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At least 397 records · Page 22

Diagnostics: Chapter 8 of the special issue: on the path to tokamak burning plasma operation

This chapter presents the activity conducted by the ITPA topical group (TG) on Diagnostics over about the last 15 years. Following a general introduction of the ITER Diagnostics led by their measurement roles, the document is organized in several subchapters detailing the design support, research and development activity conducted by each of the specialist working groups (WGs) of the TG. Please note that the magnetic diagnostics were supported at the TG without a specific WG. Their status is included in the general introduction. In the following some highlights of the subchapter’s contents are provided. Recent advances in ITER first wall (FW) diagnostics for the measurements of plasma-metallic wall interaction in support of the ITER research plan are reported. An InfraRed imaging Video Bolometer for ITER has been developed and tested on several tokamaks to measure the radiated power loss. A laser-induced breakdown spectroscopy (LIBS) technique which utilizes a pulsed laser beam to ablate locally by forming a crater, will measure local tritium inventory in the FW material. Real-time Residual Gas Analyzers will measure the neutral gas composition in a divertor port and an equatorial port during plasma operation. Due to the full metallic FW environment, the plasma-wall interaction in ITER will face several challenges such as the compromised radiated power and divertor heat flux measurements by reflection. Ray tracing and analysis codes have been developed to eliminate and correct the effects of reflection in the measurements. The characteristics of the reflecting surfaces depending on the roughness and angle of the incidence have been measured by dedicated experiments, and the results were applied to the reflection elimination. For the measurement of the metallic impurity radiation induced by eroded metallic atoms, a vacuum ultraviolet spectrometer has been developed and tested. An extensive thermonuclear diagnostic suite will be required to support the operation of ITER and the planned experimental program for future burning plasma experiments. Due to the harsh environmental conditions, the implementation of diagnostic systems in ITER is a major challenge. These conditions include high levels of neutron and gamma fluxes, neutron heating, particle bombardment. Therefore, the selection and design of diagnostic systems must take into account a number of phenomena previously unseen in diagnostic design. For this reason, the measurement of neutrons and confined or lost fast ions, with particular emphasis on alpha particles, is critical to ITER. The diagnostics associated with these measurements will be important for future plasma-burning experiments at ITER. The high neutron emission and very large plasma size in ITER make neutron diagnostics the main diagnostic method used to measure plasma parameters such as fusion power, fusion power density, ion temperature, energy of fast ions and their spatial distributions in the plasma core. Active spectroscopy techniques are methods where a neutral particle beam is injected into the plasma and information on plasma parameters is extracted from the measurement of line emission resulting from the beam-plasma interaction, either by plasma ions or by beam atoms. Spatial localization is achieved by crossing the beamline and multiple observation lines. The ITER plasma will be a high temperature, moderately dense, fully ionized collisional plasma. The plasma facing surfaces are principally metallic being fashioned from beryllium or tungsten but many other elements, arising from either structural or from operational needs, may enter this plasma. The energy range of the emitted photons range from meV (infra-red) to multi keV (x-rays) and originate from all areas of the plasma volume. The primary role of passive emission diagnostics is to identify what is in the plasma from spectral signatures. Extracting quantitative information from these measurements such as impurity content, ion temperature, rotation, degree of detachment and radiated power depends on calibrated instruments, a physics model of the atomic and molecular processes and plasma transport and an analysis workflow that takes into account environmental effects such as reflections. The particular needs for ITER have prompted a multi-machine, many-year effort to address all these aspects and this chapter reviews the work on diagnostic design, experiments and new analysis techniques. An overview of the laser diagnostics to be implemented on ITER is also provided in this paper. This includes descriptions of the Thomson scattering in the core, edge and divertor regions, polarimetry and interferometry diagnostics used for measuring plasma density and also measurements of helium density in the divertor using Laser Induced Flourescence. Techniques which can allow improvements on current measurements are also addressed in particular expanding poloidal polarimetry measurements to measure field fluctuations and proposed use of dispersion interferometery which has a number of advantages over existing methods. This paper identifies particular areas where further research and testing on existing tokamaks is useful even at this advanced stage to inform the design of diagnostics for ITER. Outstanding areas of concern for the implementation of laser diagnostics, in particular with a view to reliable operation are identified. An overview of the latest developments of microwave diagnostic systems and techniques is given. The primary focus is the contributions for ITER—the next step burning plasma experiment—which is supplemented by describing recent progress of techniques applicable for fusion experiments beyond ITER. The contributions are intentionally kept concise, and are being supplemented by a rich list of references for further studies. Radiation induced effects are receiving continuous and well-deserved attention of the ITER diagnostic community and they are in many cases one of the primary design drivers of the ITER diagnostic systems. The paper summarizes recent progress in this area focusing primarily on the ITER diagnostics but in some cases provides also outlook for the possible solutions for even more demanding radiation environment of fusion reactors beyond ITER. Despite advancements in the area of modeling and simulation of various radiation induced effects, experimental testing in a nuclear environment as close as possible to the target one is still seen as unavoidable for proper qualification of particular diagnostic functional elements. Recent advancement within three diagnostic areas: optical diagnostics, magnetics and bolometers is covered. Encouraging results on qualification of silica glass vacuum window assemblies are presented. In the area of magnetic sensors, progress of irradiation tests performed on ITER in-vessel LTCC inductive sensors is presented with outlook for novel technological approaches to inductive sensors utilizing thick printing and photolithography technologies being highlighted. Summary of advancements in the area of steady state magnetic field sensors based on Hall effect is given. New results of neutron irradiation test of the ITER borosilicate glass inserts for vacuum electrical feedthroughs are summarized finding negligible swelling at target level of neutron fluence. Off-line irradiation tests of fiber optic current sensors for plasma current measurement demonstrated that both for gamma doses up to 5 MGy and a total neutron fluence up to 10 15 cm −2 , radiation induced changes are still compatible with required measurement accuracy on ITER. The ITER bolometers are given as an example how considering radiation effects may influence the diagnostic design. Finally, outlook for future main R&D directions is outlined. All optical and laser-based diagnostics in ITER will be using mirrors to guide plasma radiation toward detectors, cameras and sensors. In the hostile plasma, radiation and particle environment the optical characteristics of diagnostic mirrors will degrade directly affecting the entire performance of involved diagnostic systems. An assessment of factors affecting mirror performance is provided. Among the prime adverse factors are deposition of plasma impurities, sputtering of mirror surface and steam ingress in the vicinity of mirrors. Within the International Tokamak Physics Activity with active support by ITER central team and domestic agencies, the structured research and development (R&D) program on mitigation of risks for diagnostic mirrors is underway. Within this program the mirror material development, the passive mitigation of mirror degradation by using diagnostic ducts and shutters along with an active mirror recovery program comprising the in-situ mirror cleaning and calibration is underway. Recent developments in diagnostic mirror R&D are described in this Chapter along with an example of their implementation of R&D solutions in ITER Infrared Thermography diagnostic. An assessment of still open engineering and physics questions, considerations on mirror risks during an early phase of ITER operation are given along with an overview of diagnostic mirror evolution in the late ITER operation stage toward the demonstration fusion power plant. Several crucial areas of diagnostic R&D outlined in ITER Research Plan are addressed. The basic control groups in a fusion reactor can be broken-down in five categories: (1) plasma position, magnetic configuration, and plasma current control, (2) profile control and confinement optimization, (3) MHD control and suppression, (4) edge dissipation control, radiation and plasma exhaust control and (5) break-down optimization. These categories are coupled via the physics (a control action in one domain will affect the other domains) and via shared actuators (e.g. ECRH for impurity accumulation avoidance, current density distribution control and MHD suppression). Consequently, a supervisory control system should determine the priority of the various control tasks, their couplings, and the interfaces with the safety and interlock system. For the systematic development of the various controllers taking the complexity of the plasma and the control system into account, a model-based approach is required. A short historical overview is given of the developments in systems and control theory and control engineering with special emphasis on those developments that are most relevant for Nuclear Fusion research and operation. An overview is given of the state of the field of fusion plasma control for the control categories. It will be shown how synthetic diagnostics are being developed in ITER and how they are used in diagnostic design and design validation and how they can be in model-based controller synthesis using relatively simple models. In modern control methods, multiple diagnostics are used to constrain relatively simple models. The constrained models provide an estimate for the state. This opens the route to state controllers, such as model predictive control. A major challenge in nuclear fusion research is the coherent combination of data from heterogeneous diagnostics and modeling codes for machine control and safety as well as physics studies. Measured data from different diagnostics often provide information about the same subset of physical parameters. Additionally, information provided by some diagnostics might be needed for the analysis of other diagnostics. A joint analysis of complementary and redundant data allows, e.g. to improve the reliability of parameter estimation, to increase the spatial and temporal resolution of profiles, to obtain synergistic effects, to consider diagnostics interdependencies and to find and resolve data inconsistencies. Physics-based modeling and parameter relationships provide additional information improving the treatment of ill-posed inversion problems. A coherent combination of all kind of available information within a probabilistic framework allows for improved data analysis results. The concept of integrated data analysis (IDA) in the framework of Bayesian probability theory is outlined and contrasted with conventional data analysis. Components of the probabilistic approach are summarized and specific ingredients beneficial for data analysis at fusion devices are discussed.

ITER↗

Sputtering Erosion in Ion and Plasma Thrusters

Low energy sputtering of molybdenum, tantalum and boron nitride with xenon ions are being studied using secondary neutral and secondary ion mass spectrometry (SNMS/SIMS). An ultrahigh vacuum chamber was used to conduct the experiment at a base pressure of 1x10(exp -9) torr. The primary ion beam is generated by an ion gun which is capable of delivering ion currents in the range of 20 to 500 nA. The ion beam can be focused to a spot size of approximately 1 mm in diameter. The mass spectrometer is positioned 10 mm from the target and 90 deg to the primary ion beam direction. SNMS and SIMS spectra were collected at various incident angles and different ion energies. For boron nitride sputtering, the target was flooded with an electron beam to neutralize the charge buildup on the surface. In the SNMS mode, sputtering of Mo and Ta can be detected at an ion energy as low as 100 eV whereas in boron nitride the same was observed up to an energy of 300 eV. However, in the positive-SIMS mode, the sputtering of Mo was observed at 10 eV incident ion energy. The SIMS spectra obtained for boron nitride clearly identifies the two isotopes of boron as well as cluster ions such as B2(sup +) and molecular ions such as BN(sup +). From the angle versus yields measurements, it was found that the maximum SNMS yield shifts towards lower incident angles at low ion energies for all three samples.

Ray, Pradosh K.↗

Results of the M.I.T. Beam Assembly Teleoperator and Integrated Control Station

To examine the issues of optimum human-machine mixtures for orbital assembly operations, a full six degree-of-freedom teleoperator system for assembly of large space structures has been developed by the Space Systems Laboratory. This consists of a free-flying neutrally buoyant Beam Assembly Teleoperator (BAT) with two manipulators, and a modular Integrated Control Station (ICS). The design and configuration of both the BAT and the ICS are described in some detail in this paper. In addition, qualitative results from early tests of the system are presented. These tests concentrated mostly on free-flying operations and grasping. Future tests will involve complete teleoperated assembly.

Spofford, J. R.↗

Charged particle measurements on a 30-CM diameter mercury ion engine thrust beam

Measurements of both thrust ions and charge exchange ions were made in the beam of a 30 centimeter diameter electron bombardment mercury ion thruster. A qualitative model is presented which describes magnitudes of charge exchange ion formation and motions of these ions in the weak electric field structure of the neutralized thrust beam plasma. Areas of agreement and discrepancy between observed and modeled charge exchange properties are discussed.

Sellen, J. M., Jr.↗

Neutralization tests on the SERT II spacecraft

Orbit precession returned the SERT II spacecraft to continuous sunlight in January 1979 for the first time since early 1972, and new experiments were planned and conducted. Neutralization of an ion beam was accomplished by a second neutralizer cathode located 1 meter away. Plasma potential measurements were made of the plasma surrounding the ion beam and connecting the beam to the second neutralizer. When the density of the connecting plasma was increased by turning on the main discharge of a neighboring ion thruster, the neutralization of the ion beam occurred with improved (lower) coupling voltage. These and other tests reported should aid in the future design of spacecraft using electric thruster systems. Data taken indicate that cross neutralization of ion thrusters in a multiple thruster array should occur readily.

Kerslake, W. R.↗

Ion thruster performance model

A model of ion thruster performance is developed for high flux density, cusped magnetic field thruster designs. This model is formulated in terms of the average energy required to produce an ion in the discharge chamber plasma and the fraction of these ions that are extracted to form the beam. The direct loss of high energy (primary) electrons from the plasma to the anode is shown to have a major effect on thruster performance. The model provides simple algebraic equations enabling one to calculate the beam ion energy cost, the average discharge chamber plasma ion energy cost, the primary electron density, the primary-to-Maxwellian electron density ratio and the Maxwellian electron temperature. Experiments indicate that the model correctly predicts the variation in plasma ion energy cost for changes in propellant gas (Ar, Kr and Xe), grid transparency to neutral atoms, beam extraction area, discharge voltage, and discharge chamber wall temperature. The model and experiments indicate that thruster performance may be described in terms of only four thruster configuration dependent parameters and two operating parameters. The model also suggests that improved performance should be exhibited by thruster designs which extract a large fraction of the ions produced in the discharge chamber, which have good primary electron and neutral atom containment and which operate at high propellant flow rates.

Brophy, J. R.↗

A facility to produce an energetic, ground state atomic oxygen beam for the simulation of the Low-Earth Orbit environment

Because of the continuing commitment to activity in low-Earth orbit (LEO), a facility is under development to produce energetic atmospheric species, particularly atomic oxygen, with energies ranging from 5 to 80 eV. This relatively high flux facility incorporates an ion engine to produce the corresponding specie ion which is charge exchanged to produce a neutral atomic beam. Ion fluxes of around 10(exp 15) sec(exp -1) with energies of 20-70 eV have been achieved. A geometrically augmented inertially tethered charge exchanger (GAITCE) was designed to provide a large column depth of charge exchange gas while reducing the gas load to the low pressure portion of the atomic beam facility. This is accomplished using opposed containment jets which act as collisional barriers to the escape of the dense gas region formed between the jets. Leak rate gains to the pumping system on the order of 10 were achieved for moderate jet mass flows. This system provides an attractive means for the charge exchange of atomic ions with a variety of gases to produce energetic atomic beams.

Ketsdever, Andrew D.↗

Non-solar UV produced ions observed optically from the 'Crit I' critical velocity ionization experiment

A critical velocity ionization experiment was carried out with a heavily instrumented rocket launched from Wallops Island on May 13, 1986. Two neutral barium beams were created by explosive shaped charges released from the rocket and detonated at 48 deg to B at altitudes near 400 km and below the solar UV cutoff. Critical velocity ionization was expected to form a detectable ion jet along the release field line, but, instead, an ion cloud of fairly uniform intensity was observed stretching from the release field line across to where the neutral barium jet reached sunlight. The process creating these ions must have been present from the time of the release; the efficiency is estimated to be equivalent to an ionization time constant of 1800 sec. This ionization is most likely from collisions between the neutral barium jet and the ambient atmospheric oxygen, and, if so, the cross section for collisional ionization is 9 x 10 to the -18th sq cm.

Stenbaek-Nielsen, H. C.↗

Space plasma physics results from Spacelab 1

The Spacelab 1 payload carried several instrument systems which together investigated a number of space plasma phenomena. These experiments used the Space Shuttle Orbiter as a platform for making controlled particle-beam, plasma and neutral gas inputs to the ionosphere and magnetosphere and for observing the outputs produced. Spacelab 1 space-plasma investigations included the Space Experiments with Particle Accelerators (SEPAC), Phenomena Induced by Charged Particle Beams (PICPAB), Atmospheric Emissions Photometric Imaging (AEPI) and the Low Energy Electron Spectrometer and Magnetometer. Among the major phenomena investigated both singly and jointly by these experiments are vehicle charging and neutralization, beam-plasma and wave-particle interactions, anomalous ionization phenomena produced by neutral-gas and plasma injections and several phenomena induced by modulated particle beam injections.

Burch, J. L.↗

Improved Joint FHC+RHC Sterile Analysis with Nu-on-E Sample

The NOvA experiment measures neutrino oscillations in a nearly pure muon neutrino beam. The neutral current (NC) and the muon neutrino charged current (CC) interaction disappearance are studied to search for active-to-sterile neutrino oscillations. NOvA consists of two functionally identical detectors placed 14 mrad off-axis of Fermilab's NuMI beamline. The Near Detector (ND) is located 100 m underground on-site at Fermilab, while the Far Detector (FD) sits on the surface 810 km away at Ash River, Minnesota. The NuMI beam is capable of running in forward or reverse horn current modes, creating a predominantly neutrino or antineutrino beam, respectively. For this analysis, a simultaneous near and far detector joint fit approach was utilized. Systematic uncertainties constrain the ND while the statistical uncertainties constrain the FD. For the upcoming analysis, we plan on including a dedicated neutrino-on-electron elastic scattering sample. This interaction is advantageous as it is subject to minimal cross-section uncertainties, which will help reduce degeneracies between other uncertainty categories. This thesis presents the sterile neutrino oscillation sensitivity results using 27.2e+20 POT in FHC mode, 12.6e+20 in RHC mode.

Haejun, Stella Oh [Cincinnati U.]↗

NOvA Sterile Neutrino Search with Additional Systematic Constraints

The NOvA experiment measures neutrino oscillations in a nearly pure muon neutrino beam. The neutral current (NC) and the muon neutrino charged current (CC) interaction disappearance are studied to search for active-to-sterile neutrino oscillations. NOvA consists of two functionally identical detectors placed 14 mrad off-axis of the Fermi National Accelerator Laboratory's NuMI beamline. The Near Detector (ND) is located 100 meters underground on-site at Fermilab, while the Far Detector (FD) is situated on the surface 810 kilometers away at Ash River, Minnesota. The NuMI beam is capable of operating in either forward or reverse horn current modes, producing predominantly neutrino or antineutrino beams, respectively. For this analysis, a simultaneous near and far detector joint fit approach was utilized. Systematic uncertainties constrain the ND while the statistical uncertainties constrain the FD. In addition to the dual baseline approach, the neutrino-on-electron elastic scattering sample was included. This interaction is advantageous as it is subject to minimal cross-section uncertainties, which will help reduce degeneracies between other uncertainty categories. This thesis presents the sterile neutrino oscillation sensitivity results using 27.2e+20 POT in FHC mode, 12.6e+20 in RHC mode, with the nu-on-e sample of 13.6e+20 POT in FHC.

Oh, Haejun [Cincinnati U.]↗

Room temperature buffer gas beam of metastable state titanium atoms

We produce beams of neutral titanium (Ti) atoms in their metastable 3d3(F4)4sa5F5 state by laser ablation into He, N2, and Ar buffer gases. The high temperatures associated with the ablation process populate the a5F5 level without the need for optical pumping. Remarkably, we observe that Ti atoms in the a5F5 state survive thousands of collisions with He and Ar buffer gas atoms without being quenched to lower-energy states. We study the yield of Ti atoms when ablated into buffer gases of varying species and pressure, quantify quenching rates and diffusion cross sections based on simple models, and provide insight into optimal design parameters for an ablation cell. Using a 3.3 cm ablation cell with interchangeable exit apertures, we produce metastable atom beams and quantify their brilliance and velocity distributions as functions of buffer gas pressure.

Schrott, Jackson↗

Validation of the imaging neutral particle analyzer in nearly MHD quiescent plasmas using injected beam ions on DIII-D

The imaging neutral particle analyzer (INPA) is a scintillator-based diagnostic that provides energy and radially resolved measurements of confined fast ions. To verify operation, understanding, and modeling of the diagnostic performance, distributions of deuterium beam ions in low density, nearly MHD-quiescent plasmas are measured on the DIII-D tokamak using the INPA. Here, the distribution is altered by changing the pitch-angle scattering rate with electron cyclotron heating (ECH). Experimental images are mostly reproduced with simulation of core fast ions charge exchanging with injected beam and edge cold neutrals in classical cases. Image comparisons between the experiment and simulation show agreement with less than 25% discrepancies near the beam injection energy of 50 keV. Other strong passive signals, observed in a localized region on the image, are suggested to come from charge exchange between cold neutrals and fast ions around the plasma boundary.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A high flux source of swift oxygen atoms

A source of swift oxygen atoms is described which has several unique features. A high current ion beam is produced by a microwave discharge, accelerated to 10 keV and the mass selected by a modified Du Pont 21-110 mass spectrometer. The O(+) beam exciting the mass spectrometer is focused into a rectangular shape with an energy spread of less than 1 eV. The next section of the machine decelerates the ion beam into a counterpropagating electron beam in order to minimize space charge effects. After deceleration, the ion beam intersects at 90 deg, a neutral oxygen atom beam, which via resonant charge exchange produces a mixture of O(+) and O. Any remaining O(+) are swept out of the beam by an electric field and differentially pumped away while the desired O beam, collimated by slits, impinges on the target. In situ monitoring of the target surface is done by X-ray photoelectron or Auger spectroscopy. Faraday cups provide flux measurements in the ion sections while the neutral flux is determined by a special torsion balance or by a quadrupole mass spectrometer specially adapted for swift atoms. While the vacuum from the source through the mass spectrometer is maintained by diffusion pumps, the rest of the machine is UHV.

Fink, M.↗

Isotope impact on Alfvén eigenmodes and fast ion transport in DIII-D

Abstract Measurements of beam driven Alfvén Eigenmode (AE) activity in matched deuterium (D) and hydrogen (H) DIII-D plasmas show a dramatic difference in unstable mode activity and fast ion transport for a given injected beam power. The dependence of the unstable AE spectrum in reversed magnetic shear plasmas on beam and thermal species is investigated in the current ramp by varying beam power in a sequence of discharges for fixed thermal and beam species at fixed density. In general, a spectrum of Reversed Shear Alfvén Eigenmodes (RSAEs) and Toroidal Alfvén Eigenmodes (TAEs) are driven unstable with sub-Alfvénic D beam injection while primarily only RSAEs are driven unstable for the H beam cases investigated. Further, for a given beam power, the driven AE amplitude is always reduced with H beams relative to D and for H thermal plasma relative to pure D or mixed D/H plasmas. Estimates of the fast ion stored energy combined with modeling using the hybrid kinetic-MHD code MEGA indicate that the dominant mechanism contributing to the difference between H and D beam drive is the faster classical slowing down of H beam ions relative to D and the resultant lower beam ion pressure. Calculations of the AE induced stored energy deficits using the reduced critical gradient model TGLFEP show quantitative agreement with the observed dependencies on injected power, isotope and minimum safety factor.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Tailoring the Physicochemical Properties of Nb Thin Films via Surface Engineering Methods

The modification of surface oxide layers formed on niobium (Nb) thin films via chemical mechanical planarization (CMP) and accelerated neutral atom beam (ANAB) processing provides a promising route toward tailoring their emergent properties and performance when used as superconducting qubits. Here, in this study, we show that CMP- and ANAB-formed Nb oxides are significantly thinner and smoother than the native oxide, as revealed by transmission electron microscopy (TEM) and atomic force microscopy. Scanning TEM and energy-dispersive X-ray spectroscopy along with X-ray photoelectron spectroscopy identified an oxidation gradient within the native and surface-engineered oxides. The topside layer is dominated by Nb 5+ (Nb 2 O 5 ), with various Nb suboxides present closer to the oxide/metal interface. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) depth profiling confirmed the presence of an oxygen content gradient and demonstrated the enhanced resistance of the CMP- and ANAB-formed oxides to oxygen surface exchange and subsequent diffusion via 18 O 2 isotopic labeling experiments. ToF-SIMS also identified an interfacial layer containing trapped hydrogen (H)-containing species at the Nb oxide/metal interface. In situ ToF-SIMS and TEM revealed migration of the H/OH interfacial layer coinciding with decomposition of the surface oxide. Furthermore, our density functional theory calculations indicated that both H from moisture present in ambient air and bulk H in Nb films tend to segregate at the interface. These findings underscore the importance of understanding surface oxidation mechanisms, hydrogen incorporation, and their impact on the designed functionalities of Nb-based devices.

36 MATERIALS SCIENCE↗

Photodissociation dynamics of the tert -butyl perthiyl radical

Here, the photodissociation dynamics of the tert-butyl perthiyl (t-BuSS) radical are investigated by fast-beam coincidence translational spectroscopy. A fast (6 keV-8 keV) beam of neutral t-BuSS radicals is produced via photodetachment of the corresponding anion, followed by photodissociation at 248 nm (5.00 eV) or 193 nm (6.42 eV) and coincident detection of the neutral products. Photofragment mass and translational energy distributions are obtained at both wavelengths. At 248 nm, the dominant product channel (90%) is found to be S loss, with a product translational energy distribution that peaks close to the maximum available energy and an anisotropic photofragment angular distribution, indicating dissociation along a repulsive excited state. A minor channel (10%) leading to the formation of S 2 + t-Bu is also observed. At 193 nm, both two- and three-body dissociation are observed. The formation of S 2 + t-Bu is the dominant two-body product channel, with multiple electronic states of the S 2 molecule produced via excited-state dissociation processes. The formation of S + t-BuS is a minor two-body channel at this dissociation energy. The three-body channels are S 2 + H + isobutene, S 2 + CH 3 + propene, and S + SH + isobutene. The first two of these channels result from a sequential dissociation process in which the loss of S 2 from t-BuSS results in ground-state t-Bu with sufficient internal energy to undergo secondary fragmentation. The third three-body channel, S + SH + isobutene, is attributed to the loss of internally excited HS 2 from t-BuSS, which then rapidly dissociates to form S + SH in an asynchronous concerted dissociation process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗