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At least 397 records · Page 22

Advances in cryogenic foam insulations.

Description of a discretely oriented thread-reinforced polyurethane foam thermal insulation system for liquid hydrogen fuel tanks. The 3-D foam and glass liner composite is designed to be adhesively bonded to the inside surface of the tank wall and to be in direct contact with liquid hydrogen. All elements of this insulation composite are capable of sustaining the loads and environmental conditions imposed by testing under simulated Space Shuttle vehicle requirements at temperatures between -423 and +350 F.

Lemons, C. R.↗

Advanced Cryogenic Insulation Systems

New materials in recent decades have enabled advances in thermal insulation systems for storage and transfer of cryogens. To preserve the cold and achieve efficient cryogenic systems, a combination of materials, testing, and engineering is required. The total heat leak into any cryogenic assembly is comprised of three main parts: 1) heat leak through the insulation, 2) heat leak through the support structures, and 3) heat leak attributed to piping penetrations and feedthroughs (and their negative effects on the insulation). This "cold triangle" approach provides a basis for evaluating performance benefits of new materials and analyzing the cost effectiveness in overall system design. Provided are thermophysical data for aerogels, aerogel composites, novel multilayered composites, and glass bubbles for standard test conditions of 293 K and 78 K under conditions from high vacuum to ambient pressure. Examples of cryogenic storage tanks show the relative importance of both insulation and structural materials for achieving designs of highest energy efficiency.

Multilayer Insulation↗

Enhancing building energy performance by effectively using phase change material and dynamic insulation in walls

Deploying phase change materials (PCMs) in building envelopes can be efficacious in reducing space heating/cooling loads and providing load shedding and shifting capacity. However, the full potential of PCM-integrated envelopes can only be harnessed if the PCM undergoes phase change using free ambient heating/cooling, and the stored energy is effectively transferred between the exterior and the interior environments. Traditional thermal insulation (with a fixed thermal resistance) limits PCM utilization, which restrains the energy saving potential of a PCM-integrated envelope to a small percentage. Proposed dynamic insulation material and system (DIMS) provides the option of varying its thermal resistance based on the indoor and outdoor conditions. Although it has been established that employing PCM as well as DIMS in building envelopes separately improves buildings’ energy performance, no prior studies that analyzed the combined influence of both technologies were identified. In this study, we examine a novel wall design, comprising a layer of PCM between two layers of DIMS. We note that the PCM-DIMS-integrated wall provides significantly higher energy saving potential than the DIMS-only integrated wall or the PCM-only integrated wall in all the climates and wall orientations analyzed in this study. Depending on the climate, the PCM-DIMS-integrated wall could provide 15–72% reduction in annual heat gain and 7–38% reduction in annual heat loss. The analysis presented in this study supports the need to develop scalable dynamic insulations combined with thermal energy storage systems for buildings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Green co-solvent-assisted one-pot synthesis of high-performance flexible lignin polyurethane foam

Although lignin is a promising candidate as a source of polyol for producing eco-friendly polyurethane foam (PUF), its direct application has limitations, primarily stemming from the brittleness of the resulting products and poor processibility at high lignin loadings. To address these technical challenges, we introduced an effective co-solvent for the lignin-based polyurethane foams (LPUFs) with up to 80wt% of lignin substitution for petroleum polyols. As a green co-solvent that involves carbon dioxide fixation during its production, propylene carbonate (PC), was blended with lignin and improved the distribution of lignin by decreasing the viscosity, providing a room-temperature reaction. The LPUFs demonstrated a comparable thermal insulation performance (R-values greater than 5 in -1 ) with commercially available PUF with a uniform size of closed-cell structure induced by the reduced viscosity of lignin-based polyol. LPUFs also showed enhanced fire retardancy and moisture resistance compared to the control PUFs, benefiting from lignin’s intrinsic fire-resistant and hydrophobic properties. To mitigate the brittleness issue at high lignin loadings, flexible polyethylene glycols (PEGs) with a high molecular weight (i.e., PEG-1000) were dissolved in PC at room temperature to further improve the mechanical strength of LPUFs. The compressive strength of LPUFs with 80 wt% lignin substitution content was remarkably improved to 226 kPa by the employment of co-solvent and PEG-1000 compared to the control PUF (<140 kPa). Moreover, the flexibility of the LPUFs was successfully controlled by simply adjusting the PEG-400/PEG-1000 ratio. In conclusion, the results of this study provide valuable insights for accelerating and broadening the utilization of lignin in sustainable materials and manufacturing areas.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Heat transport with a twist

Despite the desirability of polymers for use in many products due to their flexibility, light weight, and durability, their status as thermal insulators has precluded their use in applications where thermal conductors are required. However, recent results suggest that the thermal conductance of polymers can be enhanced and that their heat transport behaviors may be highly sensitive to nanoscale control. Here we use non-equilibrium molecular dynamics simulations to study the effect of mechanical twist on the steady-state thermal conductance across multi-stranded polyethylene wires. We find that a highly twisted double-helical polyethylene wire can display a thermal conductance up to three times that of its untwisted form, an effect which can be attributed to a structural transition in the strands of the double helix. We also find that in thicker wires composed of many parallel strands, adding just one twist can increase its thermal conductance by over 30%. However, we find that unlike stretching a polymer wire, which causes a monotonic increase in thermal conductance, the effect of twist is highly non-monotonic, and certain amounts of twist can actually decrease the thermal conductance. Finally, we apply the Continuous Chirality Measure (CCM) in an attempt to explore the correlation between heat conductance and chirality. The CCM is found to correlate with twist as expected, but we attribute the observed heat transport behaviors to structural factors other than chirality.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Zero Boiloff Storage of Cryogenic Propellants Achieved at Lewis' Supplemental Multilayer Insulation Research Facility

Tests conducted at the NASA Lewis Research Center's Supplemental Multilayer Insulation Research Facility (SMIRF) demonstrated that a hybrid thermal control system could eliminate boiloff of cryogenic propellants. This is significant because of the substantial mass and cost savings that could be achieved for any long-duration space mission that requires cryogenic propellants. With long-duration cryogenic storage, propellants will boil off because of the environmental heating of the tank. To accommodate these losses, extra propellant is required along with larger propellant tanks. Analysis of Mars mission scenarios using space-transfer cryogenic stages showed that significant savings in propellant mass and tank size could be achieved if it were possible to eliminate or significantly reduce propellant boiloff. Engineers and technicians at NASA Lewis designed, built, and tested a hybrid thermal control system to eliminate or significantly reduce cryogenic propellant boiloff. The system consists of an active cryocooling system using a cryocooler in addition to the traditional passive thermal insulation, as shown in the photo.

Plachta, David W.↗

Wrapped Multilayer Insulation

New NASA vehicles, such as Earth Departure Stage (EDS), Orion, landers, and orbiting fuel depots, need improved cryogenic propellant transfer and storage for long-duration missions. Current cryogen feed line multilayer insulation (MLI) performance is 10 times worse per area than tank MLI insulation. During each launch, cryogenic piping loses approximately 150,000 gallons (equivalent to $300,000) in boil-off during transfer, chill down, and ground hold. Quest Product Development Corp., teaming with Ball Aerospace, developed an innovative advanced insulation system, Wrapped MLI (wMLI), to provide improved thermal insulation for cryogenic feed lines. wMLI is high-performance multilayer insulation designed for cryogenic piping. It uses Quest's innovative discrete-spacer technology to control layer spacing/ density and reduce heat leak. The Phase I project successfully designed, built, and tested a wMLI prototype with a measured heat leak 3.6X lower than spiral-wrapped conventional MLI widely used for piping insulation. A wMLI prototype had a heat leak of 7.3 W/sq m, or 27 percent of the heat leak of conventional MLI (26.7 W/sq m). The Phase II project is further developing wMLI technology with custom, molded polymer spacers and advancing the product toward commercialization via a rigorous testing program, including developing advanced vacuuminsulated pipe for ground support equipment.

Dye, Scott A.↗

Wrapped Multilayer Insulation

New NASA vehicles, such as Earth Departure Stage (EDS), Orion, landers, and orbiting fuel depots, need improved cryogenic propellant transfer and storage for long-duration missions. Current cryogen feed line multilayer insulation (MLI) performance is 10 times worse per area than tank MLI insulation. During each launch, cryogenic piping loses approximately 150,000 gallons (equivalent to $300,000) in boil-off during transfer, chill down, and ground hold. Quest Product Development Corp., teaming with Ball Aerospace, developed an innovative advanced insulation system, Wrapped MLI (wMLI), to provide improved thermal insulation for cryogenic feed lines. wMLI is high-performance multilayer insulation designed for cryogenic piping. It uses Quest's innovative discrete-spacer technology to control layer spacing/ density and reduce heat leak. The Phase I project successfully designed, built, and tested a wMLI prototype with a measured heat leak 3.6X lower than spiral-wrapped conventional MLI widely used for piping insulation. A wMLI prototype had a heat leak of 7.3 W/m2, or 27 percent of the heat leak of conventional MLI (26.7 W/m2). The Phase II project is further developing wMLI technology with custom, molded polymer spacers and advancing the product toward commercialization via a rigorous testing program, including developing advanced vacuuminsulated pipe for ground support equipment.

Dye, Scott A.↗

High temperature insulation for reradiative TPS.

This paper presents the results of a program to evaluate thermal insulations for use under the radiative TPS of a shuttle orbiter vehicle. Evaluations were made for survival under the multimission requirements of shuttle acoustic/vibration loads and thermal profiles. During the first year of the program a total of 1100 specimen-cycles were completed using metal foil packaged refractory fiber insulations.

Hughes, T. A.↗

Insulation-Testing Cryostat With Lifting Mechanism

The figure depicts selected aspects of an apparatus for testing thermal-insulation materials for cryogenic systems at temperatures and under vacuum or atmospheric conditions representative of those encountered in use. This apparatus, called "Cryostat-100," is based on the established cryogen-boil-off calorimeter method, according to which the amount of heat that passes through an insulation specimen to a cryogenic fluid in a container, and thus the effective thermal conductance of the specimen, is taken to be proportional to the amount of the cryogenic fluid that boils off from the container. The design of Cryostat-100 is based partly on, and incorporates improvements over, the design of a similar prior apparatus called "Cryostat-1" described in "Improved Methods of Testing Cryogenic Insulation Materials" (KSC-12107 & KSC- 12108), NASA Tech Briefs, Vol. 24, No. 12 (December 2000), page 46. The design of Cryostat-100 also incorporates the best features of two other similar prior apparatuses called "Cryostat-2" (also described in the cited prior article) and "Cryostat- 4." Notable among the improvements in Cryostat-100 is the addition of a lifting mechanism that enables safe, rapid, reliable insertion and removal of insulation specimens and facilitates maintenance operations that involve lifting. As in Cryostat-1, the cold mass is a vertical stainless-steel cylindrical vessel subdivided into a larger measurement vessel with smaller thermal-guard vessels at both ends. During operation, all three vessels are kept filled with liquid nitrogen near saturation at ambient pressure (temperature .77.4 K). The cold mass of Cryostat-100 has a length of 1 m and diameter of 168 mm. Each specimen has a corresponding nominal length and inner diameter and a nominal thickness of 25.4 mm. Specimens that are shorter and have thicknesses between 0 and 50 mm are also acceptable. Bulk-fill, foam, clam-shell, multilayer insulation, and layered materials can be tested over a very wide range of thermal transmission: apparent thermal conductivity from 0.01 to 60 mW/m-K and heat flux from 0.1 to 500 W/sq m. A test in Cryostat-100 can be conducted at any desired gas pressure between ambient atmospheric pressure at one extreme and a vacuum with residual pressure <10(exp -5) torr (<1.33 10(exp -3) Pa) at the other extreme. The residual gas (and purge gas) is typically nitrogen, but can be any suitable purge gas (e.g., helium, argon, or carbon dioxide). Usually, the temperature on the warm boundary of the insulation specimen is maintained near the ambient value (approximately 293 K), while the boiling of liquid nitrogen at atmospheric pressure in the cold mass maintains the temperature on the cold boundary of the specimen at approximately 77 K.

Fesmire, James↗

Using Models to Predict the Hygrothermal Performance of Equipment and Piping Insulation

The development of hygrothermal models began in earnest in the 1990s, with the initial emphasis on the performance of building envelope systems. Numerous large-scale building envelope failures associated with water intrusion drove this development. The physical principles of moisture transfer that apply to building envelopes are equally valid for equipment and piping insulation systems. The main advantage of modeling is that carefully characterized models can predict the long-term hygrothermal performance of any system under different climatic and interior conditions. Thermal insulations are commonly used on outdoor equipment and piping for different applications, such as thermal energy conservation and freeze protection. The insulated equipment usually experiences moisture intrusion due to many factors, such as the duration and frequency of moisture exposure, equipment operating temperature, insulation type, exposure temperature, weather conditions, equipment thermal cycling, and weatherproofing condition. Hygrothermal models have been employed to estimate the moisture pickup of insulated equipment and piping systems, as well as the moisture redistribution and subsequent change in thermal performance as these systems become contaminated with moisture. The hygrothermal model provides insights on the parameters influencing the time of wetness, the lateral redistribution of moisture along the pipe away from the leak, and the ease by which water escapes the insulation/jacketing systems. It has been shown that the moisture leak effect decreases rapidly with distance from the leak and that one- and two-dimensional hygrothermal simulations help to identify solutions to reduce conditions that support corrosion under insulation (CUI).

Shrestha, Som↗

An analytical comparison of the efficiency of solar thermal collector arrays with and without external manifolds

An analytical comparison of the efficiency of solar thermal collector arrays with and without external manifolds is reported. A FORTRAN computer program was written for the computation of the thermal performance of solar thermal collector arrays with and without external manifolds. Arrays constructed from two example solar thermal collectors are computated. Typical external manifold sizes and thermal insulations are presented graphically and are compared with the thermal performance of the collector alone.

Source record↗

Self-pressurization of a flightweight liquid hydrogen storage tank subjected to low heat flux

Results are presented for an experimental investigation of self-pressurization and thermal stratification of a 4.89 cu m liquid hydrogen (LH2) storage tank subjected to low heat flux (0.35, 2.0, and 3.5 W/sq m) under normal gravity conditions. Tests were performed at fill levels of 83 to 84 percent (by volume). The LH2 tank was representative of future spacecraft tankage, having a low mass-to-volume ratio and high performance multilayer thermal insulation. Results show that the pressure rise rate and thermal stratification increase with increasing heat flux. At the lowest heat flux, the pressure rise rate is comparable to the homogenous rate, while at the highest heat flux, the rate is more than three times the homogeneous rate. It was found that initial conditions have a significant impact on the initial pressure rise rate. The quasi-steady pressure rise rates are nearly independent of the initial condition after an initial transient period has passed.

Hasan, M. M.↗

Thermal Barrier Coatings

In order to reduce heat transfer between a hot gas heat source and a metallic engine component, a thermal insulating layer of material is placed between them. This thermal barrier coating is applied by plasma spray processing the thin films. The coating has been successfully employed in aerospace applications for many years. Lewis Research Center, a leader in the development engine components coating technology, has assisted Caterpillar, Inc. in applying ceramic thermal barrier coatings on engines. Because these large engines use heavy fuels containing vanadium, engine valve life is sharply decreased. The barrier coating controls temperatures, extends valve life and reduces operating cost. Additional applications are currently under development.

Source record↗

Wire-Arc Spraying Of Metal Onto Insulating Foam

Wire-arc spraying used to deposit protective metallic coats on thermally insulating foams. Process relatively fast and cheap, and does not damage foam or involve toxic and polluting chemicals.

Bonds, James W., Jr.↗

Analysis of outgassing from natural fibers VIP core to improve their long-term performance

Buildings are the largest consumers of energy accounting for 40% of the total energy use in the US. The use of vacuum insulation panels (VIPs) with large R/in. values offers unique benefits in reducing building energy consumption such as providing excellent thermal insulation with significantly less thickness compared to convention insulation materials. Natural fibers are promising VIP core material because of their low cost and offer good thermal performance. However, the long-term thermal performance of the VIPs with natural fiber core can be compromised because of off-gassing from natural fibers. In this study, we utilize a mass spectrometer based analytical technique to investigate the composition of off-gassing from natural fibers. The result can be used to determine the optimal getters to help maintain the vacuum and improve the long-term thermal performance of the VIP for building insulation.

Tamraparni, Achutha [ORNL] (ORCID:0000000299658544↗

Snow thermal conductivity and conductive flux in the Central Arctic: Estimates from observations and implications for models

During the Arctic winter, the conductive heat flux through the sea ice and snow balances the radiative and turbulent heat fluxes at the surface. Snow on sea ice is a thermal insulator that reduces the magnitude of the conductive flux. The thermal conductivity of snow, that is, how readily energy is conducted, is known to vary significantly in time and space from observations, but most forecast and climate models use a constant value. This work begins with a demonstration of the importance of snow thermal conductivity in a regional coupled forecast model. Varying snow thermal conductivity impacts the magnitudes of all surface fluxes, not just conduction, and their responses to atmospheric forcing. Given the importance of snow thermal conductivity in models, we use observations from sea ice mass balance buoys installed during the Multidisciplinary drifting Observatory for the Study of Arctic Climate expedition to derive the profiles of thermal conductivity, density, and conductive flux. From 13 sites, median snow thermal conductivity ranges from 0.33 W m −1 K −1 to 0.47 W m −1 K −1 with a median from all data of 0.39 W m −1 K −1 from October to February. In terms of surface energy budget closure, estimated conductive fluxes are generally smaller than the net atmospheric flux by as much as 20 W m −2 , but the average residual during winter is −6 W m −2 , which is within the uncertainties. The spatial variability of conductive heat flux is highest during clear and cold time periods. Higher surface temperature, which often occurs during cloudy conditions, and thicker snowpacks reduce temporal and spatial variability. These relationships are compared between observations and the coupled forecast model, emphasizing both the importance and challenge of describing thermodynamic parameters of snow cover for modeling the Arctic as a coupled system.

54 ENVIRONMENTAL SCIENCES↗