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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Nonlocal Finite-Depth Circuits for Constructing Symmetry-Protected Topological States and Quantum Cellular Automata

Whether a given target state can be prepared by starting with a simple product state and acting with a finite-depth quantum circuit is a key question in condensed matter physics and quantum information science. It underpins classifications of topological phases, as well as the understanding of topological quantum codes, and has obvious relevance for device implementations. Traditionally, this question assumes that the quantum circuit is made up of unitary gates that are . Inspired by the advent of noisy intermediate-scale quantum devices, we reconsider this question with k - gates, i.e., gates that act on no more than k degrees of freedom but are not restricted to be geometrically local. First, we construct explicit finite-depth circuits of symmetric k -local gates that create symmetry-protected topological (SPT) states from an initial product state. Our construction applies to SPT states protected by global symmetries or subsystem symmetries but not to those with higher-form symmetries, which we conjecture remain nontrivial. Next, we show how to implement arbitrary translationally invariant quantum cellular automata in any dimension using finite-depth circuits of k -local gates. These results imply that the topological classifications of SPT phases and quantum cellular automata both collapse to a single trivial phase in the presence of k -local interactions. We furthermore argue that SPT phases are fragile to k -local symmetric perturbations. We conclude by discussing the implications for other phases, such as fracton phases, and surveying future directions. Our analysis opens a new experimentally motivated conceptual direction examining the stability of phases and the feasibility of state preparation without the assumption of geometric locality. Published by the American Physical Society 2024

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

All-Sputtered, Superior Power Density Thin-Film Solid Oxide Fuel Cells with a Novel Nanofibrous Ceramic Cathode

Thin film solid oxide fuel cells (TF-SOFCs) are attracting attention due to their ability to operate at comparatively lower temperatures (400–650 °C) that are unattainable for conventional anode-supported SOFCs (650–800 °C). However, limited cathode performance and cell scalability remain persistent issues. Here, we report a new approach of fabricating yttria-stabilized zirconia (YSZ)-based TF-SOFCs via a scalable magnetron sputtering process. Notable is the development and deposition of a porous La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 2.95 (LSCF)-based cathode with a unique fibrous nanostructure. This all-sputtered cell shows an open-circuit voltage of ~1.0 V and peak power densities of ~1.7 and ~2.5 W/cm 2 at 600 and 650 °C, respectively, under hydrogen fuel and air along with showing stable performance in short-term testing. The power densities obtained in this work are the highest among YSZ-based SOFCs at these low temperatures, which demonstrate the feasibility of fabricating exceptionally high-performance TF-SOFC cells with distinctive dense or porous nanostructures for each layer, as desired, by a sputtering process. This work illustrates a new, potentially low-cost, and scalable platform for the fabrication of next-generation TF-SOFCs with excellent power output and stability.

25 ENERGY STORAGE↗
DOE OSTI2022

A Lyapunov-Based Generalized Dc-Side Controller Design for PV-Connected Systems

The objective of this paper is to realize a universal dc-side controller for photovoltaic (PV) systems where the control is agnostic to the downstream converter configuration. To achieve this, the downstream power converter and its controls are manipulated into an effective power control loop that is then cast into a generalized multi-loop design framework. On the dc side, a nonlinear small-signal model of the PV input is realized exclusively in terms of PV datasheet parameters (i.e., open-circuit voltage, short-circuit current, and maximum power point). Finally, a linear controller is used to modulate the dc-side PV system with the generic downstream power controller. A Lyapunov candidate is proposed to analyze the stability of the interconnected system and provide a streamlined approach for the controller design. The proposed design is validated on a 1k VA experimental setup that interfaces a PV module to the grid.

generalized PV controller↗
NASA NTRS1995

Operational characteristics of a 200 C LC parallel resonant circuit

Research efforts are currently underway at the NASA Lewis Research Center to design and demonstrate an inverter capable of operating with a baseplate temperature of 200 C. In support of this project, various electrical components including capacitors, inductors, transformers, cables, and semiconductor switches are being developed or evaluated for integration into the inverter. In this work, a parallel LC resonant circuit was constructed and evaluated under simultaneous electrical and thermal stressing. The tests were performed in the temperature range of 25 to 200 C with an applied voltage of up to 90 V, 20 kHz. The individual components were comprised of high temperature film capacitors and powder core inductors developed in-house. The circuit was characterized in terms of the component currents and case temperatures as well as frequency of resonance as a function of applied bias and temperature. The results obtained, which have indicated good functional stability up to 200 C, are presented and discussed.

Baumann, Eric D.↗
DOE OSTI2022

A Lyapunov-Based Generalized Dc-Side Controller Design for PV-Connected Systems: Preprint

The objective of this paper is to realize a universal dc-side controller for photovoltaic (PV) systems where the control is agnostic to the downstream converter configuration. To achieve this, the downstream power converter and its controls are manipulated into an effective power control loop that is then cast into a generalized multi-loop design framework. On the dc side, a nonlinear small-signal model of the PV input is realized exclusively in terms of PV datasheet parameters (i.e., open-circuit voltage, short-circuit current, and maximum power point). Finally, a linear controller is used to modulate the dc-side PV system with the generic downstream power controller. A Lyapunov candidate is proposed to analyze the stability of the interconnected system and provide a streamlined approach for the controller design. The proposed design is validated on a 1-kVA experimental setup that interfaces a PV module to the grid.

dc-dc control↗
DOE OSTI2022

Scalable, Ultrathin, and High-Temperature-Resistant Solid Polymer Electrolytes for Energy-Dense Lithium Metal Batteries

We report all-solid-state batteries (ASSBs) demonstrate great promise, offering high energy density, good thermal stability, and safe operation compared with traditional Li-ion batteries. Among various solid-state electrolytes (SSEs), solid polymer electrolytes (SPEs) offer an attractive choice due to their thinness, low density, and good manufacturability. However, ultrathin SPEs that work with practical current densities or at high temperatures remain challenging, limiting applicable conditions of SPE-based batteries. Here, the authors report a novel scalable, ultrathin, and high-temperature-resistant SPE for ASSBs. This design includes an electrospun polyacrylonitrile (PAN) matrix and polyethylene oxide (PEO)/Li salt ionic conductor, which offers a stable LiF and Li 3 N containing SSE/Li interface. The unique interface—as well as the good mechanical strength—inhibits lithium dendrites and prevents short circuiting. As a result, symmetrical Li-Li cells deliver more than 300 h cyclability at 0.5 mA cm -2 . ASSBs fabricated with only 5 µm-thickness PAN-PEO/lithium bis(trifluoromethanesulfonyl)imide reach 300 cycles at 0.3 C rate at 60 °C. The excellent thermal stability of PAN also results in safer SPEs at high temperatures. The design extends battery operation up to temperatures of 120 and 150 °C, where it achieves 500 cycles at C/2 rate and 100 cycles at 2C rate, respectively.

25 ENERGY STORAGE↗
DOE OSTI2026

Enhanced cycling stability of Ni-rich Li-metal cells enabled by dual vinylene carbonate and tris(trimethylsilyl)borate electrolyte additives

NMC811 (LiNi 0.8 Co 0.1 Mn 0.1 O 2 ) and other high-Ni chemistries are promising cathode candidates for high-performance electric vehicles, owing to their high energy density and reduced cobalt content. However, their long-term cycling stability is hindered by surface degradation, particularly when paired with conventional electrolytes and a lithium metal anode. Electrolyte additives represent a practical approach to enhance interfacial stability and improve overall battery performance by promoting the formation of a robust electrolyte–electrode interphase (EEI). In this study, we revisit the effects of vinylene carbonate (VC) and tris(trimethylsilyl)borate (TMSB) additives on single-crystal SC-NMC811||Li cells. While TMSB only increases the open-circuit voltage and initial overpotential, it delivers superior capacity retention at C/3 compared to cells containing only VC or a dual additive system (VC and TMSB). Notably, under fast-charging conditions (1C, 2C, and 5C), the dual-additive system significantly outperforms other formulations, achieving markedly enhanced long-term capacity retention. Comprehensive electrochemical and spectroscopic analyses reveal that the VC/TMSB dual-additive system suppresses surface transition in NMC811, mitigates structural degradation by forming a thin, LiF-deficient cathode-electrolyte interface (CEI) layer. Moreover, they promote smooth and dense Li deposition and generate a LiF-deficient solid-electrolyte interphase (SEI). Consequently, the synergistic stabilization of both the CEI and SEI effectively limits the overall cell impedance growth during extended cycling. These findings provide key insights into co-additive strategies for engineering stable interfaces in high-energy Ni-rich Li-metal batteries.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Enhanced Synchronization Stability of Grid-Forming Inverters With Passivity-Based Virtual Oscillator Control

In this article, a passivity-based virtual oscillator control strategy with enhanced synchronization stability for grid-forming inverters (GFMs) is proposed. By adopting the port-controlled Hamiltonian system theory for orbital stabilization problems, an energy pumping-and-damping block is proposed to render GFMs globally asymptotically stable with respect to the prespecified solutions of the power-flow equations from any initial condition. This allows for stable integrations of GFMs to any other globally asymptotically stable systems without their explicit knowledge, e.g., helping maintain synchronism with the bulk power system in a wide range of short-circuit-ratio conditions or under large disturbances and keeping synchronism among multiple GFMs in power systems. Herein, both simulations and experiments are presented to demonstrate the proposed control approach.

42 ENGINEERING↗
NASA NTRS2013

The Correlation Radiometer - A New Application in MM-Wave Total Power Radiometry

We describe the design and performance of a 180 GHz correlation radiometer suitable for remote sensing. The radiometer provides continuous comparisons between a the observed signal and a reference load to provide stable radiometric baselines. The radiometer was assembled and tested using parts from the GeoSTAR-II instrument and is fully compatible with operation in a synthetic aperture radiometer or as a standalone technology for use in microwave sounding and imaging. This new radiometer was tested over several days easily demonstrating the required 6 hour stability requirement for observations of mean brightness temperature for a geostationary instrument.

Monolithic Microwave Integrated Circuit (MMIC)↗
DOE OSTI2026

Arctic Deployment of a Fully Integrated Self-Powered Drifting Buoy Harvesting Wave Energy via a Triboelectric Nanogenerator

The Arctic Ocean remains one of the most poorly sampled regions on Earth, where improved in situ environmental monitoring is vital for advancing oceanographic and atmospheric studies. However, data collection efforts are constrained by the short operational lifespans and high costs of conventional systems. Drifting buoys powered by pendulum-driven wave energy harvesters offer a cost-effective alternative, yet earlier designs have neither been optimized for real-world wave conditions nor validated in the Arctic. In this study, we develop a self-powered drifting buoy that integrates a pendulum-driven triboelectric nanogenerator (TENG) system with a mechanical motion rectifier, a high-gear-ratio transmission, and power management circuits. Through coupled buoy–pendulum dynamic simulations and laboratory testing using a motion simulator, we identify an optimal pendulum mass of 1.6 kg (12.7% of total buoy weight) that maximizes energy output while maintaining buoy stability. Laboratory experiments achieved average power outputs of 12.7 mW under Arctic-like wave and temperature conditions. The system was successfully deployed in the Bering Sea, where it generated 11 J of energy in 3.1 m waves, marking the first Arctic deployment of a TENG-based drifting buoy for sea surface temperature monitoring. This work establishes a cost-effective framework for designing self-powered Arctic monitoring platforms and advances the feasibility of long-term environmental observations in real Arctic waters.

marine enerby↗
DOE OSTI2025

Design of MARCO, the New Solenoidal Detector Magnet for the ePIC Experiment at BNL

MARCO is the new superconducting solenoid for ePIC, the general-purpose detector capable of delivering the full scientific scope of the Electron-Ion Collider at Brookhaven National Laboratory. Here, this 3.84 m long solenoid, with a bore diameter of 2.84 m, will provide a magnetic field of 2.0 T at the center with a nominal current of 4 kA at 4.5 K, for a total stored energy of 45 MJ. Its conductor is a NbTi Rutherford in Copper Channel (RICC), specially designed to stand the high mechanical loads induced by the magnetic field. Its copper stabilizer will assure the protection in case of quench. The coils are wound into six layers inside a thin external mandrel in brass, with a triple role of mechanical reinforcement, cryogenic support for the thermosiphon circuit and quench-back propagator. With a cold mass average radial thickness of just 7 cm, the magnet fulfills all the criterions of transparency for the particles directed to the hadronic calorimeter forecast around the cryostat. In this paper, the design of MARCO is presented, with a specific focus on the magnetic and quench analysis.

Calvelli, Valerio [Commissariat a l'Energie Atomiq↗
NASA NTRS1983

S-band SBAW microwave source, phase 2

Results of aging experiments on 1.072 GHz SBAW oscillators are discussed as well as the design, fabrication and test of 2.143 GHz SBAW delay lines. Two design approaches were implemented. The third harmonic transducer on 36 deg rotated Y cut quartz proved to be the most useful design, whereas the fifth harmonic transducer on - 50 5 deg rotated Y cut quartz suffered from high insertion loss and poor sidelobe rejection. The construction and characterization of the 2 GHz SBAW oscillator are described. Phase noise, frequency dependence on temperature, and 6-month aging were measured. Some SAW and SBAW oscillators were compared as were both the 1 and 2 GHz oscillators. The 2 GHz SBAW oscillator showed significant improvement in phase noise and temperature stability over the 2 GHz SAW oscillator developed in previous NASA programs. A technique to produce SBAW delay lines of different frequencies from a single mask is examined. The delay lines were incorporated into oscillator circuits to demonstrate the ability to select the frequency output of the SBAW oscillator.

Source record↗
NASA NTRS2010

26th Space Simulation Conference Proceedings. Environmental Testing: The Path Forward

Topics covered include: A Multifunctional Space Environment Simulation Facility for Accelerated Spacecraft Materials Testing; Exposure of Spacecraft Surface Coatings in a Simulated GEO Radiation Environment; Gravity-Offloading System for Large-Displacement Ground Testing of Spacecraft Mechanisms; Microscopic Shutters Controlled by cRIO in Sounding Rocket; Application of a Physics-Based Stabilization Criterion to Flight System Thermal Testing; Upgrade of a Thermal Vacuum Chamber for 20 Kelvin Operations; A New Approach to Improve the Uniformity of Solar Simulator; A Perfect Space Simulation Storm; A Planetary Environmental Simulator/Test Facility; Collimation Mirror Segment Refurbishment inside ESA s Large Space; Space Simulation of the CBERS 3 and 4 Satellite Thermal Model in the New Brazilian 6x8m Thermal Vacuum Chamber; The Certification of Environmental Chambers for Testing Flight Hardware; Space Systems Environmental Test Facility Database (SSETFD), Website Development Status; Wallops Flight Facility: Current and Future Test Capabilities for Suborbital and Orbital Projects; Force Limited Vibration Testing of JWST NIRSpec Instrument Using Strain Gages; Investigation of Acoustic Field Uniformity in Direct Field Acoustic Testing; Recent Developments in Direct Field Acoustic Testing; Assembly, Integration and Test Centre in Malaysia: Integration between Building Construction Works and Equipment Installation; Complex Ground Support Equipment for Satellite Thermal Vacuum Test; Effect of Charging Electron Exposure on 1064nm Transmission through Bare Sapphire Optics and SiO2 over HfO2 AR-Coated Sapphire Optics; Environmental Testing Activities and Capabilities for Turkish Space Industry; Integrated Circuit Reliability Simulation in Space Environments; Micrometeoroid Impacts and Optical Scatter in Space Environment; Overcoming Unintended Consequences of Ambient Pressure Thermal Cycling Environmental Tests; Performance and Functionality Improvements to Next Generation Thermal Vacuum Control System; Robotic Lunar Lander Development Project: Three-Dimensional Dynamic Stability Testing and Analysis; Thermal Physical Properties of Thermal Coatings for Spacecraft in Wide Range of Environmental Conditions: Experimental and Theoretical Study; Molecular Contamination Generated in Thermal Vacuum Chambers; Preventing Cross Contamination of Hardware in Thermal Vacuum Chambers; Towards Validation of Particulate Transport Code; Updated Trends in Materials' Outgassing Technology; Electrical Power and Data Acquisition Setup for the CBER 3 and 4 Satellite TBT; Method of Obtaining High Resolution Intrinsic Wire Boom Damping Parameters for Multi-Body Dynamics Simulations; and Thermal Vacuum Testing with Scalable Software Developed In-House.

Packard, Edward A.↗
DOE OSTI2023

Understanding the Degradation of La 1−x Sr x FeO 3−δ (0 ≤ x ≤ 1) Perovskite Oxides during the Oxygen Evolution Reaction in Alkaline Solution

Perovskite oxides are an emerging class of highly active catalysts for the oxygen evolution reaction (OER); however, their electrochemical stability remains poorly understood. Here, we report a systematic evaluation of the OER activity and stability of La 1−x Sr x FeO 3-δ perovskites in 1 M KOH. Their initial OER activity first increases with increasing Sr content (fromx= 0 to 0.8), and then decreases when the Sr content is increased to 1. Their stability evaluated by monitoring the element leaching from the electrodes show that La does not leach at a detectable rate, but Sr and Fe leach substantially. The leaching of Sr occurs at similar rates under open circuit potential (OCP) and OER potential, suggesting a nonelectrochemical dissolution process. The leaching of Fe is, however, strongly dependent on the electrode potential. More Fe leaching is observed under the OER potential than OCP. Additionally, the electrode with higher initial OER activity leaches more Fe. These results indicate that OER facilitates the dissolution of Fe from the electrode. The leaching of Fe, in turn, is considered responsible for the activity loss of La 1-x Sr x FeO 3−δ during OER. This study brings new insight into the degradation mechanism of La 1-x Sr x FeO 3−δ and their related perovskite oxides during electro-oxidation processes.

Electrochemistry↗
DOE OSTI2026

Booster cavity damper redesign for PIP-II

A new Higher Order Mode (HOM) damper was designed and is undergoing testing for the Booster accelerator cavity at Fermilab. In anticipation of the PIP-II upgrade, it was discovered that the higher intensity of PIP-II may cause beam instability due to an excited mode at 106 MHz. This unfortunately corresponds with the cavity’s 2nd order harmonic mode, which will sweep from 86-105.7 MHz. The new damper is a modification of an existing damper that was designed to reduce an existing static HOM at 83 MHz, with the new design intending to cover the 2nd order HOM as well. The existing damper uses an inductive coupling loop to extract RF energy from the cavity which then goes through a filter in order to reflect the fundamental frequency back into the cavity while passing HOMs to a dump load. The new damper intends to replace the filter portion of the system with a wider band variant while also changing the topology from a coaxial cable loop filter to a componentized PCB-based design. Primary design challenges include bandwidth coverage, impedance matching of the various modes, long term thermal and mechanical stability, radiation hardness, and high voltage handling. Initial designs achieved the desired damping but were found to quickly succumb to destructive arcing due to the voltages present. More finalized designs intend to address this problem through circuit design modifications as well as the use of hardier components.

Pieper, Dustin [Fermilab]↗
DOE OSTI2025

Booster Cavity Damper Redesign for PIP-II

A new Higher Order Mode (HOM) damper was designed and tested for the Booster accelerator cavity at Fermilab. In anticipation of the PIP-II upgrade, it was discovered that the higher beam intensity of PIP-II may cause beam instability due to an excited mode at 106 MHz. This unfortunately corresponds with the cavity s 2nd order harmonic mode, which will sweep from 86-105.7 MHz. The new damper is a modification of an existing damper that was designed to reduce an existing static HOM at 83 MHz, with the new design intending to cover the 2nd order HOM as well. The existing damper uses an inductive coupling loop to extract RF energy from the cavity which then goes through a filter in order to reflect the fundamental frequency back into the cavity while passing HOMs to a dump load. The new damper intends to replace the filter portion of the system with a wider band variant while also changing the topology from a coaxial cable loop filter to a componentized PCB-based design. Primary design challenges include bandwidth coverage, impedance matching of the various modes, long term thermal and mechanical stability, radiation hardness, and high voltage handling. Initial designs achieved the desired damping but were found to quickly succumb to destructive arcing due to the voltages present. More finalized designs intend to address this problem through circuit design modifications as well as the use of hardier components.

Pieper, Dustin [Fermilab]↗
NASA NTRS2016

Hot-Fire Test Results of Liquid Oxygen/RP-2 Multi-Element Oxidizer-Rich Preburners

As part of the Combustion Stability Tool Development project funded by the Air Force Space and Missile Systems Center, the NASA Marshall Space Flight Center was contracted to assemble and hot-fire test a multi-element integrated test article demonstrating combustion characteristics of an oxygen/hydrocarbon propellant oxidizer-rich staged-combustion engine thrust chamber. Such a test article simulates flow through the main injectors of oxygen/kerosene oxidizer-rich staged combustion engines such as the Russian RD-180 or NK-33 engines, or future U.S.-built engine systems such as the Aerojet-Rocketdyne AR-1 engine or the Hydrocarbon Boost program demonstration engine. To supply the oxidizer-rich combustion products to the main injector of the integrated test article, existing subscale preburner injectors from a previous NASA-funded oxidizer-rich staged combustion engine development program were utilized. For the integrated test article, existing and newly designed and fabricated inter-connecting hot gas duct hardware were used to supply the oxidizer-rich combustion products to the oxidizer circuit of the main injector of the thrust chamber. However, before one of the preburners was used in the integrated test article, it was first hot-fire tested at length to prove it could provide the hot exhaust gas mean temperature, thermal uniformity and combustion stability necessary to perform in the integrated test article experiment. This paper presents results from hot-fire testing of several preburner injectors in a representative combustion chamber with a sonic throat. Hydraulic, combustion performance, exhaust gas thermal uniformity, and combustion stability data are presented. Results from combustion stability modeling of these test results are described in a companion paper at this JANNAF conference, while hot-fire test results of the preburner injector in the integrated test article are described in another companion paper.

Protz, C. S.↗
DOE OSTI2023

A Highly Soluble Iron–Based Posolyte Species with High Redox Potential for Aqueous Redox Flow Batteries

A novel iron-based posolyte redox species are presented for an aqueous redox flow battery, (Tetrakis(2-pyridylmethyl)ethylenediamine)iron(II) dichloride, which is obtained by a simple synthetic route, shows a high redox potential of 0.788 V versus SHE, and exhibits exceptional aqueous solubility of 1.46 M. Paired with bis(3-trimethylammonio)propyl viologen tetrachloride at neutral pH, the battery demonstrates an open-circuit voltage of 1.19 V and delivers good cycling performance, with a capacity fade rate of 0.28% per day and coulombic efficiency of 99.3%. Postmortem chemical and electrochemical analyses of the posolyte species suggest future routes for stabilization of the complex. Among all the iron complexes with a redox potential above 0.4 V versus SHE, this compound exhibits the highest solubility. Furthermore, these results offer valuable insights that can be applied to the development of future posolyte species for sustainable energy storage solutions.

25 ENERGY STORAGE↗