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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Interfacial and Kinetic Origins of Voltage Loss in Neutral Zinc‐Air Batteries

Rechargeable zinc-air batteries are promising candidates for grid-scale energy storage; however, their practical deployment is limited by oxygen electrocatalysis inefficiencies and interfacial instabilities, particularly outside conventional alkaline electrolytes. Here, in this work, zinc-air batteries operating under neutral electrolyte conditions using ZnCl 2 soaked KC-PAA-PAM gel polymer electrolytes and electrochemically synthesized Ni/Fe layered double hydroxide electrocatalysts is investigated. Ni/Fe-LDH is intentionally employed as an OER-biased benchmark catalyst to diagnose electrolyte and interface driven limitations rather than as a bifunctional ORR/OER solution. Full cells exhibit highly stable cycling over hundreds of hours, yet operate at substantially suppressed charge and discharge voltages relative to the thermodynamic value. Electrochemical impedance analysis shows that ohmic losses contribute only minimally to this voltage suppression. Post-mortem X-ray photoelectron spectroscopy reveals metallic zinc accumulation on the air cathode and chloride-containing species on the anode, indicating parasitic interfacial processes. Synchrotron-based soft X-ray absorption spectroscopy confirms stable Ni 2+ and Fe 3+ oxidation states during cycling, consistent with OER-biased catalytic behavior, while neutral-electrolyte oxygen evolution measurements demonstrate strong electrolyte-induced suppression of oxygen kinetics. Together, these results show that electrolyte chemistry and cathode-side parasitic processes, rather than catalyst identity alone, dominate voltage losses in neutral zinc-air batteries, providing mechanistic insight into the fundamental challenges associated with neutral electrolyte operation.

Long duration energy storage↗
DOE OSTI2023

Information loss, mixing and emergent type III 1 factors

A manifestation of the black hole information loss problem is that the two-point function of probe operators in a large Anti-de Sitter black hole decays in time, whereas, on the boundary CFT, it is expected to be an almost periodic function of time. We point out that the decay of the two-point function (clustering in time) holds important clues to the nature of observable algebras, states, and dynamics in quantum gravity. We call operators that cluster in time “mixing” and explore the necessary and sufficient conditions for mixing. The information loss problem is a special case of the statement that in type I algebras, there exists no mixing operators. We prove that, in a thermofield double state (KMS state), if mixing operators form an algebra (close under multiplication), the resulting algebra must be a von Neumann type III 1 factor. In other words, the physically intuitive requirement that all nonconserved operators should exponentially mix is so strong that it fixes the observable algebra to be an exotic algebra called a type III1 factor. More generally, for an arbitrary out-of-equilibrium state of a general quantum system (von Neumann algebra), we show that if the set of operators that mix under modular flow forms an algebra, it is a type III1 von Neumann factor.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2020

Fully coherent energy loss effects on light hadron production in pA collisions

We single out the role of fully coherent induced gluon radiation on light hadron production in pA collisions. The effect has the same general features as for quarkonium production, however with a richer color structure as the induced radiation depends on the global color charge of the partonic subprocess final state. Baseline predictions for light hadron nuclear suppression in pPb collisions at the LHC are provided, taking into account only the effect of fully coherent energy loss, which proves to be of the same order of magnitude as gluon shadowing or saturation. This underlines the need to include fully coherent energy loss in phenomenological studies of hadron production in pA collisions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2020

Coral loss alters guarding and farming behavior of a Caribbean damselfish

Coral loss is a major element of global ecological change in the oceans that may shape the behavior of keystone species such as habitat-attached animals. Farming damselfishes cultivate and aggressively protect algal garden within their territory, thereby shaping local fish assemblages and macro-algae diversity. Following the widespread loss of live branching coral throughout Florida and the Caribbean Sea, dusky damselfish (Stegastes adustus) have modified their territorial behavior. We compared antagonistic behavior, and size and algal species composition of territories of dusky damselfish on dead branching coral rubble and live boulder coral in the Dry Tortugas National Park, USA. Even though similar numbers of “intruders” entered each habitat type, dusky damselfish on rubble territories chased out significantly more fishes, had larger territories and more species of algae were present in their gardens. This study shows that dusky damselfish successfully occupy living and dead coral areas; however, there are potential trade-offs between defending a larger territory and cultivating fewer algal species.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Mode connectivity in the loss landscape of parameterized quantum circuits

Variational training of parameterized quantum circuits (PQCs) underpins many workflows employed on near-term noisy intermediate scale quantum (NISQ) devices. It is a hybrid quantum-classical approach that minimizes an associated cost function in order to train a parameterized ansatz. In this work we adapt the qualitative loss landscape characterization for neural networks introduced in Goodfellow et al. (2014); Li et al. (2017) and tests for connectivity used in Draxler et al. (2018) to study the loss landscape features in PQC training. We present results for PQCs trained on a simple regression task, using the bilayer circuit ansatz, which consists of alternating layers of parameterized rotation gates and entangling gates. Multiple circuits are trained with 3 different batch gradient optimizers: stochastic gradient descent, the quantum natural gradient, and Adam. We identify large features in the landscape that can lead to faster convergence in training workflows.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2024

A study on the impact of using a subchannel resolution for modeling of large break loss of coolant accidents

The nuclear industry is investigating the feasibility of transitioning from 18- to 24-month fuel cycles because of the positive impact it would have on the operational costs for the current fleet of light-water reactors. A challenge to making this change is the increased risk of fuel fragmentation, relocation, and dispersal (FFRD) due to the known potential for ceramic fuel to pulverize into fine particles at the higher discharge burnups. Previous work has been performed by the Nuclear Energy Advanced Modeling and Simulation program to assess FFRD risk in high-burnup cores using the BISON fuel performance code and a coarse mesh thermal hydraulics (T/H) solution for a loss-of-coolant accident (LOCA) using the TRACE system T/H code. Because of the importance of the T/H solution for FFRD assessment, this study seeks to investigate the impact of using higher-fidelity subchannel techniques for modeling of the LOCA transient. CTF was used to model a subregion of a high-burnup core that was depleted by the Virtual Environment for Reactor Applications (VERA) multiphysics core simulator. Both coarse-mesh and pin-resolved models were created in CTF, and a consistent coarse-mesh TRACE model was also developed to allow for benchmarking the code results. Further, a large-break loss-of-coolant accident (LBLOCA) reflood transient was simulated using these three models, and results were compared. Results showed some consistent differences between the CTF and TRACE coarse models, including a higher peak cladding temperature (PCT) prediction in CTF and later quenching in CTF; however, the transient clad temperature behavior was similar, and these differences are likely due to post-critical heat flux heat transfer modeling differences and minimum film boiling temperature model differences. The pin-resolved results indicate that the PCT in the lumped model is often under-predicted by as much as 70 °C and that PCT occurs at a different location than the high-power pin in the assembly. The lumped model predicts a difference of 10 °C or less between the average and hot pins in the assembly, whereas the pin-resolved model predicts a range of over 100 °C. These results indicate that higher-fidelity T/H results may have an impact on predicted core behavior during LOCA, which may be important to consider when assessing FFRD risk.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2021

Mismatch losses in a PV system due to shortened strings

Numerous events may require intentional removal of one or more photovoltaic modules from a string, shortening the length of the string relative to others within the array, resulting in a string length mismatch. The impact of such a mismatch is not well understood either in measurable operational effects (voltage, current, power) or in the potential effects on long-term module health. It is impractical to solely approach this problem experimentally due to the size and complexity of arrays that may experience string length shortening. Here this work presents simulations, validated through limited field experiments on a two string array, providing a basis from which more complex arrays and scenarios may be explored. Refinement of the simulation achieves an overall error in IMPP for the nominal (S 1 ) and test strings (S 2 ) between the simulation and experimental values, through all test conditions, of +0.35 ± 1.46% and -0.36 ± 1.58% respectively. Shortening one of two strings by one module results in a power loss greater than the power contribution of the module alone (1.29 module equivalents); the impact increases through the maximum test case of a six module mismatch with a power loss equivalent to more than 11 modules. The impact of using string-end blocking diodes is presented with an emphasis at the array maximum power point and at open circuit. Implications are discussed for arrays of higher complexity.

14 SOLAR ENERGY↗
DOE OSTI2021

Irradiation hardening and ductility loss of Eurofer97 steel variants after neutron irradiation to ITER-TBM relevant conditions

Ten Eurofer97 steel variants, produced by non-standard fabrication-processing routes and modified alloying chemistries, were studied by neutron irradiations in the high flux isotope reactor. The irradiations were performed to ITER-TBM relevant conditions of ~255–350 °C, 2.94–3.24 dpa. We quantified the irradiation-induced degradation of the steels using mechanical property tests. All the steels suffered from irradiation hardening, where a significant increase in Vickers microhardness and yield stress (σ YS ) occurred, accompanied with severe loss of tensile elongation. The extent of hardening was material dependent. For T irr = 300±30 °C, most steels showed σ YS increase in the range of ~30% to as high as ~66%, except for a low temperature tempered steel with σYS increase below 15%. Despite large losses in elongation, most failures were ductile. Significant post-necking ductility was retained with reduction in area (RA) between 65–75%, but <50% for low temperature tempered steels. The ultimate tensile stress to yield stress (σ UTS /σ YS ) ratios decreased significantly after irradiation, highlighting irradiation-induced strain hardening capacity reduction. No major effect of irradiation on the plastic instability stress (σ PIS ) and true fracture stress of the steels was observed. By comparing the tensile stresses in true stress units and with literature, the results suggest that RAFM steel designing should target materials with a large separation between σ PIS and σ YS , to ensure the materials can maintain large work hardening and uniform deformation capability after irradiation. The tensile data of the steels additionally revealed a compelling evidence of an inverse trend between the change in RA and increase in σ YS of the neutron irradiated Eurofer97 type steels.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Robust Adaptive Control for Large-scale Inverter-based Resources with Partial and Complete Loss of Inverters

This article proposes an approach to address the current and the aggregated active power control challenge for large-scale inverter-based resources subjected to partially or completely loss of inverters and grid voltage variations. To address this problem, a distributed active power mechanism is proposed which generates desired inverters current. Then an adaptive mechanism distributes the voltage control input automatically between inverters in response to the partial or complete loss of inverters. An L2-gain-based controller is designed for each inverter to track the desired current and rejects the grid voltage disturbance. Here, simulation results show a significant robust tracking for collective active power and current.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2024

A Eulerian three-fluid flow framework for the study of fuel dispersal behavior under loss-of-coolant accident conditions

As the nuclear industry explores new fuel designs to accommodate increased burnup, studying fuel behavior during loss-of-coolant accidents is essential for ensuring the safe operation of light-water reactors. Here, this study presents a computational model to simulate the intricate three-phase flow dynamics of fuel dispersal following cladding breach, where solid fuel particles and carrier fission gases interact with the surrounding liquid or gas medium. The model utilizes a Eulerian three-fluid framework to depict the phase interaction within interpenetrating continua, treating fragmented fuel as granular material. Closure relationships for bulk-flow properties of the solid phase and detailed interfacial exchange terms in high-temperature, high-speed gas-solid-liquid flow scenarios are proposed. The model was validated using adiabatic experimental results in the literature, focusing on characterizing fuel dispersal behavior during loss-of-coolant accidents conditions. Settlement characteristics of the solids, quantified by the probability distribution of equivalent particles, closely matched probability density functions reported in experimental studies. Key highlights of this study include the theoretical description of a coupled three-phase flow with phase change, interpretation of the high-pressure boundary conditions and insights into the transient behavior of gas-solid-liquid phase dynamics during a simulated high-speed dispersal event.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2022

Effect of particle characteristics, kinetics and transport phenomena on the prediction of particle mass loss and products yields during biomass fast pyrolysis

Here a low computational cost model for the pyrolysis of biomass anisotropic particles was used to study the effect of thermal conductivity of the particle, CRECK kinetic scheme implementation, intraparticle secondary reactions, heats of reaction, and advection on particle conversion prediction. The model considers a shrinking anisotropic cylindrical particle with biomass pseudo-components, the appearance of liquid intermediates, intra-particle mass and heat transport and secondary reactions of volatiles. The model was validated against oak and birchwood single particle experiments. More accurate predictions for mass loss evolution are found when considering the change of the particle thermal conductivity anisotropy with conversion and the temperature dependency of the thermal conductivities of the biomass and the gas phase, compared to ignoring these phenomena. The CRECK biomass pyrolysis reaction scheme provides insights into the effect of biomass composition on the evolution of the liquid intermediate phase allowing future studies about the presence of heavy compounds in the bio-oil and other phenomena such as aerosol ejection. Secondary intraparticle vapor phase reactions showed a negligible effect in volatiles conversion while heterogeneous reactions slightly overestimate its conversion. Heats of reaction and product advection are important for accurate prediction of particle mass loss.

09 BIOMASS FUELS↗
DOE OSTI2022

Infrared laser ablation of poly(vinylidene fluoride): The Loss of HF

The mechanism and kinetics of infrared laser ablation of poly(vinylidene fluoride) (PVDF) in vacuum have been investigated to understand how this can be used as a polymer processing technology. The laser heats the surface and initiates decomposition of macromolecules in the molten polymer layer which rapidly leads to production of an ablative flow of polymer decomposition products. There is only a short induction period of up to 2 s before ablation begins. After the initial period, the rate of mass loss increases linearly with the time of laser exposure. Spherical particles with an average diameter of about 100 nm are formed on the surface of the powder coating obtained by laser ablation. Here, the particle distribution ranges from 50 nm to 300 nm. The main gaseous product of ablation is HF from dehydrofluorination. A second important ablation process is the formation of gaseous carbenes generated during secondary reactions. Proposed ablation reactions due to laser-induced thermal dehydrofluorination occur in two stages. In the first stage, a double bond appears in PVDF due to direct loss of HF. Subsequent detachment of HF leads to the appearance of both triple bonds and cumulene bonds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Correlating capacity fade with film resistance loss in fast charging of lithium-ion battery

Fast charging of lithium-ion (Li-ion) batteries makes it susceptible to lithium plating. Here, we report the correlation between capacity loss and cell impedance changes in the battery due to lithium electrodeposition. Li-ion pouch cells with nickel-manganese-cobalt cathode and graphite anode were charged at rates varying from 0.5C to 6C. The cell voltage evolution immediately after charging was monitored to identify the C-rates that result in lithium plating. Electrochemical impedance spectroscopy (EIS) was used to monitor the cell impedance evolution. The impedance of battery cells at C-rates lower than 1C and no lithium plating showed minimal changes from their baseline values in the period immediately after charging. However, the impedance of battery cells undergoing lithium plating and C-rates higher than 3C showed a substantial reduction immediately after charging, with recovery back to baseline values after 30 min of relaxation. These observations suggest that lithium plating causes damage to the solid electrolyte interface (SEI) layer on the anode particles during the charging period, followed by the reformation of the SEI during the relaxation period. The measured capacity loss has a linear correlation with observed impedance change. The linear relationship suggests that impedance monitoring may be used for prognostication of the state-of-health of Li-ion batteries.

25 ENERGY STORAGE↗
DOE OSTI2024

Feasibility of using crystal channeling for the beam loss mitigation in slow extraction at 8GeV

In the accelerator applications of slow extraction for High Energy Physics (HEP), one of the prime challenges is the mitigation of beam losses, which is becoming increasingly critical with the continuous rise in beam power. A significant breakthrough was achieved earlier at CERN through the successful deployment of proton beam channeling in a crystal at 400GeV, effectively diverting the beam away from extraction septa and offering new avenues for improving slow extraction efficiency. However, a crucial question remains whether this approach is still effective at lower and medium proton beam energies. In this paper, we present the promising results of the computer simulation studies of the septum shadowing at 8GeV for the Mu2e project slow extraction at Fermilab. In conclusion, across the wide range of beam parameters, the beam loss reduction is shown to range between 40% and factor of three.

43 PARTICLE ACCELERATORS↗
DOE OSTI2024

Dispersal of high-burnup fuel fragment surrogate particles during and after loss-of-coolant accident tests

The issue of fuel fragmentation, relocation, and dispersal is critical in the licensing and use of high-burnup (>62 GWd/MTU) nuclear fuel in light water reactors (LWRs). In this work, two test series are reported that examine the fragment dispersal during a burst event and an additional dispersal following the burst due to vibrations in the rod, such as those induced by accident recovery systems. To examine dispersal during the balloon and burst portion of a Loss-of-Coolant Accident event, HfO 2 fragments and yttria-stabilized zirconia pellets were filled into an as-fabricated cladding tube, which was then pressurized and subjected to loss-of-coolant accident testing in steam. Results from this test were found to be highly non-prototypic, and dispersal was both significantly more violent and significantly greater in magnitude than identified for actual fuel tests. These findings were attributed to the conservative (more dispersive) nature of the particles chosen for dispersal and to the details of the test conditions used that led to particularly wide bursts. Further, the second set of tests examined dispersal following the burst when vibrations were induced in the rod, primarily via recovery activities such as Emergency Core Cooling System actuation leading to rapid water addition. Post-burst dispersal testing was performed by inducing sinusoidal oscillations with 2–25 nm peak-to-peak amplitude and 2–5 Hz frequencies in pre-burst rods that had been refilled with HfO 2 fragments or high-burnup fragment surrogate mixture of HfO 2 fragments and yttria-stabilized zirconia sands. Testing revealed that rods with large burst openings (7 mm wide in this work) led to unmitigated dispersal from above the burst zone but that smaller bursts (5 mm wide), although still much larger than the mean fragment size of 3 mm, led to effectively no dispersal because of interparticle locking. Additionally, mixture and moisture were found to impact the amount of dispersal: mixtures increased dispersal, and moisture drastically reduced it. The implications of these findings on likely dispersal from actual fuel are discussed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Scalable semitransparent prototype organic photovoltaic module with minimal resistance loss

Semi-transparent organic photovoltaic (ST-OPV) cells are regarded as an attractive solution to building-integrated solar energy harvesting. Both the power conversion efficiency (PCE) and average photopic transmission (APT) of ST-OPVs have shown substantial increases in recent years. However, less attention has been paid to the area scaling of ST-OPV cells. In this work, we investigate the scalability of ST-OPV cells from 4 mm 2 to 1 cm 2 , as well as 9 cm 2 active area prototype module. By integrating both top and bottom metal grids onto the transparent electrodes, the series resistance loss of 1 cm 2 ST-OPV cell is significantly reduced, and is comparable to that of the grid-free 4 mm 2 cell. Nine 1 cm 2 cells are then connected in a series-parallel circuit to realize a prototype ST-OPV module. A 100% fabrication yield with only 5% PCE deviation among discrete cells is achieved. The semitransparent module shows PCE = 7.2 ± 0.1% under simulated AM 1.5G illumination at 1 sun intensity, which exhibits no connection resistance loss compared to that of the individual cells. The ST-OPV module exhibits an APT = 38.1 ± 1.1%, which enables a light utilization efficiency, LUE = 2.74 ± 0.09%. Here, the method demonstrates a promising way for ST-OPV modules to scale without compromising performance.

14 SOLAR ENERGY↗
DOE OSTI2026

Investigating charm quark energy loss in medium with the nuclear modification factor of D 0 -tagged jets

The nuclear modification factor R AA of charm jets, identified by the presence of a D 0 meson among the jet constituents, has been measured for the first time in Pb–Pb collisions at a centre-of-mass energy per nucleon pair $\sqrt{s_{NN}} = 5.02$ TeV with the ALICE detector at the LHC. The D 0 mesons and their charge conjugates are reconstructed from the hadronic decay D 0 → K – π + . Jets are reconstructed from D 0 -meson candidates and charged particles using the anti-k T algorithm with jet resolution parameter R = 0.3, in the jet transverse momentum (p T ) range 5 < $p^{ch}_{T}$$^{jet}$ < 50 GeV/c and pseudorapidity |η ch jet| < 0.6. A hint of reduced suppression in the charm-jet R AA is observed in comparison to inclusive jets in central Pb–Pb collisions with a significance of about 2σ in 20 < $p^{ch}_{T}$$^{jet}$ < 50 GeV/c, suggesting the in-medium energy loss to depend on both the difference between quark and gluon coupling strength (Casimir colour-charge effect) and quark mass (dead-cone effect). The data are compared with model calculations that include mass effects in the in-medium energy loss. Several state-of-the-art models are consistent with the data, with the LIDO model providing the best description of the data in the common kinematic range of inclusive and D 0 -tagged jets, highlighting the role of mass effects in interpreting the results.

Acharya, S. (ORCID:0000000292135329)↗
DOE OSTI2022

Potential of water quality wetlands to mitigate habitat losses from agricultural drainage modernization

Given widespread biodiversity declines, a growing global human population, and demands to improve water quality, there is an immediate need to explore land management solutions that support multiple ecosystem services. Agricultural water quality wetlands designed to provide both water quality benefits and wetland and grassland habitat are an emerging restoration solution that may reverse habitat declines in intensive agricultural areas. Installation of water quality wetlands in the Upper Midwest, USA, when considered alongside the repair and modification of aging agricultural tile drainage infrastructure, is a likely scenario that may mitigate nutrient pollution exported from agricultural systems and improve crop yields. The capacity of water quality wetlands to provide habitat within the wetland pool and the surrounding grassland is not well-studied, particularly with respect to potential habitat changes resulting from drainage infrastructure upgrades. For the current study, we produced spatially explicit models of 37 catchments distributed throughout an important region for agriculture and biodiversity, the Des Moines Lobe of Iowa. Four scenarios were considered - with and without improved drainage and with and without water quality wetlands - to estimate the net potential habitat implications of these scenarios for amphibians, grassland birds, and wild bees. Model results indicate that drainage modification alone will likely result in moderate direct losses of suitable amphibian habitat and large declines in overall habitat quality. However, inclusion of water quality wetlands at the catchment scale may mitigate these amphibian habitat losses while also increasing grassland bird and pollinator habitat. In conclusion, the impacts of water quality wetlands and drainage modernization on waterfowl in the region require additional study.

54 ENVIRONMENTAL SCIENCES↗