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At least 397 records · Page 22

Results of Magnesium in Rain Water Sampling

Lawrence Livermore National Laboratory (LLNL) is regulated under California's Industrial General Permit (IGP) under SIC code 4953 (Hazardous Waste Facilities). According to the IGP, facilities under this SIC code must sample for magnesium in their industrial stormwater runoff. In the 2015-2016 stormwater year, LLNL entered level 1 status for magnesium. In the 2016-2017 stormwater year, LLNL added filter inserts and filter rolls to storm-basin inlets but still exceeded the Numeric Action Level (NAL) and entered Level 2 status for magesium. LLNL's 2017 Level 2 Exceedance Response Action (ERA) technical report, demonstrated that the high magnesium levels are from natural processes occurring in the surrounding geology instead of anthropogenic or industrial activity. LLNL found the source of magnesium is caused from eroded minderal phases and likely dry deposition of air particulates (Esser, 2016). To further investigate the source of magnesium and to strengthen LLNL's conclusion that elevated magnesium concentrations are from natural sources, LLNL conducted sampling events to analyse the magnesium levels in direct rainfall.

54 ENVIRONMENTAL SCIENCES↗

Development of a Point of Care Technology for Military Medical Applications in Austere Environments

NASA, Lawrence Livermore National Laboratory (LLNL) and the Department of Defense (DoD) share a common interest in compact medical diagnostic technologies—also known as “point of care testing” (POCT) technologies. For NASA, the need is to take care of astronauts on deep space missions. For LLNL, the focus is on technologies needed to support homeland security applications. For DoD, the need is to support warfighters in military theaters of operation, especially for prolonged field care and en route care. A recently patented technology, “Portable Medical Diagnosis Instrument” (U.S. Patent 9824870), co-invented by NASA and LLNL, is being developed further in a partnership between NASA, LLNL and Travis Air Force Base, with a focus on military applications. This instrument, the NASA-LLNL Medical Tricorder, can be used for a wide range of clinical samples including breath, saliva and blood. One component of the Tricorder is the NASA E-Nose, a carbon nanotube-based chemical sensor, integrated into a hand-held smart phone, that can detect and measure “breath biomarkers” in the gas phase of exhaled breath. The response of the NASA E-Nose is rapid, which makes it possible to detect various gas-phase substances in real time. The NASA E-Nose, with modification, can also be used for breath condensate analysis. Another component of the Tricorder is a miniaturized microfluidic analyzer, under development by LLNL, that does not require any pumps. The microfluidic analyzer can detect and measure biomarkers in liquid samples, such as blood, saliva and breath condensate. This microfluidic system requires small quantities of liquid sample and can perform analysis very rapidly (seconds to minutes), which makes it possible to detect relevant biomarkers in near real time in the field. The Clinical Investigation Facility (CIF) at Travis Air Force Base is currently conducting research with the goal to develop improved field-able technologies and procedures for the emergency response to life threatening injuries soldiers may receive in theater. This work includes experimental large animal systems and comprehensive collection of clinical specimens and physiological data. NASA and LLNL are partnering with Travis to test and further develop the Tricorder technology for high priority military applications, initially focused on lung injury models and traumatic brain injury.

Loftus, David J.↗

FNCL Enhancements Implementation (FY25 Annual Report)

The FNCL investigations team at Lawrence Livermore National Laboratory (LLNL) has completed research and development of hardware, signal processing, and analysis tools to enhance the measurement capabilities of both the current CAEN SyS VeryFuel Fast Neutron Collar (FNCL) instrument and a next-generation FNCL prototype. The team successfully built and commissioned the LLNL Demonstrator System: a fully integrated, three-panel detector system featuring higher segmentation, plastic scintillators (EJ-276D), Silicon Photomultipliers (SiPMs), no high-voltage requirement, a reduced electronic footprint, and the LLNL-developed Gaussian Mixture Model Pulse Shape Discrimination (GMM-PSD) signal processing. An extensive experimental campaign was conducted at LLNL’s Inherently Safe Subcritical Assembly (ISSA) facility using both the baseline FNCL and the LLNL Demonstrator. The campaign results validated system performance, calibration stability, and the effectiveness of advanced signal processing and analysis algorithms in a relevant environment.

and physical protection↗

Special Analysis for the Disposal of the Lawrence Livermore National Laboratory Husman Irradiators Waste Stream at the Area 5 Radioactive Waste Management Site, Nevada National Security Site, Nye County, Nevada

This special analysis (SA) evaluates whether the Lawrence Livermore National Laboratories (LLNL) Husman Irradiators waste stream (BCLAHUSMANS00, Revision 0) is suitable for disposal by shallow land burial (SLB) at the Area 5 Radioactive Waste Management Site (RWMS). The LLNL Husman Irradiators waste stream consists of 3 fully self-shielded self-contained cesium-137 (137Cs) irradiators that have exceeded their useful lifetime (LLNL 2015). The LLNL Husman Irradiators waste stream requires an SA because the 137Cs activity concentration exceeds the Nevada National Security Site (NNSS) Waste Acceptance Criteria (WAC) Action Level (U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office [NNSA/NFO] 2013). The results indicate that all performance objectives can be met with disposal of the LLNL Husman Irradiators in a SLB trench. Addition of the LLNL Husman Irradiators inventory had no significant effect on the maximum mean and 95th percentile performance assessment results over the 1,000-year compliance period. The short half-life of 137Cs limits its potential impacts to a few hundred years after disposal. The 3 Husman Irradiators are suitable for disposal by SLB at the Area 5 RWMS.

Lawrence Livermore National Laboratories, LLNL, Hu↗

Special Analysis for the Disposal of the Lawrence Livermore National Laboratory EnergyX Macroencapsulated Waste Stream at the Area 5 Radioactive Waste Management Site, Nevada National Security Site, Nye County, Nevada

This special analysis (SA) evaluates whether the Lawrence Livermore National Laboratory (LLNL) EnergyX Macroencapsulated waste stream (B LAMACRONCAP, Revision 1) is suitable for disposal by shallow land burial (SLB) at the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada National Security Site (NNSS). The LLNL EnergyX Macroencapsulated waste stream is macroencapsulated mixed waste generated during research laboratory operations and maintenance (LLNL 2015). The LLNL EnergyX Macroencapsulated waste stream required a special analysis due to tritium (3H), cobalt-60 (60Co), cesium-137 (137Cs), and radium-226 (226Ra) exceeding the NNSS Waste Acceptance Criteria (WAC) Action Levels (U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office [NNSA/NFO] 2015).The results indicate that all performance objectives can be met with disposal of the waste stream in a SLB trench. Addition of the LLNL EnergyX Macroencapsulated inventory slightly increases multiple performance assessment results, with the largest relative increase occurring for the all-pathways annual total effective dose (TED). The maximum mean and 95th percentile 222Rn flux density remain less than the performance objective throughout the compliance period. The LLNL EnergyX Macroencapsulated waste stream is suitable for disposal by SLB at the Area 5 RWMS. The waste stream is recommended for approval without conditions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Evaluation of Polyethylene and Blank Pulsed Sphere Experiments Using Deuteron Transport Feature in COG

From the late 1960s to about 1985, LLNL undertook a series of ‘pulsed sphere’ experiments for 31 materials involving 148 different experiments using 75 different spheres. The purpose was to measure the neutron leakage spectra for different materials from 14-MeV neutrons generated by 3 H(d,n) 4 He reactions induced by an incident D+ beam from the Insulated Core Transfer (ICT) accelerator at LLNL. This deuteron beam was focused to impinge upon tritium loaded onto a titanium substrate within a low mass target assembly placed within the center of a spherical shell constructed from the material of interest. COG is a three-dimensional, continuous energy, Monte Carlo code, developed by Lawrence Livermore National Laboratory (LLNL). Recent additions to COG include alpha and deuteron particle transport in order to directly calculate (α,n) and 3 H(d,n) 4 He reactions, and resulting neutron emission spectra. Results of the direct deuteron transport calculation for the 0.8 MFP (mean free path) polyethylene sphere with PILOT B detector was previously published. The purpose of this paper is to present expanded COG results showing the neutron peak from deuterium buildup ( 2 H(d,n) 3 He) due to tritium decay in the target. Cross section data libraries used are ENDF/B-VIII.0 for neutrons and ENDF/B-VII.1 for deuterons, respectively.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Improved Regional and TeleseismicP-Wave Travel-Time Prediction and Event Location Using a Global 3D Velocity Model

A global validation dataset of 116 seismic events and 20,977 associated Pn and P arrivals is used to assess travel-time prediction and event location accuracy for the global-scale, 3D, P-wave velocity model called LLNL-G3Dv3 (Simmons et al., 2012). Strong regional trends that are observed for ak135 travel-time residuals are largely removed when LLNL-G3Dv3 is used for prediction. The 25th–75th quantile spread of travel-time residuals is reduced by 30%–40% at teleseismic distances, and the spread is reduced by ~60% at regional distances (<16°). Epicenter error decreases when more data are used to constrain event locations until more than ~40 arrivals times are used. At which point, epicenter error reduction tends to plateau. Median epicenter errors for the ak135 and LLNL-G3Dv3 models plateau at ~8:0 and ~5:5 km, respectively, for teleseismic P datasets. Median epicenter errors for the ak135 and LLNL-G3Dv3 models plateau at ~12:0 and ~4:0 km, respectively, for regional Pn datasets. We demonstrate that spatially correlated travel-time residual errors for the ak135 model lead to increasing epicenter error when ~40 to ~100 Pn arrivals are used to constrain the location. The effect of correlated error is mitigated by LLNL-G3Dv3, for which epicenter error steadily decreases to ~4 km when 100 Pn arrivals are used. The median area of 0.95 epicenter probability bounds for ak135 and LLNL-G3Dv3 are 1811 and 758 km 2 , respectively. The ak135 ellipses are inflated to achieve the desired rate of true events occurring inside the probability region, whereas LLNLG3Dv3 error ellipses based on empirical residual distributions cover the true location at the expected rate because location bias is minimal.

58 GEOSCIENCES↗

Update of Earthquake Strong-Motion Instrumentation at Lawrence Livermore National Laboratory

Following the January 1980 earthquake that was felt at Lawrence Livermore National Laboratory (LLNL), a network of strong-motion accelerographs was installed at LLNL. Prior to the 1980 earthquake, there were no accelerographs installed. The ground motion from the 1980 earthquake was estimated from USGS instruments around the Laboratory to be between 0.2 – 0.3 g horizontal peak ground acceleration. These instruments were located at the Veterans Hospital, 5 miles southwest of LLNL, and in San Ramon, about 12 miles west of LLNL. In 2011, the Department of Energy (DOE) requested to know the status of our seismic instruments. We conducted a survey of our instrumentation systems and responded to DOE in a letter. During this survey, it was found that the recorders in Buildings 111 and 332 were not operational. The instruments on Nova had been removed, and only three of the 10 NIF instruments installed in 2005 were operational (two were damaged and five had been removed from operation at the request of the program). After the survey, it was clear that the site seismic instrumentation had degraded substantially and would benefit from an overhaul and more attention to ongoing maintenance. LLNL management decided to update the LLNL seismic instrumentation system. The updated system is documented in this report.

42 ENGINEERING↗

Synthesis of SHAL and SHAL Precursor Standard, CRADA No. TC02174.0

The purpose of this CRADA was to establish a collaborative effort between SHAL Technologies and Lawrence Livermore National Laboratory that would advance the development and testing of a family of small molecule oncology drugs and companion diagnostics called selective high affinity ligands (SHALs) for the treatment of advanced non-Hodgkin’s lymphoma. These compounds were first synthesized by the LLNL chemist participating in this CRADA when the compounds were first developed (2004-2008) by the founders of SHAL Technologies (while they were employed at LLNL). This CRADA initially had five deliverables. Deliverables 1-3 involved LLNL’s synthesis of 10-50 mg of the SHALs SH7133 and SH7139 using the same bench-scale conditions used previously, their purification, and obtaining data needed to demonstrate the mass and purity of the compounds. Deliverable 4, which was to be completed by SHAL Technologies, was the comparison of the bench-scale synthetic products to the same compounds manufactured on the multigram to kilogram scale by the contract research organization (CRO) AmbioPharm Inc. The fifth deliverable was this final report. An amendment was made to add the additional tasks and deliverables needed to synthesize the third SHAL standard SH7129 (the diagnostic) and compare it to product manufactured by AmbioPharm. During the testing of the three standards synthesized by LLNL, the SHAL compounds were found to lack biological activity. When we discovered that a commercial chemical supplier provided both LLNL and our CRO AmbioPharm with a SHAL precursor that had the wrong structure, two amendments to the CRADA were made to add additional tasks and deliverables to enable us to repeat all the syntheses and conduct more extensive testing of the bench scale and manufactured products. Once the final correct products were synthesized and confirmed to have the right structures, a third amendment was added to the CRADA to enable the synthesis of two fragments of the SHALs to determine if these compounds are produced when the SHALs are metabolized. This last synthesis was included to provide the information needed to establish a second, new CRADA between SHAL Technologies and LLNL that would focus on the identifying how the SHALs are metabolized and how their metabolic products may be responsible for the selective killing of tumor cells over-expressing the protein targeted by the SHALs, HLA-DR10.

60 APPLIED LIFE SCIENCES↗

Non-Invasive Pneumothorax Detector Final Report CRADA No. TC02110.0

This was a collaborative effort between Lawrence Livermore National Security, LLC as manager and operator of Lawrence Livermore National Laboratory (LLNL) and ElectroSonics Medical Inc. (formerly known as BIOMEC, Inc.), to develop a non-invasive pneumothorax detector based upon the micropower impulse radar technology invented at LLNL. Under a Work for Others Subcontract (L-9248), LLNL and ElectroSonics successfully demonstrated the feasibility of a novel device for non-invasive detection of pneumothorax for emergency and long-term monitoring. The device is based on Micropower Impulse Radar (MIR) Ultra Wideband (UWB) technology. Phase I experimental results were promising, showing that a pneumothorax volume even as small as 30 ml was clearly detectable from the MIR signals. Phase I results contributed to the award of a National Institute of Health (NIH) SBIR Phase II grant to support further research and development. The Phase II award led to the establishment of a LLNL/ElectroSonics CRADA related to Case No. TC02045.0. Under the subsequent CRADA, LLNL and ElectroSonics successfully demonstrated the feasibility of the pneumothorax detection in human subject research trials. Under this current CRADA TC02110.0, also referred to as Phase II Type II, the project scope consisted of seven tasks in Project Year 1; five tasks in Project Year 2; and four tasks in Project Year 3. Year 1 tasks were aimed toward the delivery of the pneumothorax detector design package for the pre-production of the miniaturized CompactFlash dockable version of the system. The tasks in Project Years 2 and 3 critically depended upon the accomplishments of Task 1. Since LLNL’s task was to provide subject matter expertise and performance verification, much of the timeline of engagement by the LLNL staff depended upon the overall project milestones as determined by the lead organization ElectroSonics. The scope of efforts were subsequently adjusted accordingly to commensurate with funding availability.

42 ENGINEERING↗

Infrared Imaging Camera Final Report CRADA No. TC02061.0

This was a collaborative effort between the University of California, Lawrence Livermore National Laboratory (LLNL) and Cordin Company (Cordin) to enhance the U.S. ability to develop a commercial infrared camera capable of capturing high-resolution images in a l 00 nanoseconds (ns) time frame. The Department of Energy (DOE), under an Initiative for Proliferation Prevention (IPP) project, funded the Russian Federation Nuclear Center All-Russian Scientific Institute of Experimental Physics (RFNC-VNIIEF) in Sarov. VNIIEF was funded to develop a prototype commercial infrared (IR) framing camera and to deliver a prototype IR camera to LLNL. LLNL and Cordin were partners with VNIIEF on this project. A prototype IR camera was delivered by VNIIEF to LLNL in December 2006. In June of 2007, LLNL and Cordin evaluated the camera and the test results revealed that the camera exceeded presently available commercial IR cameras. Cordin believes that the camera can be sold on the international market. The camera is currently being used as a scientific tool within Russian nuclear centers. This project was originally designated as a two year project. The project was not started on time due to changes in the IPP project funding conditions; the project funding was re-directed through the International Science and Technology Center (ISTC), which delayed the project start by over one year. The project was not completed on schedule due to changes within the Russian government export regulations. These changes were directed by Export Control regulations on the export of high technology items that can be used to develop military weapons. The IR camera was on the list that export controls required. The ISTC and Russian government, after negotiations, allowed the delivery of the camera to LLNL. There were no significant technical or business changes to the original project.

47 OTHER INSTRUMENTATION↗

Operational Stewardship Program Development and Execution Lawrence Livermore National Laboratory - 16353

As LLNL carries out its national security missions, the Laboratory strives to ensure its facilities portfolio meets the latest technologies and enables infrastructure needs. Among the identified Science, Technology and Engineering (ST and E) areas that constitute strategic priorities, state-of-the-art facilities are needed to allow LLNL to draw collaborative partners required to advance capabilities and provide the requisite world-class forensics support in nuclear threat countermeasures. Efficient utilization of existing facilities presents a unique challenge given the advanced age and unique mission design of many of LLNL's facilities. A strategy developed in 2007 sought to focus key reinvestments into enduring facilities while strategically migrating personnel and operations out of past mission facilities with the intent of closure and final Transition and Disposition (T and D). At the time, LLNL lacked processes or procedures that met the continually changing facility mission and objectives needs. A comprehensive approach was needed to provide the framework to guide decisions along the entire life cycle of a project and/or facility. The development of an Operational Stewardship Program began in 2012 which outlines the process, and roles and responsibilities, in changing facility status to ensure good stewardship, accountability, and management and utilization of facilities. Further emphasizing LLNL forward actions, the 2015 NNSA sponsored Excess Contaminated Facilities Working Group charted the development of a common, Department-wide methodology for determining costs and risks. In December 2015, the complete Operational Stewardship Program was approved for implementation by LLNL senior management. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

2023 Annual Explosives Inventory Completion

The 2023 Lawrence Livermore National Laboratory (LLNL) annual explosives inventory was executed from May 18, 2023 to September 27, 2023 and was verified for accuracy effective September 28, 2023 following the LLNL Explosive Materials Inventory Plan. This year’s annual inventory includes changes incorporated based on the Department of Energy (DOE) Office of Inspector General (OIG) Audit Report DOE-OIG-20-50, The Department of Energy’s Storage and Disposition of Explosives Material at Selected Sites, dated July of 2020. Based on the associated recommendations, explosives at DOE and National Nuclear Safety Administration (NNSA) sites are considered "sensitive personal property" and applicable inventories must comply with 41 CFR 109, Personal Property Management. This regulation adds additional stipulations which require the annual inventory to include accountability of the total site inventory. In addition, the inventory must be performed by personnel other than the property owner, or alternatively must include independent verification. The development of the inventory plan was agreed to by the LLNL Explosives Safety Committee in conjunction with the LLNL Property and Business Division Leader. The LLNL Explosive Materials Inventory Plan was reviewed and approved by the DOE Explosives Safety Committee Chair on May 17, 2023 and by the NNSA Property Management Office on May 25, 2023.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Special Analysis for the Disposal of the Lawrence Livermore National Laboratory Low Activity Beta/Gamma Sources Waste Stream at the Area 5 Radioactive Waste Management Site, Nevada National Security Site, Nye County, Nevada

This special analysis (SA) evaluates whether the Lawrence Livermore National Laboratory (LLNL) Low Activity Beta/Gamma Sources waste stream (BCLALADOEOSRP, Revision 0) is suitable for disposal by shallow land burial (SLB) at the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada National Security Site (NNSS). The LLNL Low Activity Beta/Gamma Sources waste stream consists of sealed sources that are no longer needed. The LLNL Low Activity Beta/Gamma Sources waste stream required a special analysis because cobalt-60 (60Co), strontium-90 (90Sr), cesium-137 (137Cs), and radium-226 (226Ra) exceeded the NNSS Waste Acceptance Criteria (WAC) Action Levels (U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office [NNSA/NFO] 2015). The results indicate that all performance objectives can be met with disposal of the LLNL Low Activity Beta/Gamma Sources in a SLB trench. The LLNL Low Activity Beta/Gamma Sources waste stream is suitable for disposal by SLB at the Area 5 RWMS. However, the activity concentration of 226Ra listed on the waste profile sheet significantly exceeds the action level. Approval of the waste profile sheet could potentially allow the disposal of high activity 226Ra sources. To ensure that the generator does not include large 226Ra sources in this waste stream without additional evaluation, a control is need on the maximum 226Ra inventory. A limit based on the generator’s estimate of the total 226Ra inventory is recommended. The waste stream is recommended for approval with the control that the total 226Ra inventory disposed shall not exceed 5.5E10 Bq (1.5 Ci).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

New insights into fuel blending effects: Intermolecular chemical kinetic interactions affecting autoignition times and intermediate-temperature heat release

Fuel blending effects on chemically-dominated fuel properties, such as gasoline anti-knock quality, are influenced by fundamental chemical kinetic interactions between the blending agent and the base fuel. Historically, quantification of such interactions has focused on changes to the radical pool, including $\dot{O}$H and HO 2 , while intermolecular interactions pertaining to carbonated, non-fuel-specific intermediates are typically overlooked. In this regard, this work aims to derive new insight into intermolecular chemical kinetic interactions that are intrinsic to fuel blending effects via a case study on blends of 0–30% ethanol (by volume) into FGF-LLNL (a multi-component gasoline surrogate for FACE-F research gasoline) using a rapid compression machine at a diluted/stoichiometric fuel loading, compressed pressure of 40 bar and low- to intermediate-temperature regimes that are representative of boosted SI engine operation. Ethanol blending effects on the intermediate temperature heat release (ITHR) of FGF-LLNL are characterized using experimental measurements, where ethanol is found to promote the extent of ITHR and suppress the transition from ITHR to main ignition. Chemical kinetic modeling is undertaken using a recently updated gasoline surrogate model. Sensitivity analyses on ITHR characteristics further corroborate the ethanol blending effects, and highlight the significant dependence of ITHR on both fuel-specific and non-fuel-specific reactions. An approach allowing comprehensive characterization of the complex intermolecular chemical kinetic interactions between constitutes in a fuel blend is then proposed. Application of the approach to FGF-LLNL/E0–E30 reveals that ethanol perturbs the heat release and autoignition characteristics of FGF-LLNL not only by directly changing the $\dot{O}$H and HO 2 radical pools via fuel-specific reactions, but also through intermolecular interactions where participating intermediates can be produced and consumed by various sub-chemistries. Disabling the intermolecular interactions in carbonated species between ethanol and FGF-LLNL sub-chemistries leads to somewhat slower ITHR evolution and lower ignition reactivity. The role of the individual intermolecular interaction is also characterized using the proposed approach. Lastly, implications of intermolecular interactions for future studies that aim to improve model performance are highlighted, where it is found that further investigations on the core C0-C4 chemistry are needed for developing highly accurate chemistry models for complex fuel blends.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hyperspectral Sensors Final Report CRADA No. TC02173.0

This was a collaborative effort between Lawrence Livermore National Security, LLC as manager and operator of Lawrence Livermore National Laboratory (LLNL) and Science Applications International Corporation (SAIC), National Security Space Operations/SRBU, to develop longwave infrared (LWIR) hyperspectral imaging (HSI) sensors for airborne and potentially ground and space, platforms. LLNL has designed and developed LWIR HSI sensors since 1995. The current generation of these sensors has applications to users within the U.S. Department of Defense and the Intelligence Community. User needs are for multiple copies provided by commercial industry. To gain the most benefit from the U.S. Government’s prior investments in LWIR HSI sensors developed at LLNL, transfer of technology and know-how from LLNL HSI experts to commercial industry was needed. The overarching purpose of the CRADA project was to facilitate the transfer of the necessary technology from LLNL to SAIC thereby allowing the U.S. Government to procure LWIR HSI sensors from this company.

47 OTHER INSTRUMENTATION↗

Pilot Demonstration Test Bed for ICC Desiccant Based Cooling System Final Report CRADA No. TSB-737-93

In this CRADA project, LLNL provided a field engineering, operation, and maintenance evaluation of ICC’s Desiccant Based Cooling (DBC) System by installing and activating an instrumented test bed in a real application at LLNL. LLNL was approached by two manufacturers of newly emerging heating, ventilation and air-conditioning (HVAC) equipment for technical assistance in obtaining engineering thermodynamic evaluation of their units. Despite promising improvements in technical HVAC performance and the elimination of environmentally sensitive materials (CFC’S), they experienced market resistance in the federal sector because of the need to develop a record of technical and reliability data. LLNL selected three sites as areas where the units could potentially produce significant improvements in energy consumption and healthy air conditions. This project covered the installation activation of the pilot test bed at LLNL. The collaborative effort provided statistical and requirements bases to make a valid evaluation of the units.

42 ENGINEERING↗

Prototype Stilbene Neutron Collar II

A neutron collar using stilbene organic scintillator cells for fast neutron counting is described for the assay of fresh low enriched uranium (LEU) fuel assemblies. The prototype stilbene collar has a form factor similar to standard He-3 based collars and uses an AmLi interrogation neutron source. This report describes the simulation, using a custom LLNL developed MCNPX, of list mode neutron correlation data on various fuel assemblies. Some of these fuel assemblies have neutron absorbers (burnable Gd poisons) and partial defect s (DU, Fe, Pb pins). Calibration curves (doubles vs 235 U linear mass density) are presented for fast (with Cd lining) mode of operation. The modeling incorporates LLNL developed neutron crosstalk correction algorithms and stilbene light output detector response quench function. Pileup issues are addressed using the LLNL code GamGen / RadSrc to estimate the flux of alpha decay gammas from the fuel assemblies on the stilbene cells with and without Pb shielding. One panel of the prototype collar using 10 high-efficiency 4”x2” stilbene cells from Inrad Optics, using LLNL developed technology, has been constructed and calibrated for optimal PSD and data acquisition electronics. Several sources (AmLi, AmBe, Cf, DD, and DT) have been measured with the single panel and the measured data is consistent with the modeling. A novel part of our work was to determine the light output (LO) quench function for the Inrad 4” x 2” stilbene crystals through a LLNL-MCNPX simulation based optimized fitting of the measured LO data.

42 ENGINEERING↗