Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “FLUORIDES”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

Biogeochemistry of fluoride in a plant-solution system

Fluoride (F-) pollutants can harm plants and the animals feeding on them. However, it is largely unknown how complexing and chelating agents affect F bioavailability. Two studies were conducted that measured F- bioavailability and uptake by rice (Oryza sativa L.). In the first study, rice was grown in solution culture (pH 5.0) with 0, 2, or 4 mM F- as KF to compare the interaction of F- with humic acid (HA) and with a conventional chelating agent, N-hydroxyethylenthylenediaminetriacetic acid (HEDTA). In the second study, F was supplied at 0, 0.5, 1.0, and 2.0 mM KF with an additional 2 mM F- treatment containing solution Ca at 2x (2 mM Ca) the level used in the first study, to test the effect added Ca had on F- availability and uptake. Total biomass was greatest with HEDTA and F- < 1 mM. Leaf and stem F concentrations increased exponentially as solution F- increased linearly, with nearly no F partitioning into the seed. Results suggest that F was taken up as HF0 while F- uptake was likely restricted. Additionally, F- competed with HA for Ca, thus preventing the formation of Ca-HA flocculents. The addition of soluble Ca resulted in the precipitation of CaF2 solids on the root surface, as determined by tissue analysis and energy dispersive X-ray spectroscopy.

NASA Discipline Life Support Systems↗
DOE OSTI2013

Neutronics and Depletion Methods for Parametric Studies of Fluoride Salt Cooled High Temperature Reactors with Slab Fuel Geometry and Multi-Batch Fuel Management Schemes

The Advanced High-Temperature Reactor (AHTR) is a 3400 MWth fluoride-salt-cooled high-temperature reactor (FHR) that uses TRISO particle fuel compacted into slabs rather than spherical or cylindrical fuel compacts. Simplified methods are required for parametric design studies such that analyzing the entire feasible design space for an AHTR is tractable. These simplifications include fuel homogenization techniques to increase the speed of neutron transport calculations in depletion analysis and equilibrium depletion analysis methods to analyze systems with multi-batch fuel management schemes. This paper presents three elements of significant novelty. First, the Reactivity-Equivalent Physical Transformation (RPT) methodology usually applied in systems with coated-particle fuel in cylindrical and spherical geometries has been extended to slab geometries. Secondly, based on this newly developed RPT method for slab geometries, a methodology that uses Monte Carlo depletion approaches was further developed to search for the maximum discharge burnup in a multi-batch system by iteratively estimating the beginning of equilibrium cycle (BOEC) composition and sampling different discharge burnups. This Iterative Equilibrium Depletion Search (IEDS) method fully defines an equilibrium fuel cycle (keff, power, flux, and composition evolutions) but is computationally demanding, although feasible on single-processor workstations. Finally, an analytical method, the Non-Linear Reactivity Model, was developed by expanding the linear reactivity model to include an arbitrary number of higher order terms so that single-batch depletion results could be extrapolated to estimate the maximum discharge burnup and BOEC keff in systems with multi-batch fuel management schemes. Results from this method were benchmarked against equilibrium depletion analysis results using the IEDS.

fluoride-salt-cooled high-temperature reactor (FHR↗
DOE OSTI2012

Preliminary requirements for a Fluoride Salt-Cooled High-Temperature Test Reactor (FHTR)

A Fluoride Salt-Cooled High-Temperature Test Reactor (FHTR) design is being developed at MIT to provide the first demonstration and test of a salt-cooled reactor using high-temperature fuel. The first step is to define the requirements. The top level requirements are (1) provide the confidence that a larger demonstration reactor is warranted and (2) develop the necessary data for a larger-scale reactor. Because requirements will drive the design of the FHTR, a significant effort is being undertaken to define requirements and understand the tradeoffs that will be required for a practical design. The preliminary requirements include specifications for design parameters and necessary tests of major reactor systems. Testing requirements include demonstration of components, systems, and procedures for refueling, instrumentation, salt temperature control to avoid coolant freezing, salt chemistry and volume control, tritium monitoring and control, and in-service inspection. Safety tests include thermal hydraulics, neutronics - including intrinsic core shutdown mechanisms such as Doppler feedback - and decay heat removal systems. Materials and coolant testing includes fuels (including mechanical wear and fatigue) and system corrosion behavior. Preliminary analysis indicates a thermal power output below 30 MW, an initial core using pebble-bed or prismatic-block fuel, peak outlet temperatures of at least 700 deg. C, and use of FLi{sup 7}Be ({sup 7}LiF-BeF{sub 2}) coolant. The option to change-out the reactor core, fuel type, and major components is being investigated. While the FHTR will be used for materials testing, its primary mission is as a reactor system performance test to enable the design and licensing of a FHR demonstration power reactor. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2016

Thermal-Hydraulic design of a Fluoride High-Temperature Demonstration Reactor

The Fluoride salt-cooled High-temperature Reactor (FHR) 'Demonstration Reactor' (DR) is a novel reactor concept using molten salt coolant and tri-structural isotropic (TRISO) fuel that is being investigated at Oak Ridge National Laboratory (ORNL). The objective of the FHR DR is to advance the technology readiness level of FHRs. The FHR DR will demonstrate the technologies needed to close remaining gaps to commercial viability. The FHR DR will have a thermal power of 100 MWt, very similar to the Small modular Advanced High Temperature Reactor (SmAHTR), another FHR ORNL concept with a power of 125 MWt. The FHR DR shares features with the ORNL Advanced High Temperature Reactor (AHTR), which has a power of 3400 MWt and is cooled by a molten salt. The FHR DR combines three existing technologies: (1) high-temperature, low-pressure molten salt coolant, (2) high-temperature coated particle TRISO fuel, and (3) passive decay heat cooling systems using direct reactor auxiliary cooling systems (DRACS). This paper presents FHR DR thermal-hydraulic design calculations. The FHR DR design concept is being investigated by ORNL. Thermal-hydraulic calculations performed with the codes COMSOL and RELAP5-3D were used to determine the potential thermal and hydraulic characteristics of the concept. These results show that the FHR DR should be able to demonstrate the efficacy of the passive decay heat removal using DRACS, which is a key safety feature in a number of proposed FHR designs. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2016

MIT reactor (MITR) driven subcritical facility for the fluoride-salt-cooled high-temperature reactor (FHR) - 18623

The Fluoride-salt-cooled High temperature Reactor (FHR) uses clean salt coolants, carbon-matrix coated-particle fuel similar to that used in High-temperature Gas-cooled Reactors (HTGRs) and can be coupled to a Nuclear Air-Brayton Combined Cycle (NACC). Recent assessments indicate favorable economics and safety characteristics, but no FHR has been built. The question is what experimental facilities should be constructed to reduce technical uncertainties before a decision to build a test/demonstration reactor? The MIT Reactor (MITR) design and license would allow the construction and operation of a subcritical facility with 700 deg. C salt circulating through multiple full-width partial-height fuel assemblies operating with a power density up to 30% of a commercial FHR. This option would allow hot systems testing as a major step toward building the test/demonstration reactor. Preliminary system design, power control options, testing capabilities, and key nuclear characteristics of such a reactor-driven subcritical facility are described. A method of deriving subcritical multiplicity using surface source has been proposed and verified in this study. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2016

Tritium Release Limit for Fluoride Salt-cooled High-temperature Reactors

Tritium generation is potentially a significant issue in Fluoride salt-cooled High-temperature Reactors (FHRs). Tritium in its molecular form, T{sub 2}, is highly permeable through reactor structure materials, especially under high temperatures. Since tritium presents a potential health hazard, its release must be controlled and mitigated. However, tritium release limit for FHRs is not specified in the current radiation protection regulations since FHRs are still being developed. This study first reviews related radiation protection regulations and literature before proposing a potential limit value of the tritium release rate for FHRs. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2016

Phenomena Identification and Ranking Table (PIRT) for Fluoride High-Temperature Reactor (FHR) Neutronics

The deployment of Fluoride (salt-cooled) High Temperature Reactors (FHRs) has many potential benefits such as improved safety, improved economics, and a diversification of the energy portfolio because of its capability to supply industrial process heat. However, significant challenges remain before this class of reactors can be deployed, mostly related to its technology readiness. A recent study identified several areas in need of further development in order to advance the technology. These include the verification and validation of neutronics and thermal hydraulics modeling and simulation tools in support of design, safety analysis and licensing. The focus of this paper is to summarize the issues for verification and validation of neutronics tools. Current tools for neutronics analysis of LWRs are inadequate for the simulation of salt cooled reactors. The methodologies developed for the high temperature gas cooled reactors (HTGRs) have some relevance for FHRs because of the similarities between the two reactors such as graphite block structure, encapsulated fuel particles, and high operating temperatures. However, they are not sufficient for the accuracy desired of a code for licensing as they have a number of important differences neutronically, such as the use of liquid salt containing beryllium as a coolant and their unique fuel configuration. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2016

Neutronics Code Benchmark for Fluoride-Salt-Cooled Reactors

The fluoride-salt-cooled high-temperature reactor (FHR) is an advanced reactor design that aims to improve on the efficiency, cost, safety and non-proliferation security of nuclear energy, while exploiting existing technologies to minimize the design and licensing burden. FHRs share many design features with the high-temperature gas-cooled reactor (HTGR), namely using the same fuel form: a bed of graphite spheres, each with thousands of small coated fuel particles (TRISO) dispersed throughout it. However, rather than using a gas as a coolant, the FHR uses a molten salt which changes the behavior of the system; in particular, from a neutronics perspective, the coolant is no longer effectively transparent to neutrons, but rather contributes both to neutron moderation and absorption. It is difficult to perform exploratory reactor physics experiments for new reactor concepts, as the regulation and cost surrounding a fuel experiment is often highly restrictive and prohibitive. As such, researchers and design engineers must rely heavily on simulation capability to develop a working knowledge for how the reactor physics of a pre-prototypical reactor might behave. It is then essential to have confidence that simulation codes provide credible results. As there are no instances of FHRs deployed to date, nor are there any experimental data available on neutron behavior of pebble fuel immersed in salt, the first step is to perform a code-to-code verification of idealized scenarios that capture the physics involved with an FHR system. This summary describes the development of a code-to-code benchmark for FHR with the purpose of code verification and presents preliminary results. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2016

Commercial-scale, fluoride-salt-cooled, high-temperature reactors with novel refueling and decay heat removal capabilities

The fluoride-salt-cooled high-temperature reactor (FHR) is a new solid-fuel, graphite-moderated reactor concept. Recent work has developed test and demonstration-scale FHR designs. From this work, a new 'fuel-inside-radial-moderator' (FIRM) assembly concept has emerged that offers several important advantages, from neutron economy to refueling. In this work we discuss the potential benefits and challenges associated with designing a commercial-scale, FIRM-based FHR. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2016

Preliminary neutronic assessment of a novel fluoride-salt-cooled high-temperature reactor design

The Fluoride-Salt-Cooled High-Temperature Reactor (FHR) is a molten salt cooled, graphite moderated high temperature reactor. In this work, single-batch cycle length, block power distributions, and temperature-related reactivity effects were assessed using the SCALE code suite. Two types of parametric studies were performed. The first consisted of fixed temperature (isothermal) cases in which to determine the relationship between operation power and cycle length as well as pin power distributions. This second study calculates various isothermal reactivity coefficients based on heterogeneous temperature distributions. Reactivity coefficients with respect to the temperature of the fuel, coolant, and moderator were performed separately to determine their individual contributions. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗