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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Towards a Unified Low-Cost Flow Plate, Flow-Field, PTL Solution for Proton Exchange Membrane Electrolyzers

Proton exchange membrane (PEM) water electrolysis is a highly efficient method for hydrogen production. Research cells typically consist of one proton exchange membrane, two catalyst layers, two porous transport layers, two flow-field plates, and two endplates. In commercial systems, the machined flow-field plates that are employed in research cells are typically replaced by stamped parts or open mesh material solutions to reduce manufacturing cost at scale. Nonetheless, the cell contains about 8 total interfaces: bipolar plate / flow plate material / porous transport medium / electrode / membrane / electrode / porous transport medium / flow plate material / bipolar plate. All these materials and interfaces need to be optimized for maximum performance and efficiency. Reducing the amount of interfaces by combining individual cell components directly benefits the fabrication cost (by reducing the parts count and the needs for surface coatings) and the electrochemical performance (by reducing ohmic losses). We have designed a novel PEM electrolysis cell with a piece of channeled titanium felt functioning as both the anode flow-field and the PTL, referred to as the channeled diffusion layer (CDL). The pores of the felt facilitate both in-plane and through-plane diffusion, ensuring maximum catalyst utilization while also minimizing mass transport loss. The titanium felt can be mass manufactured with existing stamping and forming methods and is therefore a promising candidate to reduce the capital cost of PEM electrolyzers whilst improving hydrogen production efficiency. Experiments conducted with 3mg IrOx/cm2 loading MEAs have shown a approximately 40% boost in peak current by implementing the CDL design. Low catalyst-loading MEAs are being tested in ongoing experiments and their results will be discussed and compared.

08 HYDROGEN↗
DOE OSTI2024

NMPC for Mode-Switching Operation of Reversible Solid Oxide Cell Systems

Solid oxide cells (SOCs) are a promising dual-mode technology that generates hydrogen through high-temperature water electrolysis and generates power through a fuel cell reaction that consumes hydrogen. Reversible operation of SOCs requires a transition between these two modes for hydrogen production setpoints as the demand and price of electricity fluctuate. Moreover, a well-functioning control system is important to avoid cell degradation during mode-switching operation. In this work, we apply nonlinear model predictive control (NMPC) to an SOC module and supporting equipment and compare NMPC performance to classical proportional integral (PI) control strategies, while ramping between the modes of hydrogen and power production. While both control methods provide similar performance in many metrics, NMPC significantly reduces cell thermal gradients and curvatures (mixed spatial-temporal partial derivatives) during mode switching. A dynamic process flowsheet of the reversible SOC system was developed in the open-source, equation-based IDAES modeling framework. Our IDAES dynamic simulation results show that NMPC can ramp the SOC system between hydrogen and power production targets within short mode-switching times. Moreover, NMPC can comply with operating limits in the SOC system more effectively than PI, and only NMPC can directly enforce user-specified limits for mixed spatial-temporal partial derivatives of temperature. This allows for management of the trade-off be-tween operating efficiency and cell degradation, which is dependent on these temperature curvatures.

Li, Mingrui↗
NASA NTRS1971

Spacecraft oxygen recovery system

Spacecraft closed loop oxygen recovery system using electrochemical carbon dioxide concentrator, Sabatier reactor and water electrolysis subsystem

Quattrone, P. D.↗
NASA NTRS1972

Atmosphere revitalization in the space station prototype.

The atmosphere revitalization group (ARG) for the space station prototype (SSP) environmental/thermal control and life support system (ETC/LSS) has been designed to meet a comprehensive set of requirements and constraints for a flight type mission. Design definition is for a modular vehicle temperature and humidity control subsystem, contaminant control equipment, a hydrogen depolarized cell CO2 concentrator, a water electrolysis oxygen generation subsystem, CO2 reduction equipment, and a pressure and composition control subsystem. Performance requirements are for support of a crew of six. Realistic leakage rates and metabolic activity cycles, cabin temperature selectability, and controlled cabin relative humidities are specified for the design. Operational aspects of the subsystem are discussed with emphasis given to the influence of a 180-day, maintainable requirement on system design. Consideration of flight vehicle type packaging, in flight maintenance, data management systems interface and fault detection capability, and electrical supply constraints is covered.

Trusch, R. B.↗
NASA NTRS1973

Cost analysis of oxygen recovery systems

Report is made of the cost analysis of four leading oxygen recovery subsystems which include two carbon dioxide reduction subsystems and two water electrolysis subsystems, namely, the solid polymer electrolyte and the circulating KOH electrolyte. The four oxygen recovery systems were quantitatively evaluated. System characteristics, including process flows, performance, and physical characteristics were also analyzed. Additionally, the status of development of each of the systems considered and the required advance technology efforts required to bring conceptual and/or pre-prototype hardware to an operational prototype status were defined. Intimate knowledge of the operations, development status, and capabilities of the systems to meet space mission requirements were found to be essential in establishing the cost estimating relationships for advanced life support systems.

Yakut, M. M.↗
NASA NTRS1973

Cost analysis of oxygen recovery systems

The design and development of equipment for flight use in earth-orbital programs, when optimally approached cost effectively, proceed through the following logical progression: (1) bench testing of breadboard designs, (2) the fabrication and evaluation of prototype equipment, (3) redesign to meet flight-imposed requirements, and (4) qualification and testing of a flight-ready system. Each of these steps is intended to produce the basic design information necessary to progress to the next step. The cost of each step is normally substantially less than that of the following step. An evaluation of the cost elements involved in each of the steps and their impact on total program cost are presented. Cost analyses of four leading oxygen recovery subsystems which include two carbon dioxide reduction subsystem, Sabatier and Bosch, and two water electrolysis subsystems, the solid polymer electrolyte and the circulating KOH electrolyte are described.

Yakut, M. M.↗
NASA NTRS1973

Electrolytic hydrogen fuel production with solid polymer electrolyte technology.

A water electrolysis technology based on a solid polymer electrolyte (SPE) concept is presented for applicability to large-scale hydrogen production in a future energy system. High cell current density operation is selected for the application, and supporting cell test performance data are presented. Demonstrated cell life data are included to support the adaptability of the SPE system to large-size hydrogen generation utility plants as needed for bulk energy storage or transmission. The inherent system advantages of the acid SPE electrolysis technology are explained. System performance predictions are made through the year 2000, along with plant capital and operating cost projections.

Titterington, W. A.↗
NASA NTRS1973

Atmosphere revitalization for manned spacecraft - An assessment of technology readiness

The level of proficiency attained by the most effective physical and chemical regenerative processes capable of providing a habitable atmospheric environment in a spacecraft is assessed. It is shown that both the Sabatier and Bosh reactions are in a mature stage of technological readiness and can effectively reduce the carbon dioxide in a spacecraft. An electrochemical method for concentrating CO2 from an air environment offers promise to approach low levels of pCO2 control. Technological advances in the fields of solid polymer electrolytes and oxygen evolution electrocatalysts have led to a water electrolysis system that can maintain efficient performance for several years. Nitrogen supply and control of the composition of the spacecraft atmosphere is effectively provided by the circulating electrolyte technique.

Samonski, F. H., Jr.↗
NASA NTRS1973

Spacecraft oxygen recovery system

A system which uses an electrochemical carbon dioxide concentrator to remove carbon dioxide from the cabin atmosphere and a Sabatier reactor to reduce carbon dioxide with hydrogen to form methane and water is described. Oxygen is recovered from water by means of a static-feed water electrolysis system. The hydrogen thus generated is reused in the carbon dioxide concentrator. The methane is a system byproduct. The CO2 removal reactions and the implementation of the CO2 concentration concept are discussed, and test results are examined.

Quattrone, P. D.↗
NASA NTRS1975

Cost analysis of life sciences experiments and subsystems

Cost estimates for experiments and subsystems flown in the Spacelab were established. Ten experiments were cost analyzed. Estimated cost varied from $650,000 for the hardware development of the SPE water electrolysis experiment to $78,500,000 for the development and operation of a representative life sciences laboratory program. The cost of subsystems for thermal, atmospheric and trace contaminants control of the Spacelab internal atmosphere was also estimated. Subsystem cost estimates were based on the utilization of existing components developed in previous space programs whenever necessary.

Yakut, M. M.↗
NASA NTRS1975

Evaluation of the electrochemical O2 concentrator as an O2 compressor

A program was successfully completed to analytically and experimentally evaluate the feasibility of using an electrochemical oxygen (O2) concentrator as an O2 compressor. The electrochemical O2 compressor (EOC) compresses 345 kN/sq m (50 psia) O2 generated on board the space vehicle by the water electrolysis subsystem (WES) in a single stage to 20,700 kN/sq m (3000 psia) to refill spent extravehicular equipment O2 bottles and to eliminate the need for high pressure O2 storage. The single cell EOC designed, fabricated, and used for the feasibility testing is capable of being tested at O2 pressures up to 41,400 kN/sq m (6000 psia). A ground support test facility to test the EOC cell was designed, fabricated, and used for the EOC feasibility testing. A product assurance program was established, implemented, and maintained which emphasized safety and materials compatibility associated with high pressure O2 operation. A membrane development program was conducted to develop a membrane for EOC application. Data obtained using a commercially available membrane were used to guide the development of the membranes fabricated specifically for an EOC. A total of 15 membranes were fabricated.

Marshall, R. D.↗
NASA NTRS1974

Status of JPL solar powered experiments for terrestrial applications

Results of an ongoing program set up to evaluate solar terrestrial photovoltaic power sources. The results of this program, which now includes a solar array encapsulant and materials test and a solar-powered buoy study, are updated, and the results of efforts to study the dynamic interaction of a solar photovoltaic array and a water electrolysis system coupled to produce hydrogen are reported for the first time.

Yasui, R. K.↗
NASA NTRS1974

Review of hydrogen accidents and incidents in NASA operations

Safety, as a major factor in the development of a power economy based on hydrogen produced by nuclear- or solar-energy operated water electrolysis, is considered in terms of the safety problems involved in the production, handling, transportation, and use of liquid and gaseous hydrogen. These problems are reviewed through the records of accidents and incidents that have occurred in the development and operation of NASA's propulsion and power systems. Areas of research and development are suggested for increased safety and for the development of techniques to reduce the consequences of any mishaps.

Ordin, P. M.↗
NASA NTRS1975

Hydrogen production from solar energy

Three alternatives for hydrogen production from solar energy have been analyzed on both efficiency and economic grounds. The analysis shows that the alternative using solar energy followed by thermochemical decomposition of water to produce hydrogen is the optimum one. The other schemes considered were the direct conversion of solar energy to electricity by silicon cells and water electrolysis, and the use of solar energy to power a vapor cycle followed by electrical generation and electrolysis. The capital cost of hydrogen via the thermochemical alternative was estimated at $575/kW of hydrogen output or $3.15/million Btu. Although this cost appears high when compared with hydrogen from other primary energy sources or from fossil fuel, environmental and social costs which favor solar energy may prove this scheme feasible in the future.

Eisenstadt, M. M.↗