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NASA NTRS2006

Water Vapor Sensors Go Sky-High to Assure Aircraft Safety

JPL used a special tunable diode laser, which NASA scientists could tune to different wavelengths, like a radio being tuned to different frequencies, to accurately target specific molecules and detect small traces of gas. This tunable diode laser was designed to emit near-infrared light at wavelengths absorbed by the gas or gases being detected. The light energy being absorbed by the target gas is related to the molecules present. This is usually measured in parts per million or parts per billion. Multiple measurements are made every second, making the system quick to respond to variations in the target gas. NASA scientists developed this technology as part of the 1999 Mars Polar Lander mission to explore the possibility of life-giving elements on Mars. NASA has since used the tunable diode laser-based gas sensor on aircraft and on balloons to successfully study weather and climate, global warming, emissions from aircraft, and numerous other areas where chemical gas analysis is needed. SpectraSensors, Inc., was formed in 1999 as a spinoff company of JPL, to commercialize tunable diode laser-based analyzers for industrial gas-sensing applications (Spinoff 2000). Now, the San Dimas, California-based firm has come back to the market with a new product featuring the NASA-developed instrument for atmospheric monitoring. This instrument is now helping aircraft avoid hazardous weather conditions and enabling the National Weather Service to provide more accurate weather forecasts.

Source record↗

NASA NTRS2012

A Cloud Greenhouse Effect on Mars: Significant Climate Change in the Recent Past

The large variations in Mars orbit parameters are known to be significant drivers of climate change on the Red planet. The recent discovery of buried CO2 ice at the South Pole adds another dimension to climate change studies. In this paper we present results from the Ames GCM that show within the past million years it is possible that clouds from a greatly intensified Martian hydrological cycle may have produced a greenhouse effect strong enough to raise global mean surface temperatures by several tens of degrees Kelvin. It is made possible by the ability of the Martian atmosphere to transport water to high altitudes where cold clouds form, reduce the outgoing longwave radiation, and drive up surface temperatures to maintain global energy balance.

Haberle, Robert M.↗

NASA NTRS2026

Scientific Highlights and Status of the Mars Science Laboratory Mission, Years 9 through 12

We present the scientific highlights and status from years 9-12 of NASA’s Mars Science Laboratory mission, with its Curiosity rover. A thermochemolysis-based sample analysis revealed a variety of organic molecules preserved in clay mineral-rich lake/lake margin deposits of the Glen Torridon region. The stratigraphically higher clay-sulfate mineral transition on Aeolis Mons was found to be associated with a lithological change from lacustrine to dry aeolian depositional environments. Water intermittently returned to the surface after the increase in aridity, including during the deposition of wave ripple strata which indicate a climate capable of sustaining an ice-free lake in the early Hesperian. The overlying Mg sulfate-bearing unit has both poly- and monohydrated Mg sulfates and is also enriched in iron carbonate of a purity consistent with chemical sedimentation and therefore atmospheric sequestration. A channel-incised canyon within Gediz Vallis and distal alluvial deposits recorded numerous fluvial and debris flow events after the deposition, lithification, and erosion of the clay- and sulfate-bearing units. Bright clasts found in Gediz Vallis canyon are composed of native sulfur. The investigation of the modern atmosphere and environment focused on the influence of the crater and mountain topography and captured high-altitude noctilucent and iridescent clouds. Radiation monitoring now spans an 11-year solar cycle. Rover systems and science instruments remain capable of addressing mission scientific objectives. All ten scientific instruments continue to return high-value data despite degradation of the Chemistry and Camera instrument’s high-voltage system, loss of multispectral imaging capability, and loss of active neutron spectroscopy. The mission has mitigated the loss of redundant brakes on two arm joints, additional wheel wear, and highly reduced capability of the redundant flight computer. Efficiency improvements in rover energy utilization and operations staffing have allowed the mission team to maintain a high level of productivity despite declining rover power generation and funding.

Mars↗

NASA NTRS1999

Carbon Dioxide Cycling, Climate, Impacts, and the Faint Young Sun

Evidence for relatively mild climates on ancient Earth and Mars has been a puzzle in light of the faint early sun. The geologic evidence, although far from conclusive, would appear to indicate that the surfaces of both planets were, if anything, warmer ca. 3-4 Ga than they are now. The astrophysical argument that the sun ought to have brightened approx. 30% since it reached the main sequence is hard to refute. There results a paradox between the icehouse we expect and the greenhouse we think we see. The usual fix has been to posit massive CO2 atmospheres, although reduced gases (e.g., NH3 or CH4 ) have had their partisans. Evidence against siderite in paleosols dated 2.2-2.75 Ga sets a rough upper limit of 30 PAL (present atmospheric levels) on pCO2 at that time. This is an order of magnitude short of what is needed to defeat the fainter sun. We present here an independent argument against high pCO2 on early Earth that applies not only to the Archean but yet more forcefully to the Hadean era. Additional information is contained in the original extended abstract.

Zahnle, K. J.↗

NASA NTRS2013

Airborne Particles: What We Have Learned About Their Role in Climate from Remote Sensing, and Prospects for Future Advances

Desert dust, wildfire smoke, volcanic ash, biogenic and urban pollution particles, all affect the regional-scale climate of Earth in places and at times; some have global-scale impacts on the column radiation balance, cloud properties, atmospheric stability structure, and circulation patterns. Remote sensing has played a central role in identifying the sources and transports of airborne particles, mapping their three-dimensional distribution and variability, quantifying their amount, and constraining aerosol air mass type. The measurements obtained from remote sensing have strengths and limitations, and their value for characterizing Earths environment is enhanced immensely when they are combined with direct, in situ observations, and used to constrain aerosol transport and climate models. A similar approach has been taken to study the role particles play in determining the climate of Mars, though based on far fewer observations. This presentation will focus what we have learned from remote sensing about the impacts aerosol have on Earths climate; a few points about how aerosols affect the climate of Mars will also be introduced, in the context of how we might assess aerosol-climate impacts more generally on other worlds.

aerosol-climate impacts↗

NASA NTRS2017

Resolving Orbital and Climate Keys of Earth and Extraterrestrial Environments with Dynamics (ROCKE-3D) 1.0: A General Circulation Model for Simulating the Climates of Rocky Planets

Resolving Orbital and Climate Keys of Earth and Extraterrestrial Environments with Dynamics (ROCKE-3D) is a three-dimensional General Circulation Model (GCM) developed at the NASA Goddard Institute for Space Studies for the modeling of atmospheres of solar system and exoplanetary terrestrial planets. Its parent model, known as ModelE2, is used to simulate modern Earth and near-term paleo-Earth climates. ROCKE-3D is an ongoing effort to expand the capabilities of ModelE2 to handle a broader range of atmospheric conditions, including higher and lower atmospheric pressures, more diverse chemistries and compositions, larger and smaller planet radii and gravity, different rotation rates (from slower to more rapid than modern Earth's, including synchronous rotation), diverse ocean and land distributions and topographies, and potential basic biosphere functions. The first aim of ROCKE-3D is to model planetary atmospheres on terrestrial worlds within the solar system such as paleo-Earth, modern and paleo-Mars, paleo-Venus, and Saturn's moon Titan. By validating the model for a broad range of temperatures, pressures, and atmospheric constituents, we can then further expand its capabilities to those exoplanetary rocky worlds that have been discovered in the past, as well as those to be discovered in the future. We also discuss the current and near-future capabilities of ROCKE-3D as a community model for studying planetary and exoplanetary atmospheres.

Astrobiology↗

NASA NTRS1995

Simutaneous adsorption of CO2 and H2O under Mars-like conditions and application to the evolution of the Martian climate

The Martian regolith is the most substantial volatile reservoir on the planet; estimates of its adsorbed inventory have been based on simple measurements of the adsorption of either water or CO2 in isolation. Under some conditions, H2O can poison adsorbate surfaces, such that CO2 uptake is greatly reduced. We have made the first measurements of the simultaneous adsorption of CO2 and H2O under conditions appropriate to the Martian regolith and have found that at H2O monolayer coverage above about 0.5, CO2 begins to be displaced into the gas phase. We have developed an empirical expression that describes our co-adsorption data and have applied it to standard models of the Martian regolith. We find that currently, H2O does not substantially displace CO2, implying that the adsorbate inventories previously derived may be accurate, not more than 3-4 kPa (30-40 mbar). No substantial increase in atmospheric pressure is predicted at higher obliquities because high-latitude ground ice buffers the partial pressure of H2O in the pores, preventing high monolayer coverages of H2O from displacing CO2. The peak atmospheric pressure at high obliquity does increase as the total inventory of exchangeable CO2 increases.

Zent, Aaron P.↗

NASA NTRS1995

Simultaneous adsorption of CO2 and H2O under Mars-like conditions and application to the evolution of the Martian climate

The Martian regolith is the most substantial volatile reservoir on the planet; estimates of its adsorbed inventory have been based on simple measurements of the adsorption of either water or CO2 in isolation. Under some conditions, H2O can poison adsorbate surfaces, such that CO2 uptake is greatly reduced. We have made the first measurements of the simultaneous adsorption of CO2 and H2O under conditions appropriate to the Martian regolith and have found that at H2O monolayer coverage above about 0.5, CO2 begins to be displaced into the gas phase. We have developed an empirical expression that describes our co-adsorption data and have applied it to standard models of the Martian regolith. We find that currently, H2O does not substantially displace CO, implying that the adsorbate inventories previously derived may be accurate, not more than 3-4 kPa (30-40 mbar). No substantial increase in atmospheric pressure is predicted at higher obliquities because high-latitude ground ice buffers the partial pressure of H2O in the pores, preventing high monolayer coverages of H2O from displacing CO2. The peak atmospheric pressure at high obliquity does increase as the total inventory of exchangeable CO2 increases.

Zent, Aaron, P.↗

NASA NTRS2001

The Evolution of the Martian Hydrosphere: Implications for the Fate of a Primordial Ocean and the Current State of the Northern Plains

In this paper we consider the hydraulic and thermal conditions that gave rise to the elevated source regions of the Late Hesperian outflow channels and explore their implications for the evolution of the Martian hydrosphere. We find that if the outflow channel floodwaters were derived from a subpermafrost aquifer, then it implies that, throughout the planet's first billion years of evolution, as much as one third of its surface was covered by standing bodies of water and ice. Following the development of the global dichotomy, the bulk of this water would have existed as an ice-covered ocean in the northern plains. We demonstrate that the progressive crustal assimilation of this early surface reservoir of H2O (punctuated by possible episodes of less extensive flooding) was a natural consequence of the planet's subsequent climatic and geothermal evolution-potentially cycling the equivalent of a km-deep global ocean of water through the atmosphere and subsurface every approx. 10(exp 9) years. In response to the long-term decline in planetary heat flow, the progressive coldtrapping of H2O into the growing cryosphere is expected to have significantly depleted the original inventory of groundwater-a development that could well explain the apparent decline in outflow channel activity observed during the Amazonian. Although primarily a theoretical analysis, our findings appear remarkably consistent with the geomorphic and topographic evidence that Mars once possessed a primordial ocean and that a substantial relic of that body continues to survive as massive ice deposits within the northern plains. Confirmation of the presence of such deposits, combined with the potential detection of a global-scale groundwater system, would provide persuasive support for the validity of this analysis.

Clifford, Stephen M.↗

NASA NTRS2016

Characterization of Shock Effects in Calcite by Raman Spectroscopy: Results of Experiments

Carbonates comprise approx. 20% by volume of present day Earth's sedimentary rocks and store most of the terrestrial CO2 inventory. Some of the oldest meta-sedimentary rocks found on Earth contain abundant carbonate from which impact-induced release of CO2 could have played a role in the formation and evolution of the atmosphere. Carbonates are also present in the target materials for approx. 30% of all terrestrial impact structures including large impacts such as Chicxulub which happened to occur at a location with extraordinarily thick platform carbonate 3-6 km deep. The impact release of CO2 from carbonates can cause global warming as a result of the well-known greenhouse effect and have subsequent effects on climate and biota. Therefore, the shock behavior of calcite is important in understanding the Cretaceous-Paleogene event and other impacts with carbonate-bearing sediments in their target(s) such as Mars and some asteroids. A comprehensive survey utilizing a variety of techniques to characterize the effects manifest in Calcite (Iceland Spar) experimentally shocked to 60.8 GPa has been completed. Results of analysis by Raman Spectroscopy are reported here.

Bell, M. S.↗

NASA NTRS1989

Ancient lakes on Mars?

The valley systems in Mars' ancient cratered terrain provide strong evidence for a warmer and wetter climate very early in planetary history. The valley systems in some instances debouch into closed depressions that could have acted as local ponding basins for the flow. A survey of the Martian equatorial region shows that numerous local depressions at the confluence of valley systems exist. These depressions (approximately 100 km) typically are characterized by many valleys flowing into them and few or none flowing out. If ponding did take place, these basin would have contained lakes for some period during Mars' early warmer epoch. Although the collection basins are numerous, location of ones that have not suffered significant subsequent geologic modification is difficult. Some morphologic features suggest that volcanic lavas may have filled them subsequent to any early fluvial activity. Two detailed maps of valley systems and local ponding basins in USGC 1:2,000,000 subquadrangles were completed and a third is in progress. The completed regions are in Mare Tyrrhenum (MC-22 SW) and Margarifter Sinus (MC-19 SE), and the region in progress is in Iapygia (MC-21 NW). On the maps, the valley systems and interpreted margins of ponding basins are indicated. The depressions are of interest for two reasons. First, the depressions were surely the sites in which the materials eroded from the valleys were deposited. Such sediments could preserve important information about the physical conditions at the time of deposition. Second, the sediments could preserve evidence of water-atmosphere interactions during the early period of the Martian climate. Atmospheric carbon dioxide would dissolve in water, and solid carbonate minerals would tend to precipitate out to form carbonate sedimentary deposits. Formation of carbonates in this manner might account for some of the CO2 lost from the early more dense atmosphere.

Goldspiel, J. M.↗

NASA NTRS1999

Some Characteristics of the Martian Aphelion Global Cloud Belt

The presence of discrete condensate clouds on Mars is certainly not a new discovery, having been observed through most of the documented history of telescopic monitoring. Furthermore, spacecraft data have been used to study discrete cloud features in the Martian atmosphere in greater detail, e.g., morphology, seasonal occurrence. Condensate clouds, specifically discrete water ice clouds, appeared to be regarded as fairly common but, with the possible exception of the polar regions, generally uninteresting from a climatological point of view. However, recent observations indicate that in addition to their large spatial scale, the water ice clouds may in fact play a more prominent role in the Martian climate. In this paper, we wish to examine the spatial and temporal variations of the cloud belt optical depth, as well as the microphysical characteristics of the water ice particles themselves.

Wolff, M. J.↗

NASA NTRS2013

Highly Sensitive Tunable Diode Laser Spectrometers for In Situ Planetary Exploration

This paper describes highly sensitive tunable diode laser spectrometers suitable for in situ planetary exploration. The technology developed at JPL is based on wavelength modulated cavity enhanced absorption spectroscopy. It is capable of sensitively detecting chemical signatures of life through the abundance of biogenic molecules and their isotopic composition, and chemicals such as water necessary for habitats of life. The technology would be suitable for searching for biomarkers, extinct life, potential habitats of extant life, and signatures of ancient climates on Mars; and for detecting biomarkers, prebiotic chemicals and habitats of life in the outer Solar System. It would be useful for prospecting for water on the Moon and asteroids, and characterizing its isotopic composition. Deployment on the Moon could provide ground truth to the recent remote measurements and help to uncover precious records of the early bombardment history of the inner Solar System buried at the shadowed poles, and elucidate the mechanism for the generation of near-surface water in the illuminated regions. The technology would also be useful for detecting other volatile molecules in planetary atmospheres and subsurface reservoirs, isotopic characterization of planetary materials, and searching for signatures of extinct life preserved in solid matrices.

Vasudev, Ram↗

NASA NTRS1988

The role of impact cratering for Mars sample return

The preserved cratering record of Mars indicates that impacts play an important role in deciphering Martian geologic history, whether as a mechanism to modify the lithosphere and atmosphere or as a tool to sample the planet. The various roles of impact cratering in adding a broader understanding of Mars through returned samples are examined. Five broad roles include impact craters as: (1) a process in response to a different planetary localizer environment; (2) a probe for excavating crustal/mantle materials; (3) a possible localizer of magmatic and hydrothermal processes; (4) a chronicle of changes in the volcanic, sedimentary, atmospheric, and cosmic flux history; and (5) a chronometer for extending the geologic time scale to unsampled regions. The evidence for Earth-like processes and very nonlunar styles of volcanism and tectonism may shift the emphasis of a sampling strategy away from equally fundamental issues including crustal composition, unit ages, and climate history. Impact cratering not only played an important active role in the early Martian geologic history, it also provides an important tool for addressing such issues.

Schultz, P. H.↗

NASA NTRS2006

Water vapor, water-ice clouds, and dust in the North Polar Region

The behavior of water vapor, water-ice and dust in the Martian atmosphere is important for understanding the overall Martian climate system, which is characterized by three main cycles: water, including water-ice, dust, and CO2. Understanding these cycles will lend insight into the behavior of the atmospheric dynamics, the atmosphere's ability to transport dust, water-ice, and vapor to different parts of the planet, and how that ability changes as a function of dust and water-ice loading.

water vapors↗

NASA NTRS2020

The case for a multi-channel polarization sensitive LIDAR for investigation of insolation-driven ices and atmospheres

All LIDAR instruments are not the same, and advancement of LIDAR technology requires an ongoing interest and demand from the community to foster further development of the required components. The purpose of this white paper is to make the decadal survey panel aware of the need for further technical development, and the potential payoff of investing experimental time, money and thought into the next generation of LIDARs. Technologies for development: We advocate for future development of LIDAR technologies to measure the polarization state of the reflected light at selected multiple wavelengths, chosen according to the species of interest (e.g., H2O and CO2 in the Martian setting).Key scientific questions: In the coming decade, dollars spent on these LIDAR technologies will go towards addressing key climate questions on Mars and other rocky bodies, particularly those with seasonally changing (i.e. insolation driven) plumes of multiple icy volatiles such as Mars, Enceladus, Triton, or Pluto, and insolation-driven dust lifting, such as cometary bodies and the Moon. We will show from examining past Martian and terrestrial lidars that orbital and landed LIDARs can be effective for producing new insights into insolation-driven processes in current planetary climate on several bodies, beyond that available to our current fleet of largely passive instruments on planetary missions

Adrian Jon Brown↗

NASA NTRS1995

MSATT: Mars Surface and Atmosphere Through Time

The papers published here are based on a workshop entitled "Mars: Past, Present, and Future: Results from the MSATT Program." MSATT (Mars Surface and Atmosphere Through Time) was the last of the Mars data analysis programs and functioned mainly through a series of focused workshops, the final one being held at the Lunar and Planetary Institute in Houston, Texas on November 15-17, 1993. The program began and ended with workshops that brought the entire MSATT community together. Here you will find papers that address the geology, mineralogy, and meteorology of Mars in an effort to assess how the surface and atmosphere of this fascinating planet have evolved over time. Could early Mars have been warmed by a brighter young sun instead of a massive greenhouse effect? Were glaciers and hydrological cycles part of Mars' relatively recent past, or was aeolian activity responsible for the putative glacial features? Do the SNCs come from a single source region, or is more than one site involved? And what really are the properties of Martian soils and what do they tell us about the weathering environment? Clearly, these are difficult questions, but progress toward answers can be found in this issue. Also contained in this issue are a mix of theoretical and observational papers that deal with the general circulation of the current atmosphere, the factors that drive it (dust properties), and the role it plays in controlling the current climate system.

Source record↗

NASA NTRS1987

The role of regolith adsorption in the transition from early to late Mars climate

Researchers reexamined radiative transfer models of early Mars that were advanced to show the existance of a greenhouse effect. These models were reexamined with regard to the effect that regolith adsorption may have had. It is argued that while the precipitation of carbonates has probably been an important process during Mars history, the rates at which this process could have taken place under early Mars conditions would have dropped sharply once liquid water was fairly scarce. Furthermore, conditions under which liquid water was available may have involved efficient recycling of carbonate so that steady state conditions rather than irreversible CO2 removal prevailed. In contrast, the growth of regolith surface area demands corresponding and predictable CO2 removal from the atmosphere-cap system and is fully capable of terminating any enhanced temperature regime on early Mars in the absence of any other effects.

Fanale, F. P.↗