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Characterization and Absolute QE Measurements of Delta-Doped N-Channel and P-Channel CCDs

In this paper we present the methodology for making absolute quantum efficiency (QE) measurements from the vacuum ultraviolet (VUV) through the near infrared (NIR) on delta-doped silicon CCDs. Delta-doped detectors provide an excellent platform to validate measurements through the VUV due to their enhanced UV response. The requirements for measuring QE through the VUV are more strenuous than measurements in the near UV and necessitate, among other things, the use of a vacuum monochromator, and good camera vacuum to prevent chip condensation, and more stringent handling requirements. The system used for these measurements was originally designed for deep UV characterization of CCDs for the WF/PC instrument on Hubble and later for Cassini CCDs.

Jacquot, Blake C.↗

VUV Testing of Science Cameras at MSFC: QE Measurement of the CLASP Flight Cameras

The NASA Marshall Space Flight Center (MSFC) has developed a science camera suitable for sub-orbital missions for observations in the UV, EUV and soft X-ray. Six cameras were built and tested for the Chromospheric Lyman-Alpha Spectro-Polarimeter (CLASP), a joint National Astronomical Observatory of Japan (NAOJ) and MSFC sounding rocket mission. The CLASP camera design includes a frame-transfer e2v CCD57-10 512x512 detector, dual channel analog readout electronics and an internally mounted cold block. At the flight operating temperature of -20 C, the CLASP cameras achieved the low-noise performance requirements (less than or equal to 25 e- read noise and greater than or equal to 10 e-/sec/pix dark current), in addition to maintaining a stable gain of approximately equal to 2.0 e-/DN. The e2v CCD57-10 detectors were coated with Lumogen-E to improve quantum efficiency (QE) at the Lyman- wavelength. A vacuum ultra-violet (VUV) monochromator and a NIST calibrated photodiode were employed to measure the QE of each camera. Four flight-like cameras were tested in a high-vacuum chamber, which was configured to operate several tests intended to verify the QE, gain, read noise, dark current and residual non-linearity of the CCD. We present and discuss the QE measurements performed on the CLASP cameras. We also discuss the high-vacuum system outfitted for testing of UV and EUV science cameras at MSFC.

Champey, Patrick↗

VUV Testing of Science Cameras at MSFC: QE Measurement of the CLASP Flight Cameras

The NASA Marshall Space Flight Center (MSFC) has developed a science camera suitable for sub-orbital missions for observations in the UV, EUV and soft X-ray. Six cameras were built and tested for the Chromospheric Lyman-Alpha Spectro-Polarimeter (CLASP), a joint National Astronomical Observatory of Japan (NAOJ) and MSFC sounding rocket mission. The CLASP camera design includes a frame-transfer e2v CCD57-10 512x512 detector, dual channel analog readout electronics and an internally mounted cold block. At the flight operating temperature of -20 C, the CLASP cameras achieved the low-noise performance requirements (less than or equal to 25 e- read noise and greater than or equal to 10 e-/sec/pix dark current), in addition to maintaining a stable gain of approximately equal to 2.0 e-/DN. The e2v CCD57-10 detectors were coated with Lumogen-E to improve quantum efficiency (QE) at the Lyman- wavelength. A vacuum ultra-violet (VUV) monochromator and a NIST calibrated photodiode were employed to measure the QE of each camera. Four flight-like cameras were tested in a high-vacuum chamber, which was configured to operate several tests intended to verify the QE, gain, read noise, dark current and residual non-linearity of the CCD. We present and discuss the QE measurements performed on the CLASP cameras. We also discuss the high-vacuum system outfitted for testing of UV and EUV science cameras at MSFC.

Camera↗

Spectrophotometric Attachment for the Vacuum Ultraviolet

An absorption spectrophotometric attachment to a vacuum ultraviolet monochromator has been built and tested. With an empty sample chamber, the ratio of the radiant flux through the sample chamber to the radiant flux through the reference chamber was measured. By optimizing conditions at the entrance slit, the ratio was constant within experimental error over the region 1000-1600 A. The transmittance of thin celluloid films was measured with the attachment.

Axelrod, Norman N.↗

Astrobiology Survey of a Lava Cave at Lava Beds National Monument by a Rover Carrying a Remote Sensing Instrument Payload

We report here on a survey of a lava tube cave by a rover that is instrumented for astrobiology missions. The NASA Ames testbed rover, CaveR, was deployed in Valentine Cave in Lava Beds National Monument (N. CA, USA) during August of 2018. The rover carried an instrument package consisting of Near Infrared and Visible Spectrometer System (NIRVSS) a point spectrometer operating in 1590-3400 nm range, sensitive to H2O and -OH bearing minerals, pyroxenes, and carbonates (Roush, et al 2018); the bore sighted Drill Operations Camera (DOC), a monochrome imager illuminated by LEDs at 410, 540, 640, 740, 905 and 940 nm; a Realsense ™ depth sensor system for 3D model generation; and a high resolution DSLR stereo camera. The payload was mounted on a tiltable instrument platform attached to the left side of the rover. The rover was driven manually in the cave by field operators, following instructions from a remote science operations team, and simulating a mission concept with science-guided autonomy. A simulated mission took place for 3 days with a team of 3 scientists selecting targets and interpreting data from the payload. To begin the mission, the rover drove along one wall of the cave imaging continuously with the Realsense in 20 m cave segments, three total. At the start of each day, the images from a 20m segment and a panorama stitched from them were provided to the science team to examine. The science team used these data to prioritize specific points along the cave wall for the collection of NIRVSS, DOC, and DSLR data. The objective of the data collection was to identify and study putative biological and mineralogical features in the cave. The data were delivered in xGDS, a customized mapping, planning, and data base management software developed at NASA Ames (Lee, et al 2013). Once the targets for further observations were selected, a plan for collecting the observations (positions in the cave and pointing for each requested observation) was constructed using xGDS and delivered to a rover team to execute the science data collection plan. Acquired data were delivered back to the science team for analysis. Preliminary results from the experiment illustrate the utility of the system (rover plus payload) to study the cave geology and mineralogy and its potential for identifying biomineral features.

Wong, Uland↗

JPSS-2 VIIRS version 2 at-launch relative spectral response characterization

The JPSS-2 VIIRS sensor has completed its pre-launch test program and is now awaiting launch in the 2022 timeframe. The VIIRS spectral characterization, in the form of band averaged and supporting detector level relative spectral response (RSR) for each VIIRS band, was completed in 2019 and is based upon independent SpMA dual monochromator (all bands) and GSFC GLAMR laser system (reflectance bands only) spectral measurements, including first time measurements of the VIIRS SWIR bands by a laser system. The measurements and subsequent analysis effort by subject matter experts of the VIIRS DAWG has led to the July 2019 VIIRS Version 2 RSR release, the official at-launch RSR characterization for the JPSS-2 VIIRS mission. Version 2 replaces and improves upon the August 2018 Version 1 release by incorporating the GLAMR measurements into the analysis to produce an updated “fused” RSR for reflective solar bands (M1- M10, I1-I3, DNBLGS, DNBMGS) and by applying a CO2 absorption correction to the SpMA measurements for thermal band M13. For all other bands (M11, M12, M14-M16, I4, I5), the Version 1 characterization, based entirely upon the SpMA measurements, is carried forward into the Version 2 release. An assessment on compliance with spectral performance metrics finds that VIIRS is compliant on nearly all metrics, with a few minor exceptions. The version 2 RSR release includes band average (over all detectors and subsamples) RSR plus supporting RSR for each detector and subsample, and is available under EAR99 restrictions to the science community at a restricted access NASA eRoom site.

JPSS-2↗

Optical Studies of Low Reflectance Materials at Solar Reflective Wavelengths in Support of Remote Sensing Instrument Development and Calibration

We report the Bidirectional Reflection Distribution Function (BRDF) and Total Hemispheric Reflectance (THR) results of several low reflectance materials using a Table-top Goniometer (TTG) and a commercial UV-VIS-NIR spectrophotometer in support of the NASA GSFC PACE project. The newly developed TTG was utilized to perform the BRDF measurements for several black candidate samples in in-plane and out-of-plane configurations from 300 nm to 2000 nm. These measurements demonstrated the BRDF capability of the TTG to calibrate the dim calibration target with a reflectance of approximately 2 % for the OCI of the PACE project. The spectral THR of the black samples from 200 nm to 2500 nm was determined using a 10 % reflectance diffuse black standard and a monochromator-based light source equipped with a 150 mm diameter integrating sphere. The THR measurement is used to compliment and validate the BRDF measurements acquired from these samples. In this presentation, we also show examples of UV induced BRDF and THR changes on two black coatings. We will discuss validation of the BRDF scale, source stability, measurement repeatability, instrument signature, and uncertainty components.

Bidirectional Reflection Distribution Function (BR↗

Multi-Angle Imager for Aerosols (MAIA) spectral and radiometric calibration

The Multi-angle Imaging SpectroRadiometer (MISR) was launched as part of NASA’s Terra satellite suite of instruments. Still operational, it makes use of observations from multiple view angles to retrieve aerosol abundance and particle properties. The Multi-Angle Imager for Aerosols (MAIA) instrument improves on this heritage by incorporating polarimetry and an expanded spectral range. Combining these data with surface measurements, the relationship between pollution and human health will be explored. MAIA has just completed camera testing, building on the experience from MISR. Spectral calibration now makes use of a double subtractive monochromator, built with the intent to allow the exit slit output to be uniform in spectral content. For radiometric testing, hardware upgrades have included adding UV lamps to the 1.65 cm (65") integrating sphere, use of a NIST-traceable sphere to establish absolute radiances, and the addition of a UV transfer spectrometer to support characterization of the sphere output from 300 to 2500 nm. During camera build, Newton’s rings were observed in the detector Quantum Efficiency (QE) measurements. This is due to etaloning within the detector itself. Etaloning was also evident in the spectral and radiometric characterizations performed on the completed camera. Spectral metrics, including center wavelength and width, are presented here using a moment’s analysis. This better represents the band properties, particularly in bands where fringing is observed, as compared to a full-width at half-maximum determination. It is believed that the MAIA camera has been carefully characterized, and meet its spectral and radiometric requirements.

Harten, Gerard Van↗

Bi-axial Strain Measurement of Woven-Webbing Inflatable Structures Using Digital Image Correlation with RGB Filtering

Crewed inflatable softgoods structures can significantly reduce launch volume for habitable pressure vessels. To ensure the operational safety of these structures, NASA has developed an extensive testing program to evaluate the structural capability on ground test articles. This paper will discuss a current challenge faced by test engineers evaluating the strain of large-scale inflatable space structures during ground testing. Namely, the difficulty that arises using monochrome digital image correlation (DIC) to evaluate bi-axial strain for woven-webbing restraint layers. This report provides insight into a novel method of photogrammetry using red-green-blue (RGB) filtering in conjunction with DIC to evaluate the strain in each direction on a test article experiencing bi-directional strain. To evaluate this concept, a uniaxial tensile test was performed that represented a biaxial woven architecture using orthogonally interfaced straps. The resulting analysis demonstrates promise for this novel approach for isolating a specific region and direction of strain, reducing the effects of straps not in the area of interest, while allowing for a larger region of analysis. Moreover, it was shown that the application of a white basecoat prior to applying photogrammetry patterns significantly reduced data loss while performing RGB filtered DIC.

inflatable↗

JPSS-3 VIIRS Version 2 at-Launch Relative Spectral Response Characterization

The JPSS-3 VIIRS sensor has completed its pre-launch test program including measurements for characterizing the VIIRS relative spectral response (RSR) in support of the Sensor and Environmental Data Records (SDR and EDR, resp.) that will be generated from VIIRS on-orbit observations. Government team subject matter experts of the VIIRS DAWG have analyzed the VIIRS spectral measurements and produced the VIIRS spectral characterization, in the form of band-average and supporting detector level RSR for each VIIRS band. The characterization is based upon the analysis of independent SpMA dual monochromator (all bands) and GSFC GLAMR laser system (reflectance bands only) spectral measurements. The SpMA and GLAMR measurements for reflectance bands (DNB LGS and MGS, I1-I3, M1-M11) were combined to produce a “fused” RSR. For emissive bands (I4, I5, M12-M16), the SpMA measurements provide the characterization. The effort has led to the VIIRS Version 2 RSR release, the official at-launch RSR characterization for the JPSS-3 VIIRS mission. The JPSS-3 RSR are a close match to those of JPSS-2. An assessment on compliance with spectral performance metrics finds that VIIRS band-average RSR are compliant on nearly all metrics, with only a single minor exception. The Version 2 RSR release is available under EAR99 restrictions to the science community on the restricted access NASA Sharepoint.

Chris Moeller↗

Prelaunch Spectral Characterization of the Operational Land Imager-2

The Landsat-9 satellite, launched in September 2021, carries the Operational Land Imager-2 (OLI-2) as one of its payloads. This instrument is a clone of the Landsat-8 OLI and its mission is to continue the operational land imaging of the Landsat program. The OLI-2 instrument is not significantly different from OLI though the instrument-level pre-launch spectral characterization process was much improved. The focal plane modules used on OLI-2 were manufactured as spares for OLI and much of the spectral characterization of the components was performed for OLI. However, while the spectral response of the fully assembled OLI was characterized by a double monochromator system, the OLI-2 spectral characterization made use of the Goddard Laser for Absolute Measurement of Radiance (GLAMR). GLAMR is a system of tunable lasers that cover 350–2500 nm which are fiber-coupled to a 30 in integrating sphere permanently monitored by NIST-traceable radiometers. GLAMR allowed the spectral characterization of every detector of the OLI-2 focal plane in nominal imaging conditions. The spectral performance of the OLI-2 was, in general, much better than requirements. The final relative spectral responses (RSRs) represent the best characterization any Landsat instrument spectral response. This paper will cover the results of the spectral characterization from the component-level to the instrument-level of the Landsat-9 OLI-2.

Landsat-9↗

JPSS-4 VIIRS Version 2 at-Launch Relative Spectral Response Characterization

The JPSS-4 VIIRS sensor, the last in a JPSS program that will eventually span some 25+ years of on-orbit data collection, has completed its pre-launch test program. The test program included measurements for characterizing the VIIRS relative spectral response (RSR) in support of the Sensor and Environmental Data Records that will be generated from JPSS-4 VIIRS on-orbit observations after launch. Subject matter experts of the Government Team’s VIIRS DAWG have analyzed the VIIRS spectral measurements and produced the VIIRS spectral characterization, in the form of band averaged and supporting detector level RSR for each VIIRS band. The characterization is based upon the analysis of independent SpMA dual monochromator (all bands) and GSFC GLAMR laser system (reflectance bands only) spectral measurements. The SpMA and GLAMR measurements for reflectance bands (DNBLGS and DNBMGS, I1-I3, M1-M11) were combined to produce a “fused” RSR. For emissive bands (I4, I5, M12-M16), the SpMA measurements provide the entire characterization. The effort has led to the VIIRS Version 2 RSR product, the official at-launch RSR characterization for the JPSS-4 VIIRS mission, which is currently slated to be the next launch (expected Fall 2027) of the JPSS program. As expected, the JPSS-4 RSR are a close match to those of JPSS-3 and JPSS-2 (NOAA-21) VIIRS, while showing some spectral position and shape differences with SNPP and JPSS-1 (NOAA-20) VIIRS. An assessment on compliance with spectral performance metrics finds that VIIRS bandaverage RSR are compliant on nearly all metrics, with only a single minor exception. The Version 2 RSR will be available under EAR99 restrictions to the science community on the restricted access NASA Sharepoint.

SDR↗

Large Volume Airborne Contamination Monitoring To Support Nuclear Processes' Deactivation and Decommissioning

Current D and D operations at Hanford have demonstrated a flaw in the current state of the art capability of defining airborne contamination boundaries - Airborne particulate emissions of Pu-239 from CM2H operations on the Hanford Pu Finishing Plant were detected well beyond areas controlled for airborne Pu, putting numerous workers at risk for radiological assimilations - Current air samplers and CAM systems were surveying insufficient volumes of air to accurately predict where respiratory protection was required - Hanford is located in a high radon environment, making air monitoring for alpha emitting actinides challenging in high alpha radon induced backgrounds. - Inexpensive HEPA based home and industrial air purifiers filter significantly higher volumes of air than commercially available continuous-air monitoring (CAM) systems. - Inexpensive models capable of filtered air volumes exceeding 1000 times that of a CAM. - Detector system can be built to detect x-rays generated from actinide decay. - Branching ratios of x-rays are 4 orders of magnitude more intense from Plutonium decay than its gamma emissions. - Detector system can be a low resolution systems, as x-ray region of interest is not terribly congested. - Detection systems evaluated will be designed based on slabs of NaI or pixelated NaI or CsI panels. - Simple graphical user interface software will be developed to operate the detection system. - Concept is to deploy some of these air-purifying systems in nonradiological areas around SRNL to confirm radon can be rejected with confidence. - Generate some filters contaminated with plutonium via electroplated Pu or lab generated simulated particles. - then deploy units in known airborne radiological environments to establish systems ability to accurately measure actinide based hot particles Lab analyses will follow up the system analyses to ensure hot particles were correctly identified. Analysis by Scintillation: - Application of scintillation media to the surface of the filters is being explored. - Evaluating slabs of ZnS(Ag), application of powdered ZnS(Cu) and spray on Perkin Elmer Enhance. - Scintillation events would then be digitized with a digital camera and quantified. - Comparing against sensitivity of a PMT or SiPD readout. - Currently evaluating a Thorlabs 8 Megapixel Monochrome Scientific CCD Camera, hermetically sealed cooled package with a wide angle lens. - Wide angle lens allows complete view of HEPA filter from 7 inches away. - Images taken of glow in the dark paint, as well as plutonium-induced fluorescence. - Plutonium was flamed mounted on a 1 inch diameter stainless steel planchet, covered with a layer of mylar and a section of scintillating ZnS obtained from Eljon. - Currently working on reducing signal-to-noise levels to boost sensitivity. - Dark box to hold contaminated or electroplated source covered filters under fabrication. Analysis by x-ray Spectroscopy: - Branching ratios for x-ray emissions from Plutonium isotopes are orders of magnitude more intense than gamma-ray emissions. - The nuclear databases are incomplete on the branching ratios of some of the isotopes. - Evaluating some custom built SrI2 x-ray spectrometers vs a conventional windowed NaI detector. - SrI2 detectors are carbon-composite-windowed 51 mm x 51 mm. - MCNP calculations to establish self absorbance of filter media on 17 keV x-ray. Radon Rejection: - Activated charcoal pre-filter acts as a Radon trap. - Adding a time lapse feature to camera to aid in radon rejection. SRS Plutonium Fuel Form D and D Operations: Currently deploying air sampler to D and D operation of Pu-238 facility at SRS to generate some field samples to analyze.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Visualization of Thermal and Strain Dynamics in X-ray Optics by Time-Resolved Rocking Curve Imaging

The absorption of intense X-ray pulses from free-electron lasers by X-ray crystal optics triggers rapid thermal and mechanical responses, including lattice compression, expan- sion, and strain-wave propagation, which dynamically modify diffraction conditions and wavefront properties. These effects pose significant challenges for next-generation high- repetition-rate X-ray sources, particularly for crystal monochromators used in XFEL beam- lines and self-seeding. Here, we demonstrate time-resolved rocking curve imaging (TrRCI) of X-ray Bragg optics with high spatial resolution (6.4 μm) and sub-1-μrad angular resolu- tion, enabling direct visualization of lattice dynamics from nanoseconds to microseconds. By combining a high-flux beamline at SPring-8, a scintillator-coupled sCMOS detector, and a synchronized femtosecond laser system, we capture lattice dynamics induced by tran- sient laser heating with a strain sensitivity on the order of 10−6 . Our results reveal transient lattice deformation and the propagation of laser-induced strain waves over millimeter-scale distances. This approach provides experimental benchmarks for understanding heat-load effects in high-repetition-rate X-ray optics.

Source record↗

Low‐Loss Tunable Infrared Plasmons in the High‐Mobility Perovskite (Ba,La)SnO 3

Abstract BaSnO 3 exhibits the highest carrier mobility among perovskite oxides, making it ideal for oxide electronics. Collective charge carrier oscillations known as plasmons are expected to arise in this material, thus providing a tool to control the nanoscale optical field for optoelectronics applications. Here, the existence of relatively long‐lived plasmons supported by high‐mobility charge carriers in La‐doped BaSnO 3 (BLSO) is demonstrated. By exploiting the high spatial and energy resolution of electron energy‐loss spectroscopy with a focused beam in a scanning transmission electron microscope, the dispersion, confinement ratio, and damping of infrared localized surface plasmons (LSPs) in BLSO nanoparticles are systematically investigated. It is found that LSPs in BLSO exhibit a high degree of spatial confinement compared to those sustained by noble metals and have relatively low losses and high quality factors with respect to other doped oxides. Further analysis clarifies the relation between plasmon damping and carrier mobility in BLSO. The results support the use of nanostructured degenerate semiconductors for plasmonic applications in the infrared region and establish a solid alternative to more traditional plasmonic materials.

36 MATERIALS SCIENCE↗

A versatile Johansson-type tender x-ray emission spectrometer

We present a high energy resolution x-ray spectrometer for the tender x-ray regime (1.6–5.0 keV) that was designed and operated at Stanford Synchrotron Radiation Lightsource. The instrument is developed on a Rowland geometry (500 mm of radius) using cylindrically bent Johansson analyzers and a position sensitive detector. By placing the sample inside the Rowland circle, the spectrometer operates in an energy-dispersive mode with a subnatural line-width energy resolution (~0.32 eV at 2400 eV), even when an extended incident x-ray beam is used across a wide range of diffraction angles (~30° to 65°). The spectrometer is enclosed in a vacuum chamber, and a sample chamber with independent ambient conditions is introduced to enable a versatile and fast-access sample environment (e.g., solid/gas/liquid samples, in situ cells, and radioactive materials). The design, capabilities, and performance are presented and discussed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Synchrotron characterization of high-Z, current-mode x-ray detectors

Fast x-ray detectors are critical tools in pulsed power and fusion applications, where detector impulse response of a nanosecond or better is often required. Semiconductor detectors can create fast, sensitive devices with extensive operational flexibility. There is typically a trade-off between detector sensitivity and speed, but higher atomic number absorbers can increase hard x-ray absorption without increasing the charge collection time, provided carriers achieve high velocity. This paper presents x-ray pulse characterization conducted at the Advanced Photon Source of x-ray absorption efficiency and temporal impulse response of current-mode semiconductor x-ray detectors composed of Si, GaAs, and CdTe.

47 OTHER INSTRUMENTATION↗

Skyrmion fluctuations at a first-order phase transition boundary

Magnetic skyrmions are topologically protected spin textures with promising prospects for applications in data storage. They can form a lattice state due to competing magnetic interactions and are commonly found in a small region of the temperature—magnetic field phase diagram. Recent work has demonstrated that these magnetic quasi-particles fluctuate at the μeV energy scale. Here, we use a coherent x-ray correlation method at an x-ray free-electron laser to investigate these fluctuations in a magnetic phase coexistence region near a first-order transition boundary where fluctuations are not expected to play a major role. Surprisingly, we find that the relaxation of the intermediate scattering function at this transition differs significantly compared to that deep in the skyrmion lattice phase. The observation of a compressed exponential behavior suggests solid-like dynamics, often associated with jamming. We assign this behavior to disorder and the phase coexistence observed in a narrow field-window near the transition, which can cause fluctuations that lead to glassy behavior.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗