser grids with increase in the number of processors. In this paper, we propose a combination of uniform grid mesh with AMR mesh, and the merger of two different sets of solvers to overcome the scalability limitation of the Poisson solver in FLASH. The principal challenge in the proposed merger is the efficiency of the communication algorithm to map the mesh back and forth between uniform grid and AMR. We present two different parallel mapping algorithms and also discuss results from performance studies of the two implementations. Copyright © 2012 John Wiley & Sons, Ltd.
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The Br-2/H-2 redox flow cell shows promise as a high-power, low-cost energy storage device. The effect of various aspects of material selection, processing, and assembly of electrodes on the operation, performance, and efficiency of the system is determined. In particular, (+) electrode thickness, cell compression, hydrogen pressure, and (-) electrode architecture are investigated. Increasing hydrogen pressure and depositing the (-) catalyst layer on the membrane instead of on the carbon paper backing layers have a large positive impact on performance, enabling a limiting current density above 2 A cm(-2) and a peak power density of 1.4 W cm(-2). Maximum energy efficiency of 79 % is achieved. In addition, the root cause of limiting-current behavior in this system is elucidated, where it is found that Br- reversibly adsorbs at the Pt (-) electrode for potentials exceeding a critical value, and the extent of Br- coverage is potential-dependent. This phenomenon limits maximum cell current density and must be addressed in system modeling and design. These findings are expected to lower system cost and enable higher efficiency.
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