Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Pt”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Gas-phase measurements of combustion interaction with materials for radiation-cooled chambers

Foil samples of Ir and Pt are exposed to combustion products in a controlled premixed environment at atmospheric pressure. Electrical heating of the foil samples is used to control the surface temperature and to elevate it above the radiative equilibrium temperature within the test apparatus. Profiles of temperature and OH concentration in the boundary layer adjacent to the specimen surface are measured by laser-induced fluorescence. Measured OH concentrations are significantly higher than equilibrium concentrations calculated for the known mixture ratio and the measured temperature profiles. This result indicates that superequilibrium concentrations of H-atoms and O-atoms are also present in the boundary layer, due to partial equilibrium of the rapid binary reactions of the H2/O2 chemical kinetic system. These experiments are conducted as part of a research program to investigate fundamental aspects of the interaction of combustion gases with advanced high-temperature materials for radiation-cooled thrusters.

Barlow, R. S.↗
NASA NTRS1991

First results from the Goddard High-Resolution spectrograph - High-resolution observations of the 1942 A resonance line of HG II in the chemically peculiar B star, Chi Lupi

The Goddard High-Resolution Spectrograph on the HST has been used to obtain high S/N observations of the sharp-lined, Hg- and Pt-rich B-type star, Chi Lupi, with a resolving power of 87,000. The observations reveal a level of spectroscopic detail never before observed at ultraviolet wavelengths for any star other than the sun. Concentrating on the region around the resonance line of Hg II at 1942 A, the profile and central position of this line confirm beyond doubt that the Hg isotope anomaly in Chi Lupi is real and extreme, with Hg being heavily concentrated in the form of Hg-204. The problems in atomic physics which impair the accurate analysis of spectra of this quality are emphasized.

Leckrone, David S.↗
NASA NTRS1991

All-electron molecular Dirac-Hartree-Fock calculations - The group IV tetrahydrides CH4, SiH4, GeH4, SnH4, and PbH4

A basis-set-expansion Dirac-Hartree-Fock program for molecules is described. Bond lengths and harmonic frequencies are presented for the ground states of the group 4 tetrahydrides, CH4, SiH4, GeH4, SnH4, and PbH4. The results are compared with relativistic effective core potential (RECP) calculations, first-order perturbation theory (PT) calculations and with experimental data. The bond lengths are well predicted by first-order perturbation theory for all molecules, but none of the RECP's considered provides a consistent prediction. Perturbation theory overestimates the relativistic correction to the harmonic frequencies; the RECP calculations underestimate the correction.

Dyall, Kenneth G.↗
NASA NTRS1990

A resistance strain gage with repeatable and cancellable apparent strain for use to 1500 F

A temperature compensated static strain gauge, which is fabricated from Pd13Cr alloy and a Pt compensator, is being developed and has been tested over a temperature range to 1500 F at NASA-Lewis. The PdCr compensated strain gage has significantly lower apparent strain to 500 F than other high temperature strain gages. The PdCr compensated gage is protected from oxidation by a flame-sprayed alumina-4 wt pct zirconia overcoating. Test Results to 1500 F indicate apparent strain variations of less than 250 micro-epsilon and reproducibility between thermal cycles within 50 micro-epsilon. The apparent strain of the coated PdCr compensated gage can be predicted and cancelled due to its reproducibility and low value.

Lei, Jih-Fen↗
NASA NTRS1991

Wavelength dependencies of the Kerr rotation and ellipticity for the magneto-optical recording media

Here we present wavelength dependence measurements of Co/Pd and Co/Pt superlattice samples with different compositions. We explore the relationship between the composition and the magneto-optical spectra. The induced magnetization in the Pt of Co/Pt or in the Pd of Co/Pd samples plays an important role in the magneto-optical activity, and is discussed for the samples measured. The experimental set-up and the samples used are described. The measurement results of one Co/Pt sample and a series of Co/Pd samples are discussed.

Zhou, Feng Lei↗
NASA NTRS1992

High temperature strain gage technology for hypersonic aircraft development applications

An experimental evaluation of Pd 13 percent Cr and of BCL-3 alloy wire strain gages was conducted on IN100 and Cu 0.15 percent Zr alloy substrates. Testing included apparent strain, drift, gage factor, and creep. Maximum test temperature was 1144 K (1600 F). The PdCr gages incorporated Pt temperature compensation elements. The PdCr gages were found to have good resistance stability below 866 K (1100 F). The BCL 3 gages were found to have good resistance stability above 800 K (981 F), but high drift around 700 K (800 F).

Anderson, W. L.↗
NASA NTRS1991

A progressive data compression scheme based upon adaptive transform coding: Mixture block coding of natural images

A method for efficiently coding natural images using a vector-quantized variable-blocksized transform source coder is presented. The method, mixture block coding (MBC), incorporates variable-rate coding by using a mixture of discrete cosine transform (DCT) source coders. Which coders are selected to code any given image region is made through a threshold driven distortion criterion. In this paper, MBC is used in two different applications. The base method is concerned with single-pass low-rate image data compression. The second is a natural extension of the base method which allows for low-rate progressive transmission (PT). Since the base method adapts easily to progressive coding, it offers the aesthetic advantage of progressive coding without incorporating extensive channel overhead. Image compression rates of approximately 0.5 bit/pel are demonstrated for both monochrome and color images.

Rost, Martin C.↗
NASA NTRS1992

Interactions of atomic oxygen with material surfaces in low Earth orbit: Preliminary results from experiment A0114

The atomic oxygen experiment consisted of two trays (one-sixth of a Long Duration Exposure Facility (LDEF) tray each) of 64 one inch diameter solid samples. It was intended that the effects of atomic oxygen and solar ultraviolet irradiation on the surface properties of each material could be distinguished from each other and from the effects of aging. Sixteen of the samples were placed on a thermally isolated plate of highly polished aluminum, while the main plate was coated with the thermal control coating S13-GLO. Though the experiment was entirely passive, it was hoped that the effects of thermal activation might be observed, if present. The plates were expected to stabilize at temperatures differing by 20-30 C. The samples included thin films of metals Os, Ir, Pt, Ni, Mo, and Al coated onto silica optical flats, metal carbides (WC, SiC), solid carbons of various types, eight polymers, and some other coatings of various types. Analysis is essentially complete using stylus profilometry with high sensitivity Talystep and lower sensitivity Talysurf machines. Though the integrated fluence of O atoms on the LDEF was 30 times that of previous missions, etch depths of the polymers such as the polyimide Kapton show excellent agreement with extrapolations from previous flight data. However, some new effects were observed. We demonstrated on a previous experiment on STS-8 that profilometry of this kind can show steps of 50 A (for example those due to oxide film growth on metals) and this is now the preferred method for estimating etch depth (or mass loss) of erodible substances.

Gregory, John C.↗
NASA NTRS1992

The O2 reduction at the IFC modified O2 fuel cell electrode

The International Fuel Corporation (IFC) state of the art (SOA) O2 electrode (Au-10 percent Pt electrocatalyst by weight) is currently being used in the alkaline H2-O2 fuel cell in the NASA Space Shuttle. Recently, IFC modified O2 electrode, as a possible replacement for the SOA electrode. In the present study, O2 reduction data were obtained for the modified electrode at temperatures between 23.3 and 91.7 C. BET measurements gave an electrode BET surface area of about 2070 sq. cm/sq. cm of geometric surface area. The Tafel data could be fitted to two straight line regions. The slope for the lower region, designated as the 0.04 V/decade region, was temperature dependent, and the transfer coefficient was about 1.5. The 'apparent' energy of activation for this region was about 19 kcal/mol. An O2 reduction mechanism for this 0.04 region is presented. In the upper region, designated as the 0.08 V/decade region, diffusion may be the controlling process. Tafel data are presented to illustrate the increase in performance with increasing temperature.

Fielder, William L.↗
NASA NTRS1992

Theoretical investigation of gas-surface interactions

The investigation into the appearance of intruder states from the negative continuum when some of the two-electron integrals were omitted was completed. The work shows that, provided all integrals involving core contracted functions in an atomic general contraction are included, or that the core functions are radially localized, meaningful results are obtained and intruder states do not appear. In the area of program development, the Dirac-Hartree-Fock (DHF) program for closed-shell polyatomic molecules was extended to permit Kramers-restricted open-shell DHF calculations with one electron in an open shell or one hole in a closed shell, or state-averaged DHF calculations over several particle or hole doublet states. One application of the open-shell code was to the KO molecule. Another major area of program development is the transformation of integrals from the scalar basis in which they are generated to the 2-spinor basis employed in parts of the DHF program, and hence to supermatrix form. Particularly concerning the omission of small component integrals, and with increase in availability of disk space, it is now possible to consider transforming the integrals. The use of ordered integrals, either in the scalar basis or in the 2-spinor basis, would considerably speed up the construction of the Fock matrix, and even more so if supermatrices were constructed. A considerable amount of effort was spent on analyzing the integral ordering and tranformation for the DHF program. The work of assessing the reliability of the relativistic effective core potentials (RECPs) was continued with calculation of the group IV monoxides. The perturbation of the metal atom provided by oxygen is expected to be larger than that provided by hydrogen and thus provide a better test of the qualification of the RECPs. Calculations on some platinum hydrides were carried out at nonrelativistic (NR), perturbation theory (PT) and DHF levels. Reprints of four papers describing this work are included.

Dyall, Kenneth G.↗
NASA NTRS1992

The magnetic field investigation on the Ulysses mission - Instrumentation and preliminary scientific results

A fundamental feature of the heliosphere is the three-dimensional structure of the interplanetary magnetic field. The magnetic field investigation on Ulysses, the first space probe to explore the out-of-ecliptic and polar heliosphere, aims at determining the large-scale features and gradients of the field, as well as the heliolatitude dependence of interplanetary phenomena so far only observed near the ecliptic plane. The Ulysses magnetometer uses two sensors, one a Vector Helium Magnetometer, the other a Fluxgate Magnetometer. Onboard data processing yields measurements of the magnetic field vector with a time resolution up to 2 vectors/second and a sensitivity of about 10 pT. Since the switch-on of the instrument in flight on 25 October 1990, a steady stream of observations has been made, indicating that at this phase of the solar cycle the field is generally disturbed: several shock waves and a large number of discontinuities have been observed, as well as several periods with apparently intense wave activity. The paper gives a brief summary of the scientific objectives of the investigation, followed by a detailed description of the instrument and its characteristics. Examples of wave bursts, interplanetary shocks and crossings of the heliospheric current sheet are given to illustrate the observations made with the instrument.

Balogh, A.↗
NASA NTRS1991

Catalytic oxidation for treatment of ECLSS and PMMS waste streams

It is shown that catalytic oxidation is an effective technique for the removal of trace organic contaminants in a multifiltration potable processor's effluent. Essential elements of this technology are devices that deliver oxygen to the influent, and remove gaseous reaction byproducts from the effluent, via hollow-tube, gas-permeable membranes. Iodine, which poisons existing catalysis, is removed by a small deiodination bed prior to catalytic reactor entrance. The catalyst used is a mixture of Pt and Ru deposited on carbon, operating at 125-160 C and 39-90 psi pressures.

Akse, James R.↗
NASA NTRS1992

Atlas of the spectrum of a platinum/neon hollow-cathode reference lamp in the region 1130-4330 A

The spectrum of a platinum hollow-cathode lamp containing neon carrier gas was recorded photographically and photoelectrically with a 10.7 m normal-incidence vacuum spectrograph. Wavelengths and intensities were determined for about 5600 lines in the region 1130-4330 A. An atlas of the spectrum is given, with the spectral lines marked and their intensities, wavelengths, and classifications listed. Lines of impurity species are also identified. The uncertainty of the photographically measured wavelengths is estimated to be +/- 0.0020 A. The uncertainty of lines measured in the photoelectric scans is 0.01 A for wavelengths shorter than 2030 A and 0.02 A for longer wavelengths. Ritz-type wavelengths are given for many of the classified lines of Pt II with uncertainties varying from +/- 0.0004 to +/- 0.0025 A. The uncertainty of the relative intensities is estimated to be about 20 percent.

Sansonetti, Jean E.↗
NASA NTRS1992

Noble metal abundances in an early Archean impact deposit

Detailed analyses are reported on the concentrations of the noble metals Pd, Os, Ir, Pt, and Au in an early Archean spherule bed (S4) of probably impact origin from the lower Fig Tree Group, Barberton Greenstone Belt, South Africa. Compared to other sedimentary deposits of known or suspected impact origin, some noble metals are present in exceptionally high concentrations. Noble metal abundances are fractionated relative to abundances in chondrites with ratios of Os/Ir, Pt/Ir, Pd/Ir, and Au/Ir at only 80, 80, 41, and 2 percent of these values on CI chondrites. Although an extraterrestrial source is favored for the noble metal enrichment, the most plausible cause of the fractionation is by regional hydrothermal/metasomatic alteration.

Kyte, Frank T.↗
NASA NTRS1992

The platinum microelectrode/Nafion interface - An electrochemical impedance spectroscopic analysis of oxygen reduction kinetics and Nafion characteristics

The objectives of this study were to use electrochemical impedance spectroscopy (EIS) to study the oxygen-reduction reaction under lower humidification conditions than previously studied. The EIS technique permits the discrimination of electrode kinetics of oxygen reduction, mass transport of O2 in the membrane, and the electrical characteristics of the membrane. Electrode-kinetic parameters for the oxygen-reduction reaction, corrosion current densities for Pt, and double-layer capacitances were calculated. The production of water due to electrochemical reduction of oxygen greatly influenced the EIS response and the electrode kinetics at the Pt/Nafion interface. From the finite-length Warburg behavior, a measure of the diffusion coefficient of oxygen in Nafion and diffusion-layer thickness was obtained. An analysis of the EIS data in the high-frequency domain yielded membrane and interfacial characteristics such as ionic conductivity of the membrane, membrane grain-boundary capacitance and resistance, and uncompensated resistance.

Parthasarathy, Arvind↗
NASA NTRS1993

Poly(1,2,4-Triazoles) Via Aromatic Nucleophilic Displacement

Synthesis involves nucleophilic displacement of monomers with activated aromatic dihalides. Polymers exhibited desirable physical and thermal properties. Synthesis of polymers provides high-molecular-weight PT of new chemical structures, potentially more economically favorable than other routes, and, because of availability of large variety of activated aromatic dihalides, provides for facile variation of chemical structure. Useful for producing films, moldings, adhesives, and composites.

Connell, John W.↗
NASA NTRS1992

Palladium-chromium static strain gages for high temperatures

An electrical resistance strain gage that can provide accurate static strain measurement to a temperature of 1500 F or above is being developed both in fine wire and thin film forms. The gage is designed to be temperature compensated on any substrate material. It has a dual element: the gage element is a special alloy, palladium-13wt percent chromium (PdCr), and the compensator element is platinum (Pt). Earlier results of a PdCr based wire gage indicated that the apparent strain of this gage can be minimized and the repeatability of the apparent strain can be improved by prestabilizing the gage on the substrate for a long period of time. However, this kind of prestabilization is not practical in many applications and therefore the development of a wire gage which is prestabilized before installation on the substrate is desirable. This paper will present our recent progress in the development of a prestabilized wire gage which can provide meaningful strain data for the first thermal cycle. A weldable PdCr gage is also being developed for field testing where conventional flame-spraying installation can not be applied. This weldable gage is narrower than a previously reported gage, thereby allowing the gage to be more resistant to buckling under compressive loads. Some preliminary results of a prestabilized wire gage flame-sprayed directly on IN100, an engine material, and a weldable gage spot-welded on IN100 and SCS-6/(beta)21-S Titanium Matrix Composite (TMC), a National Aero-Space Plane (NASP) structure material, will be reported. Progress on the development of a weldable thin film gage will also be addressed. The measurement technique and procedures and the lead wire effect will be discussed.

Lei, Jih-Fen↗
NASA NTRS1991

Palladium-chromium static strain gage for high temperature propulsion systems

The present electrical strain gage for high temperature static strain measurements is in its fine-wire and thin-film forms designed to be temperature-compensated on any substrate material. The gage element is of Pd-Cr alloy, while the compensator is of Pt. Because the thermally-induced apparent strain of this compensated wire strain gage is sufficiently small, with good reproducibility between thermal cycles to 800 C, output figures can be corrected within a reasonable margin of error.

Lei, Jih-Fen↗