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All sources NASA NTRS DOE OSTI

DOE OSTI2022

Charge Delocalization and Vibronic Couplings in Quadrupolar Squaraine Dyes

Squaraines are prototypical quadrupolar charge-transfer chromophores that have recently attracted much attention as building blocks for solution-processed photovoltaics, fluorescent probes with large two-photon absorption cross sections, and aggregates with large circular dichroism. Their optical properties are often rationalized in terms of phenomenological essential state models, considering the coupling of two zwitterionic excited states to a neutral ground state. As a result, optical transitions to the lowest S 1 excited state are one-photon allowed, whereas the next higher S 2 state can only be accessed by two-photon transitions. A further implication of these models is a substantial reduction of vibronic coupling to the ubiquitous high-frequency vinyl-stretching modes of organic materials. Here, in this study, we combine time-resolved vibrational spectroscopy, two-dimensional electronic spectroscopy, and quantum-chemical simulations to test and rationalize these predictions for nonaggregated molecules. We find small Huang–Rhys factors below 0.01 for the high-frequency, 1500 cm –1 modes in particular, as well as a noticeable reduction for those of lower frequency modes in general for the electronic S 0 → S 1 transition. The two-photon allowed state S 2 is well separated energetically from S 1 and has weak vibronic signatures as well. Thus, the resulting pronounced concentration of the oscillator strength in a narrow region relevant to the lowest electronic transition makes squaraines and their aggregates exceptionally interesting for strong and ultrastrong coupling of excitons to localized light modes in external resonators with chiral properties that can largely be controlled by the molecular architecture.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Simple and Scalable Streaming: The GRETA Data Pipeline

The Gamma Ray Energy Tracking Array (GRETA) is a state of the art gamma-ray spectrometer being built at Lawrence Berkeley National Laboratory to be first sited at the Facility for Rare Isotope Beams (FRIB) at Michigan State University. A key design requirement for the spectrometer is to perform gamma-ray tracking in near real time. To meet this requirement we have used an inline, streaming approach to signal processing in the GRETA data acquisition system, using a GPU-equipped computing cluster. The data stream will reach 480 thousand events per second at an aggregate data rate of 4 gigabytes per second at full design capacity. We have been able to simplify the architecture of the streaming system greatly by interfacing the FPGA-based detector electronics with the computing cluster using standard network technology. A set of highperformance software components to implement queuing, flow control, event processing and event building have been developed, all in a streaming environment which matches detector performance. Prototypes of all high-performance components have been completed and meet design specifications.

Cromaz, Mario↗

DOE OSTI2024

A Highly Efficient and Affordable Hybrid System for Hydrogen and Electricity Production (Final Project)

The pursuit of clean, secure, and sustainable energy has sparked significant interest in fuel cells for power generation and electrolyzer cells for hydrogen production. Among all types of fuel and electrolyzer cells, solid oxide cells (SOCs) have emerged as promising candidates due to their high efficiency and versatility. However, conventional oxygen-ion conductive SOCs face several challenges related to their performance and durability associated with their high-temperature operation (≥ 800 ºC). This has led to a growing interest in intermediate-temperature (≤ 650 ºC) proton-conducting solid oxide cells (p-SOCs) as potential alternatives. In collaboration between Phillips 66 and Georgia Tech, this project aims to achieve a 1 kW p-SOCs system to demonstrate the commercial viability of efficient SOC systems. This report addresses four primary areas and key challenges we overcame: (1) development of efficient and durable proton-conducting electrolyte (e.g., BaHf 0.1 Ce 0.7 Yb 0.2 O 3-δ ) and electrode/catalyst materials, (2) large area cell fabrication (10 x 10 cm 2 ), (3) scalable stack design and building (250 W and 1 kW), and (4) demonstration of a 1 kW prototype system. Notably, significant challenges faced during the large area cell fabrication process were addressed by achieving cell flatness, improving fabrication yield, and ensuring electrode/electrolyte interfacial adhesion. Stack designs were also developed, focusing on reducing contact resistance and optimizing stack components (e.g., sealants). These efforts resulted in the achievement of high performance and durability with promising outputs of 250 W and 1 kW. Furthermore, the integration of these stacks into a fuel-powered system was explored, with refinements made to heat management, as well as to pressure and heating conditions. The results demonstrated the potential applicability of our p-SOC technology in commercial energy storage and power generation systems. Additionally, the report discusses techno-economic analysis and a market transformation plan, aiming to evaluate and advance the commercial feasibility of this technology.

25 ENERGY STORAGE↗

DOE OSTI2022

Experimental performance analysis of a dual source heat pump integrated with thermal energy storage

To mitigate disturbances to the electric grid resulting from the growing penetration of intermittent and decentralized renewable generation, a dual-source (air source and ground source) heat pump (DSHP) integrated with thermal energy storage (TES) was developed. The DSHP can use either ambient air or the shallow subsurface of the ground to provide space heating or space cooling to the building as the conventional heat pump and produce hot/cold water for charging TES. Using dual sources (air and ground) can reduce the required size of the expensive ground heat exchangers while retaining high energy efficiency. During the off-peak period, the DSHP cools/heats the TES with low-cost electricity or overproduced renewable power. The stored cooling/heating energy in the TES is released during peak hours of the electric grid to meet the thermal demands of the building without consuming electricity to run the DSHP. A 2-ton (7 kW) prototype DSHP was developed and integrated with a 50-gallon (189 L) TES tank filled with a phase change material. Field tests were conducted to characterize the performance of the integrated system operating in various operation modes.

Wang, Lingshi↗

NASA NTRS1979

Test and evaluation of Fern Engineering Company, Incorporated, solar heating and hot water system

Tests, test results, examination and evaluation by Underwriters Laboratory, Inc., of a single family solar heating and hot water system consisting of collector, storage, control, transport, and data acquisition are presented. The structural characteristics of the solar flat plate collectors were evaluated according to snow and wind loads indicated in various building codes to determine their suitability for use both Michigan and Pennsylvania where prototype systems were installed. The flame spread classification of the thermal insulation is discussed and the fire tests conducted on components are described. The operation and dielectrics withstand tests of the energy transport module indicate the module is capable of rated air delivery. Tests of the control panel indicate the relay coil temperatures exceed the temperature limits allowed for the insulating materials involved.

Source record↗

NASA NTRS1989

Automating the uplink process for planetary missions

The dual challenges of increased capability along with lower costs are addressed with regard to flight operations. A program has been formulated to take advantage of advances in software and hardware in order to design, and prototype where indicated, a set of tools which can be applied to the building of a more productive uplink process for NASA missions that are envisaged for the the next decade. Techniques such as object-oriented programming, expert systems, natural-language parsing, interactive graphics, and parallel processing are employed in the quest for increased productivity. The paper is organized hierarchically with the level of 'goal', 'objectives' and 'tasks'. A brief review of the uplink process is included.

Mclaughlin, William I.↗

NASA NTRS1991

Building a generalized distributed system model

A modeling tool for both analysis and design of distributed systems is discussed. Since many research institutions have access to networks of workstations, the researchers decided to build a tool running on top of the workstations to function as a prototype as well as a distributed simulator for a computing system. The effects of system modeling on performance prediction in distributed systems and the effect of static locking and deadlocks on the performance predictions of distributed transactions are also discussed. While the probability of deadlock is considerably small, its effects on performance could be significant.

Mukkamala, Ravi↗

NASA NTRS1992

Recent developments at the Goddard Engineering Test Bed

Work on the Flight Telerobotic Service (FTS) since that reported in Leake (1991) is examined, and initial work on a Hubble servicing mission is outlined. A state-of-the-art force reflecting teleoperation system that uses torque control at the joints of the slave manipulator has been implemented. The master rate/slave damper mode proposed by Langley has proved to be a very efficient operational mode, allowing force reflection ratios up to one to one. A software architecture for real-time Ada robotics systems has been proposed, and implementation has been launched. This architecture builds on the lessons learned from NASA Standard Reference Model Architecture and the prototype FTS effort. The Capaciflector sensor has been integrated into the system, and it has been used to perform a basic berthing task autonomously.

Leake, Stephen↗

NASA NTRS2004

The Integration of a Load Limiter to an Orbiter Over-Center Mechanism

This paper summarizes the design process used to relieve the predicted high loads on a Space Shuttle Orbiter mechanism prior to the STS-112 flight. The overloading of the mechanism was due to a dynamic response between the orbiter and payload that was specific to this payload s mass and attachment scheme. A solution was devised by adding a component that prevented overload of the mechanism. In addition, the introduction of the new component neither interfered with the normal operation nor required extra-vehicular activity from a crewmember. By utilizing rapid prototyping technology, engineers were able to verify clearances and feasibility while preparing to build the flight hardware. This design solution was successfully flown on STS-112 and STS-113.

Gilmore, Adam↗

NASA NTRS2010

Request-Driven Schedule Automation for the Deep Space Network

The DSN Scheduling Engine (DSE) has been developed to increase the level of automated scheduling support available to users of NASA s Deep Space Network (DSN). We have adopted a request-driven approach to DSN scheduling, in contrast to the activity-oriented approach used up to now. Scheduling requests allow users to declaratively specify patterns and conditions on their DSN service allocations, including timing, resource requirements, gaps, overlaps, time linkages among services, repetition, priorities, and a wide range of additional factors and preferences. The DSE incorporates a model of the key constraints and preferences of the DSN scheduling domain, along with algorithms to expand scheduling requests into valid resource allocations, to resolve schedule conflicts, and to repair unsatisfied requests. We use time-bounded systematic search with constraint relaxation to return nearby solutions if exact ones cannot be found, where the relaxation options and order are under user control. To explore the usability aspects of our approach we have developed a graphical user interface incorporating some crucial features to make it easier to work with complex scheduling requests. Among these are: progressive revelation of relevant detail, immediate propagation and visual feedback from a user s decisions, and a meeting calendar metaphor for repeated patterns of requests. Even as a prototype, the DSE has been deployed and adopted as the initial step in building the operational DSN schedule, thus representing an important initial validation of our overall approach. The DSE is a core element of the DSN Service Scheduling Software (S(sup 3)), a web-based collaborative scheduling system now under development for deployment to all DSN users.

Johnston, Mark D.↗

NASA NTRS2018

Developed AprilNav, an Indoor Navigation and Localization System for Autonomous Testing of Electric Sail Dynamics

An electrostatic sail (E-sail) is a new type of propulsion which harnesses the Sun's solar wind to propel a spacecraft. Voyager I took about 40 years to reach interstellar space using solid rocket propellant, whereas electrostatic sails can travel the same distance in 6-10 years by using small but constant acceleration. As part of Marshall Space Flight Center's (MSFC) Space Systems Dept. and Advanced Concepts Office, we are continuing research for the HERTS (Heliopause Electrostatic Rapid Transit System) E-sail project. Previous researchers developed a Nano Air-bearing Simulator (NAS) prototype for initial testing of E-sails; this prototype was properly documented in CAD (Computer-Aided Drafting) in order to build a second improved NAS. MSFC's Robotic Lab (Flat Floor) allows for 2-dimensional simulations of spacecraft dynamics by attaching air bearings to a system. An indoor navigation system AprilNav, was developed and has been implemented on the ceiling of the flat floor for localization and autonomous testing of the two bearing-equipped NAS. With two NAS, tether dynamics between the two simulators as well as steering control algorithms are being tested on the flat floor using AprilNav.

Schuler, Tristan↗

NASA NTRS2022

Engineering

2021 MIT Annual Report: Employing expertise in electrical, mechanical, structural, thermal, aerodynamics, optical, controls, and software engineering to build, integrate, and test systems for application in the development of advanced technology prototypes.

space communications↗

DOE OSTI2021

Membrane-Based Air Dehumidification Using Organic Ionic Liquid Desiccant

Membrane Ionic Liquid Desiccant Air Dehumidification (MILDAD) is a promising alternative to conventional dehumidification systems that employ mechanical compressors and refrigerant-based cooling with evaporator and condensing coils. However, its application has been limited due to high manufacturing and installation cost, durability issues, concerns with corrosion due to leakage and salt carry over into the downstream air and onto surfaces. This paper reviews substantial progress made with new systems based on combining advanced ionic membranes that are pressure resistant, thin walled with high water permeability, and non-porous with synthetic organic, non-crystalline ionic liquid desiccants. Alternative design configurations are discussed comparing cross flow shell-and-tube membrane contactors employing ionic membrane tubes through which ionic liquid desiccant air flows. Performance data for MILDAD prototypes is provided. Dehumidification of the incoming supply airstream and regeneration into exhausted building air is demonstrated. The latent effectiveness of the MILDAD system will be discussed along with some future steps to improve performance of the system.

Bahar, Bamdad↗

DOE OSTI2021

Cubesat system

Small cubesat systems may be available for a lower cost, have a higher reliability, and be much simpler to use than conventional cubesats. A complete turnkey system solution may be provided, including the ground station and remote field units. The satellite, ground station, and field unit may be provided separately as kits that are ready to go out-of-the-box as soon as they arrive. This enables universities, researchers, and hobbyists to obtain and deploy their own functional satellites. Furthermore, theoretical designs and functionality may be rapidly prototyped and demonstrated, which allows for proof-of-concept without needing to build a larger, more expensive satellite system and hope that the new design or functionality works as intended.

Judd, Stephen↗

DOE OSTI2021

Membrane-Based Air Dehumidification Using Organic Ionic Liquid Desiccant

ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION↗

NASA NTRS2019

Seeker 1.0: Prototype Robotic Free Flying Inspector Mission Overview

Seeker 1.0 is a prototype free flying robot that will one day be capable of inspecting human-rated spacecraft. Building off previous free flyer experience, this technology will eventually improve safety of human spacecraft by offering a variety of inspection capabilities for both routine and emergency scenarios providing increased capability and safety over current inspection methods. Seeker 1.0 is capable of 6 degree of freedom flight via a cold gas propulsion system and can operate up to 1 hour via a semi-autonomous guidance, navigation, and control system. The prototype spacecraft is capable of capturing still images at a variety of resolutions up to 13 MP. The initial test flight utilizes a command and data relay box called Kenobi. Kenobi is a derivative of the Seeker design and will communicate between Cygnus and Seeker and store data for post-mission downlink. Seeker and Kenobi have launched inside a NanoRacks External CubeSat Deployer (NRCSD-E) attached to the NG-11 Cygnus ISS resupply vehicle and will operate after Cygnus departs ISS and moves to a safe altitude. Operations will last approximately 30 minutes and will consist of basic vehicle maneuvers while capturing high-resolution still images. With any remaining time and propellant, Seeker will demonstrate additional safety capabilities and maneuvers required for operations around a crewed spacecraft. The Seeker project utilized the Class IE process that allows for streamlined flight hardware development and increased mission risk tolerance.

Spacecraft Inspection↗

DOE OSTI2024

ADRIANO2 Calorimeter performance from 2022 Prototypes

A novel high-granularity dual-readout calorimetric technique was developed as part of the T1604 collaboration research program. The building block of ADRIANO2 Calorimeter consists of a pair of optically isolated, small sized tiles made of scintillating plastic and lead glass. The two components of the dual-readout energy compensation technique. Furthermore,Cˇerenkovlightfromtheleadglassareexploitedtoforhighresolutiontimingmeasurements,whilehigh granularity from scintillating plastic can be used to probe the spatial component of the particle shower. This setup works for excellent energy resolution and particle identification for REDTOP as it is crucial for a calorimeter to detect and identify the decay products of eta/eta-prime mesons. Measurements were collected on several ADRIANO2 prototypes between February to December 2022 to evaluate the detector performance. The key metrics extracted from the analyses are presented in this paper are the efficiencies and light-yi eld for various tile configurations. The measured values will be used as input parameters for improved REDTOP Montecarlo simulation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2021

High Efficiency, Low Cost RF Sources for Accelerators and Colliders

Calabazas Creek Research, Inc. (CCR) and its collaborators are developing high efficiency, low cost RF sources. Phase and Amplitude Controlled Magnetrons: CCR, Fermilab, and Communications & Power Industries, LLC (CPI) recently developed a 100 kW, 1.3 GHz magnetron system with amplitude and phase control. The system operated at more than 80% efficiency and demonstrated rapid control of amplitude and phase. Multiple Beam Triodes: CCR, in collaboration with CPI and JP Accelerator Works, Inc., is developing 200 kW, pulsed and CW RF sources from 350 to 700 MHz with projected efficiencies exceeding 80% and cost of $0.50/Watt. Prototype tubes are scheduled for tests in spring 2021. High Efficiency Klystrons:CCR, CPI, and Leidos, Inc. are building a 1.3 GHz, 100 kW klystron operating at 80% efficiency. High power testing is scheduled for summer 2021. Multiple Beam IOTs: CCR and Georgia Tech Research Institute are developing MBIOTs with simplified input coupling and high efficiency. Simulations indicate that 3rd harmonic drive power can increase the efficiency 8-10 %. The program is developing a prototype tube to produce 200 kW peak, 100 kW average power at 704 MHz.

43 PARTICLE ACCELERATORS↗