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NASA NTRS1994

Performance model of a recirculating stack nickel hydrogen cell

A theoretical model of the nickel hydrogen battery cell has been utilized to describe the chemical and physical changes during charge and overcharge in a recirculating stack nickel hydrogen cell. In particular, the movement of gas and electrolyte have been examined as a function of the amount of electrolyte put into the cell stack during cell activation, and as a function of flooding in regions of the gas screen in this cell design. Additionally, a two-dimensional variation on this model has been utilized to describe the effects of non-uniform loading in the nickel-electrode on the movement of gas and electrolyte within the recirculating stack nickel hydrogen cell. The type of nonuniform loading that has been examined here is that associated with higher than average loading near the surface of the sintered nickel electrode, a condition present to some degree in many nickel electrodes made by electrochemical impregnation methods. The effects of high surface loading were examined primarily under conditions of overcharge, since the movement of gas and electrolyte in the overcharging condition was typically where the greatest effects of non-uniform loading were found. The results indicate that significant changes in the capillary forces between cell components occur as the percentage of free volume in the stack filled by electrolyte becomes very high. These changes create large gradients in gas-filled space and oxygen concentrations near the boundary between the separator and the hydrogen electrode when the electrolyte fill is much greater than about 95 percent of the stack free volume. At lower electrolyte fill levels, these gaseous and electrolyte gradients become less extreme, and shift through the separator towards the nickel electrode. Similarly, flooding of areas in the gas screen cause higher concentrations of oxygen gas to approach the platinum/hydrogen electrode that is opposite the back side of the nickel electrode. These results illustrate the need for appropriate pore size distributions, and the maintenance of both convective electrolyte and gas flow paths through the stack, if the recirculating stack nickel hydrogen cell design is to work properly.

Zimmerman, Albert H.↗

NASA NTRS2020

Recover Gas from Liquids in Low Gravity

This document is the final report resulting from the work conducted by undergraduate students at the University of South Alabama during the 2019/2020 academic year. Currently, on the International Space Station a solid adsorbent material is used to remove CO 2 from cabin air; however, liquid absorbent/reactive based systems are appealing because they may offer greater CO 2 capture efficiency. When liquids are used to capture CO 2 a regeneration step is required to release the CO 2 from the fluid for subsequent processing. During regeneration aerosolized droplets of water and liquid amines are produced creating a 2-phase fluid stream. Because the CO 2 stream is to be sent to a Sabatier reactor for conversion into methane, the droplets of the water and amines must be removed, necessitating the need for a vapor/liquid separation process in a microgravity environment. This class was tasked with designing a system to separate the aerosolized droplets from the gas stream. An ionic liquid was assumed to be the amine based absorber fluid that was used to capture the CO 2 , which is a key assumption because the ionic liquid has vanishingly low vapor pressure. The lack of volatility of the ionic liquid eliminates the need to manage an aerosolized amine resulting in only an aerosolized water air separation. To solve this challenge an undergraduate class used systems engineering to design and construct a hydrophobic screen separation apparatus for a 2-phase, vapor/liquid flow. The apparatus was constructed, but initial testing was not possible due to the closure of the University labs due to the corona-virus pandemic.

T Grant Glover↗

NASA NTRS1993

Probing the extent and content of low ionization gas in galaxies: QSO absorption and HI emission

The small projected separations of some QSO's and low-redshift galaxies provide unique opportunities to study the extent and content of gas in galaxies through observation of absorption in the QSO spectra. Observations of these systems provide valuable information on the connection between the absorbing gas and the galaxy, as well as detailed information on the morphology and environment of the galaxy itself. While there is direct evidence that galaxies can produce the intervening-type QSO absorption lines, over the past decade, the study of such 'QSO-galaxy pairs' (at low redshift) has been considered unsuccessful because new detections of absorption were seldom made. A fundamental problem concerning the relation between these low-redshift systems and those seen at moderate to high redshift remains unresolved. Direct and indirect measures of galaxy absorption cross sections at moderate to high redshifts (z is approximately greater than 20.5) are much larger than the optical and HI sizes of local galaxies. However, direct comparison of the low and moderate to high redshift systems is difficult since different ions are observed in different redshift regimes. Observations are presented for a new sample of QSO-galaxy pairs. Nine new QSO's which shine through nearby galaxies (on the sky-plane) were observed to search for CaII absorption in the QSO spectra at the foreground galaxy redshifts.

Womble, Donna S.↗

NASA NTRS1969

The gas-liquid chromatography of amino acids

Butyl esters separation from protein amino acids, using acid washed Chromosorb W of various mesh sizes

Gehrke, C. W.↗

NASA NTRS1993

Velocity resolved spectroscopy of molecular hydrogen emission in NGC6240

NGC6240 is a member of the class of luminous galaxies which emit a significant fraction of their total light in the infrared. Based on its highly disturbed morphology, Fosbury and Wall (1979) suggested that the system may be a merger of two gas rich galaxies. It has two nuclei separated by 2 arcsec which are visible in the near infrared and at radio wavelengths and CO observations show that the galaxy contains a large mass of molecular gas. Unusually strong H2 emission lines dominate the near infrared spectrum of this galaxy. The galaxy emits approximately 4x10(exp 7) solar luminosity in the 2.12 micron v = 1 to 0 S(1) line alone, an order of magnitude more than other merging or starburst galaxies. To provide a better understanding of the physical processes responsible for the H2 emission from NGC6240 we have begun a program to obtain high spectral resolution observations using the echelle in CGS4 on the UKIRT. Preliminary data which were obtained in February 1991 are presented here. It is intended to obtain further observations with twice the spatial and spectral resolution in June of this year.

Wright, G. S.↗

NASA NTRS1979

Parametric study of potential early commercial MHD power plants

Three different reference power plant configurations were considered with parametric variations of the various design parameters for each plant. Two of the reference plant designs were based on the use of high temperature regenerative air preheaters separately fired by a low Btu gas produced from a coal gasifier which was integrated with the power plant. The third reference plant design was based on the use of oxygen enriched combustion air preheated to a more moderate temperature in a tubular type metallic recuperative heat exchanger which is part of the bottoming plant heat recovery system. Comparative information was developed on plant performance and economics. The highest net plant efficiency of about 45 percent was attained by the reference plant design with the use of a high temperature air preheater separately fired with the advanced entrained bed gasifier. The use of oxygen enrichment of the combustion air yielded the lowest cost of generating electricity at a slightly lower plant efficiency. Both of these two reference plant designs are identified as potentially attractive for early MHD power plant applications.

Hals, F. A.↗

NASA NTRS1979

Sunspots and the physics of magnetic flux tubes. IX - Umbral dots and longitudinal overstability

The dynamical properties of the sunspot field and of a column of hot gas confined by such a vertical magnetic field are examined in order to understand the umbral dot within the context of the magnetic sunspot structure. Attention is given to the conditions necessary for gas intrusion, longitudinal as well as convective overstability, the growing modes, and the even mode. With the hypothesis that the subsurface magnetic field of a sunspot splits into many separate flux tubes with field-free gas between, it is suggested that the field-free columns occasionally punch their way up through the overlying magnetic field to the surface, appearing there as the bright, field-free umbral dots. Effects fostering the phenomenon are also discussed, that is, the enhanced temperature of a column of rising gas, the strongly reduced overhead magnetic pressure, and the initiated upward intrusion; these effects are illustrated with examples.

Parker, E. N.↗

NASA NTRS2011

Weak Lensing Results of the Merging Cluster A1758

Here we present the weak lensing results of A1758, which is known to have four cluster members undergoing two separate mergers, A1758N and A1758S. Weak lensing results of A1758N agree with previous weak lensing results of clusters lE0657-558 (Bullet cluster) and MACS J0025.4-1222, whose X-ray gas components were found to be largely separated from their clusters' gravitational potentials. A1758N has a geometry that is different from previously published mergers in that one of its X-ray peaks overlays the corresponding gravitational potential and the other X-ray peak is well separated from its cluster's gravitational potential.

Markevitch, M.↗

NASA NTRS2003

Membrane-Based Gas Traps for Ammonia, Freon-21, and Water Systems to Simplify Ground Processing

Gas traps are critical for the smooth operation of coolant loops because gas bubbles can cause loss of centrifugal pump prime, interference with sensor readings, inhibition of heat transfer, and blockage of passages to remote systems. Coolant loops are ubiquitous in space flight hardware, and thus there is a great need for this technology. Conventional gas traps will not function in micro-gravity due to the absence of buoyancy forces. Therefore, clever designs that make use of adhesion and momentum are required for adequate separation, preferable in a single pass. The gas traps currently used in water coolant loops on the International Space Station are composed of membrane tube sets in a shell. Each tube set is composed of a hydrophilic membrane (used for water transport and capture of bubbles) and a hydrophobic membrane (used for venting of air bubbles). For the hydrophilic membrane, there are two critical pressures, the pressure drop and the bubble pressure. The pressure drop is the decrease in system pressure across the gas trap. The bubble pressure is the pressure required for air bubbles to pass across the water filled membrane. A significant difference between these pressures is needed to ensure complete capture of air bubbles in a single pass. Bubbles trapped by the device adsorb on the hydrophobic membrane in the interior of the hydrophilic membrane tube. After adsorption, the air is vented due to a pressure drop of approximately 1 atmosphere across the membrane. For water systems, the air is vented to the ambient (cabin). Because water vapor can also transport across the hydrophobic membrane, it is critical that a minimum surface area is used to avoid excessive water loss (would like to have a closed loop for the coolant). The currently used gas traps only provide a difference in pressure drop and bubble pressure of 3-4 psid. This makes the gas traps susceptible to failure at high bubble loading and if gas venting is impaired. One mechanism for the latter is when particles adhere to the hydrophobic membrane, promoting formation of a water layer about it that can blind the membrane for gas transport (Figure 1). This mechanism is the most probable cause for observed failures with the existing design. The objective of this project was to devise a strategy for choosing new membrane materials (database development and procedure), redesign of the gas trap to mitigate blinding effects, and to develop a design that can be used in ammonia and Freon-21 coolant loops.

Ritchie, Stephen M. C.↗

NASA NTRS2015

Sample Acquisition and Analytical Chemistry Challenges to Verifying Compliance to Aviators Breathing Oxygen (ABO) Purity Specification

NASA has been developing and testing two different types of oxygen separation systems. One type of oxygen separation system uses pressure swing technology, the other type uses a solid electrolyte electrochemical oxygen separation cell. Both development systems have been subjected to long term testing, and performance testing under a variety of environmental and operational conditions. Testing these two systems revealed that measuring the product purity of oxygen, and determining if an oxygen separation device meets Aviator's Breathing Oxygen (ABO) specifications is a subtle and sometimes difficult analytical chemistry job. Verifying product purity of cryogenically produced oxygen presents a different set of analytical chemistry challenges. This presentation will describe some of the sample acquisition and analytical chemistry challenges presented by verifying oxygen produced by an oxygen separator - and verifying oxygen produced by cryogenic separation processes. The primary contaminant that causes gas samples to fail to meet ABO requirements is water. The maximum amount of water vapor allowed is 7 ppmv. The principal challenge of verifying oxygen produced by an oxygen separator is that it is produced relatively slowly, and at comparatively low temperatures. A short term failure that occurs for just a few minutes in the course of a 1 week run could cause an entire tank to be rejected. Continuous monitoring of oxygen purity and water vapor could identify problems as soon as they occur. Long term oxygen separator tests were instrumented with an oxygen analyzer and with an hygrometer: a GE Moisture Monitor Series 35. This hygrometer uses an aluminum oxide sensor. The user's manual does not report this, but long term exposure to pure oxygen causes the aluminum oxide sensor head to bias dry. Oxygen product that exceeded the 7 ppm specification was improperly accepted, because the sensor had biased. The bias is permanent - exposure to air does not cause the sensor to return to its original response - but the bias can be accounted for by recalibrating the sensor. After this issue was found, continuous measurements of water vapor in the oxygen product were made using an FTIR. The FTIR cell is relatively large, so response time is slow - but moisture measurements were repeatable and accurate. Verifying ABO compliance for oxygen produced by commercial cryogenic processes has a different set of sample acquisition and analytical chemistry challenges. Customers want analytical chemists to conserve as much as possible. Hygrometers are not exposed to hours of continuous flow of oxygen, so they don't bias, but small amounts of contamination in valves can cause a "fail". K bottles are periodically cleaned and recertified - after cleaning residual moisture can cause a "fail". Operators let bottle pressure drop to room pressure, introduce outside air into the bottle, and the subsequent fill will "fail". Outside storage of K‐bottles has allowed enough in‐leakage, so contents will "fail".

Graf, John↗

NASA NTRS2016

Spatially Resolved Galactic Wind in Lensed Galaxy RCSGA 032727-132609

We probe the spatial distribution of outflowing gas along four lines of sight separated by up to 6 kpc in a gravitationally lensed star-forming galaxy at z = 1.70. Using Mg II and Fe II emission and absorption as tracers, we find that the clumps of star formation are driving galactic outflows with velocities of − 170 to − 250 km/s. The velocities of Mg II emission are redshifted with respect to the systemic velocities of the galaxy, consistent with being backscattered. By contrast, the Fe II fluorescent emission lines are either slightly blueshifted or at the systemic velocity of the galaxy. Taken together, the velocity structure of the Mg II and Fe II emission is consistent with arising through scattering in galactic winds. Assuming a thin shell geometry for the outflowing gas, the estimated masses carried out by these outflows are large (approx 30-50 M/yr), with mass loading factors several times the star formation rate. Almost 20 per cent to 50 per cent of the blueshifted absorption probably escapes the gravitational potential of the galaxy. In this galaxy, the outflow is 'locally sourced', that is, the properties of the outflow in each line of sight are dominated by the properties of the nearest clump of star formation; the wind is not global to the galaxy. The mass outflow rates and the momentum flux carried out by outflows in individual star-forming knots of this object are comparable to that of starburst galaxies in the local Universe.

Bordoloi, Rongmon↗

NASA NTRS2002

Enzyme-based CO2 capture for advanced life support

Elevated CO2 levels in air can lead to impaired functioning and even death to humans. Control of CO2 is critical in confined spaces that have little physical or biological buffering capacity (e.g., spacecraft, submarines, or aircraft). A novel enzyme-based contained liquid membrane bioreactor was designed for CO2 capture and certain application cases are reported in this article. The results show that the liquid layer accounts for the major transport resistance. With addition of carbonic anhydrase, the transport resistance decreased by 71%. Volatile organic compounds of the type and concentration expected to be present in either the crew cabin or a plant growth chamber did not influence carbonic anhydrase activity or reactor operation during 1-day operation. Alternative sweep method studies, examined as a means of eliminating consumables, showed that the feed gas could be used successfully in a bypass mode when combined with medium vacuum pressure (-85 kPa) to achieve CO2 separation comparable to that with an inert sweep gas. The reactor exhibited a selectivity for CO2 versus N2 of 1400:1 and CO2 versus O2 is 866:1. The CO2 permeance was 1.44 x 10(-7) mol m-2 Pa-1 s-1 (4.3 x 10(-4) cm3 cm-2 s-1 cmHg-1) at a feed concentration of 0.1% CO2. These data show that the enzyme-based contained liquid membrane is a promising candidate technology that may be suitable for NASA applications to control CO2 in the crew or plant chambers.

NASA Discipline Life Support Systems↗

NASA NTRS2014

On Parametric Sensitivity of Reynolds-Averaged Navier-Stokes SST Turbulence Model: 2D Hypersonic Shock-Wave Boundary Layer Interactions

Examined is sensitivity of separation extent, wall pressure and heating to variation of primary input flow parameters, such as Mach and Reynolds numbers and shock strength, for 2D and Axisymmetric Hypersonic Shock Wave Turbulent Boundary Layer interactions obtained by Navier-Stokes methods using the SST turbulence model. Baseline parametric sensitivity response is provided in part by comparison with vetted experiments, and in part through updated correlations based on free interaction theory concepts. A recent database compilation of hypersonic 2D shock-wave/turbulent boundary layer experiments extensively used in a prior related uncertainty analysis provides the foundation for this updated correlation approach, as well as for more conventional validation. The primary CFD method for this work is DPLR, one of NASA's real-gas aerothermodynamic production RANS codes. Comparisons are also made with CFL3D, one of NASA's mature perfect-gas RANS codes. Deficiencies in predicted separation response of RANS/SST solutions to parametric variations of test conditions are summarized, along with recommendations as to future turbulence approach.

Hypersonic↗

NASA NTRS1997

Cluster Observations for Combined X-Ray and Sunyaev-Zel'dovich Estimates of Peculiar Velocities and Distances

Measurements of the peculiar velocities of galaxy clusters with respect to the Hubble flow allow the determination of the gravitational field from all matter in the universe, not just the visible component. The Sunyaev-Zel'dovich (SZ) effect (the inverse-Compton scattering of cosmic microwave background photons by the hot gas in clusters of galaxies) allows these velocities to be measured without the use of empirical distance indicators. Additionally, because the magnitude of the SZ effect is independent of redshift, the technique can be used to measure velocities out to the epoch of cluster formation. The SZ technique requires a determination of the temperature of the hot cluster gas from X-ray observations, and measurements of the SZ effect at millimeter wavelengths to separate the contribution from the thermal motions within the gas from that of the cluster peculiax velocity. We have constructed a bolometric receiver, the Sunyaev-Zel'dovich Infrared Experiment, specifically to make measurements of the SZ effect at millimeter wavelengths in order to apply the SZ technique to peculiar velocity measurements. This receiver has already been used to set limits to the peculiar velocities of two galaxy clusters at z approx. 0.2. As a test of the SZ technique, the double cluster pair Abell 222 and 223 was selected for observation. Measurements of the redshifts of the two components suggest that, if the clusters are gravitationally bound, they should exhibit a relative velocity of 10OO km/ s, well above the expected precision of 200 km/ s (set by astrophysical confusion) that is expected from the SZ method. The temperature can be measured from ASCA data which we obtained for this cluster pair. However, in order to ensure that the temperature estimate from the ASCA data was not dominated by cooling flows within the cluster, we requested ROSAT HRI observations of this cluster pair. Analysis of the X-ray properties of the cluster pair is continuing by combining the ROSAT observations funded under this proposal, archival PSPC data and our own PI ASCA data. The imaging data shows that neither cluster has a strong cooling flow, although A223 is the more compact of the two components. A223 also has a sub-cluster projected 1 Mpc to the North. The observed properties of this cluster pair are strikingly similar to those of the well-studied pair of A399 and A401 which are widely believed to be interacting and are in the initial stages of merging. This strengthens our selection of this cluster pair as a test for cluster peculiar motions. Combining these X-ray observations with SUZIE measurements of the SZ effect will provide important constraints on cluster merger models. This part of the program has been heavily delayed by bad weather at Mauna Kea, however SZ observations were obtained in November 1997 as part of a separately funded effort. These data are currently being analyzed.

Lange, A. E.↗

NASA NTRS2000

Microreactor System Design for a NASA In Situ Propellant Production Plant on Mars

The NASA In Situ Resource Utilization (ISRU) program is planning near-term missions to Mars that will include chemical processes for converting the carbon dioxide (CO2) and possibly water from the Martian environment to propellants, oxygen, and other useful chemicals. The use of indigenous resources reduces the size and weight of the payloads from Earth significantly, representing enormous cost savings that make human exploration of Mars affordable. Extraterrestrial chemical processing plants will need to be compact, lightweight, highly efficient under reduced gravity, and extraordinarily reliable for long periods. Microchemical and thermal systems represent capability for dramatic reduction in size and weight, while offering high reliability through massive parallelization. In situ propellant production (ISPP), one aspect of the ISRU program, involves collecting and pressurizing atmospheric CO2, conversion reactions, chemical separations, heat exchangers, and cryogenic storage. A preliminary system design of an ISPP plant based on microtechnology has demonstrated significant size, weight, and energy efficiency gains over the current NASA baseline. Energy management is a strong driver for Mars-based processes, not only because energy is a scarce resource, but because heat rejection is problematic; the low pressure environment makes convective heat transfer ineffective. Energy efficiency gains are largely achieved in the microchemical plant through extensive heat recuperation and energy cascading, which has a small size and weight penalty because the added micro heat exchangers are small. This leads to additional size and weight gains by reducing the required area of waste heat radiators. The microtechnology-based ISPP plant is described in detail, including aspects of pinch analysis for optimizing the heat exchanger network. Three options for thermochemical compression Of CO2 from the Martian atmosphere, adsorption, absorption, and cryogenic freezing, are presented, as well as three options for water decomposition, low temperature electrolysis, high temperature electrolysis, and thermochemical decomposition. Other elements of the plant include Sabatier and reverse water gas shift reactors, water recovery, chemical separations, and cryogenic storage. Data are presented supporting preliminary sizing of components, and results of the system design are compared to the existing NASA baseline that is based on conventional technologies.

TeGrotenhuis, W. E.↗

NASA NTRS1987

Rare gas analysis of size fractions from the Fayetteville meteorite

Eight size separates of grains from the Fayetteville meteorite ranging from less than 20 microns to greater than 1 millimeter are being analyzed for their rare gas elemental and isotopic composition. Measurements on five samples were performed. All five reveal a mixture of solar, planetary, cosmic ray produced and radiogenic gases. The solar component is of particular interest since it suggest that the meteorite may represent a fragment of an ancient protoplanetary regolith which was exposed to the solar wind. Solar wind elements are implanted in the outer few hundred Angstroms of exposed grains and are therefore expected to be surface correlated. At present the data do not suggest that such a correlation exists, but the final conclusion must await further analyses and data reduction.

Jordan, Jim L.↗

NASA NTRS1978

Experimental Studies of the Formation/Deposition of Sodium Sulfate in/from Combustion Gases

Processes related to the hot corrosion of gas turbine components were examined in two separate investigations. Monochromatic laser light was used to probe condensation onset and condensate film growth (via interference of reflected light) on electrically heated ribbons immersed in seeded, flat flame combustion product gases. Boron trichloride is used as the seed gas in these preliminary experiments conducted to obtain precise measurements of the dew point/deposition rates. Because of the importance of gaseous Na(g) as a precursor to NaSO4 formation, the kinetics and mechanisms of the heterogeneous reaction H(g) + NaCl(s) yields Na(g) + HCl(g) was studied using atomic absorption spectroscopy combined with microwave discharge-vacuum flow reactor techniques at moderate temperatures. Preliminary results indicate the H-atom attack of solid NaCl vaporization is negligible; hence the corresponding gas phase (homogeneous) reaction no role in the observed Na(g) production.

Rosner, D. E.↗

NASA NTRS1989

Hybrid plume plasma rocket

A technique for producing thrust by generating a hybrid plume plasma exhaust is disclosed. A plasma flow is generated and introduced into a nozzle which features one or more inlets positioned to direct a flow of neutral gas about the interior of the nozzle. When such a neutral gas flow is combined with the plasma flow within the nozzle, a hybrid plume is constructed including a flow of hot plasma along the center of the nozzle surrounded by a generally annular flow of neutral gas, with an annular transition region between the pure plasma and the neutral gas. The temperature of the outer gas layer is below that of the pure plasma and generally separates the pure plasma from the interior surfaces of the nozzle. The neutral gas flow both insulates the nozzle wall from the high temperatures of the plasma flow and adds to the mass flow rate of the hybrid exhaust. The rate of flow of neutral gas into the interior of the nozzle may be selectively adjusted to control the thrust and specific impulse of the device.

Franklin R Clung↗