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At least 397 records · Page 22

Ultraviolet-gas phase and -photocatalytic synthesis from CO and NH3

Ammonium cyanate is identified as the major product of the photolysis of gaseous NH3-CO mixtures at 206.2 or 184.9 nm. Lesser amounts of urea, biurea, biuret semicarbazide, formamide and cyanide are observed. A series of 18 reactions underlying the formation of photolysis products is presented and discussed. Photocatalytic syntheses of C-14-urea, -formamide, and -formaldehyde are carried out through irradiation of (C-14)O and NH3 in the presence of Vycor, silica gel, or volcanic ash shale surfaces. The possible contributions of the relevant reactions to the abiotic synthesis of organic nitrogen compounds on Mars, the primitive earth, and in interstellar space are examined.

Hubbard, J. S.↗

Effect of premixing quality on oxides of nitrogen in gas turbine combustors foi HC

Experiments were conducted to determine the effectiveness of several premixing prevaporizing gas turbine combustor designs in reducing formation of oxides of nitrogen at the supersonic cruise condition. An atomized spray from a single injector mounted on the axis of the mixer tube produced a high initial concentration of fuel near the axis and only moderate premixed conditions entering the combustor. A fuel spray produced by 12 flush-mounted normal injection orifices in the mixer tube wall produced a good initial despersion of fuel and resulted in nearly complete premixing. Oxides of nitrogen emission levels of the order of 0.2 g NO2/kg fuel were obtained at 99 percent combustion efficiency at an equivalence ratio of 0.4. Overall total pressure drop was less than 3 percent through the 1-meter combustor module.

Roffe, G.↗

Experimental investigation of wall shock cancellation and reduction of wall interference in transonic testing

A series of experiments were performed to evaluate the effectiveness of a three-dimensional land and groove wall geometry and a variable permeability distribution to reduce the interference produced by the porous walls of a supercritical transonic test section. The three-dimensional wall geometry was found to diffuse the pressure perturbations caused by small local mismatches in wall porosity permitting the use of a relatively coarse wall porosity control to reduce or eliminate wall interference effects. The wall porosity distribution required was found to be a sensitive function of Mach number requiring that the Mach number repeatability characteristics of the test apparatus be quite good. The effectiveness of a variable porosity wall is greatest in the upstream region of the test section where the pressure differences across the wall are largest. An effective variable porosity wall in the down stream region of the test section requires the use of a slightly convergent test section geometry.

Ferri, A.↗

An Atlas of extraterrestrial particles collected with NASA U-2 aircraft, 1974 - 1976

Extraterrestrial particles collected during U-2 flights in the stratosphere were divided into four groups: chondritic, iron-sulfur--nickel, mafic silicates, and others. The chondritic aggregates are typically composed of Fe, Mg, Si, C, S, Ca, and Ni. Detectable levels of He-4 implanted from the solar wind occur in some. Olivine, spinel, and possibly pyrrhotite and a hydrated layered-lattice silicate were identified. The chondritic ablation particles contain no sulfur and appear to have been melted. Magnetite, olivine, and pyroxene were identified. The iron-sulfur-nickel type particles resemble meteoritic iron sulfide with a small amount of nickel, and contain magnetite and troilite. The mafic silicate type particles are iron magnesium silicate grains with clumps of chondritic aggregate particles adhering to their surfaces. Olivine and possibly pyrrhotite and pyroxene were identified. Most of the iron-nickel type particles are spherules and include taenite and wustite. The other type particles include nickel-iron mounds on spheroidal glassy-like grains having chondritic-like elemental abundances.

Brownlee, D. E.↗

Photosynthesis of organic compounds in the atmosphere of Jupiter

An efficient conversion of CH4 to hydrocarbons and HCN takes place when NH3 is photolysed in the presence of CH4, H2, and He using a 184.9 nm light source. The extent of NH3 decomposition after a 1 hr exposure was determined spectrophotometrically; CH4, N2, and C2 and C3 hydrocarbons were detected and analyzed by mass spectrometry. Photolysis of one molar equivalent of NH3 results in the loss of 0.84 molar equivalent of CH4, which apparently reacts with hot hydrogen atoms produced by photolysis. The 8% of the NH3 which is not converted to N2 probably is converted to organic amines and nitrile derivatives. The results indicate that NH3 photolysis is a highly probable mechanism for the conversion of methane to more complex hydrocarbons in the upper atmosphere of Jupiter, and predict the occurrence of HCN, NH2NH2, and higher hydrocarbons in the Jovian atmosphere above the NH3 clouds.

Ferris, J. P.↗

Stratospheric aluminum oxide

Balloons and U-2 aircraft were used to collect micrometer-sized stratospheric aerosols. It was discovered that for the past 6 years at least, aluminum oxide spheres have been the major stratospheric particulate in the size range from 3 to 8 micrometers. The most probable source of the spheres is the exhaust from solid-fuel rockets.

Brownlee, D. E.↗

Nonlinear sonic boom analysis including the asymmetric effects

A numerical program is developed which takes into account the nonlinear effects of high Mach number, the entropy change across the shock, the entropy and enthalpy variations in the atmospheric layer and the gravitational effect. The program differs from the existing ones by accounting for non-axisymmetric terms. The asymmetry can be caused by the geometry of the body, the lift and also the fact that the variations in the atmospheric layer are two-dimensional. Numerical results demonstrate that the influence of these asymmetric effects tends to lower the pressure signature.

Ferri, A.↗

Investigation of slot cooling at high subsonic speeds

The paper discusses the results of an experimental and numerical investigation of tangential slot injection film cooling with zero pressure gradients in subsonic boundary layers at freestream Mach numbers of 0.4, 0.6, and 0.8. The results are compared with the predictions obtained from a finite-difference boundary-layer program developed by NASA for slot injection into turbulent supersonic boundary layers. The two sets of results are found to compare favorably. The numerical results point to the existence of a unique relation between isothermal effectiveness and adiabatic effectiveness, thereby confirming the existence of similarity conditions for temperature and velocity profiles.

Ferri, A.↗

Goals for a future SST

The paper attempts to define a desirable and reachable goal for a second generation SST. Justifications for the need of an SST are considered as is the ecological impact of a second generation SST project. Required technology advances to reach the range of 6500 nautical miles are examined along with structural weight reduction and drag reduction. Possible performance improvements due to design modifications are discussed, and environmental problems are discussed in detail with emphasis on sonic booms.

Ferri, A.↗

Wind-tunnel investigation of a variable camber and twist wing

The longitudinal aerodynamic characteristics of a 35 deg swept, variable camber and twist semispan wing in the presence of a body were studied. The variable camber and twist were incorporated to allow a near optimum lift distribution over the wing for both the cruise condition and the high lift conditions for maneuverability. The wing incorporated movable leading-edge segments whose swept hinge lines provided maximum camber variations at the outboard leading edge and movable trailing-edge segments whose swept hinge lines provided maximum camber variations near the inboard trailing edge. The model was investigated at Mach numbers of 0.60, 0.80, and 0.90 through an angle-of-attack range from 0 deg to 10 deg or buffet onset.

Ferris, J. C.↗

Possibilities and goals for the future SST

An analysis and evaluation of the social value of the SST project are presented. It is emphasized that the means of civil mass transportation reaching the same range available to military decrease the tension among neighboring nations and reduce human fatigue. The present status of the SST in the United States, together with the future goals, are described.

Ferri, A.↗

Review of Problems in Application of Supersonic Combustion

The problem of air-breathing engines capable of flying at very high Mach numbers is described briefly. Possible performance of supersonic combustion ramjets is outlined briefly and the supersonic combustion process is described. Two mechanisms of combustion are outlined: one is supersonic combustion controlled by convection process, and the second is controlled by diffusion. The parameters related to the combustion process are discussed in detail. Data and analyses of reaction rates and mixing phenomena are represented; the flame mechanism is discussed, and experimental results are presented.

Antonio Ferri↗

Effects of lengthwise lift distribution on sonic boom of SST configurations

Sonic Boom signatures produced by possible SST configurations during cruise were investigated. It is shown that optimization based on a far field analysis is not necessarily the optimum for these conditions. For an airplane length of 300 ft, near-field effects can be obtained when sufficient lift is generated near the nose of the airplane. Because of the near-field effects, sonic booms with maximum overpressures of the order of 1 lb/square foot can be obtained with possible airplane configurations having the same flight conditions at cruise.

Ferri, A.↗

Practical aspects of sonic boom problems

SST configurations selected from the point of minimizing sonic booms are investigated. It is indicated that for a total length of 300 ft and total initial weight of the same order as the present U.S. SST designs, sonic booms having shock pressure rise of the order of 0.6 lb/square foot can be obtained. Values as low as 0.3 are possible for airplanes designed for cross-country flights.

Ferri, A.↗

Sonic boom analysis for high-altitude flight at high Mach number

Numerical programs for the computation of the flow field from the airplane at the flight altitude to the ground are presented. They take into account the nonlinear effects of high Mach number, the entropy change across the shock, the entropy and enthalpy variations in the atmospheric layer, and the gravitational effect. Extension of the programs for the axisymmetric problems to handle nonaxisymmetric terms is described. The asymmetry can be caused by the geometry of the body and the lift, and also by the fact that the variations in the atmospheric layer are two-dimensional. Numerical results for ground level signatures of several configurations at various flight conditions are presented and compared with existing approximate theories to demonstrate the influences of these nonlinear effects.

Ferri, A.↗

The jet engine design that can drastically reduce oxides of nitrogen

The NOx pollution problem of hydrogen fueled turbojets and supersonic combustion ramjets (scramjets) was investigated to determine means of substantially alleviating the problem. Since the NOx reaction rates are much slower than the energy producing reactions, the NOx production depends mainly on the maximum local temperatures in the combustor and the NOx concentration is far from equilibrium at the end of a typical combustor (L approximately 1 ft). In diffusion flames, as used in present turbojets and scramjets combustor designs, the maximum local temperature occurs at the flame and is equal to the stoichiometric value. Whereas, in the heat conduction flames, wherein the flame propagates due to a heat conduction process away from the flame to the cooler oncoming premixed unburnt gases, the maximum temperature is lower than in the diffusion flame. Hence the corresponding pollution index is also lower.

Ferri, A.↗

The problem of pollution for the SST

A qualitative review of the possible effects of the exhaust gases discharged by a large fleet of SST's in the upper atmosphere is given. The review indicates the importance of the NO production in the exhaust gases. The mechanism of NO formation by the combustion process is described. A method for reduction of the NO formation is presented.

Ferri, A.↗