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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS2020

Abundant Extraterrestrial Amino Acids in the Primitive CM Carbonaceous Chondrite Asuka 12236

The Asuka (A)-12236 meteorite has recently been classified as a CM carbonaceous chondrite of petrologic type 3.0/2.9 and is among the most primitive CM meteorites studied to date. Here, we report the concentrations, relative distributions, and enantiomeric ratios of amino acids in water extracts of the A-12236 meteorite and another primitive CM chondrite Elephant Moraine(EET) 96029 (CM2.7) determined by ultra-high-performance liquid chromatography time-of-flight mass spectrometry. EET 96029 was highly depleted in amino acids and dominated by glycine, while a wide diversity of two- to six-carbon aliphatic primary amino acids were identified in A-12236, which had a total amino acid abundance of 360 ± 18 nmol g-1, with most amino acids present without hydrolysis (free). The amino acid concentrations of A-12236 were double those previously measured in the CM2.7 Paris meteorite, consistent with A-12236 being a highly primitive and unheated CM chondrite. The high relative abundance of α-amino acids in A-12236 are consistent with formation by a Strecker-cyanohydrin dominated synthesis during a limited early aqueous alteration phase on the CM meteorite parent body. The presence of predominantly free glycine, a near racemic mixture of alanine (D/L ~0.93 to 0.96), and elevated abundances of several terrestrially rare non-protein amino acids including α-amino isobutyric acid (α-AIB) and racemic isovaline, indicate that these amino acids in A-12236 are extraterrestrial in origin. Given a lack of evidence for biological amino acid contamination in A-12236, it is possible that some of the L-enantiomeric excesses (Lee ~34 to 64%) of the protein amino acids aspartic and glutamic acids and serine are indigenous to the meteorite; however, isotopic measurements are needed for confirmation. In contrast to more aqueously altered CMs of petrologic types ≤ 2.5, no L-isovaline excesses were detected in A-12236. This observation strengthens the hypothesis that extensive parent body aqueous activity is required to produce or amplify the large L-isovaline excesses that cannot be explained solely by exposure to circularly polarized radiation or other chiral symmetry breaking mechanisms prior to incorporation into the asteroid parent body.

Daniel P Glavin↗
NASA NTRS2021

Investigation on the Origins of Comets as Revealed through IR High Resolution Spectroscopy: I. Molecular Abundances

We report and analyze molecular abundances updatedin twenty comets by employingmodern data reduction procedures and molecular models. Using boxplots and scatterplots, we examine how the different molecular species are distributed among the comet population, while by means of pie charts we investigate the relative proportions of these molecular species in each comet. We compare these results with the orbital parametersof the selected targets in order to identify trends related to the dynamical history of each comet. In this way, we identify at least three chemical classes based mainly on relative abundances of CO, CH3OH, CH4, C2H6, HCN and NH3. The combination of relative abundances and orbital parameters is then compared with chemical models of planetary system formation and may offer an alternative approach to investigate the origin and evolution of the material in cometary nuclei.Our study also confirms the need to add more objects to our sample in order to improve the statistics, especially for hyper-volatiles (i.e. CH4and CO) in Jupiter Family comets.

M Lippi↗
NASA NTRS2021

First Comet Observations with NIRSPEC-2 at Keck: Outgassing Sources of Parent Volatiles and Abundances Based on Alternative Taxonomic Compositional Baselines in 46P/Wirtanen

A major upgrade to the NIRSPEC instrument at the Keck II telescope was successfully completed in time for near-infrared spectroscopic observations of comet 46P/Wirtanen during its exceptionally close flyby of Earth in 2018 December. These studies determined the abundances of several volatiles, including C2H2, C2H6, CH3OH, NH3, HCN, H2CO, and H2O. Long-slit spatial distributions of gas rotational temperature and column density are diagnostic for the presence of icy grains in the coma and understanding if different volatiles are associated with common or distinct outgassing sources. These spatial distributions suggest that C2H2, C2H6, and HCN have a common outgassing source, whereas H2O and CH3OH have additional, more extended sources. The synergy of these findings with observations by space missions (Rosetta and EPOXI) motivates continuing studies to address whether or not C2H6, C2H2, and HCN have a common source of release (plausibly associated with CO2) in a larger sample of comets and whether systematic differences exist in the release of these species compared to H2O and CH3OH. Abundances of volatiles are reported relative to H2O, as traditionally done, as well as C2H6. While not unique, the choice of C2H6 demonstrates the value of extending the chemical taxonomy of parent volatiles in comets toward additional compositional "baselines" and, importantly, closer integration between coma abundances and the underlying volatile associations as revealed by spatial distributions. Our findings on composition and sources of outgassing include information relevant to future evaluations of 46P/Wirtanen as a prospective spacecraft target.

Boncho P. Bonev↗
NASA NTRS2021

Assessing Cyanobacterial Frequency and Abundance at Surface Waters Near Drinking Water Intakes Across the United States

This study presents the first large-scale assessment of cyanobacterial frequency and abundance of surface water near drinking water intakes across the United States. Public water systems serve drinking water to nearly 90% of the United States population. Cyanobacteria and their toxins may degrade the quality of finished drinking water and can lead to negative health consequences. Satellite imagery can serve as a cost-effective and consistent monitoring technique for surface cyanobacterial blooms in source waters and can provide drinking water treatment operators information for managing their systems. This study uses satellite imagery from the European Space Agency’s Ocean and Land Colour Instrument (OLCI) spanning June 2016 through April 2020. At 300-m spatial resolution, OLCI imagery can be used to monitor cyanobacteria in 685 drinking water sources across 285 lakes in 44 states, referred to here as resolvable drinking water sources. First, a subset of satellite data was compared to a subset of responses (n = 84) submitted as part of the U.S. Environmental Protection Agency’s fourth Unregulated Contaminant Monitoring Rule (UCMR 4). These UCMR 4 qualitative responses included visual observations of algal bloom presence and absence near drinking water intakes from March 2018 through November 2019. Overall agreement between satellite imagery and UCMR 4 qualitative responses was 94% with a Kappa coefficient of 0.70. Next, temporal frequency of cyanobacterial blooms at all resolvable drinking water sources was assessed. In 2019, bloom frequency averaged 2% and peaked at 100%, where 100% indicated a bloom was always present at the source waters when satellite imagery was available. Monthly cyanobacterial abundances were used to assess short-term trends across all resolvable drinking water sources and effect size was computed to provide insight on the number of years of data that must be obtained to increase confidence in an observed change. Generally, 2016-2020 was an insufficient time period for confidently observing changes at these source waters; on average, a decade of satellite imagery would be required for observed environmental trends to outweigh variability in the data. However, five source waters did demonstrate a sustained short-term trend, with one increasing in cyanobacterial abundance from June 2016 to April 2020 and four decreasing.

remote sensing↗
NASA NTRS2021

Low Total Abundances and a Predominance of n-ω-Amino Acids in Enstatite Chondrites: Implications for Thermal Stability of Amino Acids in the Inner Solar System

Investigating the organic contents of enstatite chondrite meteorites may offer insights into both early inner solar system and early Earth chemistry. Enstatite chondrite meteorites have highly reduced and anhydrous compositions, and their bulk isotopic compositions closely resemble terrestrial values, suggesting that their parent body asteroids accreted within the inner protoplanetary disk and were a primary contributor during Earth’s late accretion (Javoy et al., 1995; Piani et al., 2020). Here, we present the first report of amino acids in enstatite chondrite meteorite samples. Three EH3 meteorites were analyzed (Dominion Range 14021, Larkman Nunatak 12001, and Larkman Nunatak 06252). The acid-hydrolyzed water extracts of the meteorites contained low abundances (1.5 – 215.9 pmol/g) of n-ω-amino acids (glycine, β-alanine, γ-amino-n-butyric acid (γ-ABA), δ-amino-n-valeric acid (δ-AVA), and ε-amino-n-caproic acid (ε-ACA)), but amino acids were not present above detection limits in the non-hydrolyzed samples. The low amino acid abundances and the predominance of n-ω-amino acids resembles amino acid distributions previously observed for thermally altered chondrites. These results suggest that the parent body asteroid was not conducive to the synthesis and/or preservation of α-amino acids, or free amino acids in general, and that EH3 chondrite-like material may not have been a primary contributor of diverse or abundant free amino acids to the early Earth.

Danielle N Simkus↗
NASA NTRS2021

Low total abundances and a predominance of n-ω-amino acids in enstatite chondrites: Implications for thermal stability of amino acids in the inner solar system

Investigating the organic contents of enstatite chondrite meteorites may offer insights into both early inner solar system and early Earth chemistry. Enstatite chondrite meteorites have highly reduced and anhydrous compositions, and their bulk isotopic compositions closely resemble terrestrial values, suggesting that their parent body asteroids accreted within the inner protoplanetary disk and were a primary contributor during Earth’s late accretion (Javoy, 1995; Piani et al., 2020). Here, we present the first report of amino acids in enstatite chondrite meteorite samples. Three EH3 meteorites were analyzed (Dominion Range [DOM] 14021, Larkman Nunatak [LAR] 12001, and Larkman Nunatak 06252). The acid-hydrolyzed water extracts of the meteorites contained low abundances (1.5–215.9 pmol per g) of n-ω-amino acids (glycine, β-alanine, γ-amino-n-butyric acid [γ- ABA], δ-amino-n-valeric acid [δ-AVA], and ϵ-amino-n-caproic acid [ϵ-ACA]), but amino acids were not present above detection limits in the nonhydrolyzed samples. The low amino acid abundances and the predominance of n-ω-amino acids resemble amino acid distributions previously observed for thermally altered chondrites. These results suggest that the parent body asteroid was not conducive to the synthesis and/or preservation of α-amino acids, or free amino acids in general, and that EH3 chondrite-like material may not have been a primary contributor of diverse or abundant free amino acids to the early Earth.

Danielle N. Simkus↗
NASA NTRS2024

Effect of the Liquid-Vacuum Transition on the Relative Abundances of Amino and Fatty Acids Sought as Biosignatures on Icy Ocean Worlds

Interpreting measurements by robotic missions searching for signs of life in material erupted by cryovolcanic ocean worlds (e.g., Enceladus, Europa, Ceres) requires linking the composition of this material to that of its subsurface liquid source. Irrespective of the properties of –and processes along– the path of ejection, material erupted on airless worlds undergoes a transition from liquid to vacuum. Here, we investigate experimentally the effect of a direct transition from liquid to vacuum environments on the relative abundances of amino and carboxylic (fatty) acids, a metric used to distinguish between biological and abiotic sources for these compounds. Amino acids were dissolved in parent solutions prepared with 1 wt.% NaCl and pH 9–10 to match properties inferred from Enceladus plume grains. Compositional analysis of the dry solids resulting from the injection of this solution into vacuum indicates a < 50% change in amino acid abundances relative to glycine. Injection of two fatty acids, phenylacetic acid (soluble and undersaturated in the parent solution) and palmitic acid (insoluble and supersaturated) resulted in a change of less than a factor of 7 in their relative abundances. At this bulk scale (all grains aggregated together), proportions of amino and fatty acids were sufficiently conserved to allow distinction between end-member example biological and abiotic sources. We did not find strong correlations between the relative enrichment or depletion of amino or fatty acids with molecular properties such as molecular mass, hydrophobicity, functionality, or charge, other than high under-or supersaturation. Most of the organic residue was deposited along the experimental injection path, which suggests that cryovolcanic conduit walls on icy ocean worlds may be enriched in organic material relative to material having undergone the liquid-vacuum transition.

Amino acids↗
NASA NTRS1971

The temperatures, abundances and gravities of F dwarf stars.

Theoretical colors computed from laboratory line data and from model stellar atmospheres have been used to interpret the colors of about 150 F and early G dwarfs. Effective temperatures have been derived from the H-beta index and from R-I, abundances have been obtained from m(sub 1) and from b-y, and gravities have been obtained from c(sub 1) and from b-y. The effective temperatures and gravities are in good agreement with values obtained from spectral scans. Absolute magnitudes have been obtained from the effective temperatures and gravities, the latter being used with assumed stellar masses to yield radii. The present results provide theoretical justification of the empirical formulas given by Crawford and by Stroemgren for the determination of absolute magnitudes and abundances from uvby photometry.

Bell, R. A.↗
NASA NTRS1972

U, Th, Pb and REE abundances and Pb 207/Pb 206 ages of individual minerals in returned lunar material by ion microprobe mass analysis.

Results of ion microprobe analyses of Apollo 11, 12 and 14 material, showing that U, Th, Pb and REE are concentrated in accessory minerals such as apatite, whitlockite, zircon, baddeleyite, zirkelite, and tranquillityite. Th/U ratios are found to vary by over a factor of 40 in these minerals. K, Ba, Rb and Sr have been localized in a K rich, U and Th poor glass phase that is commonly associated with the U and Th bearing accessory minerals. Li is observed to be fairly evenly distributed between the various accessory phases. The phosphates have been found to have REE abundance patterns (normalized to the chondrite abundances) that are fairly flat, while the Zr bearing minerals have patterns that rise steeply, by factors of ten or more, from La to Gd. All the accessory minerals have large negative Eu anomalies. Radiometric age dates (Pb 207/Pb 206) of the individual U and Th bearing minerals compare favorably with the Pb 207/Pb 206 age of the bulk rocks.

Andersen, C. A.↗
NASA NTRS1972

Mean lifetimes and equilibrium abundances in the fast CN cycle.

It is shown that the production of small nitrogen to carbon ratios is possible, in contrast to the equilibrium production in the ordinary CN cycle. Associated with such a production are high ratios of C-13/C-12 and of N-15/N-14. The final ratios depend on the conditions under which cessation of hydrogen burning occurs under astrophysical circumstances. A table showing proton capture mean lifetimes of CN nuclei is provided together with tables of the equilibrium abundances in a fast CN cycle. The ratios of final abundances of nitrogen to carbon as functions of temperature are also presented.

Caughlan, G. R.↗
NASA NTRS1973

Iron abundance in the moon from magnetometer measurements

Apollo 12 and 15 lunar surface magnetometer data with simultaneous lunar orbiting Explorer 35 data are used to plot hysteresis curves for the whole moon. From these curves a whole-moon permeability mu = 1.029 + 0.024 or - 0.019 is calculated. This result implies that the moon is not composed entirely of paramagnetic material, but that ferromagnetic material such as free iron exists in sufficient amounts to dominate the bulk lunar susceptibility. From the magnetic data the ferromagnetic free iron abundance is calculated. Then for assumed compositional models of the moon the additional paramagnetic iron is determined, yielding total lunar iron content. The calculated abundances are as follows: ferromagnetic free iron = 5 + or - 4 wt. percent, and total iron in the moon = 9 + or - 4 wt. percent.

Parkin, C. W.↗
NASA NTRS1973

Measurement of Elemental Abundance of Very Low Energy Solar Cosmic Rays

Heavy interplanetary particles were observed during a solar flare period between October 29 and November 4, 1972. The nuclear abundance was determined by a two parameter analysis (dE/dx vs E technique) of a thin window proportional counter - solid state detector device aboard the Explorer 47 (IMP-7) satellite. Energy spectra are given for C, O and Fe. The elemental abundance relative to oxygen is determined for carbon, neon, magnesium, silicon and the iron group in the energy range 0.62 to 6.9 MeV/nucleon. For the Fe/O ratio no energy dependence could be observed within the error limits.

Hovestadt, D.↗
NASA NTRS1972

Elemental abundances in the Havero meteorite.

Abundances of 15 major, minor, and trace elements have been determined in powders and interior chips derived from the Havero ureilite. The values are in close agreement with mean values for other ureilites, as reported in the literature. The powdered samples exhibited slightly higher abundances of O and Si than the interior chips. It is suggested that this may be due to alteration of the samples during the powdering process.

Gillum, D. E.↗
NASA NTRS1973

Helium abundance of the sun.

Critical review of the four methods that have been used to estimate the ratio of helium to hydrogen in the sun - the solar neutrino flux, spectral intensity of helium lines in prominences and the chromosphere, elemental abundance of solar cosmic rays, and variations of solar wind He/H. At present the measured value for the neutrino flux cannot be explained by any of the theoretical models of the sun, and thus the neutrino measurements cannot yield an estimate of He/H. Helium line intensity measurements give the most accurate values for He/H now available - i.e., 5 to 8% helium by number. However, these results refer to the chromosphere and prominences only, and questions of spatial and temporal variations of the observed quantities and of the inferred helium abundances have not yet been dealt with adequately.

Hirshberg, J.↗
NASA NTRS1973

Elemental abundance determinations for meteors by spectroscopy.

Relative elemental abundance determinations for meteors by spectroscopy are discussed. Relative abundances of spectroscopically accessible elements of four major shower meteors and one sporadic meteor are presented. A sporadic meteor with dominant sodium radiation and an iron-deficient sporadic meteor are analyzed. Empirical and theoretical tests for self-absorption in optical meteor plasmas have been conducted. Both ionization and incomplete dissociation are found to severely deplete certain neutral atoms from meteor plasmas.

Harvey, G. A.↗