Chromium and manganese in chondrites.
Chondritic Cr and Mn content studied by X ray fluorescence, noting positive correlation in H and L groups and negative correlation in carbonaceous chondrites
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Chondritic Cr and Mn content studied by X ray fluorescence, noting positive correlation in H and L groups and negative correlation in carbonaceous chondrites
Knudsen effusion measurements of stoichiometric MnTe sublimation at high temperature and low pressure
Na and Mn homogeneity in chondritic meteorites, discussing accretion processes, metamorphisms, weathering effects and specimens size
Dimensional changes (strain) along the three principal crystal axes of the antiferromagnet CsMnCl3-2H2O are studied as a function of magnetic field and temperature in the antiferromagnetic, spin flopped, and paramagnetic phases. Changes in dimensions through the phase transitions between the magnetic states are examined. By applying the molecular field model and utilizing all available information, magnetic properties of CsMnCl3-2H2O are determined. The possible usefulness of this material in a magnetic refrigeration cycle is evaluated.
A kinetic analysis is presented of the data obtained in previously described kinetic experiments relating to the photoactivation of the Mn complex required for photosynthetic O2 evolution. The results obtained from the computer simulation of the derived kinetic model compare favorably with the experimentally derived values. They also suggest that photoactivation can be rationalized in terms of a two-quantum process.
A kinetic analysis is reported of the process of Mn photoactivation that the photosynthetic evolution of O2 requires. This process is investigated in Mn-deficient Anacystis nidulans cells. The implications are discussed of the results obtained.
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The observed strengths of interstellar absorption lines of Fe II and Mn II in the spectra of alpha Vir, beta Cen, pi Sco, and zeta Oph along with laboratory f values of some of these lines between 2343 and 2606 A have been used to determine curves of growth for these ions and the f-values of ten lines of Fe II and three lines of Mn II between 1055 and 1261 A. The Fe and Mn abundances are derived.
Fe-16Mn and Fe-25Mn base alloys, which had been cold worked to yield strength levels of 201 and 178 KSI, were resistant to degradation of mechanical properties in a one atmosphere hydrogen environment at ambient temperature under the loading conditions employed in this investigation. Transmission electron microscopy established that bands of epsilon phase martensite and fcc mechanical twins were formed throughout the fcc matrix when these alloys were cold worked. In the cold worked alloys a high density of crystal defects were observed associated with both types of strain induced structures, which should contribute significantly to the strengthening of these alloys. High strength iron base alloys can be produced which appear to have some resistance to degradation of mechanical properties in a hydrogen environment under certain conditions.
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Distribution coefficients have been found for the partitioning of Ni, Co, and Mn between calcium-rich clinopyroxenes and coexisting silicate liquids. Values are found for the 1110-1360 C temperature range. The breakdown of Henry's Law was not observed. The measured clinopyroxene/liquid distribution coefficients ranged from 1.5-14.0 for Ni, 0.5-2.0 for Co, and 0.3-1.2 for Mn. Analyses of pyroxenes grown from charges differing in the amounts of transition metals indicate that Ni and Co occupy the M1 site of diopside and that Mn occupies the M1 and M2 sites. Equilibrium constants were found in terms of the activities of the components in the liquid and solid phases. These activities are based on the mole fractions. An activity/concentration model was used for the liquid phase in order to explain the variations in the clinopyroxene/liquid coefficients due to bulk composition.
Sodium content decreased in the human skeletal bones and rose in the rat bones following space flight. In man copper content rose in the femoral bone and decreased in the vertebral body and the sternum, but was unchanged in the rest of the bones. Magnesium content was decreased in the femoral bone and the sternum, and in the vertebrae, but remained unchanged in the rest of the bones. Possible mechanisms of the changes detected are discussed.
Observations of 16 UV resonance lines of Fe II and six of Mn II in five stars are used to derive new f-values for the lines of these species at wavelengths lower than 1300 A. Values of forbidden lines Fe/H and Mn/H are derived. These new values are used to reassess mean depletions and range of variations in depletions for several lines of sight. On an integrated line-of-sight basis, depletions of Fe and Mn show larger variations than P, Cl, or Zn. The mean local depletion forbidden line Fe/H is 1.65, in interstellar gas. One Fe II line, 2366.864 A, has never been detected. Its f-value is shown to be much lower than previously thought. This line is therefore not useful for interstellar studies at the present time. It is suggested that the true wavelength of 1142 A of Fe II, from UV multiplet 10, is 1142.285 A.
X-ray photoelectron spectroscopy analysis and sliding friction experiments were conducted with hot-pressed, polycrystalline Ni-Zn and Mn-Zn ferrites in sliding contact with various transition metals at room temperature in a vacuum of 30 nPa. The results indicate that the coefficients of friction for Ni-Zn and Mn-Zn ferrites in contact with metals are related to the relative chemical activity in these metals: the more active the metal, the higher is the coefficient of friction. The coefficients of friction for the ferrites correlate with the free energy of formation of the lowest metal oxide. The interfacial bond can be regarded as a chemical bond between the metal atoms and the oxygen anions in the ferrite surfaces. The adsorption of oxygen on clean metal and ferrite surfaces increases the coefficients of friction for the Ni-Zn and Mn-Zn ferrite-metal interfaces.
Ultraviolet and optical data for the Hg Mn stars Coronae Borealis and Cancri is being combined with data for the field horizontal branch population II star HD 109995 in order to derive the element abundances in their photospheres. Data collected by IUE is being utilized.
Wear experiments were conducted using replication electron microscopy and reflection electron diffraction to study abrasion and the deformed layers produced in single-crystal Mn-Zn ferrite simulated heads during contact with lapping tapes. The crystaline state of the head is changed drastically during the abrasion process. Crystalline states ranging from nearly amorphous to highly textured polycrystalline can be produced on the wear surface of a single-crystal Mn-Zn ferrite head. The total thickness of the deformed layer was approximately 0.8 microns. This thickness increased as the load and abrasive grit size increased. The anisotropic wear of the ferrite was found to be inversely proportional to the hardness of the wear surface. The wear was lower in the order 211 111 10 0110. The wear of the ferrite increased markedly with an increase in sliding velocity and abrasive grit size.
Wear experiments were conducted using replication electron microscopy and reflection electron diffraction to study abrasion and deformed layers produced in single-crystal Mn-Zn ferrites under three-body abrasion. The abrasion mechanism of Mn-Zn ferrite changes drastically with the size of abrasive grits. With 15-micron (1000-mesh) SiC grits, abrasion of Mn-Zn ferrite is due principally to brittle fracture; while with 4- and 2-micron (4000- and 6000-mesh) SiC grits, abrasion is due to plastic deformation and fracture. Both microcracking and plastic flow produce polycrystalline states on the wear surfaces of single-crystal Mn-Zn ferrites. Coefficient of wear, total thickness of the deformed layers, and surface roughness of the wear surfaces increase markedly with an increase in abrasive grit size. The total thicknesses of the deformed layers are 3 microns for the ferrite abraded by 15-micron SiC, 0.9 microns for the ferrite abraded by 4-micron SiC, and 0.8 microns for the ferrite abraded by 1-micron SiC.
This paper continues a survey of intestellar densities, abundances, and cloud structure in the Galaxy using the IUE satellite. A statistical data set of 223 O3-B2.5 stars is constructed, including 53 stars in the Galactic halo. It is found that S II lines in B stars, of luminosity classes IV and V, have possible contamination from stellar S II, particular for stars with v sin i less than 200 km/s. The mean logarithmic depletions are -1.00, -1.19. -0.63, and -0.23 (Si, Mn,Fe,S, Zn). Depletions of Si, Mn, and Fe correlate with the mean hydrogen density n-bar along the line of sight, with a turnover for n-bar greater than 1/cm. Sulfur depletions correlate with n-bar along the line of sight. The slight Zn depletion correlation also appears to be statistically insignificant. No correlation of depletion is found with the physical density derived from H2 rotational states in 21 lines of sight. Depletion variations in the disk are consistent with a Galactic abundance gradient or with enhanced mean depletions in the anticenter region.