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At least 397 records · Page 22

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DOE OSTI2023

Constructing the Mechanism of Dinoflagellate Luciferin Bioluminescence Using Computation

Dinoflagellate luciferin bioluminescence is unique since it does not rely on decarboxylation but is poorly understood compared to that of firefly, bacteria, and coelenterata luciferins. Here, in this work, we computationally investigate possible protonation states, stereoisomers, a chemical mechanism, and the dynamics of the bioluminescence intermediate that is responsible for chemiexcitation. Using semiempirical dynamics, time-dependent density functional theory static calculations, and a correlation diagram, we find that the intermediate’s functional group that is likely responsible for chemiexcitation is a 4-member ring, a dioxetanol, that undergoes [2π + 2π] cycloreversion and the biolumiphore is the cleaved structure. The simulated emission spectra and luciferase-dependent absorbance spectra agree with the experimental data, giving support to our proposed mechanism and biolumiphore. We also compute circular dichroism spectra of the intermediate’s four stereoisomers to guide future experiments in differentiating them.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1973

Calculation of separated flows at subsonic and transonic speeds

A boundary-layer integral approach is combined with a finite-difference relaxation method to calculate viscous interactions between separated flows at subsonic and transonic velocities. Results are obtained for separated laminar flows on circular-arc airfoils at zero angle of attack and are compared with data of Collins (1972). Inviscid and viscous flows are covered.

Klineberg, J. M.↗

NASA NTRS1974

A method for studying near- and far-field noise characteristics of impinging jets

A new method based on cross-correlation techniques is presented for studying the near- and far-field noise characteristics of a jet impinging on a surface. Analyses show that, in near and far fields, the noise characteristics due to the contribution of fluctuating pressure on the surface and due to the combined contribution of turbulence in the impinging jet and fluctuating pressure on the surface can be determined. Both far-field noise intensities and near-field acoustic energy fluxes can be expressed in terms of appropriate cross correlations. These correlations are obtained by making microphone measurements in three different regions: on the surface, in the near field, and in the far field. The method is currently being applied to study a cold, circular, subsonic jet impinging on a large rigid surface. Some preliminary experimental data are presented on fluctuating surface pressures and narrow-band far-field noise characteristics.

Pan, Y. S.↗

NASA NTRS1973

Acoustic results from tests of a 36-inch (0.914 m) diameter statorless lift fan

A statorless, turbotip lift fan was tested statically outdoors to determine its acoustic characteristics. Spectral and directivity results are presented with comparison to data from the same family of lift fan designs having stator vanes. Modifications to the fan were tested to evaluate circular inlet guide vanes and exhaust treatment. A comparison was made of results obtained at General Electric Edwards Flight Test Center and NASA Ames Research Center with regards to test data and differences in site characteristics.

Stimpert, D. L.↗

NASA NTRS1976

Vortex noise from nonrotating cylinders and airfoils

An experimental study of vortex-shedding noise was conducted in an acoustic research tunnel over a Reynolds-number range applicable to full-scale helicopter tail-rotor blades. Two-dimensional tapered-chord nonrotating models were tested to simulate the effect of spanwise frequency variation on the vortex-shedding mechanism. Both a tapered circular cylinder and tapered airfoils were investigated. The results were compared with data for constant-diameter cylinder and constant-chord airfoil models also tested during this study. Far-field noise, surface pressure fluctuations, and spanwise correlation lengths were measured for each configuration. Vortex-shedding noise for tapered cylinders and airfoils was found to contain many narrowband-random peaks which occurred within a range of frequencies corresponding to a predictable Strouhal number referenced to the maximum and minimum chord. The noise was observed to depend on surface roughness and Reynolds number.

Schlinker, R. H.↗

NASA NTRS1984

Morphology of buried craters: Lava thickness estimates by simulated flooding

Partially and completely buried craters on planetary surfaces are used as probes to determine the thickness and extent of the overlying material as well as the composition of underlying terrain units. Rims of craters protruding through mare basalts on the Moon have been used extensively by DeHon (1977, 1979) to develop isopach maps of both the circular and irregular maria. Such estimates are possible because of Apollo topographic data and the extensive coverage by Lunar Orbiter photographs at various sun angles. On planetary surfaces without such data, however, shadow measurements can only be made by pixel listings with appropriate assumptions concerning support data. In addition, high resolution geochemical data is not available to determine whether the exposed crater rim is composed of material dissimilar from the lavas. Because of the need for lava thickness data, flooding of lunar mare and highland craters was simulated in order to determine empirical relationships between dimensions observed in orbital images and the thickness of the lava.

Maxwell, T. A.↗

NASA NTRS1977

Portable reflectance spectrometer

A portable reflectance spectrometer is disclosed. The spectrometer essentially includes an optical unit and an electronic recording unit. The optical unit includes a pair of thermoelectrically-cooled detectors, for detecting total radiance and selected radiance projected through a circular variable filter wheel, and is capable of operating to provide spectral data in the range 0.4 to 2.5 micrometers without requiring coventional substitution of filter elements. The electronic recording unit includes power supplies, amplifiers, and digital recording electronics designed to permit recordation of data on tape casettes. Both the optical unit and electronic recording unit are packaged to be manually portable.

Goetz, A. F. H.↗

NASA NTRS1989

Magnetic fields near Mars - First results

The magnetic fields of Mars have been measured from Phobos 2 with high temporal resolution in the tail and down to an 850-km altitude. During four successive highly elliptical orbits, the position of the bow shock as well as that of a transition layer, the 'planetopause', were identified. Subsequent circular orbits at 6000-km altitude provided the first high-resolution data in the planetary tail and indicate that the interplanetary magnetic field mainly controls the magnetic tail. Magnetic turbulence was also detected when the spacecraft crossed the orbit of Phobos, indicating the possible existence of a torus near the orbit of this moon.

Riedler, W.↗

NASA NTRS1993

An Analytical Study of Dilution Jet Mixing in a Cylindrical Duct

The mixing performance in a mixing section of a rich burn/quick mix/lean burn (RQL) combustor was calculated using a 3-D numerical model in a non-reacting environment. The numerically calculated results were compared with the measured data reported by Hatch, Sowa, Samuelsen, and Holdeman, 1992. The numerical 3-D temperature fields qualitatively agree with the experimental data. Also, the development of the mixing flow and temperature non-uniformity trends throughout the mixing section for the numerically calculated results quantitatively agree with the measured data. The numerical model predicts less mixing and enhances the temperature gradients as compared to the measured data for the cases reported by Hatch et al. (1992) which include circular and slot orifice shapes (with different slant angles and aspect ratios). The predicted and measured results generally agree in the selection of the slanted slot orifice configuration yielding the best overall mixing performance (based on temperature uniformity) of all the configurations analyzed.

Oechsle, V. L.↗

NASA NTRS1993

An analytical study of dilution jet mixing in a cylindrical duct

Oechsle, V. L.↗

NASA NTRS1993

Spontaneous assembly of a self-complementary oligopeptide to form a stable macroscopic membrane

A 16-residue peptide [(Ala-Glu-Ala-Glu-Ala-Lys-Ala-Lys)2] has a characteristic beta-sheet circular dichroism spectrum in water. Upon the addition of salt, the peptide spontaneously assembles to form a macroscopic membrane. The membrane does not dissolve in heat or in acidic or alkaline solutions, nor does it dissolve upon addition of guanidine hydrochloride, SDS/urea, or a variety of proteolytic enzymes. Scanning EM reveals a network of interwoven filaments approximately 10-20 nm in diameter. An important component of the stability is probably due to formation of complementary ionic bonds between glutamic and lysine side chains. This phenomenon may be a model for studying the insoluble peptides found in certain neurological disorders. It may also have implications for biomaterials and origin-of-life research.

Non-NASA Center↗

NASA NTRS2014

Flow Phenomena in the Very Near Wake of a Flat Plate with a Circular Trailing Edge

The very near wake of a flat plate with a circular trailing edge, exhibiting pronounced shedding of wake vortices, is investigated with data from a direct numerical simulation. The separating boundary layers are turbulent and statistically identical thus resulting in a wake that is symmetric in the mean. The focus here is on the instability of the detached shear layers, the evolution of rib-vortex induced localized regions of reverse flow that detach from the main body of reverse flow in the trailing edge region and convect downstream, and phaseaveraged velocity statistics in the very near wake. The detached shear layers are found to exhibit unstable behavior intermittently, including the development of shear layer vortices as in earlier cylinder flow investigations with laminar separating boundary layers. Only a small fraction of the separated turbulent boundary layers undergo this instability, and form the initial shed vortices. Pressure spectra within the shear layers show a broadband peak at a multiple of shedding frequency. Phase-averaged intensity and shear stress distributions of the randomly fluctuating component of velocity are compared with those obtained in the near wake. The distributions of the production terms in the transport equations for the turbulent stresses are also provided.

Turbulence↗

DOE OSTI2022

Prediction of heat transfer coefficient from pressure drop using machine learning techniques in smooth horizontal pipes

Limited experimental work has been done focusing specifically on the relationship between pressure drop and heat transfer in the transient flow regime in pipes. The aim of this study was therefore to use machine learning to find a relationship between pressure drop and heat transfer coefficients of developing and fully developed flow in smooth horizontal circular tubes in the laminar, transient, quasi-turbulent and turbulent. The data are collected from literature, coming from experimentation. Pressure drops and heat transfer measurements were taken simultaneously and the relationship between pressure drop, and heat transfer was determined using multiple machine learning techniques.

20 FOSSIL-FUELED POWER PLANTS↗

NASA NTRS1992

Infrared imaging of Mars for volatile distribution and seasonal variability between 2.4 and 5.1 microns

Recent advances in ground-based infrared imaging now allow for sub-arc second spectral imaging. Data collected at the NASA Infrared Telescope Facility using protocam, a 62 x 58 InSb array camera with a circular variable filter and a plate scale 0.2 arc-seconds/pixel, are discussed. These images are a first attempt at extended seasonal infrared coverage of Mars to look for seasonal variations. Currently, data collected in Jun. 1990 at Ls = 241 (southern spring) and in Jan. 1991 Ls = 360 (late southern summer) are being reduced and analyzed. The 3 micron bound water band is the strongest surface absorption feature on Mars in the infrared. Infrared spectroscopy can also be useful in the detection of ice and frost deposits, especially in the polar regions. While imaging and spectroscopy at visible wavelengths allows for the detection of condensates, infrared information is needed to distinguish between water and CO2 ice/frost deposits. In the Jun. images, the southern polar cap totally disappears in the 3.4 micron CO2 frost band and is bright in the 3.1 micron water ice band, indicating that water ice is not a detectable component of the southern polar cap at this season. Further investigations are currently under way to look for residual water ice after the disappearance of the seasonal south polar cap in the Jan. images. The Jun. images that were focused on had a sub-earth point located at 184 longitude, and 23.8 S latitude which put the center of the disk in the southern highland region between Elysium and Amazonis. Examination of the Jun. images show that there are four surface units identifiable: a CO2 frost deposit, a northern plains unit, an equatorial unit, and a southern highland unit. At this resolution there does not appear to be any latitudinal variations in the 3 micron band that is independent of the 2.4 micron albedo features. The northern planes unit and the southern highland unit have very similar 'color' in the three micron band as demonstrated by the rise out of the band, but different brightness levels. The equatorial unit has a distinct three micron color implying a compositional difference. The albedo features at 2.4 microns have decreased contrast at longer wavelengths, till they are unrecognizable at 4 microns.

Blaney, Diana L.↗

NASA NTRS1986

The measurement of boundary layers on a compressor blade in cascade at high positive incidence angle. 2: Data report

Boundary layer and near-wake velocity measurements have been made in the well documented flow field about a double circular arc compressor blade in cascade, at an incidence angle of 5 deg. and a chord Reynolds number of 500,000. In Part 2 of this report these measurements were analyzed and presented in standard graphical format. The flow geometry, measurement techniques, and physics of the flow field were also discussed. In this, part 2 of the report, raw and analyzed data are presented in tabulated form in an attempt to make this data more accessible to computational comparison. Also included in part 2 is a description of the data analysis employed. A computer tape containing the data is available.

Deutsch, S.↗

NASA NTRS1973

An observation of polar auroral and airglow from the ISIS-II spacecraft.

This is a preliminary but comprehensive report on coordinated data obtained with the ISIS-II spacecraft, fourth in the ISIS series, launched 1 April 1971, into a near circular 1400 km orbit. The capabilities of the ISIS-I spacecraft have been extended in a number of ways, including the global mapping of the 3914, 5577 and 6300 A emissions. Data obtained during a 30-min pass over the south pole depict the nightside oval and polar cap, as well as mid-latitude airglow effects; these data are described and discussed.

Shepherd, G. G.↗

NASA NTRS1989

Thin-plate spline quadrature of geodetic integrals

Thin-plate spline functions (known for their flexibility and fidelity in representing experimental data) are especially well-suited for the numerical integration of geodetic integrals in the area where the integration is most sensitive to the data, i.e., in the immediate vicinity of the evaluation point. Spline quadrature rules are derived for the contribution of a circular innermost zone to Stoke's formula, to the formulae of Vening Meinesz, and to the recursively evaluated operator L(n) in the analytical continuation solution of Molodensky's problem. These rules are exact for interpolating thin-plate splines. In cases where the integration data are distributed irregularly, a system of linear equations needs to be solved for the quadrature coefficients. Formulae are given for the terms appearing in these equations. In case the data are regularly distributed, the coefficients may be determined once-and-for-all. Examples are given of some fixed-point rules. With such rules successive evaluation, within a circular disk, of the terms in Molodensky's series becomes relatively easy. The spline quadrature technique presented complements other techniques such as ring integration for intermediate integration zones.

Vangysen, Herman↗

NASA NTRS1991

A Rayleigh-Ritz analysis methodology for cutouts in composite structures

A new Rayleigh-Ritz stress analysis methodology that was developed for composite panels containing cutouts is described. The procedure, which makes use of a general assumed displacement field, accommodates circular and elliptical cutouts in biaxially loaded rectangular composite panels. Symmetric integral padups around the cutout can be included in the analysis. Benchmark results are presented to demonstrate the accuracy of the technique. Strength predictions based on the average stress criterion are generated and compared with experimental data. Finally, the stress analysis methodology is integrated into a design procedure for sizing integral padups around circular cutouts, and a sample problem is solved to illustrate its use.

Russell, Steven G.↗