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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

Bulk Growth of Wide Band Gap II-VI Compound Semiconductors by Physical Vapor Transport

The mechanism of physical vapor transport of II-VI semiconducting compounds was studied both theoretically, using a one-dimensional diffusion model, as well as experimentally. It was found that the vapor phase stoichiometry is critical in determining the vapor transport rate. The experimental heat treatment methods to control the vapor composition over the starting materials were investigated and the effectiveness of the heat treatments was confirmed by partial pressure measurements using an optical absorption technique. The effect of residual (foreign) gas on the transport rate was also studies theoretically by the diffusion model and confirmed experimentally by the measurements of total pressure and compositions of the residual gas. An in-situ dynamic technique for the transport rate measurements and a further extension of the technique that simultaneously measured the partial pressures and transport rates were performed and, for the first time, the experimentally determined mass fluxes were compared with those calculated, without any adjustable parameters, from the diffusion model. Using the information obtained from the experimental transport rate measurements as guideline high quality bulk crystal of wide band gap II-VI semiconductor were grown from the source materials which undergone the same heat treatment methods. The grown crystals were then extensively characterized with emphasis on the analysis of the crystalline structural defects.

Su, Ching-Hua↗
NASA NTRS1997

Bulk Growth of Wide Band Gap II-VI Compound Semiconductors by Physical Vapor Transport

The mechanism of physical vapor transport of II-VI semiconducting compounds was studied both theoretically, using a one-dimensional diffusion model, as well as experimentally. It was found that the vapor phase stoichiometry is critical in determining the vapor transport rate. The experimental heat treatment methods to control the vapor composition over the starting materials were investigated and the effectiveness of the heat treatments was confirmed by partial pressure measurements using an optical absorption technique. The effect of residual (foreign) gas on the transport rate was also studies theoretically by the diffusion model and confirmed experimentally by the measurements of total pressure and compositions of the residual gas. An in-situ dynamic technique for the transport rate measurements and a further extension of the technique that simultaneously measured the partial pressures and transport rates were performed and, for the first time, the experimentally determined mass fluxes were compared with those calculated, without any adjustable parameters, from the diffusion model. Using the information obtained from the experimental transport rate measurements as guideline high quality bulk crystal of wide band gap II-VI semiconductor were grown from the source materials which undergone the same heat treatment methods. The grown crystals were then extensively characterized with emphasis on the analysis of the crystalline structural defects.

Su, Ching-Hua↗
NASA NTRSDate not supplied

Experimental and Numerical Investigation of the NASA High Efficiency Centrifugal Compressor Vaned Stage Geometry and Aerodynamic Performance

Since its inception in the early 2010s, the NASA High Efficiency Centrifugal Compressor (HECC) has been enigmatic for the propulsion research community: experimental data and numerical simulations of the stage have generally not aligned in their quantifications of performance metrics. Typically, the fault for these disagreements is assigned to the numerical simulations as the simulations are models, and models are inherently incomplete representations of the experiment. This “incompleteness” may manifest in assumptions regarding roughness or heat transfer, simplifications of the flow path (i.e., neglecting bleed flows), or the oft-scapegoated turbulence model. In the case of HECC, recent work showed unexpected discrepancies between the intended impeller geometry defined in the design report (termed Design-Intent) and the manufactured impeller used in the experimental campaigns (termed As-Manufactured). That work used numerical simulations to establish that the geometric differences between the Design-Intent and As-Manufactured impellers were significant enough to result in drastically different performance predictions for the HECC vaneless diffuser configuration. The Design-Intent impeller simulations over predicted the performance relative to the experiment, whereas the As-Manufactured simulations better represented the experimental data, both in terms of one-dimensional performance metrics and spanwise flow profiles. This effort expands on that work by examining in detail the geometry and aerodynamic performance of the HECC vaned diffuser configuration. Further differences between the Design-Intent and As-Manufactured geometries have been discovered in the vaned diffuser and exit guide vanes, and these differences are documented herein. The summations of the geometric differences for all of the components were used to create two numerical models of HECC vaned diffuser configuration: the Design-Intent simulations which are generated from the original geometry definitions given in the design report and the As-Manufactured simulations which are the best available representation of the manufactured compressor hardware used in the experimental test campaigns. In congruence with the earlier vaneless diffuser work, the numerical predictions of the Design-Intent choked mass flow rate, total pressure ratio, and efficiency were notably greater than that of the As-Manufactured simulations. To increase confidence in the experimental dataset, measurements from a recent test campaign conducted in 2024 are used to validate the original experimental data acquired from 2012 to 2014 with good repeatability overall, especially considering the passage of time and differences in the data acquisition systems between the test campaigns. Both numerical simulations were then extensively evaluated against the experimental data. The As-Manufactured simulations provided better estimates of the stage performance than the Design-Intent cases in terms of most performance metrics. Nonetheless, more detailed results still show opportunities for improvement. Despite a more accurate representation of the physical hardware, characterization of the impeller work input remains a challenge even for rigorously developed numerical models.

centrifugal compressor↗
NASA NTRS1982

Diffusive-convective physical vapor transport of PbTe from a Te-rich solid source

Crystal growth of PbTe by physical vapor transport (sublimation) in a closed ampoule is governed by the vapor species in thermal equilibrium with the solid compound. Deviations from stoichiometry in the source material cause diffusion limitation of the transport rate, which can be modified by natural (gravity-driven) convection. Mass-transport experiments have been performed using Te-rich material wherein sublimation rates have been measured in order to study the effects of natural convection in diffusion-limited vapor transport. Linear velocities for both crystal growth and evaporation (back sublimation) have been measured for transport in the direction of gravity, horizontally, and opposite to gravity. The experimental results are discussed in terms of both the one-dimensional diffusive-advective model and current, more sophisticated theory which includes natural convection. There is some evidence that convection effects from radial temperature gradients and solutal density gradients have been observed.

Zoutendyk, J.↗
NASA NTRS2020

A Global End-Member Approach to Derive aCDOM(440) from Near-Surface Optical Measurements

This study establishes an optical inversion scheme for deriving the absorption coefficient of colored (or chromophoric, depending on the literature) dissolved organic material (CDOM) at the 440 nm wavelength, which can be applied to global water masses with near-equal efficacy. The approach uses a ratio of diffuse attenuation coefficient spectral end members, i.e., a short and long wavelength pair. The global perspective is established by sampling "extremely" clear water plus a generalized extent in turbidity and optical properties that each span three decades of dynamic range. A unique data set was collected in oceanic, coastal, and inland waters (as shallow as 0.6 m) from the North Pacific Ocean, the Arctic Ocean, Hawaii, Japan, Puerto Rico, and the east and west coasts of the United States. The data were partitioned using subjective categorizations to define a validation quality subset of conservative water masses, i.e., the inflow and outflow of properties constrain the range in the gradient of a constituent, plus 15 subcategories of water masses that were not evolving conservatively. The dependence on subcategories was confirmed with an objective methodology based on cluster analysis techniques. The latter defined five distinct classes with validation quality data present in all classes, but which also decreased in percent composition as a function of increasing class number and optical complexity. Four different algorithms based on different validation quality end members were validated with accuracies of 1.–6.2 %, wherein pairs with the largest spectral span were most accurate. Although algorithm accuracy decreased with the inclusion of more subcategories containing non-conservative water masses, changes to the algorithm fit were small when a preponderance of subcategories were included. The high accuracy for all end-member algorithms was the result of data acquisition and data processing improvements, e.g., increased vertical sampling resolution to less than 1mm and a boundary constraint to mitigate wave focusing effects, respectively. An independent evaluation with a historical database confirmed the consistency of the algorithmic approach and its application to quality assurance, e.g., to flag data outside expected ranges, identify suspect spectra, and objectively determine the in-water extrapolation interval by converging agreement for all applicable end-member algorithms. The legacy data exhibit degraded performance (as 44 % uncertainty) due to a lack of high-quality near-surface observations, especially for clear waters wherein wave-focusing effects are problematic. The novel optical approach allows the in situ estimation of an in-water constituent in keeping with the accuracy obtained in the laboratory.

Stanford B Hooker↗
NASA NTRS1995

Morphology, near-infrared luminosity, and mass of the Galactic bulge from COBE DIRBE observations

Near-infrared images of the Galactic bulge at 1.25, 2.2, 3.5, and 4.9 microns obtained by the Diffuse Infrared Background Experiment (DIRBE) onboard the Cosmic Background Explorer (COBE) satellite are used to characterize its morphology and to determine its infrared luminosity and mass. Earlier analysis of the DIRBE observations (Weiland et al. 1994) provided supporting evidence for the claim made by Blitz & Spergel (1991) that the bulge is bar-shaped with its near end in the first Galactic quadrant. Adopting various triaxial analytical functions to represent the volume emissivity of the source, we confirm the barlike nature of the bulge and show that triaxial Gaussian-type functions provide a better fit to the data than other classes of functions, including an axisymmetric spheroid. The introduction of a `boxy' geometry, such as the one used by Kent, Dame, & Fazio (1991) improves the fit to the data. Our results show that the bar is rotated in the plane with its near side in the first Galactic quadrant creating an angle of 20 deg +/- 10 deg between its major axis and the line of sight to the Galactic center. Typical axis ratios of the bar are (1:0.33 +/- 0.11:0.23 +/- 0.08), resembling the geometry of prolate spheroids. There is no statistically significant evidence for an out-of-plane tilt of the bar at 2.2 microns, and marginal evidence for a tilt of approximately equal 2 deg at 4.9 microns. The introduction of a roll around the intrinsic major axis of the bulge improves the `boxy' appearance of some functions. A simple integration of the observed projected intensity of the bulge gives a bulge luminosity of 1.2 x 10(exp 9), 4.1 x 10(exp 8), 2.3 x 10(exp 8), and 4.3 x 10(exp 7) solar luminosity, respectively, at 1.25, 2.2, 3.5, and 4.9 microns wavelength for a Galactocentric distance of 8.5 kpc. The 2.2 microns luminosity function of the bulge population in the direction of Baade's window yields a bolometric luminosity of L(sub bol) = 5.3 x 10(exp 9) solar luminosity. Stellar evolutionary models relate this luminosity to the number of main-sequence progenitor stars that currently populate the red giant branch. Combined with the recent determination of the main-sequence turnoff mass for the bulge by the Hubble Space Telescope (Holtzman et al. 1993) we derive a photometrically determined bulge mass of approximately equal to 1.3 x 10(exp 10) solar mass for a Salpeter initial mass function extended down to 0.1 solar mass.

Dwek, E.↗
NASA NTRS1992

Tidal heating and mass loss in neutron star binaries - Implications for gamma-ray burst models

A neutron star in a close binary orbit around another neutron star (or stellar-mass black hole) spirals inward owing to gravitational radiation. We discuss the effects of tidal dissipation during this process. Tidal energy dissipated in the neutron star's core escapes mainly as neutrinos, but heating of the crust, and outward diffusion of photons, blows off the outer layers of the star. This photon-driven mass loss precedes the final coalescence. The presence of this eject material impedes the escape of gamma-rays created via neutrino interactions. If an e(+) - e(-) fireball, created in the late stages of coalescence, were loaded with (or surrounded by) material with the mean column density of the ejecta, it could not be an efficient source of gamma-rays. Models for cosmologically distant gamma-rays burst that involve neutron stars must therefore be anisotropic, so that the fireball expands preferentially in directions where the column density of previously blown-off material is far below the spherically averaged value which we have calculated. Some possible 'scenarios' along these lines are briefly discussed.

Meszaros, P.↗
NASA NTRS1972

Collision integrals for isotopic hydrogen molecules.

The study was undertaken to determine the effects of reduced mass and differences in asymmetry on the collision integrals and thermal diffusion factors of isotopic hydrogen systems. Each system selected for study consisted of two diatoms, one in the j = 0 rotation state and the other in the j = 1 state. The molecules interacted with a Lennard-Jones type potential modified to include angular terms. A set of cross sections and collision integrals were obtained for each system.

Brown, N. J.↗
NASA NTRS1973

Determination of hydrogen in milligram quantities of titanium and its alloys

An accurate, versatile, and sensitive method for the determination of hydrogen in milligram-size titanium samples is presented. It involves extraction of hydrogen at 1070 K while a mercury diffusion pump transfers the evolved gases into the inlet of a mass spectrometer. All the evolved gases may then be positively identified and determined. This method can be readily adapted for use with other metals and for the study of the slow evolution of hydrogen. Reduction of interferences due to the evolution of hydrogen by reactions involving vapors such as those of water, acetone, and vacuum grease is discussed.

Otterson, D. A.↗
NASA NTRS1979

Laser aircraft

The concept of a laser-powered aircraft is discussed. Laser flight would be completely compatible with existing airports and air-traffic control, with the airplane using kerosene only power, up to a cruising altitude of 9 km where the laser satellite would lock on and beam laser energy to it. Two major components make up the laser turbofan, a heat exchanger for converting laser radiation into thermal energy, and conventional turbomachinery. The laser power satellite would put out 42 Mw using a solar-powered thermal engine to generate electrical power for the closed-cycle supersonic electric discharge CO laser, whose radiators, heat exchangers, supersonic diffuser, and ducting will amount to 85% of the total subsystem mass. Relay satellites will be used to intercept the beam from the laser satellite, correct outgoing beam aberrations, and direct the beam to the next target. A 300-airplane fleet with transcontinental range is projected to save enough kerosene to equal the energy content of the entire system, including power and relay satellites, in one year.

Hertzberg, A.↗
NASA NTRS1979

Acoustic-gravity waves in the thermosphere of Venus

The paper studies the properties of acoustic-gravity waves in the upper atmosphere of Venus by means of a two fluid model which includes the effects of wave-induced diffusion in a diffusively separated atmosphere. It is maintained that in conjunction with neutral mass spectrometer data from the Pioneer Venus orbiter, the theory should provide information on the distribution of wave sources in the Venus upper atmosphere. In addition observed wave structure in species density measurements should generally have periods less than or equal to 30-35 min, small N2, CO, and O amplitudes, and highly variable phase shifts relative to CO2. Finally, it is noted that large-density oscillations in stratospheric cloud layer constituents are also possible and may be detectable by the Pioneer Venus large probe neutral mass spectrometer.

Del Genio, A. D.↗
NASA NTRS1986

Effect of area ratio on the performance of a 5.5:1 pressure ratio centrifugal impeller

A centrifugal impeller which was initially designed for a pressure ratio of approximately 5.5 and a mass flow rate of 0.959 kg/sec was tested with a vaneless diffuser for a range of design point impeller area ratios from 2.322 to 2.945. The impeller area ratio was changed by successively cutting back the impeller exit axial width from an initial value of 7.57 mm to a final value of 5.97 mm. In all, four separate area ratios were tested. For each area ratio a series of impeller exit axial clearances was also tested. Test results are based on impeller exit surveys of total pressure, total temperature, and flow angle at a radius 1.115 times the impeller exit radius. Results of the tests at design speed, peak efficiency, and an exit tip clearance of 8 percent of exit blade height show that the impeller equivalent pressure recovery coefficient peaked at a design point area ratio of approximately 2.748 while the impeller aerodynamic efficiency peaked at a lower value of area ratio of approximately 2.55. The variation of impeller efficiency with clearance showed expected trends with a loss of approximately 0.4 points in impeller efficiency for each percent increase in exit axial tip clearance for all impellers tested.

Schumann, L. F.↗
NASA NTRS1986

Evolution of a meteorite crater as a process of random displacements

An examination of the ages and sizes of 114 terrestrial impact craters shows that their aging kinetics can be described by the diffusion laws. The macrodiffusion coefficient which determines random displacements of mineral masses on the Earth has a mean value of 0.02 sq m/year. The amount of matter in a crater that contains information about the impact event decreases with time according to the 1/T law. The basic characteristic parameter of a crater is its initial area, inasmuch as sufficiently large craters are nearly surficial formations. The relaxation time of a crater is proportional to its initial area.

Zotkin, I. T.↗
NASA NTRS1985

A wide-latitude CO survey of molecular clouds in the northern Milky Way

A wide-latitude, low angular resolution survey of CO along most of the first Galactic quadrant and part of the second was undertaken in order to investigate molecular clouds associated with the Great Rift and the diffuse component of Galactic gamma rays. The main nearby clouds have masses between a few times 10,000 and a few times 100,000 solar masses, versus a few times a million solar masses for the largest complexes elsewhere. The CO emission in the survey comes nearly equally from local clouds associated with the Great Rift and from distant clouds in the inner arms of the Galaxy 4-7 kpc from the Galactic center. The half-thickness at half-intensity of the local molecular cloud layer is greater than 50 pc and is estimated to be 75 + or - 25 pc. The results strongly support the notion that all dark nebulae are molecular clouds, and vice-versa.

Dame, T. M.↗
NASA NTRS1986

Effect of area ratio on the performance of a 5.5:1 pressure ratio centrifugal impeller

A centrifugal impeller which was initially designed for a pressure ratio of approximately 5.5 and a mass flow rate of 0.959 kg/sec was tested with a vaneless diffuser for a range of design point impeller area ratios from 2.322 to 2.945. The impeller area ratio was changed by successively cutting back the impeller exit axial width from an initial value of 7.57 mm to a final value of 5.97 mm. In all, four separate area ratios were tested. For each area ratio a series of impeller exit axial clearances was also tested. Test results are based on impeller exit surveys of total pressure, total temperature, and flow angle at a radius 1.115 times the impeller exit radius. Results of the tests at design speed, peak efficiency, and an exit tip clearance of 8 percent of exit blade height show that the impeller equivalent pressure recovery coefficient peaked at a design point area ratio of approximately 2.748 while the impeller aerodynamic efficiency peaked at a lower value of area ratio of approximately 2.55. The variation of impeller efficiency with clearance showed expected trends with a loss of approximately 0.4 points in impeller efficiency for each percent increase in exit axial tip clearance for all impellers tested.

Schumann, L. F.↗
NASA NTRS1993

Dynamical instability as the cause of the massive outbursts in Eta Carinae and other luminous blue variables

A new type of stellar envelope structure has been computationally discovered at very high stellar masses. The outer part of the envelope resembles a nearly detached, diffusely filled shell overlying an ultrahot surface of small radius. This structural anomaly is caused by a large iron bump occurring in the new opacities of Iglesias et al. (1992). The new stellar models with normal metallicity encounter a strong ionization-induced dynamical instability in the outer envelope as they rapidly transit the H-R diagram after the end of central hydrogen burning. Preliminary evolutionary and hydrodynamical calculations successfully mimic the most basic observed properties of Eta Carinae and other very luminous blue variables. The Humphreys-Davidson sloped line in the H-R diagram, however, seems to be unrelated to these variables, and is instead the observed terminus of the main-sequence phase of evolution if convective core overshooting is insignificant.

Stothers, Richard B.↗
NASA NTRS1995

Modeling of turbulent chemical reaction

Viewgraphs are presented on modeling turbulent reacting flows, regimes of turbulent combustion, regimes of premixed and regimes of non-premixed turbulent combustion, chemical closure models, flamelet model, conditional moment closure (CMC), NO(x) emissions from turbulent H2 jet flames, probability density function (PDF), departures from chemical equilibrium, mixing models for PDF methods, comparison of predicted and measured H2O mass fractions in turbulent nonpremixed jet flames, experimental evidence of preferential diffusion in turbulent jet flames, and computation of turbulent reacting flows.

Chen, J.-Y.↗
NASA NTRS1996

Non-linear resonance of fluids in a crystal growth cavity

In the microgravity environment, the effect of gravity on fluid motion is much reduced. Hence, secondary effects such as vibrations, jitters, surface tension, capillary effects, and electromagnetic forces become the dominant mechanism of fluid convection. Numerous studies have been conducted to investigate fluid behavior in microgravity with the ultimate goal of developing processes with minimal influence from convection. Industrial applications such as crystal growth from solidification of melt and protein growth for pharmatheutical application are just a few examples of the vast potential benefit that can be reaped from material processing in space. However, a space laboratory is not immune from all undesirable disturbances and it is imperative that such disturbances be well understood, quantifiable, and controlled. Non-uniform and transient accelerations such as vibrations, jitters, and impulsive accelerations exist as a result of crew activities, space vehicle maneuvering, and the operations of on-board equipment. Measurements conducted on-board a U.S. Spacelab showed the existence of vibrations in the frequency range of 1 to 100 Hz with a dominant mode of 17 Hz and harmonics of 54 Hz. The observed vibration is not limited to any coordinate plane but exists in all directions. Similar situation exists on-board the Russian MIR space station. Due to the large structure of its design, the future International Space Station will have its own characteristic vibration spectrum. It is well known that vibration can exert substantial influence on heat and mass transfer processes, thus hindering any attempts to achieve a diffusion-limited process. Experiments on vibration convection for a liquid-filled enclosure under one-g environment showed the existence of different flow regimes as vibration frequency and intensity changes. Results showed the existence of a resonant frequency, near which the enhancement is the strongest, and the existence of a high frequency asymptote. Numerical simulations of vibration convection have been conducted by Yurkov, Fu and Shieh, and by Wang. These analyses considered a two-dimensional air-filled cell under weightlessness condition and showed results similar to those of the experiments. It is not yet known whether resonance convection can be triggered by jitter alone or whether it requires the interaction of jitter with other convective forces in low gravity. An order of magnitude analysis, however, can be used to show the dependence of the resonance frequency on the fluid Prandtl number. Even though the onset of resonance convection may depend on other factors, results indicates that fluids with low Prandtl numbers are more susceptible to resonance than those with high Prandtl numbers. The current study is aimed at gaining additional insights to this problem using germanium as working fluid. Germanium was chosen for this analysis because of its common usage in solidification process and its relatively low Prandtl number (Pr = 0.02).

Wang, Francis C.↗