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At least 397 records · Page 22

An analysis of the AVE-SESAME I period using statistical structure and correlation functions

Structure and correlation functions are used to describe atmospheric variability during the 10-11 April day of AVE-SESAME 1979 that coincided with the Red River Valley tornado outbreak. The special mesoscale rawinsonde data are employed in calculations involving temperature, geopotential height, horizontal wind speed and mixing ratio. Functional analyses are performed in both the lower and upper troposphere for the composite 24 h experiment period and at individual 3 h observation times. Results show that mesoscale features are prominent during the composite period. Fields of mixing ratio and horizontal wind speed exhibit the greatest amounts of small-scale variance, whereas temperature and geopotential height contain the least. Results for the nine individual times show that small-scale variance is greatest during the convective outbreak. The functions also are used to estimate random errors in the rawinsonde data. Finally, sensitivity analyses are presented to quantify confidence limits of the structure functions.

Fuelberg, H. E.↗

Impact of land-surface moisture variability on local shallow convective cumulus and precipitation in large-scale models

Numerical experiments using state-of-the-art high-resolution mesoscale cloud model showed that land-surface moisture significantly affects the timing of onset of clouds and the intensity and distribution of precipitation. In general, landscape discontinuity enhances shallow convective precipitation. Two mechanisms that are strongly modulated by land-surface moisture-namely, random turbulent thermal cells and organized sea-breeze-like mesoscale circulations-also determine the horizontal distribution of maximum precipitation. However, interactions between shallow cumulus and land-surface moisture are highly nonlinear and complicated by different factors, such as atmospheric thermodynamic structure and large-scale background wind. This analysis also showed that land-surface moisture discontinuities seem to play a more important role in a relatively dry atmsophere, and that the strongest precipitation is produced by a wavelength of land-surface forcing equivalent to the local Rossby radius of deformation. A general trend between the maximum precipitation and the normalized maximum latent heat flux was identified. In general, large values of mesoscale latent heat flux imply strongly developed mesoscale circulations and intense cloud activity, accompanied by large surface latent heat fluxes that transport more water vapor into the atmosphere.

Chen, Fei↗

Dataset of tensile properties for sub-sized specimens of nuclear structural materials

Mechanical testing with sub-sized specimens plays an important role in the nuclear industry, facilitating tests in confined experimental spaces with lower irradiation levels and accelerating the qualification of new materials. The reduced size of specimens results in different material behavior at the microscale, mesoscale, and macroscale, in comparison to standard-sized specimens, which is referred to as the “specimen size effect.” Although analytical models have been proposed to correlate the properties of sub-sized specimens to standard-sized specimens, these models lack broad applicability across different materials and testing conditions. The objective of this study is to create the first large public dataset of tensile properties for sub-sized specimens used in nuclear structural materials. We performed an extensive literature review of relevant publications and extracted over 1,000 tensile testing records comprising 55 columns including material type and composition, manufacturing information, irradiation conditions, specimen dimensions, and tensile properties. The dataset can serve as a valuable resource to investigate the specimen size effect and develop computational methods to correlate the tensile properties of sub-sized specimens.

36 MATERIALS SCIENCE↗

A sensitivity analysis of twinning crystal plasticity finite element model using single crystal and poly crystal Zircaloy

The popularity of crystal plasticity finite element method (CPFEM) models is increasing due to their ability to predict the mechanical response of crystalline materials such as metals and metal alloys more accurately than traditional continuum mechanics models. This is since the crystal plasticity models consider the effect of atomic structure, microstructural morphology, and properties of individual grains. These CPFEM models use a large number of material parameters in order to capture the mesoscale physics which comes with the downside of the tedious calibration process. In this paper, a CPFEM code was developed to include the twinning induced grain reorientation and subsequent crystallographic slip for HPC material. The developed code is incorporated in a large-scale, parallelized nonlinear solver WARP3D. Further, a sensitivity analysis with respect to 22 material parameters was then conducted using single crystal and polycrystal representative volume element (RVE) of Zircaloy material. Loading was applied along five different crystallographic orientations for single crystal RVE and along three directions namely, rolling (RD), transverse (TD), and normal (ND) direction for polycrystal RVE. Results obtained from the sensitivity analysis were used for the calibration of material parameters for Zircaloy. Finally, developed code along with calibrated material parameters was used to investigate the effect of the hydride phase formation in Zircaloy which is a typical case observed for nuclear applications. It was found that the volume fraction of the hydride phase has a significant impact on the mechanical properties of Zircaloy.

36 MATERIALS SCIENCE↗

High altitude airborne remote sensing mission using the advanced microwave precipitation radiometer (AMPR)

The advanced microwave precipitation radiometer (AMPR) is an airborne multichannel imaging radiometer used to better understand how the earth's climate structure works. Airborne data results from the October 1990 Florida thunderstorm mission in Jacksonville, FL, are described. AMPR data on atmospheric precipitation in mesoscale storms were retrieved at 10.7, 19.35, 37.1, and 85.5 GHz onboard the ER-2 aircraft at an altitude of 20 km. AMPR's three higher-frequency data channels were selected to operate at the same frequencies as the spaceborne special sensor microwave/imager (SSM/I) presently in orbit. AMPR uses two antennas to receive the four frequencies: the lowest frequency channel uses a 9.7-in aperture lens antennas, while the three higher-frequency channels share a separate 5.3-in aperture lens antenna. The radiometer's temperature resolution performance is summarized.

Galliano, J.↗

A comparison of small and larger mesoscale latent heat and radiative fluxes: December 6 case study

Because of the small amounts of water vapor, the potential for rapid changes, and the very cold temperatures in the upper troposphere, moisture measuring instruments face several problems related to calibration and response. Calculations of eddy moisture fluxes are, therefore, subject to significant uncertainty. The purpose of this study is to examine the importance of latent heat (moisture) fluxes due to small and larger mesoscale circulations in comparison to radiative fluxes within cirrus. Scale separation is made at about 1 km because of significant changes in the structures within cirrus. Only observations at warmer than -40 C are used in this study. The EG&G hygrometer that is used for measuring dewpoint temperature (Td) is believed to be fairly accurate down to -40 C. On the other hand, Lyman-Alpha (L-alpha) hygrometer measurements of moisture may include large drift errors. In order to compensate for these drift errors, the L-alpha hygrometer is often calibrated against the EG&G hygrometer. However, large errors ensue for Td measurements at temperatures less than -40 C. The cryogenic hygrometer frost point measurements may be used to calibrate L-alpha measurements at temperatures less than -40 C. In this study, however, measurements obtained by EG&G hygrometer and L-alpha measurements are used for the flux calculations.

Gultepe, I.↗

Replication Data for: Neural network assisted analysis of bimetallic nanocatalysts using X-ray absorption near edge structure spectroscopy

The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Observational and numerical studies of extreme frontal scale contraction

The general objective of this effort is to increase understanding of how frontal scale contraction processes may create and sustain intense mesoscale precipitation along intensifying cold fronts. The five-part project (an expansion of the originally proposed two-part project) employed conventional meteorological data, special mesoscale data, remote sensing measurements, and various numerical models. First an idealized hydrostatic modeling study of the scale contraction effects of differential cloud cover on low-level frontal structure and dynamics was completed and published in a peer-reviewed journal. The second objective was to complete and publish the results from a three dimensional numerical model simulation of a cold front in which differential sensible heating related to cloud coverage patterns was apparently crucial in the formation of a severe frontal squall line. The third objective was to use a nonhydrostatic model to examine the nonlinear interactions between the transverse circulation arising from inhomogeneous cloud cover, the adiabatic frontal circulation related to semi-geostrophic forcing, and diabatic effects related to precipitation processes, in the development of a density current-like microstructure at the leading edge of cold fronts. Although the development of a frontal model that could be used to initialize such a primitive equation model was begun, we decided to focus our efforts instead on a project that could be successfully completed in this short time, due to the lack of prospects for continued NASA funding beyond this first year (our proposal was not accepted for future funding). Thus, a fourth task was added, which was to use the nonhydrostatic model to test tentative hypotheses developed from the most detailed observations ever obtained on a density current (primarily sodar and wind profiler data). These simulations were successfully completed, the findings were reported at a scientific conference, and the results have recently been submitted to a peer-reviewed journal. The fifth objective was to complete the analysis of data collected during the Cooperative Oklahoma Profiler Studies (COPS-91) field project, which was supported by NASA. The analysis of the mesoscale surface and sounding data, Doppler radar imagery, and other remote sensing data from multi frequency wind profiler, microwave radiometer, and the Radio Acoustic Sounding System has been completed. This study is a unique investigation of processes that caused the contraction of a cold front to a microscale zone exhibiting an undular bore-like structure. Results were reported at a scientific conference and are being prepared for publication. In summary, considerable progress has been achieved under NASA funding in furthering our understanding of frontal scale contraction and density current - gravity wave interaction processes, and in utilizing models and remotely sensed data in such studies.

Koch, Steven E.↗

Structure and Dynamics of Domains in Ferroelectric Nanostructures – Phase-Field Modeling (Final Technical Report)

Domain pattern formation is one of the most common phenomena in nature and is a topic of immense interest in many fields ranging from materials science and physics to chemistry and biology. This DOE sponsored research project explored the basic science concerning the thermodynamic stability of mesoscale polarization domain patterns and their temporal evolution mechanisms during formation and subsequent switching in ferroelectric nanostructures and heterostructures. The project employed the computational phase-field method in combination of microelasticity and electrostatic theories. The research was carried out in close collaboration with a number of experimental groups who used High Resolution Transmission Electron Microscopy (HRTEM), in situ TEM with Scanning Probe Microscopy (SPM), or Piezoresponse Force Microscopy (PFM) to characterize the domain structures and dynamics of ferroelectric thin films and heterostructures and who grow high-quality ferroelectric and multiferroic thin films using advanced growth techniques such as Molecular Beam Epitaxy (MBE), Pulsed Laser Deposition (PLLD), and sputtering. The research efforts of the project help establish the phase-field method as the most powerful method for understanding and predicting domain structures in ferroelectric thin films and nanostructures. The findings of the project led to the basic understanding of stability and switching mechanisms of ferroelectric domains under different mechanical boundary conditions and under either homogeneous capacitor configurations or local fields using metallic probes as electrodes and the emergence of charged domain walls during domain switching. The project predicted the spatial length scales, temperature ranges, and electromechanical conditions for different polar states in heterostructures and guided the discovery of both transient and stable novel polarization states containing vortex lattices in oxide superlattices. The project resulted in 134 journal publications and 6 PhD theses with all the PhD graduates currently working in either academia or industry within the United States. The basic understanding on the stability of mesoscale polar states and pattern evolution achieved by the project improved our ability to control and engineer properties of ferroelectric thin films and heterostructures for potential applications in nanoscale electronic devices.

36 MATERIALS SCIENCE↗

The study of mesoscale phenomena, winter monsoon clouds and snow area

The author has identified the following significant results. The clouds under a moderate winter monsoon situation taken with S190A camera reveal existence of clouds with band structure of various wavelengths. The wavelength ranges from 0.4 to 3.5 kms. There was a good relationship between the longitudinal cloud band and vertical wind shear. There was a distinct difference in size of clouds between the Japan Sea side or upwind side and the Pacific Ocean side or downwind side of the Japanese mainland. Large solid cumulus clusters have the size of 20 x 35 sq km over the Japan Sea off the coast of Hokuriku District. It was found that S190A aerial color pictures showing shadows of fair weather cumuli over the sea could be successfully used in estimating cloud height while S190A station 1 picture was more useful over the land since it could more clearly distinguish shadow from vegetation. The height of fair weather cumuli estimated from shadows agree with the lifted condensation level. It was also found that these pictures were effectively used in delineating snow cover area. S192 data, especially IR channel, were found to be effective in finding topography of nimbostratus.

Tsuchiya, K.↗

Mesoscale simulations of High Burnup Fuel Fragmentation: Applying phase-field modeling to understand high burnup fuel fragmentation during loss of coolant accident conditions

During a loss-of-coolant accident (LOCA) in a nuclear power plant, a rapid increase in temperature is experienced in the fuel. In commercial light water reactors (LWRs), the high burnup structure (HBS) forms in regions of the UO 2 fuel where local burnup is high, characterized by smaller grain sizes and large, overpressurized bubbles. During a LOCA transient, fuel in the HBS region is susceptible to fine fragmentation, where the fuel breaks up into micron-size fragments (sometimes referred to as pulverization). To better understand the mechanisms behind this phenomenon, mesoscale computational modeling using the Idaho National Laboratory code Marmot has been employed to simulate the process of HBS formation and response to a LOCA transient. The process of complete and partial HBS formation was demonstrated in prototypical LWR conditions. The simulated HBS microstructures from these simulations were passed to a phase-field model of fracture. To provide a more direct comparison with experiments, a set of experiments conducted by Studsvik on fine fragmentation/pulverization during LOCA conditions was simulated using the BISON fuel performance code. The temperature profiles from the BISON simulations were passed to a phase-field model to determine the gas bubble pressure as a function of time. These pressure histories were used in a phase-field model of fracture to determine under what conditions and in which types of bubbles fine fragmentation was likely to occur.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Emergent topological polarization textures in relaxor ferroelectrics

Relaxor ferroelectrics underpin high-performance actuators and sensors, yet the nature of polar heterogeneities driving their broadband dielectric response remains debated. Using a unified, multimodal structural refinement framework— simultaneously fitting complementary X-ray and neutron total scattering, X-ray absorption spectra, and diffuse scattering—we reconstruct 3D mesoscale polarization maps in the classic relaxor system PbMg 1/3 Nb 2/3 O 3 –PbTiO 3 . We uncover self-organized swirling polarization textures with half-skyrmion (meron) vortices, challenging models of independent polar nanoregions. These textures, characterized by smooth changes in the polarization direction, originate from overlapping volumes in which the projections of locally correlated polarization vectors onto each volume’s long axis share the same sign. Vortex cores correlate strongly with local charge and strain gradients imposed by compositional heterogeneities. In this work, our results suggest that chemical disorder, acting via depolarizing and strain fields, stabilizes topological vortex textures of the polarization field, offering a route for engineering new dielectric and ferroelectric functionalities.

Eremenko, Maksim [National Institute of Standards ↗

The Structure and Dynamics of an Observed Moist Front

The structure and dynamics of the moist cold front of 25 and 26 April 1979, the third observing day of the Severe Environmental Storms and Mesoscale experiment (SESAME), are investigated through the use of a three-dimensional mesoscale numerical model. This work is one of the first studies in which model results are compared, in a one-to-one manner, with a detailed observational analysis, namely that of Ogura and Portis (1982) as taken from the SESAME observations. In addition, frontogenetical effects, both adiabatic and diabatic, are studied on a vertical cross-section through the front; similarities and differences with the adiabatic analysis of Ogura and Portis are discussed. Many similarities exist between the modeled and analyzed fields, although the analysis tends to have weaker horizontal gradients due to the coarseness of the observational network. Vorticity and convergence near the surface were found to have the same magnitude in both the model solution and the analysis, in contrast to idealized frontogenesis models which predict vorticity to be much larger than convergence.

Orlanski, I.↗

Nonlinear influence of mesoscale land use on weather and climate

It is shown that the influence of mesoscale landscape spatial variability on the atmosphere must be parameterized or explicitly modeled in larger-scale atmospheric model simulations including general circulation models. The mesoscale fluxes of heat that result from this variability are shown to be of the same order of magnitude but with a different vertical structure than found for the turbulent fluxes. These conclusions are based on experiments in which no phase changes of water were permitted. To parameterize surface thermal inhomogeneities, the influence of landscape must be evaluated using spectral analysis or an equivalent procedure. To include the nonlinear contribution of each scale, numerical model simulations for the range of observed surface and overlying atmospheric conditions must be performed.

Pielke, R. A.↗

Cirrus cloud development in a mobile upper tropospheric trough: The November 26th FIRE cirrus case study

The period from 18 UTC 26 Nov. 1991 to roughly 23 UTC 26 Nov. 1991 is one of the study periods of the FIRE (First International Satellite Cloud Climatology Regional Experiment) 2 field campaign. The middle and upper tropospheric cloud data that was collected during this time allowed FIRE scientists to learn a great deal about the detailed structure, microphysics, and radiative characteristics of the mid latitude cirrus that occurred during that time. Modeling studies that range from the microphysical to the mesoscale are now underway attempting to piece the detailed knowledge of this cloud system into a coherent picture of the atmospheric processes important to cirrus cloud development and maintenance. An important component of the modeling work, either as an input parameter in the case of cloud-scale models, or as output in the case of meso and larger scale models, is the large scale forcing of the cloud system. By forcing we mean the synoptic scale vertical motions and moisture budget that initially send air parcels ascending and supply the water vapor to allow condensation during ascent. Defining this forcing from the synoptic scale to the cloud scale is one of the stated scientific objectives of the FIRE program. From the standpoint of model validation, it is also necessary that the vertical motions and large scale moisture budget of the case studies be derived from observations. It is considered important that the models used to simulate the observed cloud fields begin with the correct dynamics and that the dynamics be in the right place for the right reasons.

Mace, Gerald G.↗

Role of Stratospheric Air in a Severe Weather Event: Analysis of Potential Vorticity and Total Ozone

The role of dry stratospheric air descending to low and middle tropospheric levels in a severe weather outbreak in the midwestern United States is examined using ACCEPT Eta model output, Rapid Update Cycle (RUC) analyses, and Earth probe Total Ozone Mapping Spectrometer (EP/TOMS) total ozone data. While stratospheric air was not found to play a direct role in the convection, backward trajectories show stratospheric air descended to 800 hPa just west of the convection. Damaging surface winds not associated with thunderstorms also occurred in the region of greatest stratospheric descent. Small-scale features in the high-resolution total ozone data compare favorably with geopotential heights and potential vorticity fields, supporting the notion that stratospheric air descended to near the surface. A detailed vertical structure in the potential vorticity appears to be captured by small-scale total ozone variations. The capability of the total ozone to identify mesoscale features assists model verification. The total ozone data suggest biases in the RUC analysis and Eta forecast of this event. The total ozone is also useful in determining whether potential vorticity is of stratospheric origin or is diabatically generated in the troposphere.

Goering, Melissa A.↗

High-Resolution NU-WRF Simulations of a Deep Convective-Precipitation System During MC3E: Comparisons Between Goddard Microphysics Schemes and Observations - Part 1

The Goddard microphysics scheme was recently improved by adding a 4th ice class (frozen dropshail). This new 4ICE scheme was implemented and tested in the Goddard Cumulus Ensemble model (GCE) for an intense continental squall line and a moderate,less-organized continental case. Simulated peak radar reflectivity profiles were improved both in intensity and shape for both cases as were the overall reflectivity probability distributions versus observations. In this study, the new Goddard 4ICE scheme is implemented into the regional-scale NASA Unified - Weather Research and Forecasting model (NU-WRF) and tested on an intense mesoscale convective system that occurred during the Midlatitude Continental Convective Clouds Experiment (MC3E). The NU42WRF simulated radar reflectivities, rainfall intensities, and vertical and horizontal structure using the new 4ICE scheme agree as well as or significantly better with observations than when using previous versions of the Goddard 3ICE (graupel or hail) schemes. In the 4ICE scheme, the bin microphysics-based rain evaporation correction produces more erect convective cores, while modification of the unrealistic collection of ice by dry hail produces narrow and intense cores, allowing more slow-falling snow to be transported rearward. Together with a revised snow size mapping, the 4ICE scheme produces a more horizontally stratified trailing stratiform region with a broad, more coherent light rain area. In addition, the NU-WRF 4ICE simulated radar reflectivity distributions are consistent with and generally superior to those using the GCE due to the less restrictive open lateral boundaries

Regional Scale Model↗

Replication Data for: Latent Representation Learning for Structural Characterization of Catalysts

The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗