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At least 397 records · Page 22

LAW Glass Testing by Long-Term PCT to Support Disposal at IDF

About 50 million gallons of high-level mixed waste is currently stored in underground tanks at The United States Department of Energy’s (DOE’s) Hanford site in the State of Washington. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) will provide DOE’s Office of River Protection (ORP) with a means of treating this waste by vitrification for subsequent disposal. The tank waste will be separated into low- and high-activity waste fractions, which will then be vitrified respectively into Immobilized Low Activity Waste (ILAW) and Immobilized High Level Waste (IHLW) products. The ILAW product will be disposed in an engineered facility – the Integrated Disposal Facility (IDF) – on the Hanford site, while the IHLW product is designed for a national deep geological disposal facility for high-level nuclear waste. The ILAW and IHLW products must meet a variety of requirements with respect to protection of the environment before they can be accepted for disposal.

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Stabilization of Spherical Rescorcinol Resin in Grout- Maintenance of the Hanford Integrated Disposal Performance Assessment FY 2018

Operation of the low activity waste vitrification facility (LAW) part of the Waste Treatment and Immobilization Plant (WTP) at Hanford will generate several solid secondary waste (SSW) streams including used process equipment, contaminated tools and instruments, decontamination wastes, highefficiency particulate air filters (HEPA), carbon absorption beds, silver mordenite iodine sorbent beds, and spent ion exchange resins (IXr), all of which are to be disposed of in the Integrated Disposal Facility (IDF). The baseline treatment method in the IDF Performance Assessment (PA) for SSW is solidification/stabilization using cementitious material. The Hanford Mix 5 has been identified as the baseline grout for encapsulation of debris SSW (HEPA filters) and solidification/stabilization of non-debris SSW (carbon absorption beds, silver mordenite iodine sorbent beds, and spent ion exchange resins). Hanford Mix 5 is a blend of ASTM (C150-18) Type I-II cement (OPC), Class F fly ash (FA), water, BASF Pozzolith 80 and BASF Master Fiber M100 (fiber) that is currently used for disposal of debris in carbon steel containers (B25) in Hanford’s 200 West Area Low Level Waste Burial Ground trenches.

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Cesium Ion Exchange Testing Using Crystalline Silicotitanate with Hanford Tank Waste 241-AP-107

The Low-Activity Waste Pretreatment System (LAWPS) provides for the early production of immobilized low-activity waste by feeding Hanford tank supernate from tank farms to the Hanford Tank Waste Treatment and Immobilization Plant (WTP) Low-Activity Waste (LAW) Facility for immobilization. Washington River Protection Solutions requested that Hanford tank waste collected from tank 241-AP-107 (hereafter called AP-107) be processed using conceived pretreatment steps (suspended solids removal by filtration, Cs removal by ion exchange) then vitrified. A small-scale test platform to demonstrate the solids filtration, Cs removal, and LAW vitrification was constructed and installed at the Pacific Northwest National Laboratory. Bench-scale ion exchange testing with approximately 9 L of AP-107 supernate was conducted using crystalline silicotitanate (CST) ion exchange media. The IONSIV R9140-B CST was provided by Honeywell UOP, LLC in 2018 (Batch 2081000057). The ion exchange media was first tested with simulant and was previously described. This report describes the Cs ion exchange batch contact and column test results with the AP-107 tank waste.

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FY2017 ILAW Glass SPFT Testing for Disposal at IDF: Glass IDF21-EC14

About 50 million gallons of high-level mixed waste is currently stored in underground tanks at The United States Department of Energy’s (DOE’s) Hanford site in the State of Washington. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) will provide DOE’s Office of River Protection (ORP) with a means of treating this waste by vitrification for subsequent disposal. The tank waste will be separated into low- and high-activity waste fractions, which will then be vitrified respectively into Immobilized Low Activity Waste (ILAW) and Immobilized High Level Waste (IHLW) products. The ILAW product will be disposed in an engineered facility – the Integrated Disposal Facility (IDF) – on the Hanford site, while the IHLW product is designed for deep geological disposal in a national facility for high level nuclear waste. The ILAW and IHLW products must meet a variety of requirements with respect to protection of the environment before they can be accepted for disposal. The objective of the work described in this report is to perform testing, data collection, and analyses for the ILAW glass product for subsequent use in the performance assessment (PA) of the IDF to assess potential environmental risks associated with long-term storage.

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LAW Glass Testing by Long-Term PCT to Support Disposal at IDF

About 50 million gallons of high-level mixed waste is currently stored in underground tanks at The United States Department of Energy’s (DOE’s) Hanford site in the State of Washington. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) will provide DOE’s Office of River Protection (ORP) with a means of treating this waste by vitrification for subsequent disposal. The tank waste will be separated into low- and high-activity waste fractions, which will then be vitrified respectively into Immobilized Low Activity Waste (ILAW) and Immobilized High Level Waste (IHLW) products. The ILAW product will be disposed in an engineered facility – the Integrated Disposal Facility (IDF) – on the Hanford site, while the IHLW product is designed for a national deep geological disposal facility for high level nuclear waste. The ILAW and IHLW products must meet a variety of requirements with respect to protection of the environment before they can be accepted for disposal.

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WTP/Evaporator Transfer System Hydraulic Analysis

The purpose of this calculation is to determine containment piping flow rates for the 242-A Evaporator and Waste Treatment Facility (WTP) Condensate Transfer to the Liquid Effluent Retention Facility (LERF) Basin Transfer System for a 24-hour time limit.

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A Critical Review of Ion Exchange in Nuclear Waste Glasses to Support the Immobilized Low-Activity Waste Integrated Disposal Facility Rate Model

There are over 50 million gallons of waste in underground tanks at the Hanford site in Washington State which was generated as a byproduct of nuclear materials fabrication for United States strategic defensive purposes. The waste, also known as high-level waste (HLW), is comprised of both radioactive and non-radioactive contaminants. To deal with the tank waste, the United States Department of Energy (DOE) plans to separate out the liquid, or supernatant, and salt-cake portions and treat them as low-activity waste (LAW). The LAW and HLW will be vitrified in separate facilities at the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The LAW will be disposed of at the on-site Integrated Disposal Facility (IDF). The main species of concern in the immobilized low-activity waste (ILAW) include 99 Tc, 129 I, and U and other non-radioactive contaminants. Ultimately, it must be demonstrated that the contaminants released from the waste form pose minimal risk to humans and the environment. To aid in this demonstration, work is currently being done to expand the understanding of long-term glass waste form behavior, especially with regards to exposure to aqueous environments.

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FY2018 ILAW Glass SPFT Testing for Disposal at IDF: Glasses ORLEC46 and ORLEC52 (Final Report, Rev. 0)

About 50 million gallons of high-level mixed waste is currently stored in underground tanks at The United States Department of Energy’s (DOE’s) Hanford site in the State of Washington. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) will provide DOE’s Office of River Protection (ORP) with a means of treating this waste by vitrification for subsequent disposal. The tank waste will be separated into low- and high-activity waste fractions, which will then be vitrified respectively into Immobilized Low Activity Waste (ILAW) and Immobilized High Level Waste (IHLW) products. The ILAW product will be disposed in an engineered facility – the Integrated Disposal Facility (IDF) – on the Hanford site, while the IHLW product is designed for deep geological disposal in a national facility for high level nuclear waste. The ILAW and IHLW products must meet a variety of requirements with respect to protection of the environment before they can be accepted for disposal. The objective of the work described in this report is to perform testing, data collection, and analyses for the ILAW glass product for subsequent use in the performance assessment (PA) of the IDF to assess potential environmental risks associated with long-term storage.

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FY2018 Long-Term PCT of ILAW Glasses (Final Report, Rev. 0)

About 50 million gallons of high-level mixed waste is currently stored in underground tanks at The United States Department of Energy’s (DOE’s) Hanford site in the State of Washington. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) will provide DOE’s Office of River Protection (ORP) with a means of treating this waste by vitrification for subsequent disposal. The tank waste will be separated into low- and high-activity waste fractions, which will then be vitrified respectively into Immobilized Low Activity Waste (ILAW) and Immobilized High Level Waste (IHLW) products. The objective of the work described in this report is to perform testing, data collection, and analyses for the ILAW glass product to assess potential environmental risks associated with long-term storage.

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Improved High-Alkali Low-Activity Waste Formulations (Final Report, Rev. 0)

High waste loading LAW glass formulations developed for ORP by VSL and EnergySolutions contain about 0.5 wt% Cr 2 O 3 as an additive to control K-3 refractory corrosion by the glass. However, addition of Cr 2 O 3 also increases the tendency for formation of sulfate/chromate secondary phases and therefore such additions become increasingly undesirable as the ratio of sulfate to sodium in the LAW stream increases. Therefore, for such LAW streams, removal of Cr 2 O 3 as an additive could potentially increase sulfate loading in the LAW glasses, provided that K-3 refractory corrosion can be controlled by other means. The present work was directed towards developing LAW glasses with high alkali concentrations (> 24 wt%) without the use of Cr 2 O 3 as an additive. The results of the work clearly show that LAW glasses with high alkali concentrations that meet all of the WTP requirements, including K-3 refractory corrosion, can be formulated without the use of Cr 2 O 3 as an additive.

Muller, Isabelle S.↗

Screening of Additional Candidate Low-Temperature Glasses for Technetium Recovered from Hanford Effluent Management Facility Evaporator Bottoms

In this annex to a previously reported study, a series of laboratory screening tests was conducted to identify low-temperature glasses that have significant potential for use in disposition of technetium from a Hanford Tank Waste Treatment & Immobilization Plant (WTP) secondary liquid waste stream. Specifically, a glass waste form is sought that would be suitable for on-site disposition of technetium, salts, and other species in a Tc-rich stream recovered by ion exchange from the future Effluent Management Facility (EMF) evaporator concentrate. In the current study, several additional candidate glasses were identified, and testing of previous candidates was extended to include the Toxicity Characteristic Leaching Procedure (TCLP). In non-radioactive testing with rhenium surrogate, new formulations incorporated a simulated ion exchange eluate at temperatures below 750 °C to produce an amorphous, or mixed crystalline-amorphous, product. Incorporation of technetium (NaTcO 4 )-containing simulated eluate was evaluated for two of these glasses. Technetium was not retained well in these glasses, confounding the previous conclusion that Tc volatilization during vitrification can be reduced by appropriate selection of low-temperature glasses. Preliminary data for additional low-temperature glass compositions and recommendations for future work are provided. This report is a deliverable associated with requisition 55068-004-03 NFE-17-0020 "Candidate Low-T Glass Waste Forms for EMF Bottoms On-Site Disposition Alternative."

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LAW Simulant Recipes for Evaluation of Real-Time, In-Line Monitoring Instruments

Statistically designed recipes were generated for evaluation of in-line instrumentation for the Real-Time In-Line Monitoring (RTIM) program in support of the Hanford Direct-Feed Low Activity Waste (DFLAW) program. The composition matrices were prepared based on Low Activity Waste (LAW) feed vector, melter feed, and Effluent Management Facility (EMF) feed information provided by the flowsheet integration modelling for the DFLAW portion of the Waste Treatment Plant (WTP) mission. These composition matrices were converted to recipes for the LAW feed using the approaches for LAW simulant recipes developed by Savannah River National Laboratory (SRNL). Recipes for the glass forming chemicals (GFCs) were developed based on expected mineral forms to be used to for each element to be added to the recipe. The recipe matrices are shown in the Appendix.

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Enhanced Hanford Low-Activity Waste Glass Property Data Development (Phase 3)

This work was performed for the U.S. Department of Energy (DOE) Office of River Protection (ORP) to provide expert evaluation and experimental work in support of the River Protection Project vitrification technology development1. The long-term objective of this work is to expand the property-composition database for Hanford site low-activity waste (LAW) glasses and property-composition models to cover the balance of the mission for the Hanford Waste Treatment and Immobilization Plant (WTP). When this effort is complete, enhanced LAW glass property-composition models will be developed.

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IER-519 CED-2: Final Design for Thermal/Epithermal eXperiments (TEX) with Absorbers to Provide Validation Benchmarks for Hanford Tank Farms

The Hanford tank farms contain 56 million gallons of waste across 177 tanks. The primary criticality safety concern for the waste is the plutonium inventory in waste solids – approximately 670 kg in total. Criticality safety analysis credits the absorption and dilution properties of the large quantities of other elements (aluminum, chromium, iron, manganese, nickel, silicon, sodium, and zirconium) present in the waste. Of these, iron and manganese are by far the most significant neutron absorbers, particularly for the waste compositions of highest criticality safety concern. The criticality safety analyses at the Hanford Waste Treatment and Vitrification Plant (WTP) and the Savannah River tank farms also credit iron and manganese as the primary neutron absorbers to demonstrate subcriticality.

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Spent Crystalline Silicotitanate Storage Study—Post AP-105DF Processing

A Tank-Side Cesium Removal (TSCR) system is under development by Washington River Protection Solutions to support initial production of immobilized low-activity waste (LAW) by feeding Hanford tank supernate from tank farms to the Hanford Waste Treatment and Immobilization Plant (WTP) LAW Facility. Tank waste supernate is filtered to remove suspended solids and then Cs is removed by processing it through crystalline silicotitanate (CST) ion exchange media manufactured by Honeywell UOP, LLC. The Cs-loaded CST columns will be stored indefinitely, with a goal of eventual CST removal and treatment. Thus, the spent CST needs to be recoverable after undetermined storage time. Previous testing with AP-105 simulant showed that rinsing the CST bed with 3 bed volumes (1.4 apparatus volumes [AVs]) of 0.1 M NaOH resulted in a dried bed that maintained flow characteristics indicative of ease of recovery. This study explored the intermediate conditions (between feed dried in place and the 1.4 AVs of 0.1 M NaOH rinse) to evaluate CST bed properties.

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Hanford Supplemental Low Activity Waste Simulant Evaporation Testing for Removal of Organics

The Hanford site has approximately 56 million gallons of radioactive waste stored in 177 underground storage tanks. The Hanford Waste Treatment and Immobilization Plant (WTP) is being built to treat and immobilize the tank waste. The baseline method for immobilization of Low Activity Waste (LAW) is vitrification, but additional immobilization capacity is likely needed to supplement the initial melters. An alternative cementitious waste form is being investigated for that future supplemental immobilization method. However, one impediment to a cementitious waste form is the presence of Land Disposal Restricted (LDR) organic chemicals in tank waste. Developing a method to remove the organics would eliminate that impediment to permit possible use of a cementitious waste form. Savannah River National Laboratory (SRNL) performed testing to examine evaporation as a method to remove some prevalent organics from the Supplemental LAW (SLAW) stream. Samples of product streams from the evaporation were analyzed to determine partitioning of the organics. Modeling was also performed to determine if the experimental and modeling results matched. A description of the experimental details, equipment, and results of that testing are included in this report.The work is intended to inform future SLAW flowsheet development activities and gather useful data about the partitioning of constituents through a possible SLAW feed evaporator.

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Transfer and Flushing Evaluation for Potential Precipitated Solids in the 241-AP-106 to EMF Transfer Pipeline for DFLAW

Waste transfer pipeline flushing is necessary to maintain pipeline performance, but added flush fluid increases the nuclear waste inventory. During the Direct Feed Low-Activity Waste (DFLAW) mission, waste transfer lines from the Interim Low-Activity Waste Storage Tank (i.e., 241-AP-106) to the Hanford Waste Treatment and Immobilization Plant (WTP) Low-Activity Waste (LAW) Facility must have the capability of being flushed to prevent accumulation of solids and to mitigate corrosion concerns. Operational experience at Hanford has shown that the solids precipitation occurs during processing operations from dilute Hanford liquids. Pacific Northwest National Laboratory was requested to evaluate the potential precipitated solid particle transport and flushing operational capabilities of the AP-106 through the Effluent Management Facility (EMF) low-point drain LAW feed pipeline. The evaluation results do not provide operational requirements, but rather provide a scoping basis for understanding the potential operational significance of solids precipitation in the pipeline. The salt and aluminum phase solids most likely to precipitate from the LAW feeds during cooling, evaporation, or mixing have particle densities that are estimated to range from 1.62 to 2.78 g/mL and a spherical particle size range of 8 to 2100 μm, depending on the solid phase considered. Application of the method to calculate the critical deposition velocity required by TFC-ENG-STD-26 at conservatively bounding estimates for the solids concentrations demonstrates that potentially precipitated solids may deposit on the bottom of the transfer pipe invert at the lower LAW feed pipeline flow rate, but the upper LAW feed pipeline flow rate will likely prevent deposition. The system pressure limit for the AP-106 through the EMF low-point drain LAW feed pipeline likely exceeds any pressure loss at a calculated critical deposition velocity even for the most adverse potential precipitated solid. However, should solids settle as a result of no-flow conditions, the flow capabilities of the AP-106 through the EMF low-point drain LAW feed pipeline are shown, based on the available literature, to be potentially inadequate for effective flushing operations to remove solids, even at solids concentrations below the maximum specified for LAW feed. Thus, stepwise solids accumulations over multiple transfers may be an issue, and eventual line plugging may occur. Further inadequacies may potentially be realized should the cohesive nature of certain precipitates be accounted for.

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Glass Compositions and Properties of Enhanced Waste Glass with High Alumina Content for High-Level Waste

This report documents the work performed to collect critical property data on high-level waste (HLW) glasses with high alumina content. This report covers the experimental results of thermal, physical, chemical, and electrical properties of 46 high alumina (15 to 30 wt%) borosilicate waste-glass compositions with one duplicate for a total of 47 glasses. These experimental results are essential for developing property-composition models for the future operation of the Waste Treatment and Immobilization Plant (WTP) currently under construction at the Hanford Site in Richland, Washington. Pacific Northwest National Laboratory (PNNL) was requested by the U.S. Department of Energy’s Office of River Protection to provide expert evaluation and experimental work in support of the vitrification technology development program.

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