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At least 397 records · Page 22

Mechanisms for the Crystallization of Zblan

The heavy metal fluoride glasses represent a class of reasonably good glass forming compositions with very unique infrared optical properties that have been of interest to researchers for 20 years. The most extensively studied glass with the most potential for practical applications is ZBLAN which contains the fluorides of zirconium, barium, lanthanum, aluminum, and sodium. It has a broad transmission range (0.3-6 um), low index of refraction (about 1.43), low dispersion, low Raleigh scattering, ultra-low thermal 2 dispersion, and potential ultra-low signal attenuation. Potential applications include fiber amplifiers, fiber optic gyroscopes, delivery systems for laser cutting, drilling and surgery, radiation resistant data links, nonlinear optical systems, and ultra-low-loss repeater-less transcontinental and transoceanic optical fiber. Potential markets for these materials are in the tens of billions of dollars per year. Optical fiber from this system possess excellent transmission characteristics in the IR, but the glass is somewhat susceptible to nucleation and crystallization. The theoretical intrinsic loss coefficient for ZBLAN at 2 microns is 0.00 1 dB/Km. Extrinsic losses, however, cause significant attenuation. The lowest loss coefficient measured is 0.7 dB/Km. This compares with the loss coefficient for fiber optic grade fused silica glass of 0.2 dB/Km. The extrinsic losses in ZBLAN have been attributed to 1) impurities which might be lowered by containerless processing and 2) to scattering from micro-crystallites that form during glass preform production or during fiber drawing.

Ethridge, Edwin C.↗

Methods for microwave characterization of electro-optic crystals for quantum transduction

Microwave-optic quantum transducers are essential devices to develop distributed quantum networks and implement related quantum communication protocols. Three dimensional high-coherence time microwave cavities embedded with electro-optic nonlinear dielectric materials provide promising platforms to boost the efficiency of the microwave-optic frequency conversion. However, so far, the properties for such dielectric crystals operating at milli-Kelvin cryogenic temperatures have not been well understood. Here, we propose a scheme to precisely measure and benchmark the dielectric constant and analyze the dissipation mechanisms of electro-optic materials, such as Lithium Niobate, at the quantum threshold. We will use Fermilab’s three dimensional superconducting cavities with long coherence time. The proposed method of microwave characterization lays the foundations for engineering quantum transduction devices and quantum sensors with high conversion efficiency and fidelity.

Zorzetti, Silvia↗

Spatio-spectral optical fission in time-varying subwavelength layers

Transparent conducting oxides are highly doped semiconductors that exhibit favourable optical features compared with metals, including reduced material losses, tuneable electronic and optical properties, and enhanced damage thresholds. Recently, the photonic community has renewed its attention towards these materials, recognizing their remarkable nonlinear optical properties in the near-infrared spectrum. The exceptionally large and ultrafast change in the refractive index, which can be optically induced in these compounds, extends beyond the boundaries of conventional perturbative analysis and makes this class of materials the closest approximation to a time-varying system. Here we report the spatio-spectral fission of an ultrafast pulse trespassing a thin film of aluminium zinc oxide with a non-stationary refractive index. By applying phase conservation to this time-varying layer, our model can account for both space and time refraction and explain, in quantitative terms, the spatial separation of both spectrum and energy. Our findings represent an example of extreme nonlinear phenomena on subwavelength propagation distances, which provides new insights into transparent conducting oxides’ transient optical properties. This can be critical for the ongoing research on photonic time crystals, on-chip generation of non-classical states of light, integrated optical neural networks, ultrafast beam steering and frequency-division multiplexing.

integrated optics↗

Developing a high-speed terahertz imaging system based on parametric upconversion imaging for penetrative sensing

Imaging using THz waves has been a promising option for penetrative measurements in environments that are opaque to visible wavelengths. However, available THz imaging systems have been limited to relatively low frame rates and cannot be applied to study fast dynamics. This work explores the use of upconversion imaging techniques based on nonlinear optics to enable wavelength-flexible high frame rate THz imaging. UpConversion Imaging (UCI) uses nonlinear conversion techniques to shift the THz wavelengths carrying a target image to shorter visible or near-IR wavelengths that can be detected by available high-speed cameras. This report describes the analysis methodology used to design a prototype high-rate THz UCI system and gives a detailed explanations of the design choices that were made. The design uses a high-rate pulse-burst laser system to pump both THz generation and THz upconversion detection, allowing for scaling to acquisition rates in excess of 10 kHz. The design of the prototype system described in this report has been completed and all necessary materials have been procured. Assembly and characterization testing is on-going at the submission of this report. This report proposes future directions for work on high-rate THz UCI and potential applications of future systems.

47 OTHER INSTRUMENTATION↗

Quantum Information for Fusion Energy Sciences (Final Technical Report)

The simulation of plasma dynamics is a critical area of Fusion Energy Sciences (FES) due to it’s usefulness in predicting, controlling, and confining plasmas in the context of potential fusion reactors. The simulation of plasmas is a computationally difficult problem in both classical and quantum physics, motivating investigation into the potential of quantum computers to simulate these systems. This project took several concrete steps towards this goal by developing tools for improving the control, characterization, and calibration of quantum gates on a superconducting quantum computer, developing error suppression and mitigation tools to reduce errors on the quantum computer, and utilizing these advancements to simulate reduced models of plasma dynamics on the quantum computer. In order to efficiently simulate plasma physics, an optimal control method which synthesizes, directly at the pulse level, any quantum gate on qubit and qutrit systems was developed. Using four superconducting transmon quantum processors at Rigetti and LLNL, it was demonstrated that any arbitrary quantum gate on qubits and qutrits could be implemented with high fidelity, leading to a significantly reduced length of a gate sequence. A problem of interest in FES is the nonlinear optical process of laser pulse compression within a plasma. Since quantum physics is linear, simulating nonlinear operations is not naturally feasible on a quantum computer, however it is possible to simulated a quantized version of the nonlinear process. A quantization approach to convert nonlinear wave-wave interaction problems to Hamiltonian simulation problems was developed and demonstrated using two qubits on a Rigetti device. In this experiment, a number of error suppression and mitigation techniques were investigated to determine how best to utilize the finite quantum resources. This study provides an example of how plasma problems may be solved on near-term, noisy quantum computing platforms and identified a promising set of techniques. Building on the insights of these experiments, the investigation turned to linear electron-plasma wave physics. A connection was identified between a local one-dimensional lattice spin model and linear wave phenomena, allowing a plasma physics problem to be efficiently mapped to the quantum computer. In this framework, reflection and transmission of plasma waves at a sharp boundary was studied, as well as the propagation of waves through an inhomogeneous plasma medium. In addition to the suite of error suppression and mitigation techniques developed, this experiment introduced the use of a digital-analog gate scheme designed to efficiently simulate the plasma Hamiltonian. With hardware available at the conclusion of the project, simulation at the scale of 9 qubits and 15 timesteps (60 entangling layers) was achieved.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Growth of thin films of dicyanovinylanisole on quartz and teflon-coated quartz by physical vapor transport

Organic compounds offer the possibility of molecular engineering in order to optimize the nonlinearity and minimize damage due to the high-power lasers used in nonlinear optical devices. Recently dicyanovinylanisole (DIVA), ((2-methoxyphenyl) methylenepropanedinitrile) has been shown to have a second order nonlinearity 40 times that of alpha-quartz. Debe et. al. have shown that a high degree of orientational order exists for thin films of phthalocyanine grown by physical vapor transport in microgravity. The microgravity environment eliminates convective flow and was critical to the formation of highly ordered dense continuous films in these samples. This work seeks to discover the parameters necessary for the production of thin continuous films of high optical quality in Earth gravity. These parameters must be known before the experiment can be planned for growing DIVA in a microgravity environment. The microgravity grown films are expected to be denser and of better optical quality than the unit gravity films as was observed in the phthalocyanine films.

Pearson, Earl F.↗

Optical processing using photorefractive GaAs and InP

The unique features of photorefractive compound semiconductors are presented. The advantages of this class of nonlinear optical materials for optical processing are illustrated with examples using GaAs and InP. The difference between GaAs and InP in the laser power density requirement is discussed.

Liu, Duncan T. H.↗

Control of second-harmonic generation in all-dielectric intersubband metasurfaces by controlling the polarity of χ (2)

All-dielectric metasurfaces have recently led to a paradigm shift in nonlinear optics as they allow for circumventing the phase matching constraints of bulk crystals and offer high nonlinear conversion efficiencies when normalized by the light-matter interaction volume. Unlike bulk crystals, in all-dielectric metasurfaces nonlinear conversion efficiencies primarily rely on the material nonlinearity, field enhancements, and the modal overlaps, therefore most efforts to date have only focused on utilizing these degrees of freedom. In this work, we demonstrate that for second-harmonic generation in all-dielectric metasurfaces, an additional degree of freedom is the control of the polarity of the nonlinear susceptibility. We demonstrate that semiconductor heterostructures that support resonant nonlinearities based on quantum-engineered intersubband transitions provide this new degree of freedom. We can flip and control the polarity of the nonlinear susceptibility of the dielectric medium along the growth direction and couple it to the Mie-type photonic modes. Here we demonstrate that engineering the χ (2) polarity in the meta-atom enables the control of the second-harmonic radiation pattern and conversion efficiency. Our results therefore open a new direction for engineering and optimizing second-harmonic generation using all-dielectric intersubband nonlinear metasurfaces.

42 ENGINEERING↗

Quantum optics or quantum electronics.

Quantum optics or electronics, discussing electromagnetic waves control and interactions with matter, maser oscillators theory and characteristics, nonlinear optics, induced transparency, etc

Townes, C. H.↗

Future directions in optical processing

Three aspects of optical processing are discussed. The three aspects are: (1) the potential of this emerging technology; (2) the major limitations preventing wide scale implementation of optical processors and the importance of future research in these areas is emphasized; (3) the importance of nonlinear optics in developing optoelectronic interconnects for VLSI.

Neff, J. A.↗

Linear response of molecular polaritons

In this article, we show that the collective light–matter strong coupling regime where N molecular emitters couple to the photon mode of an optical cavity can be mapped to a quantum impurity model where the photon is the impurity that is coupled to a bath of anharmonic transitions. In the thermodynamic limit where N ≫ 1, we argue that the bath can be replaced with an effective harmonic bath, leading to a dramatic simplification of the problem into one of the coupled harmonic oscillators. We derive simple analytical expressions for linear optical spectra (transmission, reflection, and absorption) where the only molecular input required is the molecular linear susceptibility. This formalism is applied to a series of illustrative examples, showing the role of temperature, disorder, vibronic coupling, and optical saturation of the molecular ensemble, explaining that it is useful even when describing an important class of nonlinear optical experiments. For completeness, we provide Appendixes A–C that include a self-contained derivation of the relevant spectroscopic observables for arbitrary anharmonic systems (for both large and small N) within the rotating-wave approximation. While some of the presented results herein have already been reported in the literature, we provide a unified presentation of the results as well as new interpretations that connect powerful concepts in open quantum systems and linear response theory with molecular polaritonics.

Chemistry↗

Phase conjugation by degenerate four wave mixing in disodium fluorescein solution in methanol

Organic dyes are known to show the resonant type of nonlinear optical properties, including phase conjugation. In the present work, disodium fluorescein in methanol is used as an organic nonlinear medium for degenerate four wave mixing at 532 nm to see the intensity dependence of the phase conjugate signal at different concentrations of the solution. It is observed that the maximum reflectivity of the signal occurs in a concentration range of 5 x 10(exp -3)/cu cm to 1.2 x 10(exp -2) g/cu cm. It is also observed that the intensity of the signal drops suddenly to less than half of its maximum outside the concentration range mentioned above. An investigation of the phase conjugate signal intensity by changing the delay time between probe signal and the forward pump is also examined. Briefly discussed is the possibility of population grating in dye liquids as a source of enhancing the third order susceptibility besides the other techniques mentioned in reference. The experiment is done by beam splitting the second harmonic (532 nm) of Nd:YAG laser, Q-switched at 20 pulses/sec (pulse width is approximately 8 and 200 mJ per pulse).

Abdeldayem, Hossin↗

Number-Phase Uncertainty Relations for Optical Fields

The Hermitian phase formalism of Pegg and Barnett allows for direct calculations of the phase variance and, consequently, the number-phase uncertainty product. This gives us a unique opportunity, inaccessible before, to study the number-phase uncertainty relations for optical fields in a direct way within a consistent quantum formalism. A few examples of fields generated in nonlinear optical processes are studied from the point of view of their number-phase uncertainty relations.

Tanas, Ryszard↗

Nonlinear interferometer systems and methods

Nonlinear interferometers include a nonlinear optical medium that is situated to produce a conjugate optical beam in response to a pump beam and a probe beam. The pump, probe, and conjugate beams propagate displaced from each other along a common optical path. One of the beams is selectively phase shifted, and the beams are then returned to the nonlinear medium, with the selectively phase shift beam phase shifted again. The nonlinear medium provides phase sensitive gain to at least one of the probe or conjugate beams, and the amplified beam is detected to provide an estimate of the phase shift.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Intrinsic optical bistability of photon avalanching nanocrystals

Optically bistable materials respond to a single input with two possible optical outputs, contingent on excitation history. Such materials would be ideal for optical switching and memory, but the limited understanding of intrinsic optical bistability (IOB) prevents the development of nanoscale IOB materials suitable for devices. Here we demonstrate IOB in Nd 3+ -doped KPb 2 Cl 5 avalanching nanoparticles, which switch with high contrast between luminescent and non-luminescent states, with hysteresis characteristic of bistability. Here we elucidate a non-thermal mechanism in which IOB originates from suppressed non-radiative relaxation in Nd 3+ ions and from the positive feedback of photon avalanching, resulting in extreme, >200th-order optical nonlinearities. The modulation of laser pulsing tunes the hysteresis widths, and dual-laser excitation enables transistor-like optical switching. This control over nanoscale IOB establishes avalanching nanoparticles for photonic devices in which light is used to manipulate light.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Optical Computers and Space Technology

The rapidly increasing demand for greater speed and efficiency on the information superhighway requires significant improvements over conventional electronic logic circuits. Optical interconnections and optical integrated circuits are strong candidates to provide the way out of the extreme limitations imposed on the growth of speed and complexity of nowadays computations by the conventional electronic logic circuits. The new optical technology has increased the demand for high quality optical materials. NASA's recent involvement in processing optical materials in space has demonstrated that a new and unique class of high quality optical materials are processible in a microgravity environment. Microgravity processing can induce improved orders in these materials and could have a significant impact on the development of optical computers. We will discuss NASA's role in processing these materials and report on some of the associated nonlinear optical properties which are quite useful for optical computers technology.

Abdeldayem, Hossin A.↗

Qualification and Performance of a High-Efficiency Laser Transmitter for Deep-Space Optical Communications

A high-power Laser Transmitter Assembly (LTA) was developed to support the Deep Space Optical Communications (DSOC) technology demonstration being developed by the Jet Propulsion Laboratory. NASA’s Psyche Mission plans to host the DSOC flight subsystem for testing space-to-ground high-bandwidth laser communications en route to the 16 Psyche asteroid. We review the design, performance, and qualification of the LTA Engineering Model and Flight Model (EM and FM) delivered to JPL. The LTA uses a master-oscillator power amplifier (MOPA) design and delivers up to 4.5 W at 1550 nm, with a highly efficient, cladding-pumped, polarization-maintaining erbium-ytterbium fiber amplifier. The master oscillator generates a range of pulse widths and repetition rates to support modulation formats from 16- to 128-PPM for optical data transmission at >100 Mbps. The LTA was designed for high reliability and radiation hardness, and includes redundant signal and pumping paths to reduce single points of failure, hardware interlocks to ensure safe operation and protection against damage, closed-loop control of optical power, and detailed health and status via telemetry. The LTA EM and FM were subjected to unit-appropriate space qualification testing. We describe the performance testing of the EM and FM, for the characterization of key metrics such as wavelength stability, signal linewidth, optical pulse width, jitter, and extinction ratio, and polarization extinction ratio. The management of optical nonlinearities (self-phase modulation, Brillouin scattering, or pulse-to-pulse energy variation), which could result in an optical link penalty or damage to the LTA, is also detailed, and factors affecting the power efficiency are discussed.

Jaques, J.↗

Tunable Laser-Plasma Amplifier (Final Report)

Exploration at the laser intensity frontier has always offered new avenues for physics and reaching beyond this frontier is a grand challenge. Present-day petawatt-class lasers provide focused intensities on target of 10 22 W/cm 2 , corresponding to electric fields of 200 TV/m, while laser-plasma amplification opens a route for focused intensities well above 10 23 W/cm 2 . Intensities in this range provide the ability to test quantum electrodynamics in the unexplored low-energy, strong-field regime where signatures for new physics may arise. The behavior of matter under such extraordinary conditions is a rich and fascinating subject, not only in its own right in fundamental plasma physics, but for the many potential applications that promise to enrich the natural sciences in the future, including compact electron-beam, ion-beam particle accelerators, and ultra-bright X-ray sources. Although laser systems are now under construction internationally to access intensities of 10 23 W/cm 2 , the current technologies used appear to be fundamentally limited to these intensities. The realization of intensities beyond 10 23 W/cm 2 using parametric amplification in plasmas promises a breakthrough in high-energy density physics. Parametric amplification using Raman scattering in a plasma could provide the enabling technology for the generation of ultra-high-power laser pulses, but a more complete understanding of the nonlinear optics of plasmas is required. There is a significant gap in well-diagnosed laser-plasma instability studies of nonlinear plasma-wave phenomena, which are critical to understand for future laser-plasma devices. To achieve an efficient laser-plasma amplifier, plasma waves must be driven to large amplitude where significant energy can be rapidly transferred from the pump to the seed over the pulse duration of the seed. Simulations suggest that this nonlinear pump depletion regime can be achieved in the “pi-pulse” amplification regime. While simulations show this optimal regime with efficient amplification, it has remained elusive in experiments and there is a growing consensus within the community that thermal effects and pump beam limitations prevent laser-plasma amplifiers from progressing through the linear regime into the nonlinear pump depletion regime. Previous experiments have been significantly limited by the laser power available at the necessary wavelengths for the seed laser; therefore, the amplification is required to start in the linear regime where it is sensitive to many deleterious effects. The enabling technology (currently unique to plasma-wave amplification in the world) at the University of Rochester is the ability to provide a seed pulse with sufficient power (4 mJ/100 fs seed) to immediately drive nonlinear plasma waves into the pi-pulse regime and to tune its wavelength to optimize the efficiency of energy transfer. This in combination with the state-of-the-art OMEGA heater beams providing multiple kilojoules in a nanosecond to sufficiently heat the plasma make this system distinct from previous studies. These heater beams will provide, for the first time in Raman amplification studies, a homogeneous electron temperature high enough to prevent pump beam propagation issues that have plagued previous experiments. These systems will provide a platform for driving electron-plasma waves into the nonlinear regime where pump depletion and pulse shortening are predicted to lead to high amplification efficiencies (>30%). The Team has made significant progress through prior support from DOE Fusion Energy Sciences [DOE Office of Science Award Number DE-SC0016253 (2016-2022)]. This includes twenty-two peer-reviewed manuscripts, one patent, ten contributed talks presented at international conferences, and research that was highlighted as invited talks at fifteen international conferences. The broader impacts of this research are evident in the support of early career scientists, two Ph.D. theses, four current graduate students, a Masters Project, two undergraduate researchers, and an underrepresented minority student hired through the California Alliance for Minority Participation who now works as a Research Engineer in the group. This research met all of the funded research objectives and the highlights from primary Raman amplification thrust of this work are discussed below and form the foundation for the proposed research.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗