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At least 397 records · Page 22

Fate in humans of the plasticizer, DI (2-ethylhexyl) phthalate, arising from transfusion of platelets stored in vinyl plastic bags

Platelet concentrates were shown to contain 18-38 mg/100 ml of a phthalate plasticizer (DEHP) which arose by migration from the vinyl plastic packs in which the plateletes were prepared and stored. Transfusion of these platelets into 6 adult patients with leukemia resulted in peak blood plasma levels of DEHP ranging from 0.34 - 0.83 mg/100 ml. The blood levels fell mono-exponentially with a mean rate of 2.83 percent per minute and a half-life of 28.0 minutes. Urine was assayed by a method that would measure unchanged DEHP as well as all phthalic acid-containing metabolities. In two patients, at most 60 and 90% of the infused dose, respectively, was excreted in the urine collected for 24 hours post-transfusion. These estimates, however, could be high due to the simultaneous excretion of DEHP remaining from previous transfusions or arising from uncontrolled environmental exposures.

Rubin, R. J.↗

Depth profiles of Mn-53 in lunar rocks and soils

Results of measurements of cosmic-ray-produced Mn-53 taken down the length of the Apollo 16 deep drill core are presented. They indicate that the lunar regolith has been unmixed, on a meter scale, for the past 5 million years at the location of this core. The data are in agreement with earlier Mn-53 measurements on the Apollo 15 drill core. Mn-53 activity profiles in 14310, 12002, and 14321 are compared to each other; all three rocks have probably been on the lunar surface long enough to saturate their solar cosmic-ray-produced Mn-53 (half-life = 3.7 m.y.) activity.

Imamura, M.↗

Na-22, Ne-E, extinct radioactive anomalies and unsupported Ar-40

The possibility that the origin of extinct radioactivities depended on their living long enough for grains to form in the expanding nucleosynthetic envelope, rather than on their living long enough for meteorites to form, is examined. As an example, the interpretation of Na-22 as a detectable extinct radioactivity, with a half life of only 2.6 years, is explored and related to Ne-22 occurrence. Similar arguments involving He-4, Ar-40, K-40, K-41, and calcium, titanium, chromium, manganese, iron, nickel, and cobalt isotopes are briefly presented.

Clayton, D. D.↗

Compositional evidence regarding the influx of interplanetary materials onto the lunar surface

Siderophilic element/Ir ratios are higher in mature lunar soils from highlands sites than in those from mare sites. It is suggested that the population of materials responsible for the early intense bombardment of the moon had high ratios and that the population responsible for the essentially constant flux has low ratios. Arguments are summarized against the viewpoint that the siderophiles in most highlands breccias originated in basin-forming projectiles. Differences in mature soil siderophile concentrations at the Apollo 14 and 16 sites indicate a substantially greater concentration at the latter site immediately following the Imbrium event. Siderophile concentrations are used to estimate mean regolith depths at the landing sites. The long-lived flux is calculated to be 2.9 g per cm per aeon averaged over the past 3.7 aeons. Consideration of the relationship between mass fluence and time indicates that the mass flux decreased with a half-life of about 40 million years immediately following the Imbrium event.

Wasson, J. T.↗

High-Temperature, Low-Cycle Fatigue of Copper-Base Alloys for Rocket Nozzles. Part 1: Data Summary for Materials Tested in Prior Programs

A more detailed analysis of the results obtained in 188 previously reported low-cycle fatigue tests of various candidate materials for regeneratively-cooled, reusable rocket nozzle liners was reported. Plots of load range versus cycles were reported for each test along with a stress-strain hysteresis loop near half-life. In addition, a summary table was provided to compare N5 (cycles to a five percent load range drop) and Nf (cycles to complete specimen separation) values for each test.

Conway, J. B.↗

Nuclear waste disposal utilizing a gaseous core reactor

The feasibility of a gaseous core nuclear reactor designed to produce power to also reduce the national inventories of long-lived reactor waste products through nuclear transmutation was examined. Neutron-induced transmutation of radioactive wastes is shown to be an effective means of shortening the apparent half life.

Paternoster, R. R.↗

Comments on galactic evolution and nucleocosmochronology

Long-lived nucleochronologies are calculated for several recently proposed models of the chemical evolution of the Galaxy. Special attention is paid to the Re-187/Os-187 chronometer, for which important data have recently become available. It is found that although the rate of star formation does vary with time in the different models, the quantity that is related to the effective net rate of nucleosynthesis is constant for most of the physically plausible recent-evolution models examined. This constant net rate implies that for these models, the age of the Galaxy at the time the solar system formed is twice the mean age of the stable elements. This mean age can be estimated by the parameter 'delta max', in which case the age of the Galaxy is twice this parameter plus the age of the solar system. The present uncertainties in 'delta max' yield an age for the Galaxy of 7 to 20 billion years. However, this range could be significantly reduced by an accurate measurement of the half-life of Re-187 and more knowledge on the effect of stellar temperatures on the Os-186/Os-187 neutron-capture cross-section ratio. In fact, experiments which could be carried out in the next few years can reduce these uncertainties tremendously and enable an age determination to be made which might severely restrict cosmological models.

Hainebach, K. L.↗

Clues in the rare gas isotopes to early solar system history

The results of the radioactive dating and the discovery of gas-rich meteorites on the Moon surface are reviewed. Special attention is paid to the extinct radioactivity iodine-129. This radioactivity is produced by r-process of nucleosynthesis and it decays with a half-life of 17 m.y. It provides a clock sensitive to small changes in the early years of the solar system.

Reynolds, J. H.↗

Transmutation doping of silicon solar cells

Normal isotopic silicon contains 3.05% of Si-30 which transmutes to P-31 after thermal neutron absorption, with a half-life of 2.6 hours. This reaction is used to introduce extremely uniform concentrations of phosphorus into silicon, thus eliminating the areal and spatial inhomogeneities characteristic of chemical doping. Annealing of the lattice damage in the irradiated silicon does not alter the uniformity of dopant distribution. Transmutation doping also makes it possible to introduce phosphorus into polycrystalline silicon without segregation of the dopant at the grain boundaries. The use of neutron transmutation doped (NTD) silicon in solar cell research and development is discussed.

Wood, R. F.↗

Evidence for Al-26 in the solar system

Evidence is reviewed for the presence of short-lived Al-26 (half-life of 720,000 years) in the early solar system. Large excesses of Mg-26 of up to 5% have been found in Ca-Al-rich inclusions of the Allende meteorite. The Mg excesses correlate well with Al-27/Mg-24 and in two cases they are found in high-purity separates of coarse-grained Al-rich minerals which tend to exclude Mg. The data demonstrate that Al-26 was present in the early solar system. Mechanisms for addition of Al-26 to the solar nebula or for production within an active solar system are required within a few million years of condensation of small (centimeter-sized) objects. The Al-26 abundance in Allende inclusions is high enough to provide for effective melting of kilometer-size bodies or larger, if such bodies accreted early enough (a few million years) to incorporate the Al-26.

Papanastassiou, D. A.↗

Thermal evolution of planetary size bodies

The size dependence of planetary thermal evolution is investigated through calculations which take into account the effects of heat source differentiation and convection. The theoretical computations make use of hypothetical bodies for minor planets; Mercury, Venus and Mars are employed to represent the size spectrum of the inner planets. If started at a cold initial condition, an object with a radius less than 1000 km is unlikely to reach melting. Accretional heating, inductive heating and short half-life radioactive heating are among the mechanisms which may produce early melting and differentiation in larger planets. Core formation in Mercury and Venus is also discussed.

Hsui, A. T.↗

Lunar regolith dynamics based on analysis of the cosmogenic radionuclides Na-22, Al-26, and Mn-53

Depth profiles of Na-22 and Al-26 in the upper portions of five lunar cores are analyzed. From the analyses, it is concluded that the natural gardening processes on the lunar surface result in mixing of the regolith to a depth of 2-3 cm over a time period which is short compared with the half-life of Al-26 (0.73 m.y.). It is also concluded that the rotary drill processes which were used to obtain the deep drill samples generally resulted in loss and/or mixing of the upper portions of the cores. In contrast, the near-surface regions of the drive tube cores appear to have a well-preserved stratigraphy. Analysis of Mn-53 in samples of six lunar rocks helps substantiate the accuracy of age date estimates by other means, and provides definite information that the total lunar surface exposure of two of these rocks has occurred during a single surface event which continued to their collection.

Fruchter, J. S.↗

Decay of the zincate concentration gradient at an alkaline zinc cathode after charging

The study was carried out by observing the decay of the zincate concentration gradient at a horizontal zinc cathode after charging. This decay was found to approximate first order kinetics as expected from a proposed boundary layer model. The decay half life was shown to be a linear function of the thickness of porous zinc deposit on the cathode indicating a very rapid transport of zincate through porous zinc metal. The rapid transport is attributed to an electrochemical mechanism. The data also indicated a relatively sharp transition between the diffusion and convection transport regions. The diffusion of zincate ion through asbestos submerged in alkaline electrolyte was shown to be comparable with that predicted from the bulk diffusion coefficient of the zincate ion in alkali.

Kautz, H. E.↗

Measurements of Cl-36 in Antarctic meteorites and Antarctic ice using a Van de Graaff accelerator

The paper presents measurements of cosmic-ray produced (Cl-36) in Antarctic meteorites and ice using a Van de Graaff accelerator as an ultrasensitive mass spectrometer. Results from this ion counting technique are used to support a two-stage irradiation model for the Yamato-7301 and Allan Hills-76008 meteorites and to show a long terrestrial age for Allan Hills-77002. Yamato-7304 has a terrestrial age of less than 0.1 m.y., and the (Cl-36) content of the Antarctic ice sample from the Yamato mountain is consistent with levels expected in currently depositing snow implying that the age of the ice cap at this site is less than on (Cl-36) half-life.

Nishiizumi, K.↗

Neutron capture time scale of the s-process, estimated from s-process krypton in a meteorite

A krypton fraction enriched in s-process isotopes was extracted from a mineral fraction of the Murchison C2 chondrite. The (Kr-86)/(Kr-84) ratio is enhanced by 6 standard deviations, showing that significant amounts of Kr-86 were made in the s-process, despite the short, 10.8 yr beta-decay half-life of its precursor, Kr-85. Judging from this sample, the mean neutron capture time in the s-process was on the order of 5-100 yr for nuclei with cross sections of 125 mb.

Matsuda, J.-I.↗

Fatigue degradation in compressively loaded composite laminates

The effect of imbedded delaminations on the compression fatigue behavior of quasi-isotropic, T300/5208, graphite/epoxy laminates was investigated. Teflon imbedments were introduced during panel layup to create delaminations. Static and constant amplitude (R=10, omega = 10 Hz) fatigue tests were conducted. S-N data and half life residual strength data were obtained. During static compression loading, the maximum deflection of the buckled delaminated region was recorded. Under compression fatigue, growth of the imbedded delamination was identified as the predominant failure mode in most of the test cases. Specimens that exhibited others failures had a single low stiffness ply above the Teflon imbedment. Delamination growth during fatigue was monitored using DIB enhanced radiography. In specimens with buried delaminations, the dye penetrant (DIB) was introduced into the delaminated region through a minute laser drilled hole, using a hypodermic needle. A low kV, microfocus, X-ray unit was mounted near the test equipment to efficiently record the cyclic growth of buried delaminations on Polaroid film.

Ramkumar, R. L.↗

Actinide cosmic ray chronometers - Relative abundances and the cosmic ray lifetime

Measurements of ultraheavy cosmic rays will provide radioactive chronometers, including the actinides, which are expected to be present in the source. These primary chronometers differ from the Be-10 secondary chronometer in total inelastic cross-section and decay half-life. A propagation code, which includes nuclear fragmentation, radioactive decay, and ionization energy-loss of cosmic rays is being used to investigate the variations in the fluxes and mean ages which would be expected for various models of cosmic ray propagation. Some preliminary results in the actinide region are presented here which indicate that measurements of the relative abundances of the actinides in the cosmic rays will be very useful for understanding source abundances but less useful for studying propagation effects.

Margolis, S. H.↗

Cosmic ray exposure ages of chondrites, pre-irradiation and constancy of cosmic ray flux in the past

Calibration of the production rate of the Ne-21 nuclide was accomplished by 4 methods based on (Al-26)-age, (Mn-53)-age, Kr-81/Kr-83, and Na-22/Ne-22. These production rates are normalized to a shielding parameter ratio Ne-22/Ne-21 = 1.11 and to the chemical composition of L chondrites; a value of P(21)(1.11) = 0.31 is suggested, and a production rate equation derived in terms of the 'F' parameters for L, LL, and H chondrites. The Al-26 half-life measurements are considered to evaluate the effects resulting from preirradiation of meteorites and to examine the data on the constancy of the cosmic ray flux in the light of current astronomical observations.

Nishizumi, K.↗