Understanding the physical state of hot plasma formed through stellar wind collision in WR140 using high-resolution X-ray spectroscopy
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Asca Miyamoto↗
SEARCH · Engineering Papers
Results for “high resolution spectroscopy”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Galactic X-ray polarimetry and high-resolution X-ray spectroscopy.
Stellar X-ray spectroscopy and polarimetry are discussed in terms of the source parameters that can be determined through such studies and in terms of the constraints that these studies will place on theoretical models. The spectroscopic and polarimetric results that have been obtained to date are reviewed. These include the recent discovery of X-ray polarization in the Crab Nebula and the recent evidence for X-ray coronal line emission in the Cygnus Loop. Finally, the properties and predicted performance of a number of satellite-borne spectrometers and polarimeters are presented.
Novick, R.↗
Laser heterodyne spectroscopy
High-resolution heterodyne spectroscopic studies of the atmosphere of Venus are surveyed with attention to Doppler shifts in the 10-micron CO2 lines. While the C-12(O-16)2 emission lines formed in the mesosphere near 115 km indicate that the winds are distinctly subsolar to antisolar, C-13(O-16)2 absorption lines for the stratosphere at about 75 km confirm that the pattern is a strong retrograde rotation with an average equatorial velocity of 90 plus or minus 7 m/sec. It is concluded that the winds change from retrograde to subsolar-to-antipolar between 80 and 115 km.
Betz, A. L.↗
High resolution X-ray spectroscopy on the Einstein Observatory
The X-ray spectroscope presented features both spectral and one dimensional spatial resolution. The capabilities of observing sources like supernova remnants, X-ray stars, and the halo surrounding galaxies are discussed.
Clark, G. W.↗
High resolution X-ray spectroscopy from the Einstein Observatory
Results obtained from the Focal Plane Crystal Spectrometer (FPCS) are presented with particular reference to supernova remnants Puppis A and Cas A in the Galaxy, and N132D and N63A in the Large Magellanic Cloud. A schematic diagram of the FPCS is given, and spectrum reconstruction is outlined, noting that the final spectrum consists of a histogram of counting rate vs. energy corrected for the exposure time in each energy bin. Consideration is also given to the Virgo cluster and its two X-ray components: the hot exponent extending throughout much of the cluster and a cooler, 'halo', component centered on M87. FPCS observations of central M87 are presented, and it is postulated that the central portion of the M87 'halo' source contains material with a dominant temperature near 10 to the 7th K or below about 2 x 10 to the 6th K.
Winkler, P. F.↗
High-resolution iron-line spectroscopy
Methods of resolving the iron lines, the most common X-ray emission lines in both galactic and extragalactic X-ray sources, are reviewed. A self-focussing crystal spectrometer is shown to be the most suitable instrument, and the optimum crystal geometry is spherical (Schnopper and Taylor 1980). The principles of operation of such a spherical crystal imaging spectrometer are examined and its sensitivity is shown to be two orders of magnitude better than a focal plane crystal spectrometer on AXAF. A Spacelab version of this payload would be very cost-effective.
Griffiths, R. E.↗
Stratospheric composition measurements of earth and Titan using high-resolution tunable diode laser spectroscopy
Field and laboratory measurements of species of atmospheric interest made as part of the JPL diode laser spectroscopy program are presented. Stratospheric measurements of NO2, NO, CO2, and H2O made in November 1985 using the BLISS instrument are reported, together with recent laboratory measurements of spectral line parameters of HNO3 and HO2NO2. In addition, a novel diode laser instrument concept for the in situ sensing of Titan's atmosphere is described for the Saturn Orbiter/Titan Probe (SOTP) Cassini Mission.
Webster, Christopher R.↗
Absolute infrared band strength measurement of the ClO radical by Fourier transform infrared spectroscopy
High-resolution (0.005/cm) FTIR spectra of the X2Pi(i)-X2Pi(i) (1-0) rovibrational bands of (C-35)(O-16) and (Cl-37)(O-16) were obtained in 1 torr of helium carrier gas. After measuring the strengths of approximately 830 individual IR lines from several spectra, a total band strength of 13.1 + or - 1.1/sq cm atm and a first Herman-Wallis coefficient of (4.12 + or - 0.62) x 10 to the -3rd were determined.
Lang, Valerie I.↗
High-resolution X-ray spectroscopy of the supernova remnant N132D
A joint nonequilibrium ionization analysis of spectral data from the Einstein Observatory of the SNR N132D in the LMC is presented on the basis of data from the Focal Plane Crystal Spectrometer (FPCS) and the Solid State Spectrometer (SSS), and lower spectral resolution data from the IPC and the Monitor Proportional Counter (MPC). The FPCS detected individual emission lines of O VII, O VIII, Ne IX, Ne X, Fe XVII, and possibly Fe XX. Measured line widths for the oxygen lines suggest Doppler broadening that is roughly consistent with optically measured expansion velocities of 2250 km/s. At the SSS/IPC temperature, FPCS flux ratios constrain the O/Fe abundance to be at least 1.9 times its solar value and the O/Ne abundance to be 0.2-1.0 times its solar value. Models for remnants with progenitor masses of 20 and 25 solar masses are completely consistent with the data, while remnants with progenitor masses of 13 and 15 solar masses can be made consistent if the progenitors are required to eject a large fraction of their iron cores.
Hwang, Una↗
High-Resolution Infrared Space Observatory Spectroscopy of the Unidentified 21 Micron Feature
We present Infrared Space Observatory SWS06 mode observations of the 21 micron feature in eight sources, including a first "detection of the feature in IRAS Z02229+6208. The observed feature peak-to-continuum ratios range from 0.13 in IRAS Z02229+6208 to 1.30 in IRAS 07134+1005. The normalized spectra, obtained by the removal of the underlying continua and by scaling the features to the same peak flux value. show that all features have the same intrinsic profile and peak wavelength. There is no evidence for any discrete substructure due to molecular bands in the observed spectra, suggesting that the 21 micron feature is due to either a solid substance or a mixture of many similarly structured large molecules.
Volk, Kevin↗
New Atomic Data for Doubly Ionized Iron Group Atoms by High Resolution UV Fourier Transform Spectroscopy
Currently available laboratory spectroscopic data of doubly ionized iron-group element were obtained about 50 years ago using spectrographs of modest dispersion, photographic plates, and eye estimates of intensities. The accuracy of the older wavelength data is about 10 mAngstroms at best, whereas wavelengths are now needed to an accuracy of 1 part in 10(exp 6) to 10(exp 7) (0.2 to 2 mAngstroms at 2000 Angstroms). The Fourier transform (FT) spectroscopy group at Imperial College, London, and collaborators at the Harvard College Observatory have used a unique VUV FT spectrometer in a program focussed on improving knowledge of spectra of many neutral and singly and doubly ionized, astrophysically important, iron group elements. Spectra of Fe II and Fe III have been recorded at UV and VUV wavelengths with signal-to-noise ratios of several hundred for the stronger lines. Wavelengths and energy levels for Fe III are an order of magnitude more accurate than previous work; analysis is close to completion. f-values for Fe II have been published.
Smith, Peter L.↗
Microcalorimeters with NTD and Expitaxial Germanium Thermistors for High Resolution X-Ray Spectroscopy
This is a progress report for the second year of a three year SR&T grant to continue the advancement of NTD-based microcalorimeters. We reported last year that we re-prioritized certain aspects of the statement of work and chose to emphasize issues of array development in the first year rather than wait until year two. Consequently, some of the projects scheduled for the first year were delayed to the second year and we report on those topics here. These include: a) Measurements that map out JFET , thermistor, l/f and feedback resistor noise; b) Investigations that evaluate the limits of the JFET preamplifier circuitry as it pertains to stability at the 2 eV level; The results of a) and b) have led to preliminary measurements that demonstrate 3.08 eV resolution at 6 keV. c) Calculations that can predict the current performance.
Silver, Eric↗
Micro-Calorimeters with NTD and Epitaxial Germanium Thermistors for High Resolution X-Ray Spectroscopy
This is a progress report for the third year of a three year SR&T grant to continue the advancement of NTD-based microcalorimeters. We highlight our progress to date that allowed us to garner an additional three years of funding for this work.
Brinton, John↗
Mapping the intracluster medium in the era of high-resolution X-ray spectroscopy
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Congyao Zhang↗
Electronic structure of non-centrosymmetric PtBi2 studied by angle-resolved photoemission spectroscopy
Using high-resolution angle-resolved photoemission spectroscopy (ARPES), we have systematically studied the electronic structure of non-centrosymmetric PtBi2 with a layered structure. Through photon energy dependent measurements, the surface state and the bulk state were identified. Consistent with the non-centrosymmetric structure, different surface states were observed on opposite PtBi2(001) surfaces. Experimental bulk bands agree nicely with first-principle calculations. By combining ARPES and calculations, energy bands that contribute to triply degenerate point fermion were all detected. We also suggest that there are “canted” tube-like Fermi surfaces that might cause strong anisotropy in electronic transportation in non-centrosymmetric PtBi2.
Jiang, Wenxiang (ORCID:000000020524259X)↗
Operando High-Energy-Resolution X-ray Spectroscopy of Evolving Cu Nanoparticle Electrocatalysts for CO 2 Reduction
Advances in electrocatalysis research rely heavily on building a thorough mechanistic understanding of catalyst active sites under realistic operating conditions. Only recently have techniques emerged that enable sensitive spectroscopic data collection to distinguish catalytically relevant surface sites from the underlying bulk material under applied potential in the presence of an electrolyte layer. Here, we demonstrate that operando high-energy-resolution fluorescence detected X-ray absorption spectroscopy (HERFD-XAS) is a powerful spectroscopic method which offers critical surface chemistry insights in CO 2 electroreduction with sub-electronvolt energy resolution using hard X-rays. Combined with the high surface area-to-volume ratio of 5 nm copper nanoparticles, operando HERFD-XAS allows us to observe with clear evidence the breaking of chemical bonds between the ligands and the Cu surface as part of the ligand desorption process occurring under electrochemical potentials relevant for the CO 2 reduction reaction (CO 2 RR). In addition, the dynamic evolution of oxidation state and coordination number throughout the operation of the nanocatalyst was continuously tracked. With these results in hand, undercoordinated metallic copper nanograins are proposed to be the real active sites in the CO 2 RR. In conclusion, this work emphasizes the importance of HERFD-XAS compared to routine XAS in catalyst characterization and mechanism exploration, especially in the complicated electrochemical CO 2 RR.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
A review of the application of 2D isotropic-anisotropic correlation NMR spectroscopy in structural studies of chalcogenide glasses
The application of solid-state high-resolution NMR spectroscopy in the structural investigation of chalcogenide glasses in Ge/As/P/Si-X (X = S, Se,Te) systems has remained challenging even for the spin-1/2 nuclides ( 29 Si, 31 P, 77 Se, 125 Te), owing to their low natural abundance (except for 31 P), slow spin-lattice relaxation rate and large CSA and chemical shift distribution induced line broadening effects. However, most of these deleterious effects can be successfully overcome in two-dimensional (2D) isotropic-anisotropic correlation NMR experiments, especially when performed at high magnetic field and in conjunction with the Car-Purcell-Meiboom-Gill (CPMG) echo train acquisition. Here, we present a short introduction to the basic principles of such experiments and review their applications over the last decade in deciphering various short- and intermediate- range structural characteristics of chalcogenide glasses in S-Se, Se-Te, Ge-Se, As-Se and Si-Se systems as well as in investigating the molecular dynamics in a P-Se supercooled liquid. We anticipate possible future applications of these 2D isotropic-anisotropic correlation NMR experiments, particularly in conjunction with density functional theory-based calculations of NMR chemical shift tensor parameters and additional signal enhancement schemes, in addressing complex structural correlations and distributions in chalcogenide glasses.
2D NMR↗
Metal ion dopant-induced famatinite to chalcostibite phase transformation of copper antimony sulphide colloidal nanostructures: effect on photophysical and pseudocapacitance properties
Here, the strategic doping of transition metal ions into copper antimony sulphide (CAS) semiconducting nanostructures can significantly influence their photophysical and pseudocapacitive properties, for which there are few reports and therefore is the focus of this study. Accordingly, highly crystalline metal ion (Mn 2+ , Fe 2+ , Co 2+ , Ni 2+ and Zn 2+ ) doped off-stoichiometric copper rich/poor, antimony-rich/poor, and sulphur-poor CAS nanostructures (10–23 nm) were grown via colloidal (hot-injection) synthesis using metal diethyldithiocarbamate precursors. Importantly, metal ion doping significantly influences the structure and composition of the off-stoichiometric CAS nanostructures. Data from powder X-ray diffraction, Raman spectroscopy, high-resolution scanning/transmission electron microscopy, and energy dispersive X-ray spectroscopy confirm that the heavier metal ion dopants induce a novel phase transformation from famatinite (fCAS) to chalcostibite (cCAS) nanostructures. The influence of the metal ion dopants is also observed in the optical properties of as-synthesized nanostructures. This involves blue-shifted ultraviolet-visible absorption, reduced Urbach tailing, and tunable bandgaps between 2.17 and 2.38 eV. Also, the doped nanostructures display broad visible-near infrared photoluminescence via a triple radiative pathway with relatively short decay lifetimes between 0.2 and 6.1 ns. This is mediated by electronic transitions involving intrinsic (copper/antimony/sulphur interstitial) and extrinsic (metal ion interstitial) defect states. Additionally, electrodes prepared from Mn 2+ -doped fCAS nanostructures show enhanced pseudocapacitance via Na+ surface adsorption and intercalation relative to undoped fCAS electrodes, while Zn 2+ -doped cCAS electrodes exhibit pseudocapacitance via a combination of Na+ surface adsorption, intercalation, and redox reactions. These electrodes exhibit reduced charge transfer resistance, improved electronic conductivity and notably enhanced specific capacitance (∼222 F g −1 ), and charge transport, as measured in 1 M Na 2 SO 4 electrolyte via cyclic voltammetry and electrochemical impedance spectroscopy. To this end, the discovery of the metal ion-induced phase transformation presents a new avenue for optimizing the functional properties of fCAS and cCAS nanostructures, highlighting the critical role of metal ion-related defects in controlling the optical and electrochemical properties, towards potential solar absorption and energy storage applications.
25 ENERGY STORAGE↗