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At least 397 records · Page 22

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NASA NTRS2016

Performance of Silica Gel in the Role of Residual Air Drying. Part II.

Removal of carbon dioxide (CO2) is a necessary step in air revitalization and is often accomplished with sorbent materials. Since moisture competes with CO2 in zeolite sorbent materials, it is necessary to remove the water first. This is typically accomplished in two stages: “bulk” removal and “residual” drying. Silica gel is used as the bulk drying material in the Carbon Dioxide Removal Assembly (CDRA) in operation on the ISS (International Space Station). There has been some speculation that silica gel may also be capable of serving as both bulk and residual drying material to reduce system mass and Foreign Object Debris (FOD). Previous research tested silica gel alone as drying material. However, the silica gel volume used was not comparable to the current amount used on the CDRA. Therefore, the tests were repeated with the new silica gel volume. This paper discusses the fabrication and assembly of the modified canister to accommodate the new volume, the testing, and the evaluation of the test results.

Air Revitalization↗

NASA NTRS2019

Dynamics and Variability of the Spring Dry Season in the United States Southwest as Observed in AmeriFlux and NLDAS-2 Data

The spring dry season occurring in an arid region of the Southwest United States, which receives both winter storm track and summer monsoon precipitation, is investigated. Bimodal precipitation and vegetation growth provide an opportunity to assess multiple climate mechanisms and their impact on hydroclimate and ecosystems.We detect multiple shifts from wet to drier conditions in the observational record and land surface model output. Focusing on the recent dry period, a shift in the late 1990s resulted in earlier and greater spring soil moisture draw down, and later and reduced spring vegetation green-up, compared to a prior wet period (1979 - 1997). A simple soil moisture balance model shows this shift is driven by changes in winter precipitation.The recent post-1999 dry period, as well as an earlier one from 1948 - 1966, are both related to the cool tropics phase of Pacific decadal variability which influences winter precipitation. In agreement with other studies for the Southwest United States, we find the recent drought cannot be explained in terms of precipitation alone, but also is due to the rising influence of temperature, thus highlighting the sensitivity of this region to warming temperatures. Future changes in the spring dry season will therefore be affected by how tropical decadal variability evolves, and also by emerging trends due to human-driven warming.

Pascolini-Campbell, Madeleine↗

NASA NTRSDate not supplied

Efficacy of Dried Plum to Countermeasure Simulated Spaceflight Exposure

Human exploration of the space environment has been a topic of interest for decades; however, the threat to physiological health posed by ionizing radiation and microgravity effects remains a concern. Previous research utilizing combined hindlimb unloading and irradiation to simulate spaceflight effects found that a dried plum diet can mitigate adverse effects of simulated spaceflight on skeletal health. Though the mechanism is not fully understood we believe this protective effect is due to its high antioxidant capacity and polyphenolic content. This study seeks to extend these findings to investigate if dried plum is an effective countermeasure in other tissues relating to aging and neurotoxicity. Male C57BL/6 J mice were assigned to one of eight groups (n = 10/group) and were fed either a controlled diet or dried plum diet, underwent normal loading or hindlimb unloading as well as exposure 2 Gy gamma radiation or sham exposure. At the end of the experiment, mice were euthanized, and RNA was extracted from brain and bone marrow tissue and PCR was employed to analyze significant changes in gene expression profiles. Analysis of five house-keeping genes revealed genes B2M (neurotoxicity) and GUSB (aging) to be the most stable genes across all treatments and were used to find the fold change within our genes of interest. Through this, and analysis via ANOVA, we were able to identify genes with significant altered expression levels within brain and bone marrow tissues related to neurotoxicity and aging. Considering previous research, we hypothesize that the dried plum diet’s antioxidative properties ameliorated the oxidative stress from irradiation and microgravity via altered levels of gene expression. Identified expression changes will provide insights into molecular mechanisms behind the observed protective effects. These findings present potential avenues for future interventions to alleviate negative impacts of spaceflight on astronaut health.

Faisal Ahmad↗

NASA NTRSDate not supplied

The Efficacy of Dried Plum to Counter Spaceflight Microgravity and Radiation

Faisal Ahmad↗

NASA NTRSDate not supplied

Cleanroom Microbes Survive Drying, Vacuum, and Proton Irradiation

Introduction : The goal of planetary protection at NASA is to mitigate the risk of contaminating sensitive target bodies with biological life. While many cleaning procedures have been put in place to reduce bioburden on spacecraft, microbes are experts at evolving to survive harsh conditions. Specifically, the dry, low-nutrient environment of a cleanroom (commonly used for assembly of spacecraft) can represent an environment where extremophiles can survive. Methods : Scientists at NASA MSFC wished to gather a snapshot of the microbial population within a variety of cleanrooms on site. A study was undertaken to collect air, surface, and floor samples from clean-rooms and isolate unique morphologies. From this study, 95 isolates were collected and saved in a microbial library. About 86% of these were identified at least to a genus level. Following identification, 24 microbes were selected, based on a literature review, as potential extremophiles. These were grown in liquid cultures, diluted to a set optical density, washed with water, and then applied to a sterilized Kapton coupon. Droplets were allowed to dry overnight in a biosafety cabinet. Coupons were then installed in a pelletron and pumped down to high vacuum (~1E-6 Torr). Samples were then subjected 100 keV protons at a fluence of 2x10 15 p+/cm 2 up to 4x10 15 p+/cm 2 . Following exposure, samples were returned to the microbiology lab where they were pro-cessed by submerging in water, vortexing, and then plating either droplets or spread plates. Recovery data collected was qualitative with a ranking or +, minor, or – for growth. Some selected radiotolerant strains were sequenced using the Illumina sequencing platform. The resulting genomes were annotated with the Rapid Annotations using Subsystems Technology (RAST) server and analyzed for conserved and unique stress response relevant genomic signatures to identify clues related to specific tolerances. Results and Discussion : After five rounds of proton radiation, we narrowed our isolates to five, non-spore forming bacteria that demonstrated survival: Arthrobacter koreensis, Paenarthrobacter nitroguajacolicus, Mycetocola manganoxydans , and an Erwinia sp. Furthermore, we exposed these four microbes to 254 nm wavelength light at an intensity of 80 W/m 2 at a distance of ~18 cm for 10 minutes. Only A. koreensis demonstrated survival following UV exposure. Finally, we performed whole genome sequencing on the four strains to look for genetic markers of stress resistance. When we compared the genomes of the four strains, we found that genes coding for GGDEF and EAL domains with PAS/PAC sensors were only found in A. koreensis . These domains, modulated by PAS/PAC sensors, are hypothesized to facilitate survival under drying, desiccation, and proton irradiation. Drying and Desiccation : PAS domains sense hydration changes and modulate GGDEF and EAL domain activity to adjust c-di-GMP levels, enhancing resistance to desiccation. For instance, in Pseudomonas aeruginosa , the PAS domain of RbdA modulates activity under varying hydration conditions, affecting stress responses [1]. Proton Irradiation : Proton irradiation causes oxidative stress, leading to ROS generation. PAS domains detect this stress and modulate GGDEF and EAL domains to manage oxidative stress responses. In Shewanella , EAL domain proteins modulated by PAS sensors help bacteria adapt to extreme conditions [2]. These genes upregulate other stress response genes, protecting membrane function, protein stability, DNA repair, and antioxidant defenses. The modulation of c-di-GMP by PAS domains is crucial for bacterial adaptation to stress conditions, enabling dynamic physio-logical adjustments [3]. Understanding these mechanisms provides insights into bacterial stress responses and strategies for controlling bacterial growth [4]. Conclusions : These findings indicate that clean-rooms harbor extremophile microbes that may be able to survive conditions in deep space. Furthermore, while we identified certain stress-response genes that may be at least partly responsible for the phenotypes observed in this study, there are likely unidentified genes or characteristics about A. koreensis , and other bacteria, that may allow them to survive in harsh environments. Future studies will focus on identifying these unknown genes and characteristics, further elucidating the mechanisms of extremophile survival and potentially informing the development of new biotechnologies for space exploration and other extreme environments.

Chelsi Cassilly↗

DOE OSTI2017

Ultrasonic Clothes Dryer Dries Clothes in Half the Time

Scientists at Oak Ridge National Laboratory are about to change the way that you do laundry. They recently developed an ultrasonic drying concept that uses vibrations instead of heat to dry clothes. This technology is expected to be up to five times more efficient than today’s products and will dry your clothes in half the time. In about two years, researchers took this basic science concept and recently developed it into a full-scale press dryer and clothes dryer drum – setting the stage for it to one day go to market through partners like General Electric Appliances. The ultrasonic dryer, which is supported by the Department of Energy’s Building Technologies Office, is expected to cut drying time to about 20 minutes per load – down significantly from the average 50 minutes it currently takes Americans to do their laundry.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2025

Considerations for Thermal Annealing of Zr-Alloy Cladding During Dry Storage

In January 2025, the U.S. Department of Energy (DOE) sponsored a technical workshop with fuel vendors that provided a forum for increased collaboration on backend fuel cycle research. The workshop reviewed observations of thermal annealing of irradiated zirconium alloys in simulated dry storage conditions and discussed implications to the industry’s interest in reducing wet storage to optimize operational flexibility and the expected trend of increasing discharge burnup (and decay heats), which could lead to an increase in dry storage temperatures. One approach to accommodate increased decay heats in dry storage is to increase the regulatory temperature limit during dry storage, which is now 400°C. However, this could lead to thermal annealing of the cladding, which will tend to increase creep rates, creep strains, and ductility while decreasing yield strength. These considerations are compounded by bonding between the pellet and cladding at high burnup, which results in the pellet carrying more load during fuel rod deformations, especially in bending, which is the dominant deformation phenomenon in canister drop analyses. Because the U.S. Nuclear Regulatory Commission (NRC) recommends yield strength as a primary failure criterion for accident analyses in storage and transportation, particularly for canister drop scenarios, the purpose of the workshop was to develop options for alternative failure criterion that could replace yield strength in canister drop analyses. Topics discussed were (1) the regulatory framework, (2) the effect of thermal annealing on microhardness and tensile properties of cladding materials, (3) the effect of thermal annealing on fuel rod failure during bending, bending fatigue, and pinch loading, and (4) an alternative failure criterion for canister drop analyses. This paper provides a summary of the key discussions and outcomes of the workshop

Cantonwine, Paul [ORNL] (ORCID:0009000522247033)↗

DOE OSTI2019

Dry cask radiation shielding validation and estimation of cask surface dose rate with MAVRIC during long-term storage

The dry storage cask became a semi-permanent solution for spent nuclear fuel since no permanent solution has been finalized over the past three decades. Considering the difficulty of deep geological repository projects in many aspects, prolonging the service life of dry casks longer than a few decades has become an option for spent nuclear fuel storage. It must be ensured that dry cask safety objectives, including radiation shielding, criticality safety, structure health, decay heat removal, and containment be fulfilled during the prolonged service life. This paper presents numerical modeling results of the radiation dose rate distribution on a TN-32 cask surface aged up to 300 years. The numerical modeling method was validated with measurement data, and the difference between the calculated results and measurement data in the total dose rate is 7%. The detailed radiation distribution variations over cask surfaces along the axial and radial directions for 300 years of storage were obtained, and their azimuthal angular dependence was established. The maximum total dose rate over the cask surfaces is less than 10 mrem/hour (9.258 ± 0.212 mrem/hour) after 40 years, and this outcome fulfills all dose rate requirements from 10 CFR 71.47(b). After 300 years of storage, the average total dose rates on the side surface and top surface are 0.150 ± 0.007mremmrem/hour and 0.057 ± 0.003mremmrem/hour, respectively, while the maxima are 0.601 ± 0.014 mrem/hour and 0.112 ± 0.006 mrem/hour, respectively. The variations in the fuel gamma ray, structure gamma ray, neutron and secondary gamma-ray contributions to the total dose rate are presented and analyzed in this work. The neutron and gamma-ray dose rate contributions by energy group are presented and analyzed at the cask top, mid-plane, and bottom at the selected storage times.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2025

Toward integrating high-fidelity CFD approaches in the thermal-hydraulic analysis of turbulent dry cask systems

Nuclear power plants have been supplying resilient and reliable electricity for decades, contributing to energy independence of the U.S.. However, nuclear waste management remains one of the most significant challenges in the industry. The safety of dry cask storage systems relies heavily on their thermal-hydraulic performance. Computational Fluid Dynamics (CFD) simulations are often used to demonstrate this performance and ensure that the system design meets safety standards. This study presents reduced numerical models for various types of dry cask systems. These numerical models can produce efficient and fast results based on the employed modeling strategies. Additionally, the study uses a novel approach to high-fidelity simulations to evaluate modeling assumptions in dry cask modeling. Large Eddy Simulations (LES) are used for this purpose, particularly in regions where fluid velocity is relatively high and the turbulence characteristics become important. Furthermore, the results of these high-fidelity simulations will enhance the interpretation of outcomes produced from a lower-fidelity CFD model.

CFD↗

DOE OSTI2021

Grafted nickel-promoter catalysts for dry reforming of methane identified through high-throughput experimentation

High-throughput synthesis of a series of monometallic and bimetallic catalysts (45 bimetallic and 50 monometallic samples) consisting of nickel and one of nine different metal promoters (B, Co, Cu, Fe, Mg, Mn, Sn, V and Zn) supported on one of six different metal oxides alumina, ceria, magnesia, silica and titania) is carried out via organometallic grafting using a robotic platform. The catalysts are evaluated for their activity and selectivity for the dry reforming of methane at a feed ratio of CH 4 :CO 2 of 1 at 650–800 °C in a parallel flow reactor system. The type of oxide support prevails over the type of additive for both catalyst activity and stability. On Al 2 O 3 and MgO, Fe was found to be the best promoter; on SiO 2 , Cu is the best promoter at 700 °C and higher, while on TiO 2 , Mn is found to enhance the conversion at 800 °C. On CeO 2 , all additives except Fe have beneficial effects. Twenty-five catalysts show > 90% methane conversion with ten catalysts showing > 95% conversion at 800 °C with the H 2 :CO ratios ranging from 0.8 to 1.2. Amongst the ten highest performers, NiFe/Al 2 O 3 and NiFe/MgO are more active than Ni/Al 2 O 3 and Ni/MgO, respectively and were stable over a period of 25 h at 800 °C. Characterization on the as-prepared samples reveals highly dispersed phase, while after reduction in H 2 , highly dispersed and reduced nickel particles up to 10 nm are formed. The particles do not increase in size under dry reforming reaction conditions at 800 °C. An increased hydrogen consumption observed during H 2 -TPR of the nickel particles is positively correlated with methane conversion for Al 2 O 3 -based catalysts. The resistance to deactivation by coking and variation in coke structure are investigated by spectroscopic and microscopic methods to identify the relationship between metal promoters, alloy formation, and type of surface carbon deposits. Carbon whiskers were observed on the ten selected spent samples and are preferentially deposited on Ni rather than on the promoters. Carbon nanotube formation and metal particle removal from support were not observed to cause deactivation while amorphous carbon formation was clearly linked to catalyst deactivation, as amorphous carbon could encapsulate nickel, either on the support or at the end of the carbon nanotube. Furthermore, the organometallic grafting technique is an efficient and suitable technique for synthesizing highly dispersed and homogeneous phases which lead to high conversion and high durability for dry reforming of methane.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2016

Mechanisms of dimensional instability caused by differential drying in wet cured cement paste

This paper examines the mechanisms of wet curing and subsequent drying at 23 °C and 40% RH influencing the curling of cement paste, plate-like beams. Both experimental and model results show that as the duration of the wet curing is increased, the member peak deflection also increases from one sided drying. Experiments suggest that the extended wet curing causes a pore structure refinement resulting in greater saturation and consequently greater shrinkage. A simplified 1-D, drying diffusion and shrinkage model is able to adequately predict experimentally measured peak curling deflections, and confirms the effect of saturation on curling. The results provide important insight into the volume stability of slabs and the potential negative impact of wet curing on slab curling.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2018

Shape effect on drying behavior of cement-based materials: Mechanisms and numerical analysis

The shape of the specimen or structure has a direct impact on the behavior of drying concrete. This effect is not taken into account in most of shrinkage models and codes. Only the current B4 model and its previous version B3 model incorporate a shape factor. The determination of this coefficient is based on the nonlinear moisture diffusion analysis, which can explain the shape effect on the shrinkage rate. However, the model integrates this coefficient in the ultimate shrinkage values as well. An experimental study has been performed to confirm and understand this behavior. The mass loss and drying shrinkage of cylinders showed higher rate and ultimate values than the prisms, for the same effective cross section thickness. To explain this result, the drying, the differential shrinkage, the internal stress and the damaged depth were determined for both shapes through numerical modeling. The main input data of the model were the measured mass loss and shrinkage. The calculated desorption isotherm curve of the cylinder was below that of the prism, which is consistent with its higher ultimate mass-loss. The determination of stress profiles indicates slower stress mitigation for the cylinder. The cylinder develops a larger relative damaged area, defined as the part of the specimen where cracking is likely to occur due to tensile stresses. The results actually show that differential shrinkage between the edge and the core is more pronounced for the cylinder and decreases with time.

36 MATERIALS SCIENCE↗

DOE OSTI2017

Influence of Osmotic Drying with an Aqueous Poly(ethylene Glycol) Liquid Desiccant on Alumina Objects Gelcast with Gelatin

Gelcasting and liquid desiccant drying are novel forming and drying methods used to mitigate common issues associated with the fabrication of complex advanced ceramic objects. Here, the molecular weight and osmotic pressure of aqueous poly(ethylene glycol) (PEG) desiccant solutions were simultaneously varied to understand their influence on the net mass loss rates of gelcast alumina samples prepared using gelatin as a gelling agent. Additionally, the amount of PEG diffusion and water diffusion to and from the ceramic samples after 150 min of immersion in the liquid desiccant was correlated to the solution properties as was the final bulk density of the sintered samples. Furthermore, solutions with high molecular weight and low osmotic pressure resulted in low PEG gain and low water loss, while solutions with low molecular weight and high osmotic pressure resulted in high PEG gain and high water loss. In some cases, more than 40 wt% of the total water per sample was removed through the liquid desiccant drying process.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Controlled 3D nanoparticle deposition by drying of colloidal suspension in designed thin micro-porous architectures

Nanoparticle deposition by drying of colloidal suspension in thin micro-porous architectures has attracted a lot of attention in scientific research as well as industrial applications. However, the underlying mechanisms of such three-dimensional (3D) deposition are not yet fully revealed due to the complexity of the co-occurring processes of two-phase fluid flows, phase change and mass transport. Consequently, the control of 3D nanoparticle deposition remains a challenge. We use a combined experimental and numerical approach to achieve controlled 3D nanoparticle deposition by drying of colloidal suspension in two pillar-based thin micro-porous architectures. By the design of pillar layout, rectangular-spiral and circular-spiral deposition configurations are obtained globally. By varying the surface wettability, vertically symmetric and sloped nanoparticle depositions can be achieved locally. While the numerical modeling reveals the mechanisms of liquid internal flow, as well as the impact of local drying rate on nanoparticle transport, accumulation and final deposition, the experimental results of deposition configurations validate the controlling strategies. This combined experimental and numerical work provides a framework to achieve desired 3D nanoparticle deposition in thin micro-porous architectures, with a thorough understanding of the underlying mechanisms of two-phase fluid flows, phase change and mass transport.

36 MATERIALS SCIENCE↗

DOE OSTI2019

Dry reforming of methane with isotopic gas mixture over Ni-based pyrochlore catalyst

Dry reforming of methane was carried out using isotopic 13 CO 2 and C 18 O 2 gases over a Ni-based pyrochlore catalyst that was synthesized using the modified Pechini method. In this method, 1 wt% Ni was doped into the La 2 Zr 2 O 7 pyrochlore structure. The catalyst was characterized by H 2 -TPR, TPO, and XRD and tested for its methane reforming activity under CO 2 dry-reforming reaction conditions. Here, the results of repeated TPR/TPO cycles up to 950 °C showed that the consecutive TPR profiles were nearly identical, indicating that the catalyst was stable at high temperatures, and that the nickel oxidation/reduction processes were reversible. The dry-reforming experimental results using labelled 13 CO 2 gas showed the syngas production for this material proceeded through the activation of CH 4 with O that came from breaking one of the CO bonds of CO 2 with the latter reaction (CO 2 activation) likely occurring at oxygen vacancies at or near the Ni particle-pyrochlore interface. It was also found that only a small portion of the CO originated from CH 4 . A variation of the same experimental test, but using 12 C 18 O 2 , revealed only 12 C 18 O was formed and no 12 C 16 O was detected, ruling out the possibility of reaction with the lattice oxygen in the catalyst structure with this material. Over this catalyst, the activated CH 4 appeared to dissociate to elemental carbon on the catalyst surface, which was determined to be the source of carbon from a post reaction TPO of the catalyst that was exposed to the 13 CO 2 — 12 CH 4 mixture. No carbon deposition appeared to originate from 13 CO 2 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2017

Spectral analysis of amazon canopy phenology during the dry season using a tower hyperspectral camera and modis observations

The association between spectral reflectance and canopy processes remains challenging for quantifying large-scale canopy phenological cycles in tropical forests. In this paper, we used a tower-mounted hyperspectral camera in an eastern Amazon forest to assess how canopy spectral signals of three species are linked with phenological processes in the 2012 dry season. We explored different approaches to disentangle the spectral components of canopy phenology processes and analyze their variations over time using 17 images acquired by the camera. The methods included linear spectral mixture analysis (SMA); principal component analysis (PCA); continuum removal (CR); and first-order derivative analysis. In addition, three vegetation indices potentially sensitive to leaf flushing, leaf loss and leaf area index (LAI) were calculated: the Enhanced Vegetation Index (EVI), Normalized Difference Vegetation Index (NDVI) and the entitled Green-Red Normalized Difference (GRND) index. We inspected also the consistency of the camera observations using Moderate Resolution Imaging Spectroradiometer (MODIS) and available phenological data on new leaf production and LAI of young, mature and old leaves simulated by a leaf demography-ontogeny model. The results showed a diversity of phenological responses during the 2012 dry season with related changes in canopy structure and greenness values. Because of the differences in timing and intensity of leaf flushing and leaf shedding, Erisma uncinatum, Manilkara huberi and Chamaecrista xinguensis presented different green vegetation (GV) and non-photosynthetic vegetation (NPV) SMA fractions; distinct PCA scores; changes in depth, width and area of the 681-nm chlorophyll absorption band; and variations over time in the EVI, GRND and NDVI. At the end of dry season, GV increased for Erisma uncinatum, while NPV increased for Chamaecrista xinguensis. For Manilkara huberi, the NPV first increased in the beginning of August and then decreased toward September with new foliage. Variations in red-edge position were not statistically significant between the species and across dates at the 95% confidence level. The camera data were affected by view-illumination effects, which reduced the SMA shade fraction over time. When MODIS data were corrected for these effects using the Multi-Angle Implementation of Atmospheric Correction Algorithm (MAIAC), we observed an EVI increase toward September that closely tracked the modeled LAI of mature leaves (3–5 months). Compared to the EVI, the GRND was a better indicator of leaf flushing because the modeled production of new leaves peaked in August and then declined in September following the GRND closely. Finally, while the EVI was more related to changes in mature leaf area, the GRND was more associated with new leaf flushing.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2015

Release and control of hydrogen sulfide during sludge thermal drying

The release of hydrogen sulfide (H2S) during sludge drying is a major environmental problem because of its toxicity to human health. A series of experiments were performed to investigate the mechanisms and factors controlling the H2S release. Results of this study show that: 1) the biomass and activity of sulfate-reducing bacteria (SRB) in sludge were the major factors controlling the amount of H2S release, 2) the sludge drying temperature had an important effect on both the extent and the timing of H2S release from the sludge, and 3) decreasing sludge pH increased the H2S release. Based on the findings from this study, a new system that integrates sludge drying and H2S gas treatment was developed to reduce the amount of H2S released from sludge treatments.

sludge, H2S, treatment, drying, control↗

DOE OSTI2021

The adsorption of As(V) on poorly crystalline Fe oxyhydroxides, revisited: Effect of the reaction media and the drying treatment

Arsenic (As) adsorbed on Fe oxyhydroxides (adsorbent) is widely occurring in many environmental settings such as in acid mine drainage systems or in the hydrometallurgical operations to form Fe-As coprecipitates. However, the influence of the reaction media and the drying treatment on the microstructure of the directly formed adsorbents at various pHs was still not fully understood. In this work, As adsorption behaviors on various forms of Fe oxyhydroxides were systematically investigated by using XRD, FTIR, Raman, XANES, and HRTEM. Overall, the results revealed that at weak acidic pH, more As could adsorbed on the suspension adsorbent formed in sulfate and chloride media than that in nitrate media, possibly due to the microstructure alteration of the adsorbent in the presence of sulfate and chloride. Besides, the increasing crystallinity of the Fe oxyhydroxides and the aggregation effect after drying were the major reasons why less As could be hold by the dried adsorbents than that of the corresponding suspension adsorbents. These findings could shed more light on the nature of the Fe oxyhydroxides which may be helpful for more precisely predicting the fate of some toxic metal(loid)s in the environment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗