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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

Circumpolar hoods and clouds and their relation to the Martian H2O cycle

Water exists in both vapor and solid phases in the Martian atmosphere. The polar hoods are shrouds of condensate clouds which obscure both polar regions at times during their respective fall and winter seasons. The hemispheric asymmetries in the polar hood clouds are reviewed and their significance to the seasonal water cycle is discussed. Comparisons of images acquired using short wavelength filters, which provide maximum cloud contrast, and long wavelength filters, which are sensitive to surface features including the surface cap, provide correlations between cloud formation and large scale planetary dynamics.

James, Philip B.↗
NASA NTRS1988

Measurements of H2O in the terrestrial mesosphere and implications for extra-terrestrial sources

Recent measurements of mesospheric water vapor and their implications for the existence of extraterrestrial sources of water are discussed. This study was prompted by the work of L. Frank and others who, based on their interpretation of transient dark spots visible in ultraviolet images of the Earth's dayglow emission, have proposed that a large flux of small comets enters the Earth's upper atmosphere each day. To date, however, analysis does not conclusively refute or support the idea of an external source.

Olivero, John J.↗
NASA NTRS1988

Diurnal and annual cycles of H2O in the Martian regolith

The atmospheric heat engines of Earth and Mars are compared. Although water latent heat transfer drives the circulation of the Earth's atmosphere, particularly in the tropics, its contribution to the circulation of the martian atmosphere is negligible. The working fluid on Mars is CO2, which exerts its greatest influence on atmospheric circulation at the poles. The diurnal and seasonal flux of water within the martian regolith is also examined. Calculations indicate that, for a mean annual temperature of 200 K, a diurnal and annual temperature variation of 30 K will drive a maximum exchange of 1.2 pr micrometer and 120 pr micrometer of water, respectively.

Philip, John R.↗
NASA NTRS1988

Atmospheric H2O and the search for Martian brines

Abundant martian brines would have important implication for current theories of volatile migration on Mars, since, although the presence of metastable brines is quite plausible, any brine in the reasonably near-surface should be completely depleted on a timescale short in relation to the age of Mars. It is important to determine whether brines exist in the martian subsurface, for the current paradigm for understanding martian volatile regime requires substantial alteration if they are found to exist. It is determined, however, that the prospect for detection of a subsurface brine via atmospheric water vapor measurements is marginal. Four reasons are given for this conclusion.

Zent, Aaron P.↗
NASA NTRS1988

A study of H2O ice in the 3 micron spectrum of OH 231.8+4.2 (OH 0739-14)

Moderate resolution IR spectra of OH 231.8+4.2 in the 2.0-3.8-micron spectral region are presented. It is shown that the large-scale features of the observed spectra can only be modeled with an unusually large upper limit to the grain-size distribution (0.6-0.7 microns). Two new absorption features have been found in the wings of the 3.08-micron feature, near 2.95 and 3.2 microns. The results suggest that a mixture of amorphous and crystalline ice may have produced the 3.08-micron feature in this object.

Smith, Robert G.↗
NASA NTRS1988

Multichannel processes of H2O in the 18 eV region

Measurements were made of: (1) the fluorescence cross sections of OH(A 2Sigma+) fragments; (2) the absolute cross sections producing H atoms in the n = 2, 3, and 4 states; (3) the cross section for producing excited O atoms which has an upper limit of 5 x 10 to the -21 sq cm; and (4) the fluorescence cross section for producing H2(a 3Sigma g +) fragments. It is shown that, in the 16-20 eV region, there are excellent correspondences in the peak positions and spacings among the photoabsorption, photoionization spectra, and fluorescence functions of OH(A) and H(n).

Wu, C. Y. Robert↗
NASA NTRS1990

Enhancement of Pt/SnO2 Catalysts by Addition of H2O

Water vapor in pretreatment gas restores essential hydroxyl groups. Platinum on tin oxide (Pt/SnO2) is good catalyst for oxidation of carbon monoxide (CO) at temperatures from about 25 degrees C to 100 degress C. Activity of Pt/SnO2 for CO oxidation significantly enhanced by pretreating it at approximately 225 degrees C with reducing gas such as CO. Technique useful in manufacture of high-power CO2 lasers for industrial and scientific uses.

Schryer, David R.↗
NASA NTRS1990

The effect of H2O and pretreatment on the activity of a Pt/SnO2 catalyst

CO oxidation catalysts with high activity at 25 C to 100 C are important for long-life, closed-cycle operation of pulsed CO2 lasers. A reductive pretreatment with either CO or H2 has been shown to significantly enhance the activity of a commercially available platinum on tin (IV) oxide (Pt/SnO2) catalyst relative to an oxidative or inert pretreatment or no pretreatment. Pretreatment at temperatures of 175 C and above causes an initial dip in the observed CO2 yield before the steady-state yield is attained. This dip has been found to be caused by dehydration of the catalyst during pretreatment and is readily eliminated by humidifying the catalyst or the reaction gas mixture. It is hypothesized that the effect of humidification is to increase the concentration of OH groups on the catalyst surface which play a role in the reaction mechanism.

Vannorman, John D.↗
NASA NTRS1989

Effects of H2O, CO2, and N2 air contaminants on critical airside strain rates for extinction of hydrogen-air counterflow diffusion flames

Dish-shaped counterflow diffusion flames centered by opposing laminar jets of H2 and clean and contaminant O2/N2 mixtures in an argon bath at 1 atm were used to study the effects of contaminants on critical airside strain. The jet velocities for both flame extinction and restoration are found for a wide range of contaminant and O2 concentrations in the air jet. The tests are also conducted for a variety of input H2 concentrations. The results are compared with those from several other studies.

Pellett, G. L.↗
NASA NTRS1989

Effects of H2O, CO2, and N2 Air Contaminants on Critical Airside Strain Rates for Extinction of Hydrogen-Air Counterflow Diffusion Flames

Coaxial tubular opposed jet burners (OJB) were used to form dish shaped counterflow diffusion flames (CFDF), centered by opposing laminar jets of H2, N2 and both clean and contaminated air (O2/N2 mixtures) in an argon bath at 1 atm. Jet velocities for flame extinction and restoration limits are shown versus wide ranges of contaminant and O2 concentrations in the air jet, and also input H2 concentration. Blowoff, a sudden breaking of CFDF to a stable ring shape, occurs in highly stretched stagnation flows and is generally believed to measure kinetically limited flame reactivity. Restore, a sudden restoration of central flame, is a relatively new phenomenon which exhibits a H2 dependent hysteresis from Blowoff. For 25 percent O2 air mixtures, mole for mole replacement of 25 percent N2 contaminant by steam increased U(air) or flame strength at Blowoff by about 5 percent. This result is consistent with laminar burning velocity results from analogous substitution of steam for N2 in a premixed stoichiometric H2-O2-N2 (or steam) flame, shown by Koroll and Mulpuru to promote a 10 percent increase in experimental and calculated laminar burning velocity, due to enhanced third body efficiency of water in: H + O2 + M yields HO2 + M. When the OJB results were compared with Liu and MacFarlane's experimental laminar burning velocity of premixed stoichiometric H2 + air + steam, a crossover occurred, i.e., steam enhanced OJB flame strength at extinction relative to laminar burning velocity.

Pellett, G. L.↗
NASA NTRS1991

The P/Halley: Spatial distribution and scale lengths for C2, CN, NH2, and H2O

From P/Halley long slit spectroscopic exposures on 12 dates, extending from Oct. 1985 to May 1986, spatial profiles were obtained for emissions by C2, CN, NH2, and OI(1D). Haser model scale lengths were fitted to these data. The extended time coverage allowed the checking for consistency between the various dates. The time varying production rate of P/Halley severely affected the profiles after perihelion, which is shown in two profile sequences on adjacent dates. Because of the time varying production rate, it was not possible to obtain reliable Haser model scale lengths after perihelion. The pre-perihelion analysis yielded Haser model scale lengths of sufficient consistency that they can be used for production rate determinations, whenever it is necessary to extrapolate from observed column densities within finite observing apertures. Results of scale lengths reduced to 1 AU are given and discussed.

Fink, Uwe↗
NASA NTRS1989

An interim reference model for the variability of the middle atmosphere H2O vapor distribution

Water vapor is an important minor constituent in the studies of the middle atmosphere for a variety of reasons, including its role as a source for active HO(y) chemicals and its use in analysis of transport processes. A number of in situ and remote techniques were employed in the determination of water vapor distributions. Two of the more complete data sets were used to develop an interim reference profile. First, there are the seven months of Nimbus 7 limb infrared monitor of the stratosphere (LIMS) data obtained during Nov. 1978 to May 1979 over the range 64S to 84N latitude and from about 100 to 1 mb in the mid-mesosphere at several fixed Northern Hemisphere mid-latitude sites. These two data sets were combined to give a mid-lattitude, interim reference water vapor profile for the entire vertical range of the middle atmosphere and with accuracies of better than 25 percent. The daily variability of stratospheric water vapor profiles about the monthly mean was also established from these data sets for selected months. Information is also provided on the longitudinal variability of LIMS water vapor profiles about the daily, weekly, and monthly zonal means. Generally, the interim reference water vapor profile and its variability are consistent with prevailing ideas about chemistry and transport.

Remsberg, E. E.↗
NASA NTRS1991

Alteration of the UV-visible reflectance spectra of H2O ice by ion bombardment

Satellite in the Jovian and Saturnian system exhibit differences in reflectivity between their 'leading' and 'trailing' surfaces which can affect the local vapor pressure. Since these differences are thought to be due to differences in the flux of bombarding magnetospheric ions, the influence of ion impact on the UV-visible reflectance of water ice surfaces (20-90 K) by keV ion bombardment was studied. An observed decrease in reflectance in the UV is attributed to rearrangement processes that affect the physical microstructure and surface 'roughness'. The ratio in reflectance of bombarded to freshly deposited films is compared to the ratio of the reflectance of the leading and trailing hemispheres for Europa and Ganymede.

Sack, N. J.↗
NASA NTRS1992

Electrochemical System Would Supply O2, H2O, N2, And H2

Electrochemical system includes fuel cells that convert high-energy-density chemical propellants to atmospheric gases. System provides cooling, water, and electrical energy. Applicable to terrestrial enclosed environments, laboratories, chemical processing plants, or portable medical facilities.

Walter, Richard T.↗
NASA NTRS1991

The 2.5-5.0 micron spectra of Io: Evidence for H2S and H2O frozen in SO2

The techniques of low temperature spectroscopy are applied to identify the constituents of the ices covering the surface of Io, a satellite of Jupiter. Infrared spectra of Io in the 4000-2000 cm exp -1 region, including new observational data, are analyzed using laboratory studies of plausible surface ices.

Salama, F.↗
NASA NTRS1992

Gibbs free energy of reactions involving SiC, Si3N4, H2, and H2O as a function of temperature and pressure

Silicon carbide and silicon nitride are considered for application as structural materials and coating in advanced propulsion systems including nuclear thermal. Three-dimensional Gibbs free energy were constructed for reactions involving these materials in H2 and H2/H2O. Free energy plots are functions of temperature and pressure. Calculations used the definition of Gibbs free energy where the spontaneity of reactions is calculated as a function of temperature and pressure. Silicon carbide decomposes to Si and CH4 in pure H2 and forms a SiO2 scale in a wet atmosphere. Silicon nitride remains stable under all conditions. There was no apparent difference in reaction thermodynamics between ideal and Van der Waals treatment of gaseous species.

Isham, M. A.↗