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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Analysis of particulate contamination on tape lift samples from the VETA optical surfaces

Particulate contamination analysis was carried out on samples taken from the Verification Engineering Test Article (VETA) x-ray detection system. A total of eighteen tape lift samples were taken from the VETA optical surfaces. Initially, the samples were tested using a scanning electron microscope. Additionally, particle composition was determined by energy dispersive x-ray spectrometry. Results are presented in terms of particle loading per sample.

Germani, Mark S.↗
NASA NTRS1994

Surface characterization and contamination analysis

The research activity for this first year has focussed on three distinct activities: (1) the use of an integrating sphere to improve upon the gathering of spectral data from a variety of surfaces; (2) the use of optical fiber spectrometry to determine levels of contamination from tape residues on critical bonding surfaces; and (3) an exploratory activity in the use of spectroscopic ellipsometry for the analysis of thin films of contaminants on critical surfaces has also begun.

Workman, Gary L.↗
NASA NTRS2018

Effectiveness of Surface Treatment Techniques for Composite Bonding with Different Contamination Levels

Various surface treatment techniques have been developed to promote adhesive bond performance for composite structural components in aerospace applications. The condition of the pre-bond surface is critical to achieving desirable bond quality. Contamination on bonding surfaces is well recognized as a major threat to ultimate bond performance. Variation in contamination level has brought additional challenges into manufacturing process control. High fidelity surface treatment techniques are required for effective removal of contaminants over a wide range of contamination levels. In this study, a common contaminant, i.e. silicone mold release, was introduced to pre-bond composite surfaces with different concentrations. Plasma and laser surface treatment techniques were performed and their effectiveness in restoring and enhancing desirable bond quality was investigated. Surface characterization techniques, including water contact angle goniometry, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy, were conducted to assess the condition of contaminated surfaces and the improvement induced by plasma and laser surface treatments. Failure modes from a customized double cantilever beam test were investigated before and after surface treatments. Fundamental mechanisms of plasma and laser surface treatments on the composite bonding surfaces were also investigated.

Fang, Xiaomei↗
NASA NTRS1982

Thermocapillary flows and their stability: Effects of surface layers and contamination

The fluid mechanics and heat transfer of motions driven by surface tension gradients (Marangoni convection) were analyzed theoretically to obtain an understanding of the convection accompanying the process of growing high quality single crystals from the melt in a mu-g environment. The geometries considered include two dimensional liquid filled slots and axisymmetric float zone configurations.

Davis, S. H.↗
NASA NTRS1989

Effects of the contamination environment on surfaces and materials

In addition to the issues that have always existed, demands are being placed on space systems for increased contamination prevention/control. Optical surveillance sensors are required to detect low radiance targets. This increases the need for very low scatter surfaces in the optical system. Particulate contamination levels typically experienced in today's working environments/habits will most likely compromise these sensors. Contamination (molecular and particulate) can also affect the survivability of space sensors in both the natural and hostile space environments. The effects of di-octyl phthalate (DOP) on sensors are discussed.

Maag, Carl R.↗
NASA NTRS1975

Correlation of an optical system degradation with contamination on a critical surface

The loss of sensitivity of a radiantly cooled radiometer during space operation was investigated. A quartz crystal microbalance (QCM), mounted in the proximity of the instrument filter lens and held at its temperature, measured the contaminant at the location during a vacuum test. The temperature cycling of the lens and the QCM verified the contamination of the lens as the cause of the deterioration. Data on the instrument performance in space and in the chamber allowed estimation of the rate of contaminant accretion on the lens in space service. That rate was used to estimate the contaminant partial pressure. The nature of material was inferred by comparison of the partial pressures and the saturated vapor pressures of materials at the temperature of the contaminated surface. These data, in conjunction with data on fields of view of the lens, are used to identify the sources of contamination.

Scialdone, J. J.↗
NASA NTRSDate not supplied

Recent Advances in LIBS for Real-Time Detection of Silicone Contaminants on CFRP Surfaces

Laser induced breakdown spectroscopy (LIBS) is a materials characterization technique that has been advanced and refined to provide in situ, real-time quality control of carbon fiber reinforced polymer (CFRP) surfaces. As part of an effort to improve process control for adhesive bonding, a LIBS system was designed and assembled at NASA Langley Research Center (LaRC) to enable detection of ultralow concentrations of silicone contamination on CFRP adherends. The LIBS instrument provides high sensitivity detection and quasi-nondestructive surface characterization of CFRP adherends prior to adhesive bonding. This review focuses on the advancements at LaRC using LIBS as a quality control tool for the detection of silicone contaminants for improved adhesive bonding reliability of CFRP materials. This work describes how the LIBS technique was advanced by analyzing the laser parameters, studying the laser-matter interactions, and performing time-resolved measurements to determine the optimal plasma conditions for elemental detection. In addition, LIBS results were compared to X-ray photoelectron spectroscopy data to enable quantitative analysis from analytical calibration curves. Examples are shown of how to perform surface mapping of silicone contamination. Finally, a brief discussion is also presented on LIBS instrumentation, recommendations for laser parameters and instrumentation components, and LIBS technique maturity.

Surface characterization, Carbon fiber reinforced ↗
NASA NTRSDate not supplied

Recent Advances in LIBS for Real-Time Detection of Silicone Contaminants on CFRP Surfaces

Laser induced breakdown spectroscopy (LIBS) is a materials characterization technique that has been advanced and refined to provide in situ, real-time quality control of carbon fiber reinforced polymer (CFRP) surfaces. As part of an effort to improve process control for adhesive bonding, aLIBS system was designed and assembled at the NASA Langley Research Center (LaRC) to enable detection of ultra low concentrations of silicone contamination on CFRP adherends. The LIBS instrument provides high sensitivity detection and quasi-nondestructive surface characterization ofCFRP adherends prior to adhesive bonding. This review focuses on the advancements at LaRC using LIBS as a quality control tool for the detection of silicone contaminants for improved adhesive bonding reliability of CFRP materials. This work describes how the LIBS technique was advanced by analyzing the laser parameters, studying the laser-matter interactions, and performing time-resolved measurements to determine the optimal plasma conditions for elemental detection. In addition, LIBS results were compared to X-ray photoelectron spectroscopy data to enable quantitative analysis from analytical calibration curves. Examples are shown of how to perform surface mapping of silicone contamination. Finally, a brief discussion is presented on LIBS instrumentation, recommendations for laser parameters and instrumentation components, and LIBS technique maturity

Rodolfo I. Ledesma↗
NASA NTRS1999

Changes in the Optical Properties of Materials Are Observed After 18 Months in Low Earth Orbit

Materials located on the exterior of spacecraft in low Earth orbit are subjected to a number of environmental threats, including atomic oxygen, ultraviolet radiation, thermal cycling, and micrometeroid and debris impact. Atomic oxygen attacks materials vulnerable to oxidation. Ultraviolet radiation can break chemical bonds and cause undesirable changes in optical properties. Thermal cycling can cause cracking, and micrometeroid and debris impacts can damage protective coatings. Another threat is contamination. The outgassing of volatile chemicals can contaminate nearby surfaces, changing their thermal control properties. Contaminated surfaces may undergo further change as a result of atomic oxygen and ultraviolet radiation exposure. The Passive Optical Sample Assembly (POSA) experiment was designed as a risk mitigation experiment for the International Space Station. Samples were characterized before launch, exposed for 18 months on the exterior of Mir, and characterized upon their return. Lessons learned from POSA about the durability of material properties can be applied to the space station and other long-duration missions.

Jaworske, Donald A.↗
DOE OSTI2024

Novel alkali intercalated and acid-exfoliated biochars with enhanced surface areas for contaminant adsorption applications

Cost-effective and eco-friendly adsorbents are essential in environmental engineering and biochar is a promising material from the perspective. A novel and efficient surface modification approach involving alkali intercalation and acid exfoliation was designed in this study to enhance the physicochemical properties of biochar. Here, the alkali intercalation process utilizes potassium hydroxide (KOH), while acid exfoliation involves varying HNO 3 , H 2 SO 4 , and H 3 PO 4 concentrations. A simple two-stage pyrolysis process was employed to facilitate the intercalation-exfoliation modification. The modified biochars were characterized using BET, SEM, XRD, etc., to understand physicochemical properties. To quantify the effectiveness of the modifications, adsorption of malachite green dye as a model moiety was investigated. Dye removal sorption rates exceeding 99 % were recorded in the case of the biochars modified through a two-step process using KOH and 0.1MH 3 PO 4 . Specifically, the highest contaminant removal of 99.9 % was recorded when 60 mg of the KOH-0.1MH 3 PO 4 biochar was employed, which is significantly higher than unmodified biochar’s 45.41 % removal at a higher dosage of 100 mg. Moreover, the adsorption kinetics revealed that all the modified biochars attained the maximum removal concentrations (~99 % removal) in a mere 300 min, indicating a tenfold improvement in adsorption rate from unmodified biochar's requirement of over 5000 min. The results achieved through this study provide a cost-effective, fast, and environment-friendly technology for enhancing the adsorption characteristics and performance of biochars toward contaminant removal.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRSDate not supplied

Reducing Landing Site Contamination Using 3-D Trajectory Optimization for Surface Hoppers

Rocket-powered vehicles utilizing Vertical Take-off Vertical Landing (VTVL) are a compelling alternative to surface rovers for exploring planetary and lunar bodies. These so called “hoppers” provide enhanced mobility for accessing locations difficult to reach, and over a wider region of the surface. However, contamination and plume interactions from rocket exhaust deposited at landing sites is anticipated since landing approaches are typically along a vertical direction during the final descent. Consequently, exhaust products may alter the surface chemistry, potentially confounding compositional analysis for samples collected in the vicinity of the landing site or jeopardize mining efforts. There has been no rigorous study on flight maneuvers that can mitigate plume-to-surface interactions. A multi-objective optimization tool has been developed to simulate propulsive hops on a planetary body and minimize both fuel consumption and site alterations. Trajectories are derived by multi-objective optimization and include solutions with significant reduction in contamination for a modest increase in fuel consumption. For these solutions, surface-to-surface propulsive transfer is demonstrated, but the method can also be modified for orbit-to-surface transfers (e.g., landers).

guidance↗
NASA NTRSDate not supplied

Reducing Landing Site Contamination Using 3-D Trajectory Optimization for Surface Hoppers

Rocket-powered vehicles utilizing Vertical Take-off Vertical Landing (VTVL) are a compelling alternative to surface rovers for exploring planetary and lunar bodies. These so called “hoppers” provide enhanced mobility for accessing locations difficult to reach, and over a wider region of the surface. However, contamination and plume interactions from rocket exhaust deposited at landing sites is anticipated since landing approaches are typically along a vertical direction during the final descent. Consequently, exhaust products may alter the surface chemistry, potentially confounding compositional analysis for samples collected in the vicinity of the landing site or jeopardize mining efforts. There has been no rigorous study on flight maneuvers that can mitigate plume-to-surface interactions. A multi-objective optimization tool has been developed to simulate propulsive hops on a planetary body and minimize both fuel consumption and site alterations. Trajectories are derived by multi-objective optimization and include solutions with significant reduction in contamination for a modest in-crease in fuel consumption. For these solutions, surface-to-surface propulsive transfer is demonstrated, but the method can also be modified for orbit-to-surface transfers (e.g., landers).

guidance↗
NASA NTRS1979

Wipe-rinse technique for quantitating microbial contamination on large surfaces

The evaluation of an improved wipe-rinse technique for the bioassay of large areas was undertaken due to inherent inadequacies in the cotton swab-rinse technique to which assay of spacecraft is currently restricted. Four types of contamination control cloths were initially tested. A polyester-bonded cloth (PBC) was selected for further evaluation because of its superior efficiency and handling characteristics. Results from comparative tests with PBC and cotton swabs on simulated spacecraft surfaces indicated a significantly higher recovery efficiency for the PBC than for the cotton (90.4 versus 75.2%). Of the sampling area sites studied, PBC was found to be most effective on surface areas not exceeding 0.74 sq m (8.0 sq ft).

Kirschner, L. E.↗
DOE OSTI2023

An Investigation on the Pollen-Induced Soiling Losses in Utility-Scale PV Plants

Soiling, the accumulation of dust and other contaminants on the surface of photovoltaic (PV) modules, is a common factor that can negatively impact the performance of PV systems. In this study, the authors aim to analyze the impact of pollen on soiling losses in PV systems located in North Carolina, USA, particularly during the spring season. The performance data of two utility-scale PV plants was collected and analyzed using the two soiling extraction methods. Environmental data, including croplands and vegetation was also collected and analyzed to identify correlations with soiling losses. The results of the study may help improve understanding of necessary operation and maintenance activities for PV plants and provide new insights into the phenomenon of pollen deposition on PV systems.

correlation↗
NASA NTRS1974

Mathematical estimation of the level of microbial contamination on spacecraft surfaces by volumetric air sampling

Microbiological sampling methods presently used for enumeration of microorganisms on spacecraft surfaces require contact with easily damaged components. Estimation of viable particles on surfaces using air sampling methods in conjunction with a mathematical model would be desirable. Parameters necessary for the mathematical model are the effect of angled surfaces on viable particle collection and the number of viable cells per viable particle. Deposition of viable particles on angled surfaces closely followed a cosine function, and the number of viable cells per viable particle was consistent with a Poisson distribution. Other parameters considered by the mathematical model included deposition rate and fractional removal per unit time. A close nonlinear correlation between volumetric air sampling and airborne fallout on surfaces was established with all fallout data points falling within the 95% confidence limits as determined by the mathematical model.

Oxborrow, G. S.↗
NASA NTRS1976

Chemical Analysis of Outgassing Contaminants on Spacecraft Surfaces

Samples of S-13 paint on aluminum, reflection grating anomalies as affected by dielectric coatings, and rocket effluents were analyzed along with Skylab window scrapings and a gas activated semiconductor. Development of an HCl detector is also discussed. Results are briefly summarized.

Mcnutt, R. C.↗