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At least 397 records · Page 22

Predictive Engineering Tools for Injection-Molded Long-Carbon-Fiber Thermoplastic Composites

This quarterly report summarizes the status for the project planning to complete all the legal and contract documents required for establishing the subcontracts needed and a Cooperative Research and Development Agreement (CRADA) with Autodesk, Inc., Toyota Motor Engineering and Manufacturing North America (Toyota), and Magna Exterior and Interiors Corporation (Magna). During the second quarter (1/1/2013 to 3/31/2013), all the technical and legal documents for the subcontracts to Purdue University, University of Illinois, and PlastiComp, Inc. were completed. The revised CRADA documents were sent to DOE, Autodesk, Toyota, and Magna for technical and legal reviews. PNNL Legal Services contacted project partners’ Legal counterparts for completing legal documents for the project. A non-disclosure agreement was revised and sent to all the parties for reviews.

Compounding↗

Predictive Engineering Tools for Injection-Molded Long-Carbon-Fiber Thermoplastic Composites - FY13 Third Quarterly Report

This quarterly report summarizes the status for the project planning to obtain all the approvals required for a Cooperative Research and Development Agreement (CRADA) with Autodesk, Inc., Toyota Motor Engineering and Manufacturing North America (Toyota), and Magna Exterior and Interiors Corporation (Magna). The CRADA documents have been processed by PNNL Legal Services that is also coordinating the revision effort with the industrial parties to address DOE’s comments.

Compounding↗

Predictive Engineering Tools for Injection-Molded Long-Carbon-Fiber Thermoplastic Composites - FY13 Fourth Quarterly Report

This quarterly report summarizes the status of the project planning to obtain all the approvals required for a Cooperative Research and Development Agreement (CRADA) with Autodesk, Inc., Toyota Motor Engineering and Manufacturing North America (Toyota), and Magna Exterior and Interiors Corporation (Magna). The final CRADA documents processed by PNNL’s Legal Services were submitted to all the parties for signatures.

Compounding↗

Predictive Engineering Tools for Injection-Molded Long-Carbon-Fiber Thermoplastic Composites - FY 2016 First Quarterly Report

During the first quarter of FY 2016, the following technical progress has been made toward project milestones: 1) Virginia Tech completed fiber orientation (FO) measurements for the samples taken at Locations A, B, C and D (Figure 1) from the 30wt% LCF/PP and 30wt% LCF/PA66 ribbed and non-ribbed complex parts using Virginia Tech’s established procedure. Virginia Tech delivered to PNNL all the measured fiber orientation data for validating ASMI fiber orientation predictions. 2)Virginia Tech performed fiber length distribution (FLD) measurements for the samples taken at Locations A, B, C and D from these complex parts using Virginia Tech’s established procedure. Virginia also re-assessed previous data and measured fiber length distributions in the corresponding nozzle purging materials and delivered to PNNL all the measured length data for validating ASMI fiber length predictions. 3)Based on measured fiber orientation data, Autodesk identified the parameters of the anisotropic rotary diffusion reduced strain closure (ARD-RSC) model [1] and provided PNNL with the values of these parameters that were used in ASMI analyses of the complex parts. 4) Magna provided Virginia Tech with additional samples cut out from the 30wt% LCF/PP and 30wt% LCF/PA66 ribbed parts (Figure 1) for fiber length and orientation measurements. 5) In discussion with Autodesk, PNNL performed 3D ASMI analyses of the 30wt% LCF/PP and 30wt% LCF/PA66 ribbed and non-ribbed complex parts to predict fiber orientations and length distributions in these parts. The issues observed through the analyses regarding fiber orientation distributions profiles and abnormal length distributions were reported to Autodesk. Autodesk is working to resolve these issues. 6) PNNL completed 3D ASMI analyses of the complex parts and compared predicted fiber orientation results at Locations A, B, and C on the non-ribbed parts, and at Locations A, B, C and D on the ribbed parts with the corresponding measured data. PNNL also evaluated the within-15%-agreement criterion using the principal tensile and flexural moduli computed based on predicted vs. measured fiber orientation results. 7) PNNL developed and discussed with Toyota, Magna and PlastiComp a method to perform weight and cost reduction for making the 30wt% LCF/PA66 ribbed part through comparative three-point bending simulations of this part and of similar parts in steel.

36 MATERIALS SCIENCE↗

A novel digital lifecycle for Material‐Process‐Microstructure‐Performance relationships of thermoplastic olefins foams manufactured via supercritical fluid assisted foam injection molding

Abstract This research significantly enhances the applicability of thermoplastic olefins (TPOs) in the automotive industry using supercritical N 2 as a physical foaming agent, effectively addressing the limitations of traditional chemical agents. It merges experimental results with simulations to establish detailed material‐process‐microstructure‐performance (MP2) relationships, targeting 5–20% weight reductions. This innovative approach labeled digital lifecycle (DLC) helps accurately predict tensile, flexural, and impact properties based on the foam microstructure, along with experimentally demonstrating improved paintability. The study combines process simulations with finite element models to develop a comprehensive digital model for accurately predicting mechanical properties. Our findings demonstrate a strong correlation between simulated and experimental data, with about a 5% error across various weight reduction targets, marking significant improvements over existing analytical models. This research highlights the efficacy of physical foaming agents in TPO enhancement and emphasizes the importance of integrating experimental and simulation methods to capture the underlying foaming mechanism to establish material‐process‐microstructure‐performance (MP2) relationships. Highlights Establishes a material‐process‐microstructure‐performance (MP2) for TPO foams Sustainably produces TPO foams using supercritical (ScF) N 2 with 20% lightweighting Shows enhanced paintability for TPO foam improved surface aesthetics Digital lifecycle (DLC) that predicts both foam microstructure and properties DLC maps process effects & microstructure onto FEA mesh for precise prediction

Engineering↗

Effect of Hydrothermal Aging on Injection Molded Short Jute Fiber Reinforced Poly(Lactic Acid) (PLA) Composites

This work focused on the durability of short jute fiber reinforced poly(lactic acid) (PLA) composites in distilled water at different temperatures (23, 37.8 and 60 °C). Morphological, thermal and mechanical properties (tensile, flexural, and impact) of jute/PLA composites were investigated before and after aging. Different from traditional synthetic fiber reinforced polymer composites, the stability of jute/PLA composites in water was significantly influenced by hydrothermal temperature. The mechanical properties of the composites and molecular weight of PLA matrix declined quickly at 60 °C, however, this process was quite slower at temperatures of 23 and 37.8 °C. Impact properties of the composites were hardly decreased, but the tensile and flexural properties suffered a drop though to various degrees with three degradation stages at 23 and 37.8 °C. The poor interface of composites and the degradation of PLA matrix were the main damage mechanism induced by hydrothermal aging. Furthermore, considering the hydrolysis of PLA matrix, the cleavage of PLA molecular chain in different aging time was quantitatively investigated for the first time to illustrate hydrolysis degree of PLA matrix at different aging time.

36 MATERIALS SCIENCE↗

Wetting and Erosion of ZrO{sub 2}-Graphite Refractory by CaO-SiO{sub 2} and CaO-Al{sub 2}O{sub 3}-Based Mold Slags for Submerged Entry Nozzle

To moderate the erosion in a slag-line zone and extend the service life of a submerged entry nozzle during continuous casting of high-Mn and high-Al steel, the current study developed a low-reaction CaO-Al{sub 2}O{sub 3}-based slag with lower SiO{sub 2} and higher Al{sub 2}O{sub 3} contents than that of conventional CaO-SiO{sub 2}-based slag. The static sessile drop technique and dynamic rotating cylinder method were utilized to investigate the erosion behavior of ZrO{sub 2}-graphite refractory by the above slags. The main results indicated that silicate-based slag could wet the ZrO{sub 2}-graphite substrate completely, while the aluminate-based slag spread rapidly in the first 20 minutes, and then a slag drop with an unchanged profile formed on the substrate. The equilibrium contact angles with the substrate at 1623 K were 0 and 79 deg for the CaO-SiO{sub 2} and CaO-Al{sub 2}O{sub 3} based slags, respectively. The comparison of the influences of the rotating speed and the temperature revealed that the decrease of erosion rate could be realized by the developed slag. An examination of ZrO{sub 2}-saturation limit also indicated that the low-reaction slag could dissolve much more ZrO{sub 2} oxidation, accompanied by a less-negative effect on the viscosity of the molten slag.

36 MATERIALS SCIENCE↗

Influence of Melt-Pouring Temperature and Composition of Primary Coating of Shell Mold on Tensile Strength and Creep Resistance of Ni-Based Superalloy

Eight investment castings of Inconel 713C superalloy were fabricated, varying in the melt-pouring temperature, from 1400 to 1520 °C, and CoAl{sub 2}O{sub 4} inoculant content, 0 or 5 wt.%, in the primary coat. Their influence on grain size on tensile and creep properties was investigated. The best combination of yield stress (815 MPa) and elongation (A{sub 4} = 7.65%) at ambient temperature was obtained in surface-modified castings poured from 1520 °C. The longest time to rupture was for the unmodified castings (76.8 h) poured from 1520 °C, while for the modified variant, the time to rupture was lower around, 7.4 h, which was still a satisfactory value. During tensile testing, microcracks were formed in large eutectic γ′, carbides and borides, due to the accumulation of stress at interfaces with the matrix. During creep, N-type rafting of γ′ precipitates and phase transformation MC + γ → γ′ + M{sub 23}C{sub 6} took place.

36 MATERIALS SCIENCE↗

Quality Assessment of Al Castings Produced in Sand Molds Using Image and CT Analyses

Nowadays, the economic production of aluminum casts is becoming increasingly important. Therefore, the decision of whether to use alloys based on the primary aluminum (low Fe content, but high costs) or the secondary aluminum (high Fe content, but reasonable costs) for a cast product is a common problem. The main expected influence of higher iron content is to increase porosity and decrease mechanical and fatigue properties. Therefore, this work is focused on assessment of the higher Fe content influence on porosity and iron-rich intermetallic phases formation and, hence, changes in the mechanical properties, with simultaneously keeping the production economical. The quality of castings was measured by application of the 2D technology (image analysis) and the 3D technology (CT analysis), as well. Results show that technologies of assessment are comparable and length of the Fe-rich phases is not critical for mechanical properties, but it is important for porosity formation in materials with the higher amount of Fe.

36 MATERIALS SCIENCE↗

Household mold and dust allergens: Exposure, sensitization and childhood asthma morbidity

Background: Few studies address concurrent exposures to common household allergens, specific allergen sensitization and childhood asthma morbidity. Objective: To identify levels of allergen exposures that trigger asthma exacerbations in sensitized individuals. Methods: We sampled homes for common indoor allergens (fungi, dust mites (Der p 1, Der f 1), cat (Fel d 1), dog (Can f 1) and cockroach (Bla g 1)) for levels associated with respiratory responses among school-aged children with asthma (N=1233) in a month-long study. Blood samples for allergy testing and samples of airborne fungi and settled dust were collected at enrollment. Symptoms and medication use were recorded on calendars. Combined effects of specific allergen sensitization and level of exposure on wheeze, persistent cough, rescue medication use and a 5-level asthma severity score were examined using ordered logistic regression. Results: Children sensitized and exposed to any Penicillium experienced increased risk of wheeze (odds ratio [OR] 2.12 95% confidence interval [CI] 1.12, 4.04), persistent cough (OR 2.01 95% CI 1.05, 3.85) and higher asthma severity score (OR 1.99 95% CI 1.06, 3.72) compared to those not sensitized or sensitized but unexposed. Children sensitized and exposed to pet allergen were at significantly increased risk of wheeze (by 39% and 53% for Fel d 1>0.12 {mu}g/g and Can f 1>1.2 {mu}g/g, respectively). Increased rescue medication use was significantly associated with sensitization and exposure to Der p 1>0.10 {mu}g/g (by 47%) and Fel d 1>0.12 {mu}g/g (by 32%). Conclusion: Asthmatic children sensitized and exposed to low levels of common household allergens Penicillium, Der p 1, Fel d 1 and Can f 1 are at significant risk for increased morbidity. - Highlights: Black-Right-Pointing-Pointer Few studies address concurrent allergen exposures, sensitization and asthma morbidity. Black-Right-Pointing-Pointer Children with asthma were tested for sensitivity to common indoor allergens. Black-Right-Pointing-Pointer Homes were sampled for these allergens and asthma morbidity monitored during the subsequent month. Black-Right-Pointing-Pointer Children exposed and sensitized to Penicillium, Der p, Fel d, Can f risk increased asthma morbidity. Black-Right-Pointing-Pointer These children might benefit from targeted intervention strategies.

60 APPLIED LIFE SCIENCES↗

A leaf-molded transparent triboelectric nanogenerator for smart multifunctional applications

Transparent, flexible and highly efficient portable power sources are essential components of the next generation electronics and optoelectronic devices. However, complicated technology, expensive cost, environmental pollution and low-efficient output have limited its development. Herein, based on periodic contact/separation between human skin and the microstructured polydimethylsiloxane (PDMS) film, we demonstrate a transparent flexible triboelectric nanogenerator (TENG) through a relatively simple, low-cost, environmental-friendly and high-efficient method. For the first time, the natural leaves with rich surface textures were introduced to make microstructures on PDMS films as effective friction surface in the TENG. Furthermore, long silver nanowires (200 µm in length at least) through novel synthesis were assembled as high-performance electrode, resulting in the entirely flexible and transparent TENG. Owing to the unique design, the transparent flexible TENG was eventually obtained with an enhanced output (Voc=56 V; Isc=3.1 μA) and remarkable transparency (88%). Owing to compelling features of the TENG, a self-powered user-interactive wearable system was successfully established by integrating a flexible electrochromic device (ECD). The remarkable color-tunable ability via mechanical control of our system, highly inspired by chameleons, is potentially useful in military camouflage, monitoring human activity visually, as well as replacing performance of face change in Sichuan Opera. Therefore, this research is a substantial advancement toward the construction of transparent nanogenerator and its multifunctional applications in energy conversation, wearable electronics, healthcare, culture experience, and even environmental protection.

42 ENGINEERING↗