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At least 397 records · Page 22

Evaporation dominates evapotranspiration on Alaska’s Arctic Coastal Plain

The dynamics of evapotranspiration (ET), such as the partitioning to evaporation and transpiration, of polygonal ground on the Arctic Coastal Plain are not well understood. We assessed ET dynamics, including evaporation and transpiration partitioning, created by microtopographic features associated with high- and low-centered polygons. Chamber ET and leaf-level transpiration measurements were conducted in one-week field campaigns in two growing seasons with contrasting weather conditions. We found that ET was greater in the drier and warmer sampling period (2013) compared to the colder and wetter one (2014). Evaporation dominated ET, particularly in the wetter and colder sampling period (>90% in 2014 vs. 80% in 2013). In the 2013 sampling period, wetter and warmer conditions increased ET and the contribution of transpiration to ET. If the soils warm with degrading permafrost, ET and the fraction contributed by transpiration may increase to a certain threshold, when moisture must increase with rising temperatures to further increase these fluxes. While the fraction of transpiration may rise with warmer soils, it is unlikely that transpiration will completely dominate ET. This work highlights the complexities of understanding ET in this dynamic environment and the importance of understanding differences across polygonal ground.

58 GEOSCIENCES↗

Melanopogenesis: dark matter of (almost) any mass and baryonic matter from the evaporation of primordial black holes weighing a ton (or less)

The evaporation of primordial black holes with a mass in the 1 gram≲ MPBH≲1000 kg range can lead to the production of dark matter particles of almost any mass in the range 0.1 MeV≲ m DM ≲ 10 18 GeV with the right relic density at very early times, τ≲ 10 -10 s. We calculate, as a function of the primordial black holes mass and initial abundance, the combination of dark matter particle masses and number of effective dark degrees of freedom leading to the right abundance of dark matter today, whether or not evaporation stops around the Planck scale. In addition, since black hole evaporation can also lead to the production of a baryon asymmetry, we calculate where dark matter production and baryogenesis can concurrently happen, under a variety of assumptions: baryogenesis via grand unification boson decay, via leptogenesis, or via asymmetric co-genesis of dark matter and ordinary matter. Finally, we comment on possible ways to test this scenario.

79 ASTRONOMY AND ASTROPHYSICS↗

Prospects for the observation of Primordial Black Hole evaporation with the Southern Wide field of view Gamma-ray Observatory

We report primordial Black Holes (PBHs) are remnants of objects formed in the early Universe. Their lifetime is an increasing function of their mass, so PBHs in the right mass range can end their lives in an evaporation event that is potentially detectable by our instruments now. This evaporation may result in a γ-ray flash that can be detected by the current generation of Very-High-Energy γ-ray detectors. The Southern Wide field of view Gamma-ray Observatory (SWGO) will be part of the next generation of these instruments. It will be able to establish limits on PBH evaporations for integration windows between 0.5 and 5 s, in a radius of 0.25 pc around the Earth, being sensitive to a rate of the order of ~50 pc -3 yr -1 , more than one order of magnitude more constraining than the currently established best limits.

79 ASTRONOMY AND ASTROPHYSICS↗

Gravitational waves from primordial black hole evaporation with large extra dimensions

Abstract The spectra of gravitational waves from black hole evaporation generically peak at frequencies of order the Hawking temperature, making this signal ultra-high frequency for primordial black holes evaporating in the early universe. This motivates us to consider small black holes in theories with large extra dimensions, for which the peak frequency can be lowered substantially, since the true bulk Planck scaleM * can be much smaller than the effectiveM Pl . We study the emission of brane-localized gravitons during the Hawking evaporation of ultra-light primordial black holes in the context of theories with large extra dimensions, with the ultimate goal of computing the contribution to the stochastic gravitational wave background. To accurately model black hole evolution, we compute greybody factors for particles of spin-0, 1/2, 1, and 2 emitted on the brane and in the bulk, presuming the majority of emission proceeds during the Schwarzschild phase. We then compute the power spectrum and present day spectral density parameter for brane-localized gravitons contributing to a gravitational wave signal. We find that for an optimal choice of parameters, the peak frequency plateaus in the sub-MHz regime, within range of planned high-frequency gravitational wave detectors, making this scenario a target for detection once their sensitivity exceeds ΔN eff bounds.

Astronomy & Astrophysics↗

Quarkonium production in an improved color evaporation model

In this paper, we propose an improved version of the color evaporation model to describe heavy quarkonium production. In contrast to the traditional color evaporation model, we impose the constraint that the invariant mass of the intermediate heavy quark-antiquark pair be larger than the mass of produced quarkonium. We also introduce a momentum shift between the heavy quark-antiquark pair and the quarkonium. Finally, numerical calculations show that our model can describe the charmonium yields as well as the ratio of ψ' over J/ψ better than the traditional color evaporation model.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

High Efficiency Evaporated CdSeTe/CdTe Solar Cells With and Without MgZnO Buffer Layer

High efficiencies of ~19% CdTe solar cell devices were made using a thermal evaporation technique to deposit absorber layers of CdSe and CdTe. The absorber films were very high quality for a device fabrication, and with demonstrated high efficiency, it is a viable option to employ thermal evaporation in research and manufacturing. We also investigated four different interfaces scenarios of with and without MZO and CdSe in the device near front interface. The results clearly indicate that Se plays a key role in improving device performance, but the MZO is not necessarily required unless experiment goals demanded. Removing the MZO layer from the device structure and being able to use thermal evaporator for CdTe deposition will help with cost reduction in manufacturing.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Tuning Superhydrophilic Nanostructured Surfaces to Maximize Water Droplet Evaporation Heat Transfer Performance

Spraying water droplets on air fin surfaces is often used to augment the performance of air-cooled Rankine power plant condensers and wet cooling tower heat exchangers for building air-conditioning systems. To get the best performance in such processes, the water droplets delivered to the surface should spread rapidly into an extensive, thin film and evaporate with no liquid leaving the surface due to recoil or splashing. This paper presents predictions of theoretical/computational modeling and results of experimental studies of droplet spreading on thin-layer, nanostructured, superhydrophilic surfaces that exhibit very high wicking rates (wickability) in the porous layer. Analysis of the experimental data in the model framework illuminates the key aspects of the physics of the droplet-spreading process and evaporation heat transfer. This analysis also predicts the dependence of droplet-spreading characteristics on the nanoporous surface morphology and other system parameters. The combined results of this investigation indicate specific key strategies for design and fabrication of surface coatings that will maximize the heat transfer performance for droplet evaporation on heat exchanger surfaces. The implications regarding wickability effects on pool boiling processes are also discussed.

Engineering↗

Experimental search for evaporating primordial black holes

Primordial black holes (PBHs) are black holes which may form in the early Universe through the gravitational collapse of primordial cosmological density fluctuations. Due to Hawking radiation these PBHs are supposed to evaporate by emitting particles. Recent developments in the experimental searching for evaporating PBHs in the local Universe are reviewed. The technique of searching for the gamma-ray bursts (GRBs) from evaporating PBHs on shower arrays is discussed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Nano-Structured Mesoporous Silica Wires with Intra-Wire Lamellae via Evaporation-Induced Self-Assembly in Space-Confined Channels

Evaporation-induced self-assembly (EISA) of silica sol-gel ethanol-water solution mixtures with block-copolymer were studied inside uniform micro/nano channels. Nano-structured mesoporous silica wires, with various intra-wire self-assembly structures including lamellae, were prepared via EISA process but in space-confined channels with the diameter ranging from 50 nm to 200 nm. Membranes made of anodized aluminum oxide (AAO) and track-etched polycarbonate (EPC) were utilized as the arrays of space-confined channels (i.e., 50, 100, and 200-nm EPC and 200-nm AAO) for infiltration and drying of mixture solutions; these substrate membranes were submerged in mixture solutions consisting of a silica precursor, a structure-directing agent, ethanol, and water. After the substrate channels were filled with the solution under vacuum impregnation, the membrane was removed from the solution and dried in air. The silica precursor used was tetra-ethyl othosilicate (TEOS), and the structure-directing agent employed was triblock copolymer Pluronic-123 (P123). It was found that the formation of the mesoporous nanostructures in silica wires within uniform channels were significantly affected by the synthesis conditions including (1) pre-assemble TEOS aging time, (2) the evaporation rate during the vacuum impregnation, and (3) the air-dry temperature. The obtained intra-wire structures, including 2D-hexagonal rods and lamellae, were studied by scanning transmission electron microscopy (STEM). A steric hindrance effect seems to explain well the observed polymer-silica mesophase formation tailored by TEOS aging time. The evaporation effect, air-drying effect, and AAO-vs-EPC substrate effect on the mesoporous structure of the formed silica wires were also presented and discussed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Deposition of Colloidal Particles during the Evaporation of Sessile Drops: Dilute Colloidal Dispersions

The deposition of colloidal silica particles during the evaporation of sessile drops on a smooth substrate has been modeled by the simultaneous solution of the Navier–Stokes equations, the convective-diffusive equation for particles, and the diffusion equation for evaporated vapor in the gas phase. Isothermal conditions were assumed. A mapping was created to show the conditions for various deposition patterns for very dilute suspensions. Based on values of the Peclet (Pe) number and Damkholer numbers (Da and Da −1 ), the effects of adsorption and desorption were discussed according to the map. Simulations were also done for suspensions with a high particle concentration to form a solid phase during the evaporation by using a packing criterion. The simulations predicted the height and width of the ring deposit near the contact line, and the results compared favorably to experimental particle deposition patterns.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effluent Management Facility Evaporator Bottom-Waste Streams Formulation and Waste Form Qualification Testing

This report describes the results from grout formulation and cementitious waste form qualification testing performed by Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions, LLC (WRPS). These results are part of a screening test that investigates three grout formulations proposed for wide-range treatment of different waste stream compositions expected for the Hanford Effluent Management Facility (EMF) evaporator bottom waste. This work supports the technical development need for alternative disposition paths for the EMF evaporator bottom wastes and future direct feed low-activity waste (DFLAW) operations at the Hanford Site. High-priority activities included simulant production, grout formulation, and cementitious waste form qualification testing. The work contained within this report relates to waste form development and testing, and does not directly support the 2017 Integrated Disposal Facility (IDF) performance assessment (PA). However, this work contains valuable information for use in PA maintenance past FY 2017 and future waste form development efforts. The provided results and data should be used by (1) cementitious waste form scientists to further the understanding of cementitious leach behavior of contaminants of concern (COCs), (2) decision makers interested in off-site waste form disposal, and (3) the U.S. Department of Energy, their Hanford Site contractors and stakeholders as they assess the IDF PA program at the Hanford Site. The results reported help fill existing data gaps, support final selection of a cementitious waste form for the EMF evaporator bottom waste, and improve the technical defensibility of long-term waste form risk estimates.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Effluent Management Facility Evaporator Bottoms: Waste Streams Formulation and Waste Form Qualification Testing

This report describes the results from grout formulation and cementitious waste form testing performed by Pacific Northwest National Laboratory for Washington River Protection Solutions, LLC (WRPS). These results are part of a screening test that investigates grout formulations proposed for encapsulating a wide range of compositions predicted to be present in evaporator bottoms wastes from the Hanford Effluent Management Facility (EMF). This work supports the technical development need for alternative treatment and disposition paths for the EMF evaporator bottoms waste and future direct-feed low-activity waste (DFLAW) operations at the Hanford Site. High-priority activities included simulant production, grout formulation, and cementitious waste form testing. The work contained within this report relates to waste form development and testing, but does not directly support the 2017 Integrated Disposal Facility (IDF) performance assessment (PA). However, this work contains information useful for future PA updates [beyond fiscal year (FY) 2017] and future waste form development efforts. These analytical results can be used by (i) cementitious waste form scientists to further the understanding of cementitious leach behavior of contaminants of concern (COCs), (ii) decision makers interested in off-site waste form disposal, and (iii) the U.S. Department of Energy, their Hanford Site contractors, and stakeholders as they continue to assess the IDF PA program at the Hanford Site. The reported results help fill existing data gaps, support final selection of a cementitious waste form for the EMF evaporator bottoms waste, and improve the technical defensibility of long-term waste form risk estimates.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Effluent Management Facility Evaporator Bottoms: Waste Streams Formulation and Waste Form Qualification Testing

This report describes the results from grout formulation and cementitious waste form testing performed by Pacific Northwest National Laboratory for Washington River Protection Solutions, LLC (WRPS). These results are part of a screening test that investigates grout formulations proposed for encapsulating a wide range of compositions predicted to be present in evaporator bottoms wastes from the Hanford Effluent Management Facility (EMF). This work supports the technical development need for alternative treatment and disposition paths for the EMF evaporator bottoms waste and future direct-feed low-activity waste (DFLAW) operations at the Hanford Site. High-priority activities included simulant production, grout formulation, and cementitious waste form testing. The work contained within this report relates to waste form development and testing, but does not directly support the 2017 Integrated Disposal Facility (IDF) performance assessment (PA). However, this work contains information useful for future PA updates [beyond fiscal year (FY) 2017] and future waste form development efforts. These analytical results can be used by (i) cementitious waste form scientists to further the understanding of cementitious leach behavior of contaminants of concern (COCs), (ii) decision makers interested in off-site waste form disposal, and (iii) the U.S. Department of Energy, their Hanford Site contractors, and stakeholders as they continue to assess the IDF PA program at the Hanford Site. The reported results help fill existing data gaps, support final selection of a cementitious waste form for the EMF evaporator bottoms waste, and improve the technical defensibility of long-term waste form risk estimates.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterization results for the 2020 tank farm 2H and 3H evaporator overhead samples

The 2020 annual 2H and 3H Evaporator overhead samples were received at Savannah River National Laboratory (SRNL) on December 22, 2020. The delivered samples were analyzed for concentration of cesium-137 ( 137 Cs), strontium-90 (90 Sr) and iodine-129 ( 129 I) to validate compliance with the Effluent Treatment Project Waste Acceptance Criteria (ETP WAC, Rev. 7). The concentration of all three radionuclides, 137 Cs, 90 Sr, and 129 I, in the 2H Evaporator overhead sample were found to be less than the corresponding ETP WAC limits. Radiochemical analysis of the 3H Evaporator overhead sample indicated a 137 Cs content about an order of magnitude higher than the acceptable threshold value, and 90 Sr and 129 I concentrations within the acceptance limits.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Full Technical Report: High-Rate Carbide Growth by Evaporation

Boron carbide (B 4 C) is an attractive inertial confined fusion (ICF) ablator and a unique ultra-hard material with numerous current and potential applications. What makes B 4 C attractive as an ablator is its relatively high density and the ability to form a stable glassy phase combined with excellent chemical and mechanical stability. Despite these advantages, the fabrication of B 4 C ablators has remained a challenge. Magnetron sputtering, our current frontrunner approach for B 4 C deposition, exhibits low deposition rates (< 2 μm/h) and undesirable nodular defects within the film structure that are believed to generate from the dusty plasma around the sputtering source. The goals of this project were to (1) establish alternative plasma-free, electron beam evaporation (EBE) capabilities for the deposition of thin films that are needed in mission-critical programs and; (2) demonstrate the feasibility to deposit B 4 C films at high rates by EBE in a bottom-up geometry and characterize their stoichiometry. In this feasibility study, we initially developed the capability to convert a general-use vacuum chamber into an electron beam evaporator as needed, or on demand. Then, we successfully used this setup to deposit films made of boron carbide and various other materials. By adjusting the deposition parameters and the evaporation source material, we were able to demonstrate the feasibility of reaching deposition rates as high as 8 μm/h, which is about 4 times the maximum rates obtained through sputtering methods. We predict that these values can still be further improved by implementing enhanced thermal control measures for the target source and optimizing electron beam parameters (ie. current, sweeping and frequency) since ceramic materials with similar densities to B 4 C can exhibit deposition rates of about twice this value. We anticipate that the skills and capabilities developed throughout this project will prove relevant not only to the HED and ICF campaigns but also to numerous existing and prospective applications focused on the development of ultra-hard carbide coatings. The fresh set of tools here developed will also facilitate the preparation and research on future new target materials of interest beyond B 4 C.

36 MATERIALS SCIENCE↗

Evaluation of Hanford Supernatant Waste Evaporation

• Hanford site in Washington has 27 underground “double-shell” storage tanks containing radioactive waste. Storage space is utilized to max capacity. • Construction of new tanks is undesirable, but volume reduction is still possible by vacuum evaporation of liquid waste. • Excess evaporation may create additional problems in solids precipitation, waste density and corrosivity. • Evaporation of liquid waste was simulated to determine possible outcomes.

Barkai, Benjamin [Savannah River National Laborato↗

The Evaporation and Survival of Cluster Galaxy Coronae. I. The Effectiveness of Isotropic Thermal Conduction Including Saturation

We simulate the evolution of cluster galaxy hot interstellar medium (ISM) gas that is a result of the effects of ram pressure and thermal conduction in the intracluster medium (ICM). At the density and temperature of the ICM, the mean free paths of ICM electrons are comparable to the sizes of galaxies, therefore electrons can efficiently transport heat that is due to thermal conduction from the hot ICM to the cooler ISM. Galaxies consisting of dark matter halos and hot gas coronae are embedded in an ICM-like “wind tunnel” in our simulations. In this paper, we assume that thermal conduction is isotropic and include the effects of saturation. We find that as heat is transferred from the ICM to the ISM, the cooler denser ISM expands and evaporates. This process is significantly faster than gas loss due to ram pressure stripping; for our standard model galaxy, the evaporation time is 160 Myr, while the ram pressure stripping timescale is 2.5 Gyr. Thermal conduction also suppresses the formation of shear instabilities, and there are no stripped ISM tails since the ISM evaporates before tails can form. Observations of long-lived X-ray emitting coronae and ram pressure stripped X-ray tails in galaxies in group and cluster environments therefore require that thermal conduction is suppressed or offset by some additional physical process. The most likely process is anisotropic thermal conduction that is due to magnetic fields in the ISM and ICM, which we simulate and study in the next paper in this series.

79 ASTRONOMY AND ASTROPHYSICS↗

Dynamics of canopy stomatal conductance, transpiration, and evaporation in a temperate deciduous forest, validated by carbonyl sulfide uptake

Abstract. Stomatal conductance influences both photosynthesis and transpiration, thereby coupling the carbon and water cycles and affecting surface–atmosphere energy exchange. The environmental response of stomatal conductance has been measured mainly on the leaf scale, and theoretical canopy models are relied on to upscale stomatal conductance for application in terrestrial ecosystem models and climate prediction. Here we estimate stomatal conductance and associated transpiration in a temperate deciduous forest directly on the canopy scale via two independent approaches: (i) from heat and water vapor exchange and (ii) from carbonyl sulfide (OCS) uptake. We use the eddy covariance method to measure the net ecosystem–atmosphere exchange of OCS, and we use a flux-gradient approach to separate canopy OCS uptake from soil OCS uptake. We find that the seasonal and diurnal patterns of canopy stomatal conductance obtained by the two approaches agree (to within ±6 % diurnally), validating both methods. Canopy stomatal conductance increases linearly with above-canopy light intensity (in contrast to the leaf scale, where stomatal conductance shows declining marginal increases) and otherwise depends only on the diffuse light fraction, the canopy-average leaf-to-air water vapor gradient, and the total leaf area. Based on stomatal conductance, we partition evapotranspiration (ET) and find that evaporation increases from 0 to 40 % of ET as the growing season progresses, driven primarily by rising soil temperature and secondarily by rainfall. Counterintuitively, evaporation peaks at the time of year when the soil is dry and the air is moist. Our method of ET partitioning avoids concerns about mismatched scales or measurement types because both ET and transpiration are derived from eddy covariance data. Neither of the two ecosystem models tested predicts the observed dynamics of evaporation or transpiration, indicating that ET partitioning such as that provided here is needed to further model development and improve our understanding of carbon and water cycling.

59 BASIC BIOLOGICAL SCIENCES↗