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NASA NTRS1973

Heat and ionization sources in the interstellar medium

This is a review of the astrophysical sources of heat and ionization in interstellar clouds and in the intercloud medium. Observational data on density, ionization, and temperatures of H I regions are summarized, and the heat and ionization requirements are specified in terms of heat input and hydrogen ionization rate. A wide variety of sources and mechanisms are reviewed and contrasted, and corresponding estimates of heat input and hydrogen ionization rate are presented in tabular form.

Silk, J.↗

NASA NTRS1973

Photodesorption from interstellar dust grains

An experiment to measure the photodesorption of physisorbed gases from a cold fused quartz substrate by near UV photons is described. The observed yield (mol/photon) is as large as .00001, a higher yield is likely in the vacuum UV. Included is a discussion of the photodesorption process and some applications to the interstellar medium. The observed yield is enough to maintain molecular abundances in moderate density interstellar clouds in equilibrium.

Greenberg, L. T.↗

NASA NTRS1974

Depletion of interstellar sodium and calcium

New measurements of the Ca II/Ca I ratios in interstellar clouds lead to the conclusion that not only Ca, but also Na, is underabundant in these regions. Recent calculations of element depletion by accretion of atoms onto dust grains probably cannot account for the observed abundance range. The extreme underabundance of Ca, and some part of the abundance range, probably reflect the composition of the grain cores.

White, R. E.↗

NASA NTRS1974

On ionization in H I regions

A comparison is made of the K I, Na I, Ca II, and H I interstellar absorption lines formed in relatively low-density interstellar clouds in H I regions. The data indicate that the fractional ionization (ratio of electron density to hydrogen density) is nearly constant for a range in hydrogen densities covering a factor of 15. If ionization balance exists in the clouds, then ionization of hydrogen by either low-energy cosmic rays or soft X-rays cannot be the principal source of the observed free electrons, and the hydrogen ionization rate is less than 10 to the -16th power per sec for these processes.

Hobbs, L. M.↗

NASA NTRS1974

Behaviour of comet Kohoutek /1973f/

The spectral identification of CH3CN and HCN provides the first support for the hypothesis first proposed by Wurm (1943), of chemically stable 'parent molecules' for the less stable radicals and ions seen in the coma and the tail. These two molecules were among the earliest discovered in dense interstellar clouds. Circumstantial evidence for the presence of water as the dominant volatile component in the nucleus has been growing for some time. However, a much more volatile species is required to explain the observed behavior of the comet. CO, formaldehyde, or methane would quickly evaporate as the comet approached the sun.

Mendis, D. A.↗

NASA NTRS1973

Chemistry in interstellar space

The particular characteristics of chemistry in interstellar space are determined by the unique environmental conditions involved. Interstellar matter is present at extremely low densities. Large deviations from thermodynamic equilibrium are, therefore, to be expected. A relatively intense ultraviolet radiation is present in many regions. The temperatures are in the range from 5 to 200 K. Data concerning the inhibiting effect of small activation energies in interstellar clouds are presented in a table. A summary of measured activation energies or barrier heights for exothermic exchange reactions is also provided. Problems of molecule formation are discussed, taking into account gas phase reactions and surface catalyzed processes.

Donn, B.↗

NASA NTRS1974

Rotational excitation of HCN by collisions

Rate constants for the rotational excitation of HCN by collisions with He atoms at temperatures below 100 K were computed from first principles and are presented in tabular form. The potential energy surface was obtained by using the uniform electron gas model of Gordon and Kim (1972) and then joined smoothly to the asymptotic long-range perturbation theory potential valid at large separations. Quantum close-coupling theory was used to analyze the collision dynamics. Individual rates are believed to be accurate to within 50% above 30 K and within a factor of two below 20 K. The results should be extendable to excitation by collision with H2 and may therefore be of value in the study of interstellar clouds.

Green, S.↗

NASA NTRS1974

Comets: Data, problems and objectives

Relevant results from the observations of Comet Kohoutek are presented with an outline summary of basic knowledge concerning comets, both subjects being confined to data related to the nature and origin of comets rather than the phenomena (for example, plasma phenomena are omitted). Places of cometary origin in the developing solar system are discussed, along with the proto-Uranus-Neptune region versus the much more distant fragmented interstellar cloud region, now frequented by comets of the Opik-Oort cloud. The Comet Kohoutek results add new insights, particularly with regard to the parent molecules and the nature of meteoric solids in comets, to restrict the range of the physical circumstances of comet formation.

Whipple, F. L.↗

NASA NTRS1974

Highly ionized atoms observed with Copernicus

Based on high-resolution observations using the Princeton satellite/spectrometer on Copernicus the O VI doublet is discussed in detail, in conjunction with data for the resonance lines of N V, Si IV, and S IV reported in five stars. The temperature, density, and the possible extent of the O VI producing region are discussed. The ratio N(S IV)/N(O VI) is used to derive a lower limit to the temperature in the O VI producing region. In near pressure equilibrium with normal interstellar clouds and H II regions minimum densities are found to be consistent with a hot plasma.

York, D. G.↗

NASA NTRS1975

Electron microscopy of irradiation effects in space

The paper discusses several discoveries made in the study of lunar material. In the examination of the effects of solar wind implantations the topics covered include (1) solar wind radiation damage parameters and their aging characteristics, (2) the theory of the ancient solar wind, (3) the solar wind sputtering erosion rate, (4) the physicochemical properties of amorphous coatings, (5) maturity indexes and the macroscopic properties of the lunar regolith, (6) solar wind gas bubbles, (7) the composition of very heavy nuclei in the contemporary solar wind, and (8) track aging processes. Conclusions are drawn from the results about other extraterrestrial features such as the parent bodies of the meteorites, early solar nebulas, and interstellar clouds.

Maurette, M.↗

NASA NTRS1974

The origin of life

Research in the areas of precambrian paleontology, chemical evolution of genetically important monomers, prebiotic dehydration-condensation reactions, organic compounds in meteorites and interstellar space, and biological exploration of the planets is summarized. Fossils in precambrian cherts and findings of eukaryotic cells are described, and recent investigations of prebiotic conditions, energy sources, and starting materials for genetic molecules are outlined. Studies of homogeneous and heterogeneous dehydrations and of nonaqueous thermal dehydrations are described. The detection of amino acids, purines, and pyrimidines in meteorites and of biologically significant molecules in interstellar clouds is discussed, as well as the possibilities of life on Jupiter, Mars, and Titan.

Horowitz, N. H.↗

NASA NTRS1975

Observations of the interstellar gas with the Copernicus satellite

Results are reviewed for Copernicus far-UV measurements of the absorption lines of H I, D I, H2, and heavier elements in the interstellar gas. Column densities along several lines of sight, as estimated from Ly-alpha absorption-line profiles, confirm that wide differences in the gas density are present in various directions. The measurement of interstellar D I implies an open universe unless alternate sources for this nuclide are found. Analysis of reddened stars for which the line of sight passes through one or more interstellar clouds indicates a depletion of several heavy elements in the gas. It is suggested that the depleted elements may be present in grains rather than molecules and that the intercloud medium may consist primarily of H II with a few small H I clouds.

Morton, D. C.↗

NASA NTRS1976

Ultraviolet observations of local gas

From satellite measurements of ultraviolet spectra of stars, an average density of approximately 1.1/cu cm for hydrogen atoms, in both atomic and molecular form, is estimated for regions of space along the galactic plane within about 1 kpc of the sun. About 20% of the atoms are bound in molecular form although this figure is uncertain since the ultraviolet measurements avoid the very dense interstellar clouds. Discrete values for this percentage are observed to vary markedly; regions with less than average density seem to have fractional abundances of H2 several orders of magnitude lower than average. A ratio of CO/H is observed for regions in front of stars observed by the Copernicus satellite.

Jenkins, E. B.↗

NASA NTRS1976

Absolute rate parameters for the reaction of ground state atomic oxygen with dimethyl sulfide and episulfide

It is pointed out that the investigated reaction of oxygen with dimethyl sulfide may play an important role in photochemical smog formation and in the chemical evolution of dense interstellar clouds. Kinetic data were obtained with the aid of the flash photolysis-resonance fluorescence method. The photodecomposition of molecular oxygen provided the oxygen atoms for the experiments. The decay of atomic oxygen was studied on the basis of resonance fluorescence observations. Both reactions investigated were found to be fast processes. A negative temperature dependence of the rate constants for reactions with dimethyl sulfide was observed.

Lee, J. H.↗

NASA NTRS1976

Observations of intensity and linear polarization of CTB 80 at 6 and 2.8 cm

The paper presents observations of the distribution of intensity and linear polarization over the radio source CTB 80 at 6 and 2.8 cm. The physical nature of the source is examined, particularly the relation between the strong central component and a ridgelike structure that extends across the northern half in the E-W direction. The structure, nonthermal spectrum, and polarization of the central component are found to be very similar to those of a supernova remnant, but the ridge is shown to be unlike any feature of any other SNR. It is suggested that the ridge may have resulted from expansion of the remnant shell into a dense interstellar cloud or, alternatively, that CTB 80 might be a nearby extragalactic radio source similar to Centaurus A.

Velusamy, T.↗

NASA NTRS1976

Observations of interstellar titanium toward 47 stars

Results are presented from photoelectric scans of the interstellar 3384-A line of Ti II obtained at a resolution of 3.7 km/s for 47 stars. Although the depletion of titanium from the interstellar gas is large and highly variable, its ratio to the depletion of interstellar calcium is relatively constant; titanium is less depleted than calcium by a factor of about four. A method for determining approximate electron densities from the Ca II and Ti II column densities is applied to 51 interstellar clouds.

Stokes, G. M.↗

NASA NTRS1976

The origin of OB associations and extended regions of high-energy activity in the Galaxy through supernova cascade processes

A number of observed characteristics of OB associations, including their positive total energies and subgroup structure, are explained by the hypothesis that an association is composed of stars formed by compression of interstellar clouds in blast waves of several generations of supernovae. The later-generation supernovae are simply the most massive stars formed by this mechanism in the earlier generations. This supernova cascade process may also be responsible for giant loops such as the North Polar Spur. Enhanced high-energy gamma-ray emission is expected from the loops.

Ogelman, H. B.↗

NASA NTRS1977

Indirect observation of unobservable interstellar molecules

It is suggested that the abundances of neutral non-polar interstellar molecules unobservable by radio astronomy can be systematically determined by radio observation of the protonated ions. As an example, observed N2H(+) column densities are analyzed to infer molecular nitrogen abundances in dense interstellar clouds. The chemistries and expected densities of the protonated ions of O2, C2, CO2, C2H2 and CH4 are then discussed. Microwave transition frequencies fo HCO2(+) and C2H3(+) are estimated, and a preliminary astronomical search for HCO2(+) is described.

Herbst, E.↗