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At least 397 records · Page 22

Lightning Charge Retrievals: Dimensional Reduction, LDAR Constraints, and a First Comparison with LIS Satellite Data

A "dimensional reduction" (DR) method is introduced for analyzing lightning field changes (DELTAEs) whereby the number of unknowns in a discrete two-charge model is reduced from the standard eight (x, y, z, Q, x', y', z', Q') to just four (x, y, z, Q). The four unknowns (x, y, z, Q) are found by performing a numerical minimization of a chi-square function. At each step of the minimization, an Overdetermined Fixed Matrix (OFM) method is used to immediately retrieve the best "residual source" (x', y', z', Q'), given the values of (x, y, z, Q). In this way, all 8 parameters (x, y, z, Q, x', y', z', Q') are found, yet a numerical search of only 4 parameters (x, y, z, Q) is required. The DR method has been used to analyze lightning-caused DeltaEs derived from multiple ground-based electric field measurements at the NASA Kennedy Space Center (KSC) and USAF Eastern Range (ER). The accuracy of the DR method has been assessed by comparing retrievals with data provided by the Lightning Detection And Ranging (LDAR) system at the KSC-ER, and from least squares error estimation theory, and the method is shown to be a useful "stand-alone" charge retrieval tool. Since more than one charge distribution describes a finite set of DELTAEs (i.e., solutions are non-unique), and since there can exist appreciable differences in the physical characteristics of these solutions, not all DR solutions are physically acceptable. Hence, an alternative and more accurate method of analysis is introduced that uses LDAR data to constrain the geometry of the charge solutions, thereby removing physically unacceptable retrievals. The charge solutions derived from this method are shown to compare well with independent satellite- and ground-based observations of lightning in several Florida storms.

Koshak, W. J.↗

Lightning Charge Retrievals: Dimensional Reduction, LDAR Constraints, and a First Comparison with LIS Satellite Data

A "dimensional reduction" ("DR") method is introduced for analyzing lightning field changes ((Delta)Es) whereby the number of unknowns in a discrete two-charge model is reduced from the standard eight (x, y, z, Q, x', y', z', Q') to just four (x, y, z, Q). The four unknowns (x, y, z, Q) are found by performing a numerical minimization of a chi-square function. At each step of the minimization, an overdetermined fixed matrix (OFM) method is used to immediately retrieve the best "residual source" (x', y', z', Q'), given the values of (x, y, z, Q). In this way, all eight parameters Ix. y, z, Q, x', y', z', Q') are found, yet a numerical search of only four parameters (x, y, z, Q) is required. The DR method has been used to analyze lightning-caused (Delta)Es derived from multiple ground-based electric field measurements at the NASA Kennedy Space Center (KSC) and U.S. Air Force Eastern Range (ER). The accuracy of the DR method has been assessed by comparing retrievals with data provided by the lightning detection and ranging (LDAR) system at the KSC-ER. and from least squares error estimation theory, and the method is shown to be a useful "stand alone" charge retrieval tool. Since more than one charge distribution describes a finite set of (Delta)Es (i.e., solutions are nonunique), and since there can be appreciable differences in the physical characteristics of these solutions, not all DR solutions are physically acceptable. Hence. an alternative and more accurate method of analysis is introduced that uses LDAR data to constrain the geometry of the charge solutions. thereby removing physically unacceptable retrievals. The charge solutions derived from this method are shown to compare well with independent satellite- and ground-based observations of lightning m several Florida storms.

Koshak, W. J.↗

Impact of Lightning and Convection on Reactive Nitrogen in the Tropical Free Troposphere

Latitudinal distributions of NO, NO(y), O3, CO, CH3I, and H2O mixing ratios at 8.9-12 km were obtained between 30deg N and 1deg S by DC-8 aircraft measurements made in February 1994 during Pacific Exploratory Mission-West B (PEM-West B). Very low NO(y), mixing ratios with a median value of 51 parts per trillion by volume (pptv) were observed at 9.5-12 km at 1deg N-14deg N during two flights made within 3 days. A very low median O3 mixing ratio of 19 parts per billion by volume (ppbv) and high mixing ratios of H2O and CH3I were simultaneously observed, suggesting that the low NO(y), values were probably due to the convective transport of air from the tropical marine boundary layer to this altitude. The median NO(y)/O3 ratio being a factor of 2 smaller than in the air masses in the tropical marine boundary layer might suggest the possibility that the heterogeneous removal of HNO3 during convective transport further reduced NO(y) levels. In addition to the measurements between 9.5 and 12 km, low values of NO(y) and O3 were observed between 4 and 12 km at 1deg N. Divergent wind fields at 200 and 1000 hPa and infrared (IR) cloud images show that there was large scale convection (greater than 1000 km x 1000 km) in the northeast of New Guinea Island centered around Odeg S and 150deg E as part of systematic convective activity of the Intertropical Convergence Zone (ITCZ) and the South Pacific Convergence Zone (SPCZ). This type of large scale convection could have transported air with low levels of NO(y) and O3 to the middle and upper troposphere over a wide area in the tropics. On the other hand, NO mixing ratios of 50-200 pptv and high NQ,/NOY ratios of 0.4-0.6 were observed at 9.5 km between 4deg S and 10deg S. High H2O Mixing ratios of 600-1200 parts per million by volume (ppmv) and low CO mixing ratios of 65 ppbv observed in the air mass indicated that the high NO values were probably due to NO production by lightning. Satellite observations showed relatively frequent lightning flashes over the New Guinea Island for 3 days prior to the aircraft measurements. These results are considered to be consistent with the idea that, in general, marine convection is not accompanied by lightning activity, whereas convection over land is. Because of the large areal extent of the influences from these processes, the convective transport of low NO(y) air and NO production by lightning should play critical roles in controlling the abundance of reactive nitrogen in the equatorial region.

Kawakami, S.↗

Ion neutral coupling in the high latitude thermosphere, part 1

Measurements of the neutral wind in the polar F region from Dynamics Explorer-2 (DE-2) were used to illustrate asymmetries in the neutral circulation that are dependent on the sign of the B sub y component of the interplanetary magnetic field (IMF). Individual DE-2 orbits and averaged data sets from different Universal times are presented. The data are categorized according to the sign of the hourly averaged IMF B sub y component measured by ISEE-3 for the hour preceding the DE-2 measurement. The major features observed are: (1) an asymmetry in the polar cap neutral flow velocity with the region of most rapid antisunward flow shifting from the dawn side to the dusk side of the polar cap as B sub y changes from positive to negative; (2) a shift in magnetic local time of the region of entry of neutral gas into the polar cap from a location on the dawn side of the noon-midnight meridian for B sub y positive to one more biased towards the dusk side for B sub y negative; (3) an enhancement in the velocities associated with the dawn, anti-clockwise neutral vortex B suby y negative relative to those observed for B sub y positive. The B sub y neutral wind asymmetries can be explained by similar asymmetries, previously observed, in the polar ion convection pattern. They imply a direct causal relationship between solar wind/magnetosphere coupling and neutral thermospheric dynamics.

Killeen, T. L.↗

The series Bi2Sr2Ca(n-1) Cu(n)O(2n+4) (1 less than or equal to n less than or equal to 5): Phase stability and superconducting properties

Phase relations at 850 and 870 C, melting transitions in air, oxygen, and helium were studied for Bi(2.1)Sr(1.9) CuO6 and for the Bi2Sr2Ca(n-1) Cu(n)O(2n+4) for n = 1, 2, 3, 4, 5, and infinity (CaCuO2). Up to 870 C, the n = 2 composition resides in the compatibility tetrahedron bounded by Bi(2+x)(Sr,Ca)(3-y) Cu2O8, (Sr,Ca)14 Cu24O41, Ca2CuO3, and a Bi-Sr-Ca-O phase. The n is greater than or equal to 3 compositions reside in the compatibility tetrahedron Bi(2+x)(Sr,Ca)(3-y) Cu2O8 - (Sr,Ca)14 Cu24O41 - Ca2CuO3 - CuO up to 850 C. However, Bi(2+x)Sr(4-y) Cu3O10 forms for n is greater than or equal to 3 after extended heating at 870 C. Bi(2+x)Sr(2-y) CuO6 and Bi(2+x)(Sr,Ca)(3-y) Cu2O8 melt in air at 914 C and 895 C respectively. During melting, all of the compositions studied lose 1 to 2 percent by weight of oxygen from the reduction of copper. Bi(2+x)Sr(2-y) CuO6, Bi(2+n)(Sr,Ca)(3-y) Cu2O8, and Bi(2+x)(Sr,Ca)(4-y) Cu3O10 exhibit crystallographic alignment in a magnetic field, with the c-axes orienting parallel to the field.

Deguire, Mark R.↗

By-controlled convection and field-aligned currents near midnight auroral oval for northward interplanetary magnetic field

Using the Dynamics Explorer (DE) 2 magnetic and electric field and plasma data, B(sub y)- controlled convection and field-aligned currents in the midnight sector for northward interplanetary magnetic field (IMF) are examined. The results of an analysis of the electric field data show that when IMF is stable and when its magnitude is large, a coherent B(sub y)-controlled convection exists near the midnight auroral oval in the ionosphere having adequate conductivities. When B(sub y) is negative, the convection consists of a westward (eastward) plasma flow at the lower latitudes and an eastward (westward) plasma flow at the higher latitudes in the midnight sector in the northern (southern) ionosphere. When B(sub y) is positive, the flow directions are reversed. The distribution of the field-aligned currents associated with the B(sub y)-controlled convection, in most cases, shows a three-sheet structure. In accordance with the convection the directions of the three sheets are dependent on the sign of B(sub y). The location of disappearance of the precipitating intense electrons having energies of a few keV is close to the convection reversal surface. However, the more detailed relationship between the electron precipitation boundary and the convection reversal surface depends on the case. In some cases the precipitating electrons extend beyond the convection reversal surface, and in others the poleward boundary terminates at a latitude lower than the reversal surface. Previous studies suggest that the poleward boundary of the electrons having energies of a few keV is not necessarily coincident with an open/closed bounary. Thus the open/closed boundary may be at a latitude higher than the poleward boundary of the electron precipitation, or it may be at a latitude lower than the poleward boundary of the electron precipitation. We discuss relationships between the open/closed boundary and the convection reversal surface. When as a possible choice we adopt a view that the open/closed boundary agrees with the convection reversal surface, we can explain qualitatively the configuration of the B(sub y)-controlled convection on the open and close field line regions by proposing a mapping modified in accordance with IMF B(sub y).

Taguchi, S.↗

Spread of denitrification from 1987 Antarctic and 1988-1989 Arctic stratospheric vortices

Vertical profiles of N2O and NO(y) taken by the ER-2 outside the vortex are used to construct average vertical profiles of F(NO(y)) = NO(y)/(A-N2O), where A is the tropospheric content of N2O three years prior to the measurements. The southern hemisphere had less nitrous oxide in the range 400 less than Theta less than 470 K, by up to 25% relative to the northern hemisphere. F(NO(y)) is the ratio of NOy produced to N2O lost in a stratospheric air mass since entry from the troposphere. The profiles of F(NO(y)) have the following characteristics: (1) Relative to 1991-1992, a year without denitrification inside or outside the vortex, the northern hemisphere in 1988-1989 showed denitrification outside the vortex ranging up to 25% and averaging 17% above Theta = 425 K. (2) Relative to the northern hemisphere in 1991-1992, the southern hemisphere in 1987 showed denitrification outside the vortex ranging up to 32% and averaging 20% above Theta = 400 K. (3) Below Theta = 400 K the southern hemisphere showed enhancements of F(NO(y)) relative to the northern hemisphere in 1991-1992 ranging up to 200% at Theta = 375 K, outside the vortex. Corresponding profiles of residual water, R(H2O) = H2O - 2(1.6 - CH4), are considered and shown to be consistent with those of F(NO(y)) in the sense that they show deficits outside the Antarctic vortex, which was both dehydrated and denitrified, but not outside the 1988-1989 Arctic vortex, which was denitrified but not dehydrated. R(H2O) is the water content of stratospheric air with the contribution from methane oxidation subtracted. Comparison of F(NO(y)) and R(H2O) below 400 K outside the Antarctic vortex leads to the suggetion that dehydration in the Antarctic vortex occurs by the sedimentation of ice crystals large enough to fall out of the stratosphere, whereas denitrification occurs mainly on mixed nitric acid-water crystals which evaporate below the base of the vortex at Theta = 400 K but above the tropopause.

Tuck, A. F.↗

Estimates of total organic and inorganic chlorine in the lower stratosphere from in situ and flask measurements during AASE 2

Aircraft sampling has provided extensive in situ and flask measurements of organic chlorine species in the lower stratosphere. The recent Airborne Arctic Stratospheric Expedition 2 (AASE 2) included two independent measurements of organic chlorine species using whole air sample and real-time techniques. From the whole air sample measurements we derive directly the burden of total organic chlorine (CCl(y)) in the lower stratosphere. From the more limited real-time measurements we estimate the CCl(y) burden using mixing ratios and growth rates of the principal CCl(y) species in the troposphere in conjunction with results from a two-dimensional photochemical model. Since stratospheric chlorine is tropospheric in origin and tropospheric mixing ratios are increasing, it is necessary to establish the average age of a stratospheric air parcel to assess its total chlorine (Cl(sub Total)) abundance. Total inorganic chlorine (Cl(y)) in the parcel is then estimated by the simple difference, Cl(y) = Cl(sub Total) - CCl(y). The consistency of the results from these two quite different techniques suggests that we can determine the CCl(y) and Cl(y) in the lower stratosphere with confidence. Such estimates of organic and inorganic chlorine are crucial in evaluating the photochemistry controlling chlorine partitioning and hence ozone loss processes in the lower stratosphere.

Woodbridge, E. L.↗

Measurements of Nitric Acid and Aerosol Species Aboard the NASA DC-8 Aircraft During the SASS Ozone and Nitrogen Oxide Experiment (SONEX)

The SASS Ozone and Nitrogen Oxides Experiment (SONEX) over the North Atlantic during October/November 1997 offered an excellent opportunity to examine the budget of total reactive nitrogen (NO(sub y)) in the upper troposphere (8 - 12 km altitude). The median measured NO(sub y) mixing ratio was 425 parts per trillion by volume (pptv). Two different methods were used to measure HNO3: (1) the mist chamber technique and, (2) chemical ionization mass spectrometry. Two merged data sets using these HNO3 measurements were used to calculate NO(sub y) by summing the reactive nitrogen species (a combination of measured plus modeled results) and comparing the resultant values to measured NO(sub y) (gold catalytic reduction method). Both comparisons showed good agreement in the two quantities (slope > 0.9 and r(exp 2) > 0.9). Thus, the total reactive nitrogen budget in the upper troposphere over the North Atlantic can be explained in a general manner as a simple mixture of NO(sub x). (NO + NO2), HNO3, and PAN. Median values of NO(sub x)/NO(sub y) were approximately equal to 0.25, HNO3/NO(sub y) were approximately equal to 0.35 and Peroxyacetyl Nitrate (PAN)/NO(sub y) were approximately equal to 0. 17. Particulate NO3 and alkyl nitrates together composed <10 % of NO(sub y), while model estimated HNO4 averaged 12%.

Talbot, Robert W.↗

Improving the Accuracy of Quadrature Method Solutions of Fredholm Integral Equations That Arise from Nonlinear Two-Point Boundary Value Problems

In this paper we are concerned with high-accuracy quadrature method solutions of nonlinear Fredholm integral equations of the form y(x) = r(x) + definite integral of g(x, t)F(t,y(t))dt with limits between 0 and 1,0 less than or equal to x les than or equal to 1, where the kernel function g(x,t) is continuous, but its partial derivatives have finite jump discontinuities across x = t. Such integral equations arise, e.g., when one applied Green's function techniques to nonlinear two-point boundary value problems of the form y "(x) =f(x,y(x)), 0 less than or equal to x less than or equal to 1, with y(0) = y(sub 0) and y(l) = y(sub l), or other linear boundary conditions. A quadrature method that is especially suitable and that has been employed for such equations is one based on the trepezoidal rule that has a low accuracy. By analyzing the corresponding Euler-Maclaurin expansion, we derive suitable correction terms that we add to the trapezoidal rule, thus obtaining new numerical quadrature formulas of arbitrarily high accuracy that we also use in defining quadrature methods for the integral equations above. We prove an existence and uniqueness theorem for the quadrature method solutions, and show that their accuracy is the same as that of the underlying quadrature formula. The solution of the nonlinear systems resulting from the quadrature methods is achieved through successive approximations whose convergence is also proved. The results are demonstrated with numerical examples.

Sidi, Avram↗

Measurements of Nitric Acid and Aerosol Species Aboard the NASA DC-8 Aircraft During the SASS OZone and Nitrogen Oxide Experiment (SONEX)

The SASS Ozone and Nitrogen Oxides Experiment (SONEX) over the north Atlantic during October/November 1997 offered an excellent opportunity to examine the budget of total reactive nitrogen (NO(y)) in the upper troposphere (8 - 12 km altitude). The median measured NO(y) mixing ratio was 425 parts per trillion by volume (pptv). Two different methods were used to measure HNO3: (1) the mist chamber technique and, (2) chemical ionization mass spectrometry. Two merged data sets using these HNO3 measurements were used to calculate NO(y) by summing the reactive nitrogen species (a combination of measured plus modeled results) and comparing the resultant values to measured NO(y) (gold catalytic reduction method). Both comparisons showed good agreement in the two quantities (slope greater than 0.9 and r(sup 2) greater than 0.9). Thus, the total reactive nitrogen budget in the upper troposphere over the North Atlantic can be explained in a general manner as a simple mixture of NO(x). (NO + NO2), HNO3, and PAN. Median values of NO(x)/NO(y) were approx. = 0.25, HNO3/NO(y) approx. = 0.35 and PAN/NO(y) approx. = 0.17. Particulate NO3 and alkyl nitrates together composed less than 10% of NO(y), while model estimated HNO4 averaged 12%.

Talbot, Robert W.↗

Lunar Meteorites and Implications for Compositional Remote Sensing of the Lunar Surface

Lunar meteorites (LMs) are rocks found on Earth that were ejected from the Moon by impact of an asteroidal meteoroid. Three factors make the LMs important to remote-sensing studies: (1) Most are breccias composed of regolith or fragmental material; (2) all are rocks that resided (or breccias composed of material that resided) in the upper few meters of the Moon prior to launch and (3) most apparently come from areas distant from the Apollo sites. How Many Lunar Locations? At this writing (June 1999), there are 18 known lunar meteorite specimens. When unambiguous cases of terrestrial pairing are considered, the number of actual LMs reduces to 13. (Terrestrial pairing is when a single piece of lunar rock entered Earth's atmosphere, but multiple fragments were produced because the meteoroid broke apart on entry, upon hitting the ground or ice, or while being transported through the ice.) We have no reason to believe that LMs preferentially derive from any specific region(s) of the Moon; i.e., we believe that they are samples from random locations. However, we do not know how many different locations are represented by the LMs; mathematically, it could be as few as 1 or as many as 13. The actual maximum is < 13 because in some cases a single impact appears to have yielded more than one LM. Yamato 793169 and Asuka 881757 are considered "source-crater paired" or "launch paired" because they are compositionally and petrographically similar to each other and distinct from the others, and both have similar cosmic-ray exposure (CRE) histories. The same can be said of QUE 94281 and Y 793274. Thus the 13 meteorites probably represent a maximum of 11 locations on the Moon. The minimum number of likely source craters is debated and in flux as new data for different isotopic systems are obtained. Conservatively, considering CRE data only, a minimum of about 5 impacts is required. Compositional and petrographic data offer only probabilistic constraints. An extreme, but not unreasonable viewpoint, is that such data offer no constraint. For example, if one were to cut up the Apollo 17 landing site (which was selected for its diversity) into softball-sized pieces, some of those pieces (e.g., sample 70135) would be crystalline mare basalts like Y 793169 whereas others (e.g., sample 73131 would be feldspathic regolith breccias like MAC 88104/ 88105. However, nature is not so devious. Warren argues that LMs come from craters of only a few kilometers in diameter. If so, even though CRE data allow, for example, that ALHA 81005 and Y 791197) were launched simultaneously from the same crater, the probability is nevertheless low because the two meteorites are compositionally and mineralogically distinct. Thus, within the allowed range (5-11) for the number of locations represented by the LMs, values at the high end of the range are probably more likely. Mare Meteorites: Three LMs consist almost entirely of mare basalt. Two, Y 793169 and Asuka 881757, are unbrecciated, low-Ti, crystalline rocks that are compositionally and mineralogically similar (but not identical) to each other; they probably derive from a single lunar-mare location. The third, EET 87521/96008, is a fragmental breccia consisting predominantly of VLT mare basalt. Thus, these LMs probably represent only two lunar mare locations. The basaltic LMs have mineral and bulk compositions distinct from Apollo mare basalts. The petrography of Calcalong Creek has not been described in detail, but compositionally it is unique in that it corresponds to a mixture (breccia) of about one-half feldspathic material (i.e., the mean composition of the feldspathic lunar meteorites, below), one-fourth KREEP norite, one-fourth VLT mare basalt (like EET 87521), and 1% CI chondrite. With 4 micro g/g Th and correspondingly high concentrations of other incompatible elements, it is the only lunar meteorite that is likely to have come from within the Procellarum KREEP Terrane (PKT). Yamato 793274 and QUE 94281 are together distinct in being fragmental breccias containing subequal parts of feldspathic highland material and VLT mare basalt. Jolliff et al. estimate a mare to highland ratio of 54:46 for QUE 94281 and 62:38 for Y 793274; this difference is well within the range observed for soils collected only centimeters apart (in cores) at interface site like Apollo 15 and 17 [11]. Although the two meteorites were found on opposite sides of Antarctica, they are probably launch-paired. The strongest evidence is that the pyroclastic glass spherules that occur in both are of two compositional groups and the two groups are essentially the same in both meteorites. Yamato 791197 is nominally a feldspathic lunar meteorite (below), but among FLMs, it probably contains the highest abundance of clasts and glasses of mare derivation. As a consequence, its composition is at the high-Fe, low-Mg end of the range for FLMs and is not included in the FLM average of Table 1. Its composition is consistent with about 10% mare-derived material. Similarly, the two small (Y 82) pieces of Y 82192/82193186032 are more mafic than the large (Y 86) piece, probably as a result of about 7% mare-derived material. All Apollo missions went to areas in or near the PKT, and, consequently, all Apollo regolith samples are contaminated with Th-rich material from the PKT. At the nominally "typical" highland site, Apollo 16, about 30% of the regolith (<1-mm fines) is Th-rich ejecta from the Imbrium impact and about 6% is mare material probably derived from mare basins. Thus Apollo 16 regolith is not typical of the highlands. Among Apollo rocks, the compositions of the FLMs correspond most closely to the feldspathic granulitic breccias of Apollo 16 and 17. (Additional information is contained in original)

Korotev, R. L.↗

Dimensional Reduction: A Method for Retrieving Lightning Charge

A method is introduced for retrieving the locations and magnitudes of charges deposited by a lightning flash using multiple ground-based electric field change measurements. The method, called Dimensional Reduction, reduces the number of unknowns in a discrete 2-charge model from the standard of eight (x, y, z, Q, x' , y' , z' , Q') to just four (x, y, z, Q). This reduction is accomplished by analyzing "residual measurements" that are formed by subtracting from each ground-based electric field change the contribution due to the source (x, y, z, Q). Using an improved analytic solution to the four-parameter point charge model (or "Q-model") the residual measurements are inverted to find the associated "residual source." For flash charge depositions that look approximately like two arbitrary charges, the residual source will be modeled accurately when (x, y, z, Q) is accurate. Hence, one need only minimize a chi-squared goodness-of-fit that is a function of the four variables (x, y, z, Q), rather than one that is a function of the eight variables (x, y, z, Q, x , y , z , Q ). The accuracy of the method is assessed by inverting computer-simulated electric field changes produced from known charge sources. The method is also applied to analyze real lightning electric field change data derived from the NASA Kennedy Space Center (KSC) and United States Air Force (USAF) Eastern Range (ER) ground-based field mill network It is shown that the charge retrievals compare favorably with associated ancillary ground- and satellite- based lightning measurements.

Koshak, William↗

Spatial distributions of Tribrachidium, Rugoconites, and Obamus from the Ediacara Member (Rawnsley Quartzite), South Australia

The spatial distribution of in situ sessile organisms, including those from the fossil record, provides information about life histories, such as possible dispersal and/or settlement mechanisms, and how taxa interact with one another and their local environments. At Nilpena Ediacara National Park (NENP), South Australia, the exquisite preservation and excavation of 33 fossiliferous bedding planes from the Ediacara Member of the Rawnsley Quartzite reveals in situ communities of the Ediacara Biota. Here, the spatial distributions of three relatively common taxa, Tribrachidium, Rugoconites, and Obamus, occurring on excavated surfaces were analyzed using spatial point pattern analysis. Tribrachidium have a variable spatial distribution, implying that settlement or post-settlement conditions/preferences had an effect on populations. Rugoconites display aggregation, possibly related to their reproductive methods in combination with settlement location availability at the time of dispersal and/or settlement. Additionally, post-settlement environmental controls could have affected Rugoconites on other surfaces, resulting in lower populations and densities. Both Tribrachidium and Rugoconites also commonly occur as individuals or in low numbers on a number of beds, thus constraining possible reproductive strategies and environmental/substrate preferences. The distribution of Obamus is consistent with selective settlement, aggregating near conspecifics and on substrates of mature microbial mat. This dispersal process is the first example of substrate-selective dispersal among the Ediacara Biota, thus making Obamus similar to numerous modern sessile invertebrates with similar dispersal and settlement strategies. Resumen La distribución espacial de los organismos sésiles in situ, incluyendo los del registro fósil, brinda información sobre las historias de vida, tal como los posibles mecanismos de dispersión y/o asentamiento, y sobre cómo los taxones interactúan entre sí y entre sus entornos locales. En el Parque Nacional Nilpena Ediacara (NENP), Australia Meridional, la excelente preservación y excavación de 33 planos de lecho fosilífero del Miembro Ediacara de la Cuarcita Rawnsley revela comunidades in situ de la biota ediacárica. En este estudio analizamos las distribuciones espaciales de tres taxones relativamente comunes, Tribrachidium, Rugoconites y Obamus, que se encuentran en superficies excavadas mediante el análisis de patrones de puntos espaciales. Tribrachidium tiene una distribución espacial variable, lo que implica que las condiciones/preferencias durante o después del asentamiento tuvieron un efecto en las poblaciones. Rugoconites muestran agregación, posiblemente relacionado con sus métodos reproductivos en combinación con la disponibilidad de lugares de asentamiento en el momento de la dispersión y/o asentamiento. Además, los controles ambientales posteriormente al asentamiento podrían estar afectando a Rugoconites en otras superficies, lo que resultaría en poblaciones y densidades más bajas. Tanto Tribrachidium como Rugoconites ocurren como individuos en varios lechos, restringiendo las posibles estrategias reproductivas y las preferencias ambientales/de sustrato. La distribución de Obamus es consistente con un asentamiento selectivo, agregando cerca de sus congéneres y sobre sustratos de tapete microbiano maduro. Este proceso de dispersión es el primer ejemplo de dispersión selectiva de sustrato entre la biota ediacárica, lo que hace que Obamus sea similar a numerosos invertebrados sésiles modernos con estrategias similares de dispersión y asentamiento.

Phillip C. Boan↗

Oxidation behavior of nickel-chromium-aluminum-yttrium - Magnesium oxide and nickel-chromium-aluminum-yttrium - zirconate type of cermets

The 1100 and 1200 C cyclic oxidation resistance of dense Ni-Cr-Al-Y - MgO, Ni-Cr-Al-Y - CaZrO3, Ni-Cr-Al-Y - SrZrO3, Ni-Cr-Al-Y - MgZro3 cermets and a 70 percent dense Ni-Cr-Al-Y developmental material was determined. The cermets contained 60 and 50 volume percent of Ni-Cr-Al-Y which formed a matrix with the oxide particles imbedded in it. The cermets containing MgO were superior to cermets based on zirconates and to the porous Ni-Cr-Al-Y material.

Zaplatynsky, I.↗

Failure Study of Composite Materials by the Yeh-Stratton Criterion

The newly developed Yeh-Stratton (Y-S) Strength Criterion was used to study the failure of composite materials with central holes and normal cracks. To evaluate the interaction parameters for the Y-S failure theory, it is necessary to perform several biaxial loading tests. However, it is indisputable that the inhomogeneous and anisotropic nature of composite materials have made their own contribution to the complication of the biaxial testing problem. To avoid the difficulties of performing many biaxial tests and still consider the effects of the interaction term in the Y-S Criterion, a simple modification of the Y-S Criterion was developed. The preliminary predictions by the modified Y-S Criterion were relatively conservative compared to the testing data. Thus, the modified Y-S Criterion could be used as a design tool. To further understand the composite failure problem, an investigation of the damage zone in front of the crack tip coupled with the Y-S Criterion is imperative.

Yeh, Hsien-Yang↗

A Simulation of Bromoform's Contribution to Stratospheric Bromine

Many chlorinated and brominated compounds that are inert in the troposphere are destroyed in the stratosphere and act as an in-situ source of stratospheric reactive chlorine and bromine. Other halogenated compounds that are reactive in the troposphere might contribute to the stratosphere's halogen budget in two ways. First, like their unreactive companions, rapid convective transport might carry them to the upper troposphere and make them available for subsequent advection by the mean circulation into the stratosphere before they are oxidized or photolyzed. Second, it is more likely that they are destroyed in the troposphere, and the chlorine and bromine that is released might then be transported to the stratosphere. We evaluate the relative influence of these processes on stratospheric bromine in a three-dimensional chemistry and transport model which simulates the distribution of bromoform (CHBr3). CHBr3 is parameterized as a short-lived, ocean-surface source gas whose destruction by photolysis and reaction with hydroxyl (OH) in the troposphere and stratosphere yields inorganic bromine (Br(sub y)). Many of the observed features of CHBr3 are simulated well, and comparisons with observations are used to show that the model represents aspects of transport in the upper troposphere and lower stratosphere that are critical to the evaluation. In particular, the model maintains the observed troposphere-stratosphere distinctness in transport pathways and reproduces the observed seasonal dependence of the mixture of air in the middle- and high-latitude lowermost stratosphere. We estimate that adding CHBr3 to models which already include the long-lived organic brominated compounds (halons and methyl bromide) will increase the simulated stratospheric mass of Br(sub y) by about 15 percent. In-situ stratospheric destruction of CHBr3 produces Br(sub y) in amounts which are comparable to that transported into the stratosphere after photolysis and oxidation of CHBr3 in the troposphere. In our simulations the mass of Br(sub y) produced from the destruction of CHBr3 does not exceed the mass of Br(sub y) produced from the destruction of the long-lived compounds at any level in the stratosphere. However, Br(sub y) from the loss of CHBr3 accounts for approximately one-third of the total Br(sub y) in the lowest kilometer of the stratosphere.

Nielsen, J. Eric↗

Deoxypyridinoline in the Urine of Rats with Unloaded Hindlimbs

The urinary excretion of deoxypyridinoline (U-Dpd), a nonreducible collagen crosslink in bone released by osteoclastic activity, is thought to be an accurate marker of bone resorption. The role of increased resorption in the osteopenia of a space flight model which unloads the hindlimbs by suspending the tail is controversial. To assess skeletal resorption in the model we measured U-Dpd (Pyrilinks-D, Metro Biosystems, Inc.) in serial 24 hour urine specimens collected from 250 a (Y) and 450 a (M) male rats with unloaded hindlimbs for four weeks. Both groups of rats were fed AIN76 diets with calcium restricted to 0.2% in Y and to 0.1 % in M. Blood was obtained after 28 days for parathyroid hormone (PTH), 1,25-dihydroxyvitamin D (1,25-D) and alkaline phosphatase (Alkptase). Basal U-Dpd was higher and more variable in Y than M (475+/-200 vs 67+/-9, nM/mM creatinine, p<.001). Repeated measures ANOVA in Y revealed decreases in U-Dpd, 36% in control (C) and 24% in unloaded (S) rats (p<.005). There was a nadir in YS on the 14th day not observed in YC (p<.05). U-Dpd in MC showed no change, but increased in MS by the 14th day and remained elevated. At the end of the experiment, body weights in both Y and M were less in S than C (337+/-16 vs 306+/-12g and 485+/-10 vs 461+/-6g, p=.002). Bill was inversely related to U-Dpd only in M (r=0.699, p=.024). PTH, similar in C and S in Y (52+/-15 vs 42+/-7pg/ml, NS) and M (68+/-13 vs 61+/-12, NS), was unrelated to U-Dpd. 1,25-D tended toward higher values in YC than YS (197+/-103 vs 119+/-30, NS) and correlated with U-Dpd (0.773, p=.015). Alkptase, 1.3 times higher in Y than M, was similar in C and S at the end of unloading. These findings indicate that bone resorption, as reflected by U-Dpd, is suppressed in young and stimulated in mature rats exposed to a space flight model. U-Dpd reflects reduced growth from the diet change in young control and experimental rats and loss of Bill in mature animals exposed to the space flight model, 2 situations with opposite effects on bone resorption.

Arnaud, Sara B.↗