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At least 397 records · Page 22

Rapid, specific determination of iodine and iodide by combined solid-phase extraction/diffuse reflectance spectroscopy

A new, rapid methodology for trace analysis using solid-phase extraction is described. The two-step methodology is based on the concentration of an analyte onto a membrane disk and on the determination by diffuse reflectance spectroscopy of the amount of analyte extracted on the disk surface. This method, which is adaptable to a wide range of analytes, has been used for monitoring ppm levels of iodine and iodide in spacecraft water. Iodine is used as a biocide in spacecraft water. For these determinations, a water sample is passed through a membrane disk by means of a 10-mL syringe that is attached to a disk holder assembly. The disk, which is a polystyrene-divinylbenzene composite, is impregnated with poly(vinylpyrrolidone) (PVP), which exhaustively concentrates iodine as a yellow iodine-PVP complex. The amount of concentrated iodine is then determined in only 2 s by using a hand-held diffuse reflectance spectrometer by comparing the result with a calibration curve based on the Kubelka-Munk function. The same general procedure can be used to determine iodide levels after its facile and exhaustive oxidation to iodine by peroxymonosulfate (i.e., Oxone reagent). For samples containing both analytes, a two-step procedure can be used in which the iodide concentration is calculated from the difference in iodine levels before and after treatment of the sample with peroxymonosulfate. With this methodology, iodine and iodide levels in the 0.1-5.0 ppm range can be determined with a total workup time of approximately 60 s with a RSD of approximately 6%.

Non-NASA Center↗

Transduction-like gene transfer in the methanogen Methanococcus voltae

Strain PS of Methanococcus voltae (a methanogenic, anaerobic archaebacterium) was shown to generate spontaneously 4.4-kbp chromosomal DNA fragments that are fully protected from DNase and that, upon contact with a cell, transform it genetically. This activity, here called VTA (voltae transfer agent), affects all markers tested: three different auxotrophies (histidine, purine, and cobalamin) and resistance to BES (2-bromoethanesulfonate, an inhibitor of methanogenesis). VTA was most effectively prepared by culture filtration. This process disrupted a fraction of the M. voltae cells (which have only an S-layer covering their cytoplasmic membrane). VTA was rapidly inactivated upon storage. VTA particles were present in cultures at concentrations of approximately two per cell. Gene transfer activity varied from a minimum of 2 x 10(-5) (BES resistance) to a maximum of 10(-3) (histidine independence) per donor cell. Very little VTA was found free in culture supernatants. The phenomenon is functionally similar to generalized transduction, but there is no evidence, for the time being, of intrinsically viral (i.e., containing a complete viral genome) particles. Consideration of VTA DNA size makes the existence of such viral particles unlikely. If they exist, they must be relatively few in number;perhaps they differ from VTA particles in size and other properties and thus escaped detection. Digestion of VTA DNA with the AluI restriction enzyme suggests that it is a random sample of the bacterial DNA, except for a 0.9-kbp sequence which is amplified relative to the rest of the bacterial chromosome. A VTA-sized DNA fraction was demonstrated in a few other isolates of M. voltae.

Methanococcus/genetics/growth & development/metabo↗

Picturing Data With Uncertainty

NASA is in the business of creating maps for scientific purposes to represent important biophysical or geophysical quantities over space and time. For example, maps of surface temperature over the globe tell scientists where and when the Earth is heating up; regional maps of the greenness of vegetation tell scientists where and when plants are photosynthesizing. There is always uncertainty associated with each value in any such map due to various factors. When uncertainty is fully modeled, instead of a single value at each map location, there is a distribution expressing a set of possible outcomes at each location. We consider such distribution data as multi-valued data since it consists of a collection of values about a single variable. Thus, a multi-valued data represents both the map and its uncertainty. We have been working on ways to visualize spatial multi-valued data sets effectively for fields with regularly spaced units or grid cells such as those in NASA's Earth science applications. A new way to display distributions at multiple grid locations is to project the distributions from an individual row, column or other user-selectable straight transect from the 2D domain. First at each grid cell in a given slice (row, column or transect), we compute a smooth density estimate from the underlying data. Such a density estimate for the probability density function (PDF) is generally more useful than a histogram, which is a classic density estimate. Then, the collection of PDFs along a given slice are presented vertically above the slice and form a wall. To minimize occlusion of intersecting slices, the corresponding walls are positioned at the far edges of the boundary. The PDF wall depicts the shapes of the distributions very dearly since peaks represent the modes (or bumps) in the PDFs. We've defined roughness as the number of peaks in the distribution. Roughness is another useful summary information for multimodal distributions. The uncertainty of the multi-valued data can also be interpreted by the number of peaks and the widths of the peaks as shown by the PDF walls.

Kao, David↗

Promethazine affects autonomic cardiovascular mechanisms minimally

Promethazine hydrochloride, Phenergan, is a phenothiazine derivative with antihistaminic (H1), sedative, antiemetic, anticholinergic, and antimotion sickness properties. These properties have made promethazine a candidate for use in environments such as microgravity, which provoke emesis and motion sickness. Recently, we evaluated carotid baroreceptor-cardiac reflex responses during two Space Shuttle missions 18 to 20 hr after the 50 mg intramuscular administration of promethazine. Because the effects of promethazine on autonomic cardiovascular mechanisms in general and baroreflex function in particular were not known, we were unable to exclude a possible influence of promethazine on our results. Our purpose was to determine the ground-based effects of promethazine on autonomic cardiovascular control. Because of promethazine's antihistaminic and anticholinergic properties, we expected that a 50-mg intramuscular injection of promethazine would affect sympathetically and vagally mediated cardiovascular mechanisms. Eight healthy young subjects, five men and three women, were studied at rest in recumbency. All reported drowsiness as a result of the promethazine injection; most also reported nervous excitation, dry mouth, and fatigue. Three subjects had significant reactions: two reported excessive anxiety and one reported dizziness. Measurements were performed immediately prior to injection and 3.1 +/- 0.1 and 19.5 +/- 0.4 hr postinjection. We found no significant effect of promethazine on resting mean R-R interval, arterial pressure, R-R interval power spectra, carotid baroreflex function, and venous plasma catecholamine levels.

Clinical Trial↗

Geology of the Gusec cratered plains from the Spirit rover transverse

The cratered plains of Gusev traversed by Spirit are generally low-relief rocky plains dominated by impact and eolian processes. Ubiquitous shallow, soil-filled, circular depressions, called hollows, are modified impact craters. Rocks are dark, fine-grained basalts, and the upper 10 m of the cratered plains appears to be an impact-generated regolith developed over intact basalt flows. Systematic field observations across the cratered plains identified vesicular clasts and rare scoria similar to original lava flow tops, consistent with an upper inflated surface of lava flows with adjacent collapse depressions. Crater and hollow morphometry are consistent with most being secondaries. The size frequency distribution of rocks >0.1 m diameter generally follows exponential functions similar to other landing sites for total rock abundances of 5-35%. Systematic clast counts show that areas with higher rock abundance and more large rocks have higher thermal inertia. Plains with lower thermal inertia have fewer rocks and substantially more pebbles that are well sorted and evenly spaced, similar to a desert pavement or lag. Eolian bed forms (ripples and wind tails) have coarse surface lags, and many are dust covered and thus likely inactive. Deflation of the surface _5-25 cm likely exposed two-toned rocks and elevated ventifacts and transported fines into craters creating the hollows. This observed redistribution yields extremely slow average erosion rates of _0.03 nm/yr and argues for very little long-term net change of the surface and a dry and desiccating environment similar to today's since the Hesperian (or _3 Ga).

Spirit↗

Improved Model of a Mercury Ring Damper

A short document discusses the general problem of mathematical modeling of the three-dimensional rotational dynamics of rigid bodies and of the use of Euler parameters to eliminate the singularities occasioned by the use of Euler angles in such modeling. The document goes on to characterize a Hamiltonian model, developed by the authors, that utilizes the Euler parameters and, hence, is suitable for use in computational simulations that involve arbitrary rotational motion. In this formulation unlike in prior Euler-parameter-based formulations, there are no algebraic constraints. This formulation includes a general potential energy function, incorporates a minimum set of momentum variables, and takes an explicit state-space form convenient for numerical implementation. Practical application of this formulation has been demonstrated by the development of a new and simplified model of the rotational motion of a rigid rotor to which is attached a partially filled mercury ring damper. Models like this one are used in guidance and control of spin-stabilized spacecraft and gyroscope-stabilized seekers in guided missiles.

Fahrenthold, Eric P.↗

Multiphysics Modeling for Dimensional Analysis of a Self-Heated Molten Regolith Electrolysis Reactor for Oxygen and Metals Production on the Moon and Mars

The technology of direct electrolysis of molten lunar regolith to produce oxygen and molten metal alloys has progressed greatly in the last few years. The development of long-lasting inert anodes and cathode designs as well as techniques for the removal of molten products from the reactor has been demonstrated. The containment of chemically aggressive oxide and metal melts is very difficult at the operating temperatures ca 1600 C. Containing the molten oxides in a regolith shell can solve this technical issue and can be achieved by designing a self-heating reactor in which the electrolytic currents generate enough Joule heat to create a molten bath. In a first phase, a thermal analysis model was built to study the formation of a melt of lunar basaltic regolith irradiated by a focused solar beam This mode of heating was selected because it relies on radiative heat transfer, which is the dominant mode of transfer of energy in melts at 1600 C. Knowing and setting the Gaussian-type heat flux from the concentrated solar beam and the phase and temperature dependent thermal properties, the model predicts the dimensions and temperature profile of the melt. A validation of the model is presented in this paper through the experimental formation of a spherical cap melt realized by others. The Orbitec/PSI experimental setup uses an 3.6-cm diameter concentrated solar beam to create a hemispheric melt in a bed of lunar regolith simulant contained in a large pot. Upon cooling, the dimensions of the vitrified melt are measured to validate the thermal model. In a second phase, the model is augmented by multiphysics components to compute the passage of electrical currents between electrodes inserted in the molten regolith. The current through the melt generates Joule heating due to the high resistivity of the medium and this energy is transferred into the melt by conduction, convection and primarily by radiation. The model faces challenges in two major areas, the change of phase as temperature increases, and the dominance of radiative heat flux as heat transfer mechanism within the melt the change of phase concerns the regolith itself which is present in states ranging from a fine grain regolith with low thermal conductivity and low density to a vitrified melt with much higher thermal conductivity, and higher density. As the regolith is heated, it starts to soften around 1300 C the melt iS very viscous and evolving gas bubbles out in thick, lava-like fashion. By 1600 C the regolith is completely melted and the viscosity is low The second challenge resides in the proper modeling of the radiative heat flux requiring the addition of the computing-demanding radiative-heat-transfer function to the general heat transfer equation. The model Includes temperature-dependent properties (density, thermal conductivity, heat capacity, and viscosity, and absorption coefficients) and solves the radiative heat flux equation assuming gray (fine grains) and semi-transparent (melt) media and using an absorption coefficient spectral found in the literature for terrestrial minerals similar in composition to those of lunar regolith simulant

Dominguez, Jesus A.↗

Michigan Orbital DEbris Survey Telescope Observations of the Geosynchronous Orbital Debris Environment. Observing Years: 2007-2009

NASA uses the Michigan Orbital DEbris Survey Telescope (MODEST), the University of Michigan's 0.61-m aperture Curtis-Schmidt telescope at the Cerro Tololo Inter-American Observatory in Chile, to help characterize the debris environment in geosynchronous orbit; this began in February 2001 and continues to the present day. Detected objects that are found to be on the U.S. Space Surveillance Network cataloged objects list are termed correlated targets (CTs), while those not found on the list are called uncorrelated targets (UCTs). This Johnson Space Center report provides details of observational and data-reduction processes for the entire MODEST dataset acquired in calendar years (CYs) 2007, 2008, and 2009. Specifically, this report describes the collection and analysis of 36 nights of data collected in CY 2007, 43 nights of data collected in CY 2008, and 43 nights of data collected in CY 2009. MODEST is equipped with a 2048 x 2048-pixel charged coupled device camera with a 1.3 by 1.3 deg field of view. This system is capable of detecting objects fainter than 18th magnitude (R filter) using a 5-s integration. This corresponds to a 20-cm diameter, 0.175-albedo object at 36,000 km altitude assuming a diffuse Lambertian phase function. The average number of detections each night over all 3 years was 26. The percentage of this number that represented the UCT population ranged from 34% to 18%, depending on the observing strategy and the field center location. Due to the short orbital arc over which observations are made, the eccentricity of the object s orbit is extremely difficult to measure accurately. Therefore, a circular orbit was assumed when calculating the orbital elements. A comparison of the measured inclination (INC), right ascension of ascending node (RAAN), and mean motion to the quantities for CTs from the U.S. Space Surveillance Network shows acceptable errors. This analysis lends credibility to the determination of the UCT orbital distributions. Figure 1 shows the size distribution of 3,143 objects detected in the data processed for CYs 2007, 2008, and 2009. The actual peak of the absolute magnitude distribution for the functional correlated targets is 10th magnitude, whereas the peak was 11th magnitude in 2002 2003 and 10th magnitude for 2004-2006. An absolute magnitude of 10.5 corresponds to objects with average diameters of 6.3 m, assuming an albedo of 0.175 and a diffuse Lambertian phase function. This result generally agrees with the known sizes of intact satellites. The absolute magnitude distribution for the UCTs is broad, but starts to roll off near 25 cm diameter or 17.5 magnitude. This roll off in the distribution reflects the detection capability of MODEST, not the true nature of the population. The true population is believed to continue at the same slope through fainter magnitudes based on comparisons with the LEO break-up law.

Abercromby, K. J.↗

Real-Time Distributed Embedded Oscillator Operating Frequency Monitoring

A document discusses the utilization of embedded clocks inside of operating network data links as an auxiliary clock source to satisfy local oscillator monitoring requirements. Modem network interfaces, typically serial network links, often contain embedded clocking information of very tight precision to recover data from the link. This embedded clocking data can be utilized by the receiving device to monitor the local oscillator for tolerance to required specifications, often important in high-integrity fault-tolerant applications. A device can utilize a received embedded clock to determine if the local or the remote device is out of tolerance by using a single link. The local device can determine if it is failing, assuming a single fault model, with two or more active links. Network fabric components, containing many operational links, can potentially determine faulty remote or local devices in the presence of multiple faults. Two methods of implementation are described. In one method, a recovered clock can be directly used to monitor the local clock as a direct replacement of an external local oscillator. This scheme is consistent with a general clock monitoring function whereby clock sources are clocking two counters and compared over a fixed interval of time. In another method, overflow/underflow conditions can be used to detect clock relationships for monitoring. These network interfaces often provide clock compensation circuitry to allow data to be transferred from the received (network) clock domain to the internal clock domain. This circuit could be modified to detect overflow/underflow conditions of the buffering required and report a fast or slow receive clock, respectively.

Pollock, Julie↗

Plasticity Tool for Predicting Shear Nonlinearity of Unidirectional Laminates Under Multiaxial Loading

This study implements a plasticity tool to predict the nonlinear shear behavior of unidirectional composite laminates under multiaxial loadings, with an intent to further develop the tool for use in composite progressive damage analysis. The steps for developing the plasticity tool include establishing a general quadratic yield function, deriving the incremental elasto-plastic stress-strain relations using the yield function with associated flow rule, and integrating the elasto-plastic stress-strain relations with a modified Euler method and a substepping scheme. Micromechanics analyses are performed to obtain normal and shear stress-strain curves that are used in determining the plasticity parameters of the yield function. By analyzing a micromechanics model, a virtual testing approach is used to replace costly experimental tests for obtaining stress-strain responses of composites under various loadings. The predicted elastic moduli and Poisson's ratios are in good agreement with experimental data. The substepping scheme for integrating the elasto-plastic stress-strain relations is suitable for working with displacement-based finite element codes. An illustration problem is solved to show that the plasticity tool can predict the nonlinear shear behavior for a unidirectional laminate subjected to multiaxial loadings.

Wang, John T.↗

Harvesting NASA's Common Metadata Repository (CMR)

As part of NASA's Earth Observing System Data and Information System (EOSDIS), the Common Metadata Repository (CMR) stores metadata for over 30,000 datasets from both NASA and international providers along with over 300M granules. This metadata enables sub-second discovery and facilitates data access. While the CMR offers a robust temporal, spatial and keyword search functionality to the general public and international community, it is sometimes more desirable for international partners to harvest the CMR metadata and merge the CMR metadata into a partner's existing metadata repository. This poster will focus on best practices to follow when harvesting CMR metadata to ensure that any changes made to the CMR can also be updated in a partner's own repository. Additionally, since each partner has distinct metadata formats they are able to consume, the best practices will also include guidance on retrieving the metadata in the desired metadata format using CMR's Unified Metadata Model translation software.

Earth Resources↗

The Semiannual and 4.4-Year Modulations of Extreme High Tides

In most places extreme high tides undergo a clear seasonal variation. It is well known that semidiurnal tides tend to peak during equinox seasons, and diurnals during solstice seasons. This is a consequence of the solar and lunar declinations, which when large maximize diurnal tides at the expense of semidiurnals. The semiannual range modulation of tidal extremes for a pure semidiurnal tide is determined mainly by the amplitude of the K2 constituent; a pure diurnal is determined mainly by P1. Mixed tidal regimes tend to experience maxima very roughly around the times of solstice, but not always, with the semiannual modulation generally a complicated function of constituent amplitudes and phases. These modulations are here mapped worldwide by analyzing tidal extremes predicted with a global tide model. The known 4.4-year modulation in extreme tides is a consequence of declinational and perigean effects coming in and out of phase. The phase of the 4.4-year modulation is controlled by the phase of the semiannual modulation, irrespective of whether the tide is diurnal, semidiurnal, or mixed.

Ray, R. D.↗

Radiation Dose Assessments of Solar Particle Events with Spectral Representation at High Energies for the Improvement of Radiation Protection

For radiation dose assessments of major solar particle events (SPEs), spectral functional forms of SPEs have been made by fitting available satellite measurements up to approx.100 MeV. However, very high-energy protons (above ~500 MeV) have been observed with neutron monitors (NMs) in ground level enhancements (GLEs), which generally present the most severe radiation hazards to astronauts. Due to technical difficulties in converting NM data into absolutely normalized fluence measurements, those functional forms were made with little or no use of NM data. A new analysis of NM data has found that a double power law in rigidity (the so-called Band function) generally provides a satisfactory representation of the combined satellite and NM data from approx.10 MeV to approx.10 GeV in major SPEs (Tylka & Dietrich 2009). We use the Band function fits to re-assess human exposures from large SPEs. Using different spectral representations of large SPEs, variations of exposure levels were compared. The results can be applied to the development of approaches of improved radiation protection for astronauts, as well as the optimization of mission planning and shielding for future space missions.

Kim, Myung-Hee↗

High frequency green function for aerodynamic noise in moving media. I - General theory. II - Noise from a spreading jet

It is shown how a high frequency analysis can be made for general problems involving flow-generated noise. In the parallel shear flow problem treated by Balsa (1976) and Goldstein (1982), the equation governing sound propagation in the moving medium could be transformed into a wave equation for a stationary medium with an inhomogeneous index of refraction. It is noted that the procedure of Avila and Keller (1963) was then used to construct a high frequency Green function. This procedure involves matching a solution valid in an inner region around the point source to an outer, ray-acoustics solution. This same procedure is used here to construct the Green function for a source in an arbitrary mean flow. In view of the fact that there is no restriction to parallel flow, the governing equations cannot be transformed into a wave equation; the analysis therefore proceeds from the equations of motion themselves.

Durbin, P. A.↗

Design concept (milestone 2) for space vehicle entry and landing navigation programs

Detailed specifications and functional flow diagrams for space vehicle entry and landing navigation programs are reported. General design criteria, overall functions, and interfaces between the following three programs are considered: external observations program, noisy observations program, and navigation analysis program.

Diamant, L. S.↗

The Total Gaussian Class of Quasiprobabilities and its Relation to Squeezed-State Excitations

The class of quasiprobabilities obtainable from the Wigner quasiprobability by convolutions with the general class of Gaussian functions is investigated. It can be described by a three-dimensional, in general, complex vector parameter with the property of additivity when composing convolutions. The diagonal representation of this class of quasiprobabilities is connected with a generalization of the displaced Fock states in direction of squeezing. The subclass with real vector parameter is considered more in detail. It is related to the most important kinds of boson operator ordering. The properties of a specific set of discrete excitations of squeezed coherent states are given.

Wuensche, Alfred↗

The Reconstruction Problem Revisited

The role of reconstruction in avoiding oscillations in upwind schemes is reexamined, with the aim of providing simple, concise proofs. In one dimension, it is shown that if the reconstruction is any arbitrary function bounded by neighboring cell averages and increasing within a cell for increasing data, the resulting scheme is monotonicity preserving, even though the reconstructed function may have overshoots and undershoots at the cell edges and is in general not a monotone function. In the special case of linear reconstruction, it is shown that merely bounding the reconstruction between neighboring cell averages is sufficient to obtain a monotonicity preservinc,y scheme. In two dimensions, it is shown that some ID TVD limiters applied in each direction result in schemes that are not positivity preserving, i.e. do not give positive updates when the data are positive. A simple proof is given to show that if the reconstruction inside the cell is bounded by the neighboring cell averages (including corner neighbors), then the scheme is positivity preserving. A new limiter that enforces this condition but is not as dissipative as the Minmod limiter is also presented.

Suresh, Ambaby↗

Proposed Functional Description for Phased Arrays

Generally speaking, many photonic engineers, while working in a systems development mode, still focus on presenting the unique physical details of the optical elements, instead of using functional representation to describe the system. The purpose of this presentation is to introduce symbols that can be used to represent the functional intent of most of the phased array architecture.

Phased Arrays systems development mode optical ele↗