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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22

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NASA NTRS1982

Analytical modeling of operating characteristics of premixing-prevaporizing fuel-air mixing passages. Volume 1: Analysis and results

A model for predicting the distribution of liquid fuel droplets and fuel vapor in premixing-prevaporizing fuel-air mixing passages of the direct injection type is reported. This model consists of three computer programs; a calculation of the two dimensional or axisymmetric air flow field neglecting the effects of fuel; a calculation of the three dimensional fuel droplet trajectories and evaporation rates in a known, moving air flow; a calculation of fuel vapor diffusing into a moving three dimensional air flow with source terms dependent on the droplet evaporation rates. The fuel droplets are treated as individual particle classes each satisfying Newton's law, a heat transfer, and a mass transfer equation. This fuel droplet model treats multicomponent fuels and incorporates the physics required for the treatment of elastic droplet collisions, droplet shattering, droplet coalescence and droplet wall interactions. The vapor diffusion calculation treats three dimensional, gas phase, turbulent diffusion processes. The analysis includes a model for the autoignition of the fuel air mixture based upon the rate of formation of an important intermediate chemical species during the preignition period.

Anderson, O. L.↗

NASA NTRS1983

Analytical Modeling of Operating Characteristics of Premixing-prevaporizing Fuel-air Mixing Passages

A model for predicting the distribution of liquid fuel droplets and fuel vapor in premixing-prevaporizing fuel-air mixing passages of the direct injection type is described. This model consists of three computer programs: a calculation of the two dimensional or axisymmetric air flow field neglecting the effects of fuel; a calculation of the three dimensional fuel droplet trajectories and evaporation rates in a known, moving air flow; and a calculation of fuel vapor diffusing into a moving three dimensional air flow with source terms dependent on the droplet evaporation rates. The air flow calculation can treat compressible swirling flows in arbitrary ducts with arbitrary distributions of temperature and velocity as initial conditions. The fuel droplets are treated as initial conditions. The fuel droplets are treated as individual particle classes each satisfying Newton's law, a heat transfer, and a mass transfer equation. The vapor diffusion calculation treats three dimensional, gas phase, turbulent diffusion processes with the turbulence level determined by the air flow calculations and the source terms determined by the droplet evaporation rates.

Anderson, O. L.↗

NASA NTRS2005

Transient Catalytic Combustor Model With Detailed Gas and Surface Chemistry

In this work, we numerically investigate the transient combustion of a premixed gas mixture in a narrow, perfectly-insulated, catalytic channel which can represent an interior channel of a catalytic monolith. The model assumes a quasi-steady gas-phase and a transient, thermally thin solid phase. The gas phase is one-dimensional, but it does account for heat and mass transfer in a direction perpendicular to the flow via appropriate heat and mass transfer coefficients. The model neglects axial conduction in both the gas and in the solid. The model includes both detailed gas-phase reactions and catalytic surface reactions. The reactants modeled so far include lean mixtures of dry CO and CO/H2 mixtures, with pure oxygen as the oxidizer. The results include transient computations of light-off and system response to inlet condition variations. In some cases, the model predicts two different steady-state solutions depending on whether the channel is initially hot or cold. Additionally, the model suggests that the catalytic ignition of CO/O2 mixtures is extremely sensitive to small variations of inlet equivalence ratios and parts per million levels of H2.

Struk, Peter M.↗

NASA NTRS2010

A Computer Model for Analyzing Volatile Removal Assembly

A computer model simulates reactional gas/liquid two-phase flow processes in porous media. A typical process is the oxygen/wastewater flow in the Volatile Removal Assembly (VRA) in the Closed Environment Life Support System (CELSS) installed in the International Space Station (ISS). The volatile organics in the wastewater are combusted by oxygen gas to form clean water and carbon dioxide, which is solved in the water phase. The model predicts the oxygen gas concentration profile in the reactor, which is an indicator of reactor performance. In this innovation, a mathematical model is included in the computer model for calculating the mass transfer from the gas phase to the liquid phase. The amount of mass transfer depends on several factors, including gas-phase concentration, distribution, and reaction rate. For a given reactor dimension, these factors depend on pressure and temperature in the reactor and composition and flow rate of the influent.

Guo, Boyun↗

NASA NTRS2012

Solar Electric Propulsion Vehicle Demonstration to Support Future Space Exploration Missions

Human and robotic exploration beyond Low Earth Orbit (LEO) will require enabling capabilities that are efficient, affordable, and reliable. Solar Electric Propulsion (SEP) is highly advantageous because of its favorable in-space mass transfer efficiency compared to traditional chemical propulsion systems. The NASA studies have demonstrated that this advantage becomes highly significant as missions progress beyond Earth orbit. Recent studies of human exploration missions and architectures evaluated the capabilities needed to perform a variety of human exploration missions including missions to Near Earth Objects (NEOs). The studies demonstrated that SEP stages have potential to be the most cost effective solution to perform beyond LEO transfers of high mass cargoes for human missions. Recognizing that these missions require power levels more than 10X greater than current electric propulsion systems, NASA embarked upon a progressive pathway to identify critical technologies needed and a plan for an incremental demonstration mission. The NASA studies identified a 30kW class demonstration mission that can serve as a meaningful demonstration of the technologies, operational challenges, and provide the appropriate scaling and modularity required. This paper describes the planning options for a representative demonstration 30kW class SEP mission.

Smith, Bryan K.↗

DOE OSTI2025

Optimal Design and Operation of Intensified Absorbers with 3D-Printed Packing for Solvent-Based CO 2 Capture

Many potential solvent-based carbon capture processes suffer from a high heat of absorption of CO 2 that adversely affects the thermodynamic driving force. While interstage coolers are often used for removing a portion of the generated heat by removing the solvent or a portion of the solvent from a stage and cooling and returning it back to the absorber, they can be placed only at discrete locations in the tower. This work investigates intensified absorbers with 3D-printed packing that includes an internal cooler and therefore can be potentially used for maximizing the operational efficiency of the absorbers for CO 2 capture. The intensified absorber is modeled by using a generic, first-principles, equation-oriented absorber column model. Since the placement of these intensified packings would cause a loss of area/volume used for mass transfer, optimization of the proposed intensified absorber is performed by optimally selecting the locations at which to place these devices and designing them such that the trade-off due to the addition of the heat removal area and the resulting loss in the mass transfer area is accounted for. Results show that optimally placed and designed intensified packings can lead to a significant increase in the capture efficiency of the process in comparison to a similar column with no internal cooling. It is also observed that by optimally placing and designing intensified packings, the lean solvent flow rate to the absorber can be decreased, and the CO 2 lean loading can be increased while still maintaining the same capture efficiency. These process changes can lead to a substantial reduction in the cost of capture.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1977

Evaporative winds in X-ray binaries

Evaporation of gas from the surface of HZ Her by Her X-1 and its implications regarding the mass transfer process are examined further. The powerful soft X-ray flux results in an evaporation rate greater than previous estimates. The evaporative flow is shown to be subsonic at first, with the result that the capture of evaporated gas by Her X-1 may be efficient, and the self-excited wind mechanism is possible. A criterion for stabilization of mass transfer by stellar wind mass loss is derived. Possible mechanisms for the long-period variability of HZ Her are discussed. Evaporative winds are also estimated for Sco X-1 and Cyg X-2 spectra.

Basko, M. M.↗

NASA NTRSDate not supplied

Progress in Simulated Water Well Performance on Mars

Recent studies of human Mars missions considered the impacts of an abundant supply of in-situ, accessible water on these mission scenarios. Discovery of exposed water ice scarps in Martian mid-latitudes has bolstered the evidence for massive amounts of almost pure water in buried deposits in regions considered candidates for these future human missions. This paper describes progress towards adapting a long-standing terrestrial technique for accessing and extracting water from these mid-latitude sources of ice. This approach relies on mechanical drills to access the ice through overlying debris. Once the ice layer has been reached, a technique known as a Rodriguez Well, or Rodwell, is used to melt the ice, store the resulting water in a subsurface cavity until needed, and then pump the water to the surface for use. Previous work by the authors utilized a computer simulation to predict the performance of a Martian Rodwell. This simulation was originally developed to predict performance in terrestrial Polar Regions. Whereas the basic approach is appropriate for a similar well on Mars, several parameters had been empirically derived and required experiments simulating the Martian environment to determine the values appropriate for a Martian Rodwell simulation. These experiments have now been completed and preliminary values have been determined for the empirical parameters. Test results are consistent with a dimensionless Sh(Ra) correlation developed by Bower and Saylor (2009) and based on lab tests of water evaporating from a pool into a large air chamber. They are also consistent with correlations derived by Ingersoll (1970) and by Hecht (2002), based on natural-convection heat transfer. Each of these earlier correlations found Sh~Ra1/3, with the 1/3rd power characteristic of large Ra where the boundary layer over the pool surface is turbulent. A somewhat surprising result was that this power-law was found to extend into a range of Ra where laminar flow would be expected. Another surprising result was found in that instead of following established correlations for natural-convection heat transfer over flat plates, the dimensionless heat-transfer rates (Nu) were much larger and approximately independent of Ra. This suggests that mass transfer from the pool enhances convective heat transfer, possibly by enhanced mixing in the boundary layer. Although this possibility has been suggested in the literature, if it is proven to be true under these conditions it could play an important role in the use of a Rodwell on Mars, where evaporative mass transfer is enhanced relative to terrestrial wells.

Human Mars Mission↗

DOE OSTI2022

Design of a Combined Proportional Integral Derivative Controller to Regulate the Temperature Inside a High-Temperature Tubular Solar Reactor

Solar fuels are proven to be promising candidates for thermochemical energy storage. However, the transient nature of solar radiation is an obstacle to maintaining a stable operational temperature inside a solar reactor. To overcome this challenge, the temperature of a solar reactor can be regulated by controlling the incoming solar radiation or the feedstock flowrate inside the reactor. In this work, a combined proportional integral derivative (PID) controller is implemented to regulate the temperature inside a high-temperature tubular solar reactor with counter-current flowing gas/particles. The control model incorporates two control systems to regulate incoming solar radiation and gas flow simultaneously. The design of the controller is based on a reduced-order numerical model of a high-temperature tubular solar reactor that is vertically oriented with an upward gas flow and downward particle flow. The reactor receives heat circumferentially through its wall over a finite segment of its length. Formulation of the heat transfer model is presented by applying the energy balance for the reactor tube and considering heat and mass transfer inside. A set of governing differential equations are solved numerically by using the finite volume method to obtain reactor wall, particles, and gas temperatures along the reactor length with various boundary conditions. Simulation results are used to tune the PID controller parameters by utilizing the Ziegler–Nichols tuning method. Both the simulation results and the controller performance are visualized on the LABVIEW platform. The controller is challenged to track different temperature setpoints with different scenarios of transient solar radiation. Here, the performance of the PID controller was compared to experimental results obtained from an industrial PID controller embedded in a 7 kW electric furnace. Results show that the combined PID controller is successful in maintaining a stable temperature inside the reactor by regulating the incoming solar radiation and the flowrate via small steady-state error and reasonable settling time and overshoot.

14 SOLAR ENERGY↗

DOE OSTI2021

Temperature Effects on Droplet Oscillation Decay with Application to Fuel Property Measurement

Observation of oscillation decay in droplets has been shown to be an effective approach in determining physical properties such as viscosity and surface tension for emerging biofuels using μl quantities. Herein this work extends the approach to higher temperatures relevant to fuel injection conditions for internal combustion engines. Experiments are conducted that use high-resolution strobed imaging of moving, heated, μm-sized, fuel droplets to capture shape oscillation decay through image processing and analysis. Two fuels are investigated, iso-butanol and a primary reference fuel (PRF 84), which is a mixture of iso-octane and n-heptane. A piezoelectric droplet generator is used to generate a continuous train of single droplets, which are given an initial perturbation and subsequently undergo damped oscillations, captured using strobed imaging. Surface tension and viscosity calculated at four different temperatures ranging from 30°C-55°C using the frequency and decay time associated with the fundamental mode are found to be within ~ 10% of reference values obtained from the literature. Complementary numerical simulations are performed that utilize a volume-of-fluid approach to track transient droplet oscillation phenomena along with heat and mass transfer in a 2D axisymmetric domain. Simulations, where droplet size and temperature can be independently varied, capture an expected decrease in oscillation frequency and increase in decay time, with increase in fuel temperature. The simulations are further used to study the relative contribution to deviations in surface tension and viscosity predictions due to heat and mass transfer from the droplet, as well as viscous effects violating the inviscid flow assumption in the droplet oscillation theory. Mass loss effects are found to be negligible. Temperature change due to heat transfer is found to have the next highest sensitivity, particularly for the more volatile PRF 84, which has a lower viscosity and associated Ohnesorge number. For isobutanol, which has a higher viscosity and Ohnesorge number, viscous effects contribute the most to deviation in fuel property predictions.

09 BIOMASS FUELS↗

DOE OSTI2023

Analysis of gas storage and transport in Eagle Ford shale using pressure pulse decay measurements with He, Kr and CO 2

Detailed characterization of gas transport and storage in low-permeability and organic-rich shales is associated with an array of challenges due to the complex morphology of the pore space, representing a broad range of pore sizes, combined with the heterogeneous fabric of the shale matrix. These factors, and their interplay during gas transport and sorption, complicate a) the analysis of shale samples at the laboratory scale (~ up to a ft. In length), and b) the prediction of natural gas production and carbon sequestration potential at larger scales. Here, in this work, tandem experiments with inert (helium – He) and adsorbing (krypton - Kr and carbon dioxide - CO 2 ) gases were performed and analyzed to develop an efficient workflow for characterizing and modeling transport and sorption at the laboratory scale. In particular, pressure pulse-decay (PPD) measurements were conducted on an Eagle Ford shale core sample at room temperature using He, Kr, and CO 2 . PPD measurements with He (a non-sorbing gas) were employed to probe the overall porosity, including natural fractures, microcracks, mesopores, and micropores. A triple-porosity model (TPM) was adopted to interpret the gas transport in the shale sample: The pore space is represented by three interacting continua, including macropores (larger fractures), mesopores (including microcracks), and micropores. To facilitate the application of the TPM, a modified analytical approach is introduced to extract effective transport parameters (in terms of the characteristic time for transport at relevant porosity levels) directly from the PPD measurements with He. To validate the modeling approach, model parameters extracted from two He PPD measurements are demonstrated to provide excellent agreement with a 3rd He PPD measurement performed at a higher pressure. The effective transport parameters, extracted from the He experiments, were subsequently converted for application to the Kr and CO 2 PPD experiments, by accounting for relevant transport modes and differences in fluid properties. Excess adsorption isotherms were extracted from the equilibrium pressures of the Kr and CO 2 PPD experiments using the He pore volume as a baseline. These adsorption isotherms were then integrated into the TPM to predict combined gas transport and sorption for Kr and CO 2 , with transport coefficients translated from the He measurements. The predictions for Kr and CO 2 are demonstrated to be in excellent agreement with the experimental observations. This, in turn, demonstrates that the proposed analytical approach provides for an effective characterization of mass transfer rates in shales, that can be applied directly in a TPM representation of mass transfer and sorption.

58 GEOSCIENCES↗

DOE OSTI2023

Stragglers of the thick disc

Young alpha-rich (YAR) stars have been detected in the past as outliers to the local age - [α/Fe] relation. These objects are enhanced in α-elements, but they are apparently younger than typical thick disc stars. Here, we study the global kinematics and chemical properties of YAR giant stars in the APOGEE DR17 survey and show that they have properties similar to those of the standard thick disc stellar population. This leads us to conclude that YAR are rejuvenated thick disc objects, and the most likely explanation is that they are evolved blue stragglers. This is confirmed by their position in the Hertzsprung–Russel diagram (HRD). Extending our selection to dwarfs allowed us to obtain the first general straggler distribution in an HRD of field stars. We also compared the elemental abundances of our sample with those of standard thick disc stars and found that our YAR stars are shifted in oxygen, magnesium, sodium, and the slow neutron-capture element cerium. Although we detected no sign of binarity for most objects, the enhancement in cerium may be a signature of a mass transfer from an asymptotic giant branch companion. The most massive YAR stars suggest that mass transfer from an evolved star may not be the only plausible formation pathway and that other scenarios, such as collision or coalescence, should be considered.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2023

The Evolution of Population III and Extremely Metal-poor Binary Stars

Numerical simulations have now shown that Population III (Pop III) stars can form in binaries and small clusters and that these stars can be in close proximity to each other. If so, they could be subject to binary interactions such as mass exchange that could profoundly alter their evolution, ionizing UV and Lyman–Werner photon emission and explosion yields, with important consequences for early cosmological reionization and chemical enrichment. Here we investigate the evolution of Pop III and extremely metal-poor binary stars with the MESA code. We find that interactions ranging from stable mass transfer to common envelope evolution can occur in these binaries for a wide range of mass ratios and initial separations. Mass transfer can nearly double UV photon yields in some of these binaries with respect to their individual stars by extending the life of the companion star, which in turn can enhance early cosmological reionization but also suppress the formation of later generations of primordial stars. Binary interactions can also have large effects on the nucleosynthetic yields of the stars by promoting or removing them into or out of mass ranges for specific SN types. We provide fits to total photon yields for the binaries in our study for use in cosmological simulations.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2021

Quasi-periodic Oscillations in the TESS Light Curve of TX Col, a Diskless Intermediate Polar on the Precipice of Forming an Accretion Disk

One of the fundamental properties of an intermediate polar is the dynamical nature of the accretion flow as it encounters the white dwarf’s (WD’s) magnetosphere. Many works have presumed a dichotomy between disk-fed accretion, in which the WD accretes from a Keplerian disk, and stream-fed accretion, in which the matter stream from the donor star directly impacts the WD’s magnetosphere without forming a disk. However, there is also a third, poorly understood regime in which the accretion flow consists of a torus of diamagnetic blobs that encircles the WD. This mode of accretion is expected to exist at mass-transfer rates below those observed during disk-fed accretion, but above those observed during pure stream-fed accretion. We invoke the diamagnetic-blob regime to explain the exceptional Transiting Exoplanet Survey Satellite light curve of the intermediate polar TX Col, which transitioned into and out of states of enhanced accretion during Cycles 1 and 3. Power-spectral analysis reveals that the accretion was principally stream fed. However, when the mass-transfer rate spiked, large-amplitude quasi-periodic oscillations (QPOs) abruptly appeared and dominated the light curve for weeks. The QPOs have two striking properties: they appear in a stream-fed geometry at elevated accretion rates, and they occur preferentially within a well-defined range of frequencies (∼10–25 cycle day{sup −1}). We propose that during episodes of enhanced accretion, a torus of diamagnetic blobs forms near the binary’s circularization radius and that the QPOs are beats between the white dwarf’s spin frequency and unstable blob orbits within the WD’s magnetosphere. We discuss how such a torus could be a critical step in producing an accretion disk in a formerly diskless system.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRSDate not supplied

Validation and Development of a Fast-Running CFD Model for the No-Vent Fill of Liquid Propellant Tank

Cryogenic fluids, while offering higher energy density than storable propellants, present several handling challenges, including gradual boil-off and tank self-pressurization. Transferring these propellants between tanks can be problematic, as the receiving tank's temperature and pressure often lead to flashing and rapid boil-off upon injection. The No-Vent Fill (NVF) technique mitigates these risks by preventing liquid fuel from being expelled overboard. By controlling tank pressure and ensuring appropriate condensation in the ullage region, the NVF process avoids exceeding vent pressure limits. In this study, Loci/STREAM-VOF simulations were compared with data from NASA K-site test runs on a 2.1 cubic meter tank with a bottom orifice under various no-vent fill conditions, including different wall temperatures, flow rates, and inlet liquid temperatures. The effort demonstrated that Loci/STREAM-VOF is capable of quantitatively capturing the important physics of NVF with submerged jets: (1) validation of the liquid-vapor interface turbulence velocity using previous experimental data showed good agreement at different fill levels; (2) validation of the CFD Stanton number for mass transfer provided an adequate mass transfer coefficient range; (3) consistent pressure agreements were found in the pressure history for both cold and warm conditions; and (4) the variations of final pressure with flow rate and inlet liquid temperature were well predicted by the CFD simulation. The application of NVF for low-gravity conditions will be studied in future work.

CFD↗

NASA NTRSDate not supplied

Validation and Development of a Fast-Running CFD Model for the No-Vent Fill of Liquid Propellant Tank

CFD↗

DOE OSTI2026

Eddy Covariance Theory: A Review

Eddy covariance (EC), the gold standard for measuring ecosystem scale gas and heat exchanges, has transformed our understanding of the breathing of the biosphere, and thus global change biology. Despite numerous methodological improvements and insights gained from the technique, the community faces persistent challenges that have been present since the first EC measurements. Here, we review the theoretical developments underpinning EC. We present theoretical developments in four important areas that have relevance to EC measurements of the net ecosystem exchanges (NEE) of gases and heat from a single tower: (i) measuring the total vertical flux density, (ii) flux attenuation, (iii) coordinate rotations, and (iv) energy balance closure. Persistent problems with EC measurements, such as the inability to close the energy budget, led us to identify two priorities for revisiting the theory underlying: (i) sensible heat flux calculations, and (ii) constraining the mean vertical wind velocity. We present a framework for improved calculation of sensible heat flux derived from first principles of fluid mechanics and thermodynamics that considers coupled heat and mass transfer so that conservation of both is obeyed. These refinements are motivated by the need for unbiased measurements of energy and mass transfer between the land surface and atmosphere for ecosystem research and to validate satellite observations and land surface models.

ecosystem fluxes↗

DOE OSTI2021

Harnessing Photoelectrochemistry for Wastewater Nitrate Treatment Coupled with Resource Recovery

Wastewater is a misplaced resource well suited to recover nutrients, value-added chemicals, energy, and clean water. A photoelectrochemical device is proposed to transform wastewater nitrates to ammonia and nitrous oxide, coupled with water oxidation. Numerical models were developed to quantify the dependence of process efficiencies and nitrogen-removal rates on light absorber band gaps, electrocatalytic kinetic parameters, competing oxygen reduction and hydrogen evolution reactions, and the reacting nitrate species concentrations that affect the mass-transfer limited current densities. With a single light-absorber and state-of-the-art catalysts, optimal solar-to-chemical efficiencies of 7% and 10% and nitrogen-removal rates of 260 and 395 gN m -2 day -1 are predicted for nitrate reduction to ammonia and nitrous oxide, respectively. The influence of competing reactions on the performance depends on the nitrate concentration and band gap of the light absorber modeled. Oxygen reduction is more dominant than hydrogen evolution to compete with the nitrate reduction reaction, but it is mass-transfer limited. Even with kinetic parameters that enhanced the driving forces for the competing reactions, the performance is only minimally affected by these reactions for optimally selected band gaps and nitrate concentrations larger than 100 mM. Here, theoretically predicted peak nitrogen removal rates and specific energy intensities are competitive with reported estimates for electrochemical and Sharon-Anammox processes for ammonia recovery and nitrogen removal, respectively. This result, together with the added benefit of harnessing sunlight to produce value-added products, indicates promise in the photoelectrochemical approach as a tertiary pathway to recover nutrients and energy from wastewater nitrates.

25 ENERGY STORAGE↗