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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Kinetics of the reaction O + ClO yields Cl + O2

The kinetics of the reaction O + ClO yields Cl + O2 (k1) were studied by using resonance fluorescence to monitor the decay of O atoms which had been generated from the laser photolysis of ClO. A discharge flow system was used to generate the ClO and its concentration was measured directly by multipass absorption spectrometry. The results are k1(298) = (4.2 + or -0.8) x 10 to the -11th cu cm/s (including systematic errors) with E/R determined to lie in the range + or - 200 K. The literature data are reviewed and a composite value of k1(T) = 6.0 x 10 to the -11th exp-(100/T) is recommended for stratospheric modeling calculations. The atmospheric implications of the revised rate constant are discussed briefly.

Margitan, J. J.↗
NASA NTRS1984

The first orbiting astronomical infrared telescope system Its development and performance

The Infrared Astronomical Satellite (IRAS) was launched on January 25, 1983, and has provided astronomers with their first extended views of the universe in the 8 to 120 micron wavelength region. The infrared telescope system is one of several United States contributions to this international project sponsored by the U.S.A., The Netherlands, and the U.K. This telescope employs four bands of detectors cooled to 2.4 K to achieve a noise equivalent flux density in the 10 to the -18th to 10 to the -19th watts/sq cm range and will operate for approximately eleven months before depletion of its supply of superfluid helium. This paper describes major problems, early flight results, and technical lessons learned during the course of the telescope's development and flight operations.

Conrad, A. G.↗
NASA NTRS1985

The lithium isotope ratio in five F or G dwarfs

Observations of the 6707-A LiI doublet obtained at high resolution and photometric precision are reported for two F dwarfs and three G dwarfs known to have narrow lines and strong 6707-A absorption. Adjacent lines of Ca 1 and Fe 1 are used to predetermine accurately the position and the broadening of theoretical LiI profiles fitted to the observed ones, leaving the abundances of Li-6 and Li-7 as the only adjustable parameters of the calculated profiles. Upper limits R = (Li-6)/(Li-7) less than 0.1 are obtained for four of the stars, while R is less than about 0.1 for Xi UMa A. The total Li/H abundances range from 3 x 10 to the -10th to 10 x 10 to the -10th, with uncertainties probably not exceeding a factor of 2.

Hobbs, L. M.↗
NASA NTRS1985

Pioneer 10 search for gravitational waves - Limits on a possible isotropic cosmic background of radiation in the microhertz region

The nature of the response of the Doppler tracking system to a stochastic background of gravitational radiation is discussed. Using data acquired in 1981 by the Deep Space Network with the Pioneer 10 spacecraft, interesting upper limits are placed on the energy density of the background in three frequency bands extending from 7 x 10 to the -7th to 10 to the -4th Hz, a region that has been inaccessible previously by any technique.

Anderson, J. D.↗
NASA NTRS1985

Photodissociation rates of OH, OD, and CN by the interstellar radiation field

The photoabsorption cross sections for OH, OD, and CN in the vacuum ultraviolet region are measured. The cross sections for the hydroxyl radicals are of the order of 10 to the -17th sq cm, but the photoabsorption for CN is so low that only an upper limit of 2 x 10 to the -18th sq cm is obtained. The molecular photodissociative processes are discussed. The photodissociation cross sections are inferred from the photoabsorption cross sections. On the basis of the measured data, the photodissociation rates by the interstellar radiation field are computed and discussed.

Nee, J. B.↗
NASA NTRS1985

On the nature of the UX Ursa Majoris-type nova-like variables - CPD-48 deg 1577

A series of low-dispersion spectra and one high-dispersion spectrum have been obtained of the catacylsmic variable CPD-48 deg 1577. Like other UX UMa stars, this variable exhibits the flat continuum of a luminous, thick, steady state accretion disk dominating its light from the far UV to the infrared. A wind mass loss rate of less than about 10 to the -9th solar mass/yr and an accretion rate of roughly 5 x 10 to the -9th solar mass/yr is roughly consistent with the range which characterizes other UX UMa stars. An SWP echelle spectrum reveals detailed line profile information on the N V, Si IV, and C IV resonance lines. He II 1640 A is remarkably weak and even absent in two of the spectra. The known properties and evolutionary status of CPD-48 deg 1577 and the other UX UMa stars are summarized.

Sion, E. M.↗
NASA NTRS1985

Remote displacement measurement using a passive interferometer with a fiber-optic link

Remote displacement measurement is demonstrated using a Fabry-Perot cavity with a multimode optical fiber link. The sensing cavity modulates, as a function of its length, the spectrum of a light-emitting diode (LED). The light returns via the fiber and is analyzed by a tunable reference cavity. A closed-loop control causes the reference cavity to track the sensing cavity length within 2 x 10 to the -12th m. Displacement range is 2 x 10 to the -6th m. The reference cavity length is measured interferometrically, using a laser, to obtain the sensing cavity length. Advantages of this sensing technique include compatibility with multimode fiber-optic components, high immunity to optical losses, and large dynamic range.

Beheim, G.↗
NASA NTRS1985

Submillimeter observations of evolved stars

Broadband submillimeter observations of thermal emission from several evolved stars have been obtained using the United Kingdom Infrared Telescope on Mauna Kea, Hawaii. The observations were carried out at an effective wavelength of 400 microns in order to estimate the mass loss rates in dust from the stars. Direct estimates of mass loss rates are in the range 10 to the -9th to 10 to the -6th solar mass/yr. Analysis of the spectrum of IRC + 10216 confirmed previous estimates of dust grain emissivity in the range 10-1000 microns. The infrared properties of IRC + 10216 are found to be similar to the carbon rich object CRL 3068. No systematic difference was found between the dust masses of carbon rich and oxygen rich envelopes. The largest mass loss rates in dust were obtained for the bipolar objects OH 231.8 + 4.2 CRL 2688, CRL 618, and NGC 7027. It is suggested that the ratios of gas to dust, and the slopes of the far infrared to submillimeter wavelength continua of these stars objects are probably representative of amorphous rather than crystalline grains.

Sopka, R. J.↗
NASA NTRS1985

Rate constant for the reaction Cl + HO2NO2 yielding products

The rates for the reaction of Cl atoms iwth HO2NO2 were calculated from data obtained by the use of the discharge flow/resonance fluorescence (DF/RF) and the discharge flow/mass spectrometric (DF/MS) techniques. The total rate constant, k1, for the overall reaction: 1a (Cl + HO2NO2 yielding HCl + NO2 +O2), 1b (yielding HO2 + ClNO2), and the two possible additional channels was found to be less than 1.0 x 10 to the -13th cu cm/s at 296 K. The value of (k1a + k1b) was found to be 3.4 + or - 1.4) x 10 to the -14th cu cm/s. Thus, the reaction of Cl with peroxynitric acid is too slow, by a factor of 100, to contribute significantly to the hydrogen abstraction by Cl in the stratosphere.

Simonaitis, R.↗
NASA NTRS1985

Observation of far-infrared transitions between excited states of OH

Spectra of the Kleinmann-Low nebula in Orion detected the 84.42 and 84.60 micron transitions between the 2Pi(3/2) J = 7/2 and 2Pi(3/2) J = 5/2 levels of OH with respective fluxes of 1 x 10 to the -17th and 1.4 x 10 to the -17th W/sq cm. When compared to the 119 micron flux levels of OH discussed by Watson (1982) and the 163 micron flux levels of OH by Viscuso et al. (1985), these results suggest appreciable self-absorption of OH line radiation within the nebula. The CO emission due to the J = 31 to 30 rotational transition at 84.411 microns makes a substantial contribution to the observed 84.22 micron flux, and is probably at least partially absorbed at the 84.42 micron OH transition frequency.

Viscuso, P. J.↗
NASA NTRS1985

Slow plastic strain rate compressive flow in binary CoAl intermetallics

Constant-velocity elevated temperature compression tests have been conducted on a series of binary CoAl intermetallics produced by hot extrusion of blended prealloyed powders. The as-extruded materials were polycrystalline, and they retained their nominal 10-micron grain size after being tested between 1100 and 1400 K at strain rates ranging from 2 x 10 to the -4th to 2 x 10 to the -7th per sec. Significant plastic flow was obtained in all cases; while cracking was observed, much of this could be due to failure at matrix-oxide interfaces along extrusion stringers rather than to solely intergranular fracture. A maximum in flow strength occurs at an aluminum-to-cobalt ratio of 0.975, and the stress exponent appears to be constant for aluminum-to-cobalt ratios of 0.85 or more. It is likely that very aluminum-deficient materials deform by a different mechanism than do other compositions.

Whittenberger, J. D.↗
NASA NTRS1985

Real-time measurement of sodium chloride in individual aerosol particles by mass spectrometry

The method of particle analysis by mass spectrometry has been applied to the quantitative measurement of sodium chloride in individual particles on a real-time basis. Particles of known masses are individually introduced, in the form of a beam, into a miniature Knudsen cell oven (1600 K). The oven is fabricated from rhenium metal sheet (0.018 mm thick) and is situated in the ion source of a quadrupole mass spectrometer. A particle once inside the oven is trapped and completely volatilized; this overcomes the problem of partial volatilization due to particles bouncing from the filament surface. Individual particles are thermally volatilized and ionized inside the rhenium oven, and produce discrete sodium ion pulses whose intensities are measured with the quadrupole mass spectrometer. An ion pulse width of several milliseconds (4-12 ms) is found for particles in the mass range 1.3 x 10 to the -13th to 5.4 x 10 to the -11th g. The sodium ion intensity is found to be proportional to the particle mass to the 0.86-power. The intensity distribution for monodisperse aerosol particles possesses a geometric standard deviation of 1.09, showing that the method can be used for the determination of the mass distribution function with good resolution in a polydisperse aerosol.

Sinha, M. P.↗
NASA NTRS1985

An upper limit for the absorption cross section of the oxygen C 3 Delta u - a 1 Delta g transition

Frederick and Cicerone (1985) have proposed that photodissociation of O2 (a 1 Delta g) by the process O2 (a 1 Delta g) + h-nu + O2 (C 3 Delta u) to O(3 P) + O(3 P) may be a major source of odd oxygen in the upper stratosphere and mesosphere. They argued that, since the process is forbidden only by change in the spin multiplicity, it might have been a cross section intermediate between a fully allowed and a strictly forbidden transition, i.e., 10 to the -20th to 10 to the -19th sq cm near 250 nm. In order to test this proposal, absorption by O2 (a 1 Delta g) has been measured in the 190-290 nm wavelength region. No absorption above the detection limit could be observed for O2 (a 1 Delta g) concentrations of (4-7) x 10 to the 15th/cu cm. An upper limit of 8 x 10 to the -22 sq cm was calculated for the cross section.

Simonaitis, R.↗
NASA NTRS1986

An ultrahigh vacuum multipurpose specimen chamber with sample introduction system for in situ transmission electron microscopy investigations

A commercial transmission electron microscope (TEM), with flat-plate upper pole piece configuration of the objective lens, and top-entry specimen introduction was modified by introducing an ultrahigh vacuum (UHV) specimen chamber for in situ TEM experimentation. The pumping and design principles and special features of this UHV chamber, which makes it possible to obtain 5 x 10 to the -10th mbar pressure at the site of the specimen, while maintaining the airlock system that allows operation in the 10 to the -10th mbar range within 15 min after specimen change, are described. Design operating pressures and image quality (resolution of metal particles smaller than 1 nm in size) were achieved. Schematic drawings and design dimensions are included.

Heinemann, K.↗
NASA NTRS1986

Kinetic studies of the reaction of the SO radical with NO2 and ClO from 210 to 363 K

The rates of the reactions of the SO radical with NO2 and ClO (significant in the upper atmosphere of earth and Venus) were determined in a discharge flow system near 1 torr pressure with detection of radical and molecular species using collision-free sampling mass spectrometry. The rate constants were obtained from the decay of SO radicals in the presence of an excess of NO2 and ClO. The NO2 reaction was examined between 210 and 363 K and found to be temperature invariant: SO + NO2 yields SO2 + NO; k1 = (1.37 + or - 0.10) x 10 to the -11th cu cm/s. In addition, the ClO reaction was observed to be independent of temperature between 248 and 363 K: SO + ClO yields SO2 + Cl; k2 = (3.22 + or - 0.48) x 10 to the -11th cu cm/s. A comparison was made with previous investigations of these reactions at room temperature and with other radical-radical reactions involving SO or ClO.

Brunning, J.↗
NASA NTRS1986

Uranium series dating of Allan Hills ice

Uranium-238 decay series nuclides dissolved in Antarctic ice samples were measured in areas of both high and low concentrations of volcanic glass shards. Ice from the Allan Hills site (high shard content) had high Ra-226, Th-230 and U-234 activities but similarly low U-238 activities in comparison with Antarctic ice samples without shards. The Ra-226, Th-230 and U-234 excesses were found to be proportional to the shard content, while the U-238 decay series results were consistent with the assumption that alpha decay products recoiled into the ice from the shards. Through this method of uranium series dating, it was learned that the Allen Hills Cul de Sac ice is approximately 325,000 years old.

Fireman, E. L.↗
NASA NTRS1986

Macroscopic T nonconservation - Prospects for a new experiment

Breakdown of time-reversal invariance can be detected in macroscopic samples as a magnetic alignment along an electric field. It is shown that both fundamental and practical limits to the detection of this effect in paramagnets correspond to measurement of electron electric dipole moments down to d(e) of about 10 to the -28th e cm on 50-g quantities of EuS near its Curie point; this compares to the current limit of d(e) not greater than 10 to the -24th e cm. Strategies for still greater sensitivity are outlined.

Bialek, W.↗
NASA NTRS1986

Gravitational microlensing by the galactic halo

A simple model of microlensing by massive objects that might be present in the halo of the Galaxy is presented. It is shown that in any nearby galaxy one star out of a million is strongly microlensed by a 'dark' object located in the Galactic halo, if the halo is made up of objects more massive than about 10 to the -8th solar mass. Monitoring the brightness of a few million stars in the Magellanic Clouds over a time scale between two hours and two years may lead to a discovery of 'dark halo' objects between 10 to the -6th and 10 to the -2nd solar mass, or it may put strong upper limits on the number of such objects.

Paczynski, B.↗