Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Nb”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Undercooling of bulk high temperature metals in the 100 meter drop tube

The 100-meter drop tube at NASA Marshall Space Flight Center provides an excellent opportunity to study the effects of containerless, microgravity processing in metals and alloys. In a series of experiments high melting temperature pure metals were melted in an electron beam furnace and dropped in vacuum. Sample sizes ranged from 0.175 to 1.2 grams. Large undercoolings on the order of 18 percent of the melting temperature were observed in Ti, Zr, Nb, Mo, Rh, Ta, and Pt. Undercoolings of 5 to 18 percent T(m) were observed in Ru and Ir. These undercooling results are consistent, repeatable, and occur in a high percentage of experiments. The experimental technique will be presented as well as the resultant microstructures of undercooled drops. The data will be discussed with respect to nucleation theory.

Hofmeister, William↗
NASA NTRS1988

Accurate experimental and theoretical comparisons between superconductor-insulator-superconductor mixers showing weak and strong quantum effects

A systematic study of the gain and noise in superconductor-insulator-superconductor mixers employing Ta based, Nb based, and Pb-alloy based tunnel junctions was made. These junctions displayed both weak and strong quantum effects at a signal frequency of 33 GHz. The effects of energy gap sharpness and subgap current were investigated and are quantitatively related to mixer performance. Detailed comparisons are made of the mixing results with the predictions of a three-port model approximation to the Tucker theory. Mixer performance was measured with a novel test apparatus which is accurate enough to allow for the first quantitative tests of theoretical noise predictions. It is found that the three-port model of the Tucker theory underestimates the mixer noise temperature by a factor of about 2 for all of the mixers. In addition, predicted values of available mixer gain are in reasonable agreement with experiment when quantum effects are weak. However, as quantum effects become strong, the predicted available gain diverges to infinity, which is in sharp contrast to the experimental results. Predictions of coupled gain do not always show such divergences.

Mcgrath, W. R.↗
NASA NTRS1987

A magnetohydrodynamic simulation of reconnection in the magnetotail during intervals with southward interplanetary magnetic field

Results are reported from a simulation of the interaction between the solar wind and the earth magnetosphere, using a time-dependent three-dimensional MHD model. The calculation was performed for several orientations of the IMF between dawnward pointing and southward. When the IMF has a dawnward component, the plasma sheet rotates northward on the dawnside of the tail and toward the south on the duskside. As the southward component becomes larger, the plasma sheet becomes thinner and develops a wavy cross section because of patchy or localized tail reconnection. The field-aligned currents (FACs) associated with this localized reconnection have a filamentary layered structure. When projected onto the polar cap the filamentary FACs are located in the same region as the tail region 1 currents. At lower latitudes strong region 2 sense currents that originate in the plasma sheet are found. FACs are found on field lines that map to the polar cap even for southward IMF. These currents have many of the properties of the observed polar-cusp currents. The polar-cusp FACs evolve from the polar-cap NB(z) FACs as the IMF is rotated from northward to southward.

Walker, R. J.↗
NASA NTRS1989

Rapidly solidified titanium alloys by melt overflow

A pilot plant scale furnace was designed and constructed for casting titanium alloy strips. The furnace combines plasma arc skull melting techniques with melt overflow rapid solidification technology. A mathematical model of the melting and casting process was developed. The furnace cast strip of a suitable length and width for use with honeycomb structures. Titanium alloys Ti-6Al-4V and Ti-14Al-21 Nb were successfully cast into strips. The strips were evaluated by optical metallography, microhardness measurements, chemical analysis, and cold rolling.

Gaspar, Thomas A.↗
NASA NTRS1988

Rapid solidification research at the NASA Lewis Research Center

This paper describes the research program initiated at the NASA Lewis Research Center for the study of rapid solidification of high temperature materials, with the major purpose for the development of advanced high-temperature and heat-flux materials for aircraft and aerosphace applications. Particular attention is given to the development of three alloys: Ni-aluminides, Nb-alloys, and Cu-alloys. Rapid solidification processing yielded alloys with novel microstructures, very fine grain sizes, reduced chemical segregation, and metastable extended solid solutions.

Locci, Ivan E.↗
NASA NTRS1989

Nuclear collective flow and charged-pion emission in Ne-nucleus collisions at E/A = 800 MeV

Triple-differential cross sections of charged pions were measured for collisions of Ne projectiles at E/A = 800 MeV with NaF, Nb, and Pb targets. The reaction plane was estimated event by event from the light-baryon momentum distribution. For heavy targets, preferential emission of charged pions away from the interaction zone toward the projectile side was observed in the transverse direction. Such a preferential emission, which is not predicted by cascade calculations, may be attributed to a stronger pion absorption by the heavier spectator remnant.

Gosset, J.↗
NASA NTRS1989

Ellipsometric method for the measurement of temperature and optical constants of incandescent transition metals

The development of a unique noncontact temperature measurement device utilizing rotating analyzer ellipsometry is described. The technique circumvents the necessity of spectral emissivity estimation by direct measurement concomitant with radiance brightness. Simultaneous determinations of dielectric constants and refractive indices allow changes in the physical and chemical state of a heated surface to be monitored. The results of optical property measurements at 633 nm as functions of temperature between 1000 and 2500 K for eight transition metals including Hf, Ir, Mo, Nb, Pd, Pt, Ta, and V are presented together with preliminary results of oxidation studies on iridium.

Hansen, George P.↗
NASA NTRS1988

Kaersutite-bearing xenoliths and megacrysts in volcanic rocks from the Funk Seamount in the souhtwest Indian Ocean

The petrography, mineral chemistry, and whole-rock compositions of volcanic rocks dredged from the Funk Seamount, located 60 km NW of Marion Island in the southwestern Indian Ocean, are presented together with the mineral chemistry of their inclusions. On the basis of these characteristics, the possible relationships between the Funk Seamount's volcanic rocks and the megacrysts and xenoliths in these rocks are discussed. It is argued that the Funk Seamount lavas derive from a similar mantle source region as that of the Marion Island and Prince Edward Island hotspot lavas. The geochemical signature of these lavas implies derivation from a source that is enriched (e.g., in Ti, K, P, and Nb) over the depleted mantle source regions for the adjacent mid-ocean ridge basalts.

Reid, Arch M.↗
NASA NTRS1989

The role of repair in the survival of mammalian cells from heavy ion irradiation - Approximation to the ideal case of target theory

Experiments are discussed in which the cell-cycle dependency of the repair deficiency of the S/S variant of the L5178Y murine leukemic lymphoblast was examined by treatment with the heavy ions, Ne-20, Si-28, Ar-40, Fe-56, and Nb-93. Evidence from those studies provide support for the notion that as the linear energy transfer of the incident radiation increases the ability of the S/S cell to repair radiation damage decreases until it is eliminated around 500 keV/micron. In the region of the latter linear energy transfer value, the behavior of the S/S cell approximates the ideal case of target theory where post-irradiation metabolism does not influence cell survival.

Lett, J. T.↗
NASA NTRS1989

Tribological properties of ceramic/Ti3Al-Nb sliding couples for use as candidate seal materials to 700 deg C

Tribological properties of Ti3Al-Nb intermetallic disks sliding against alumina-boria-silicate fabric were ascertained in air at temperatures from 25 to 700 C. These materials are candidates for sliding seal applications for the National AeroSpace Plane. The tests were done using a pin on disk tribometer. Sliding was unidirectional at 0.27 m/sec under a nominal contact stress of 340 kPa. Gold sputter or ion plating deposited films were used to reduce friction and wear. Rhodium and palladium films were used beneath the gold lubricating films to prevent diffusion of the substrate into the gold at high temperature. The friction and wear of the unlubricated specimens was unacceptable. Friction coefficients were generally greater than 1.0. The ion plated gold films, when used with a rhodium diffusion barrier reduced friction by almost a factor of 2. Wear was also substantially reduced. The sputter deposited films were not adherent unless the substrate was sputter cleaned immediately prior to film deposition. Palladium did not function as a diffusion barrier.

Dellacorte, Christopher↗
NASA NTRS1989

Identification of a cast iron alloy containing nonstrategic elements

A program was performed to address the mechanical and environmental needs of Stirling engine heater head and regenerator housing components, while reducing the dependence on strategic materials. An alloy was developed which contained no strategic elemental additions per se. The base is iron with additions of manganese, molybdenum, carbon, silicon, niobium, and ferro-chromium. Such an alloy should be producible on a large scale at very low cost. The resulting alloy, designated as NASAUT 4G-Al, contained 15 Mn, 15 Cr, 2 Mo, 1.5 C, 1.0 Si, 1.0 Nb (in weight percent) with a balance of Fe. This alloy was optimized for chemistry, based upon tensile strength, creep-rupture strength, fracture behavior, and fatigue resistance up to 800 C. Alloys were also tested for environmental compatibility. The microstructure and mechanic properties (including hardness) were assessed in the as-cast condition and following several heat treatments, including one designed to simulate a required braze cycle. The alloy was fabricated and characterized in the form of both equiaxed and columnar-grained castings. The columnar grains were produced by directional solidification, and the properties were characterized in both the longitudinal and transverse orientations. The NASAUT 4G-Al alloy was found to be good in cyclic-oxidation resistance and excellent in both hydrogen and hot-corrosion resistance, especially in comparison to the baseline XF-818 alloy. The mechanical properties of yield strength, stress-rupture life, high-cycle-fatigue resistance, and low-cycle-fatigue resistance were good to excellent in comparison to the current alloy for this application, HS-31 (X-40), with precise results depending in a complex manner on grain orientation and temperature. If required, the ductility could be improved by lowering the carbon content.

Cooper, C. V.↗
NASA NTRS1989

Oxidation of high-temperature intermetallics; Proceedings of the Workshop, Cleveland, OH, Sept. 22, 23, 1988

The present conference on the high-temperature oxidation behavior of aerospace structures-applicable intermetallic compounds discusses the influence of reactive-element additions on the oxidation of Ni3Al base alloys, the effect of Ni3Al oxidation below 850 C on fracture behavior, the oxidation of FeAl + Hf, Zr, and B, the synergistic effect of Al and Si on the oxidation resistance of Fe alloys, and pack cementation coatings of Cr-Al on Fe, Ni, and Co alloys. Also discussed are the formation of alumina on Nb- and Ti-base alloys, the oxidation behavior of titanium aluminide alloys, silicide coatings for refractory metals, the oxidation of chromium disilicide, and the oxidation behavior of nickel beryllides.

Grobstein, Toni↗
NASA NTRS1989

AMTEC recirculating test cell component testing and operation

Alkali metal thermoelectric converter operation in a recirculating test cell (RTC), which requires a small electromagnetic pump (EM) and a high-temperature beta-double-prime alumina-solid-electrolyte (BASE)-to-metal seal, is discussed. The design of a pump and an active metal braze seal and the initial operation of a cell using these components are described. The pump delivered 0.25 cu cm/min against a 28-psia head. A braze seal system was selected after shear strength tests of Ta or Nb brazed to BASE by a variety of fillers including TiCuNi, TiNi, and TiNiCr. The TiCuNi filler was chosen for environment cell testing and showed no failure or observable degradation after short-term tests up to 1055 K. The pump and the Nb/TiCuNi/BASE seal were used in a test that demonstrated all the operational functions of the RTC for the first time. An increase in the radiation reduction factor at constant input power was observed, indicating that the condenser was being wet by sodium resulting in an increased reflectivity.

Underwood, M. L.↗
NASA NTRS1989

Strategic materials availability and supply

An evaluation is made of the supply sources and current availability of elements involved in superalloy compositions, as well as of development trends in the substitution of strategic materials for superalloys, giving attention to the results thus far achieved by NASA's Conservation of Strategic Aerospace Materials program, which formally operated only from 1980 to 1984 but whose various research initiatives have been continued under other NASA programs. Peacetime and wartime economies' need and probable availability analyses are presented for bauxite/aluminum, the Pt-group metals, and the alloying elements Mn, Nb, Ta, Co, Cr, Ni, W, Fe, Cu, Ti, Mo, and Mg.

Stephens, Joseph R.↗
NASA NTRS1990

Oxidation characteristics of Ti-25Al-10Nb-3V-1Mo intermetallic alloy

Static oxidation kinetics of the super-alpha 2 titanium-aluminide alloy Ti-25Al-10Nb-3V-1Mo (at. percent) were investigated in air over the temperature range of 650 to 1000 C using thermogravimetric analysis. The oxidation kinetics were complex at all exposure temperatures and displayed up to three distinct oxidation rates. Breakaway oxidation occurred after long exposure times at high temperatures. Oxidation products were determined using x ray diffraction techniques, electron microprobe analysis, and energy dispersive x ray analysis. Oxide scale morphology was examined by scanning electron microscopy of the surfaces and cross sections of oxidized specimens. The oxides during the parabolic stages were compact and multilayered, consisting primarily of TiO2 doped with Nb, a top layer of Al2O3, and a thin bottom layer of TiN. The transition between the second and third parabolic stage was found to be linked to the formation of a TiAl layer at the oxide-metal interface. Porosity was formed during the third stage, causing degradation of the oxide and the beginning of breakaway oxidation.

Wallace, Terryl A.↗
NASA NTRS1990

AlSb/InAs/AlSb quantum wells

Researchers studied the InAs/AlSb system recently, obtaining 12nm wide quantum wells with room temperature mobilities up to 28,000 cm(exp 2)/V center dot S and low-temperature mobilities up to 325,000 cm(exp 2)/V center dot S, both at high electron sheet concentrations in the 10(exp 12)/cm(exp 2) range (corresponding to volume concentrations in the 10(exp 18)/cm(exp 2) range). These wells were not intentionally doped; the combination of high carrier concentrations and high mobilities suggest that the electrons are due to not-intentional modulation doping by an unknown donor in the AlSb barriers, presumably a stoichiometric defect, like an antisite donor. Inasmuch as not intentionally doped bulk AlSb is semi-insulating, the donor must be a deep one, being ionized only by draining into the even deeper InAs quantum well. The excellent transport properties are confirmed by other observations, like excellent quantum Hall effect data, and the successful use of the quantum wells as superconductive weak links between Nb electrodes, with unprecendentedly high critical current densities. The system is promising for future field effect transistors (FETs), but many processing problems must first be solved. Although the researchers have achieved FETs, the results so far have not been competitive with GaAs FETs.

Kroemer, Herbert↗
NASA NTRS1991

Effects of dust accumulation and removal on radiators surfaces on Mars

Tests were carried out to assess the impact of wind blown dust accumulation and abrasion on radiator surfaces on Mars. High emittance arc-textured copper and niobium-1 percent-zirconium samples were subjected to basaltic dust laden wind at Martian pressure (1000 Pa) at speeds varying from 19 to 97 m/s in the Martian Surface Wind Tunnel. The effect of accumulated dust was also observed by pre-dusting some of the samples before the test. Radiator degradation was determined by measuring the change in the emittance after dust was deposited and/or removed. The principle mode of degradation was abrasion. Arc textured Nb-1 percent-Zr proved to be more susceptible to degradation than Cu, and pre-dusting appeared to have lessened the abrasion.

Gaier, James R.↗
NASA NTRS1990

High-temperature metal purification using a compact, portable rf heating and levitation system on the wake shield

The potential use of a compact, battery-operated rf levitator and heating system to purify high-temperature melting materials in space is described. The wake shield now being fabricated for the Space Vacuum Epitaxy Center will provide an Ultra-high vacuum (10(exp -14) Torr hydrogen, 10(exp -14) Torr helium, 10(exp -30) Torr oxygen). The use of the wake shield to purify Nb, Ti, W, Ir, and other metals to a purity level not achievable on earth is described.

Hahs, C. A.↗