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At least 397 records · Page 22

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NASA NTRS1979

Rate constant for the reaction H + NO2 from 195 to 400 K with FP-RF and DF-RF techniques

Measurements are made of the rate constant for the reaction H + NO2 yielding OH + NO over significant temperature ranges with the flash photolysis-resonance fluorescence (FP-RF) technique and also with the discharge flow-resonance fluorescence (DF-RF) technique. Since it is important to study chemical reactions with more than one technique, the above reaction is investigated with the FP-RF technique over the temperature range 230-400 K. The results reported do not agree with earlier determinations. Accordingly, a separate set of measurements is made with the DF-RF technique over the temperature range 195-368 K; the results are also reported. The reaction is also considered theoretically, especially with regard to the question of temperature dependence and absolute magnitude of the rate constant.

Michael, J. V.↗

NASA NTRS1980

Absolute rate constant of the reaction between chlorine /2P/ atoms and hydrogen peroxide from 298 to 424 K

The absolute rate constant of the reaction between chlorine (2P) atoms and hydrogen peroxide was determined from 298 to 424 K, using the discharge flow resonance fluorescence technique. Pseudo-first-order conditions were used with hydrogen peroxide in large excess. A fast flow-sampling procedure limited hydrogen peroxide decomposition to less than 5% over the temperature range studied. At 298 K, the rate constant is (4.1 plus or minus 0.2) x 10 to the minus 13th cu cm/molecule-sec.

Keyser, L. F.↗

NASA NTRS1980

Absolute rate constant of the reaction OH + H2O2 yields HO2 + H2O from 245 to 423 K

The absolute rate constant of the reaction between the hydroxyl radical and hydrogen peroxide was measured by using the discharge-flow resonance fluorescence technique at total pressure between 1 and 4 torr. At 298 K the result is (1.64 + or - 0.32) x 10 to the -12th cu cm/molecule s. The observed rate constant is independent of pressure, surface-to-volume ratio, the addition of vibrational quenchers, and the source of OH. The temperature dependence has also been determined between 245 and 423 K; the resulting Arrhenius expression is k cu cm/molecule s is equal to (2.51 + or - 0.6) x 10 to the -12th exp(-126 + or - 76/T).

Keyser, L. F.↗

NASA NTRS1980

Ground-state rotational constants of /C-13/H3D

Rotational constants for the vibrational ground state of (C-13)H3D, which has been detected in the atmospheres of Jupiter and Saturn, are reported. High-resolution spectra of monodeuteromethane were obtained in the region 1800 to 2500 kaysers by a vacuum Fourier interferometer, and the values of the rotational constants B0, D0J, D0JK, H0JJJ, H0JJK and H0JKK were calculated by an analysis of ground-state combination differences in the nu 2(A1) band. The calculated frequency and intensity of this transition are found to be in agreement with the observed values.

Chackerian, C., Jr.↗

NASA NTRS1980

Rate constant for the reaction of hydroxyl radical with formaldehyde over the temperature range 228-362 K

Absolute rate constants for the reaction OH + H2CO have been measured over the temperature range 228-362 K using the flash photolysis-resonance fluorescence technique. The results were independent of variations in forbidden H2CO, total pressure of forbidden Ar and flash intensity (i.e., initial forbidden OH). The rate constant was found to be invariant with temperature in this range, the best representation being k1 = (1.05 + or - 0.11) x 10 to the -11th cu cm/molecule sec where the error is two standard deviations. This result is compared with previous absolute and relative determinations of k1. The reaction is also discussed from a theoretical point of view.

Stief, L. J.↗

NASA NTRS1982

Constant-Pressure Hydraulic Pump

Constant output pressure in gas-driven hydraulic pump would be assured in new design for gas-to-hydraulic power converter. With a force-multiplying ring attached to gas piston, expanding gas would apply constant force on hydraulic piston even though gas pressure drops. As a result, pressure of hydraulic fluid remains steady, and power output of the pump does not vary.

Galloway, C. W.↗

NASA NTRS1981

Corrosion of 310 stainless steel in H2-H2O-H2S gas mixtures: Studies at constant temperature and fixed oxygen potential

Corrosion of SAE 310 stainless steel in H2-H2O-H2S gas mixtures was studied at a constant temperature of 1150 K. Reactive gas mixtures were chosen to yield a constant oxygen potential of approximately 6 x 10 to the minus 13th power/cu Nm and sulfur potentials ranging from 0.19 x 10 to the minus 2nd power/cu Nm to 33 x 10 to the minus 2nd power/cu Nm. The kinetics of corrosion were determined using a thermobalance, and the scales were analyzed using metallography, scanning electron microscopy, and energy dispersive X-ray analysis. Two corrosion regimes, which were dependent on sulfur potential, were identified. At high sulfur potentials (p sub S sub 2 less than or equal to 2.7 x 10 to the minus 2nd power/cu Nm) the corrosion rates were high, the kinetics obeyed a linear rate equation, and the scales consisted mainly of sulfide phases similar to those observed from pure sulfication. At low sulfur potentials (P sub S sub 2 less than or equal to 0.19 x 10 to the minus 2nd power/cu Nm) the corrosion rates were low, the kinetics obeyed a parabolic rate equation, and scales consisted mainly of oxide phases.

Rao, D. B.↗

NASA NTRS1980

Liquid distribution and the dielectric constant of wet snow

The mixing theory of Polder and Van Santen is revised for application to three cases of wet snow. The dielectric constant is calculated for a range of liquid contents and porosities. These calculated values compare favorably with experimental data for the two cases in which data available. The application to a snow cover with a heterogeneous distribution of liquid is discussed. The possibility of applying this theory the calculate the imaginary part of the dielectric constant must be explored further.

Colbeck, S. C.↗

NASA NTRS1980

Theoretical microwave spectral constants for C2N, C2N/+/, and C3H

Theoretical microwave spectral constants have been computed for C2N, C3H, and C2N(+). For C2N these are compared with values obtained from optical data. Calculated hyperfine constants are also presented for HNC, DNC, and HCNH(+). The possibility of observing these species in dense interstellar clouds is discussed.

Green, S.↗

NASA NTRS1980

Variations in the solar constant due to solar active regions

Solar activity is expected to affect the solar constant at some level. Recent observations and data analysis show the amount of variation to be expected for active regions, faculae, and sunspots on the apparent solar brightness. It is concluded that the maximum effect is about 20 times greater for sunspots than for faculae per unit area. Because facular areas are 25-30 times those for sunspots, the effect on the solar constant of faculae and sunspots is approximately equal and opposite, being typically in the neighborhood of 40-100 parts per million (ppm), but on occasion able to reach over 200 ppm. The issue of energy balance is not discussed here, for it requires further data analysis as well as information on the facular and sunspot limb darkening.

Chapman, G. A.↗

NASA NTRS1981

Short and long term variations in the solar constant

Short and long term variations in the solar constant are examined theoretically. The variations observed by the Solar Maximum Mission, lasting several days and associated with the passage of sunspot groups, strikingly demonstrates the well known lack of a bright ring effect around sunspots. This suggests that sunspot magnetic fields do not simply block the heat flowing upward into the photosphere. Rather, it is suggested that gravitational draining occurs; this cools sunspots and transports downward the heat that would otherwise flow into the photosphere. A model of sunspot temperature with depth shows modest support when compared with the empirical model of Van't Veer. Secular trends in the solar constant may occur and be associated with the influence of the convection zone magnetic field upon convective heat transport. As a start to understanding this problem, the Schwarzschild criterion has been modified to include the effects of magnetic field.

Schatten, K. H.↗

NASA NTRS1981

Reactions of ethynyl radicals - Rate constants with CH4, C2H6, and C2D6

An experiment to measure ethynyl radical reactivity with other simple molecules is described. Flash photolysis of CF3C2H, a C2H precursor, was kinetically and spectroscopically analyzed for C2H reactions with CH4, C2H6, and C2D6 and rate constants for the abstraction reaction at room temperature were determined. The experimental apparatus is described, and the acetylene feedstock purification procedures are outlined. Rate constants are provided, and additional examination of the effects of added helium showed no alterations over the pressure range 20-700 torr.

Laufer, A. H.↗

NASA NTRS1981

Dynamical constants and reference parameters for Mars

Dynamical constants and other fundamental reference parameters for Mars have been derived from analyses of Viking lander ranging and Doppler tracking data covering a time span of nearly four years. Precise values have been obtained for the coordinates of the spin axis and for the rotation rate, suggesting that these Viking-derived values are definitive and are suitable for adoption by the IAU. Preliminary results have been obtained for a small seasonal variation in the rotation rate, and progress has been made toward a direct determination of the precession constant.

Michael, W. H., Jr.↗

NASA NTRS1982

Steps toward the Hubble constant. VIII - The global value

The problem of determining the global Hubble constant is approached by using two distance indicators whose dispersion in absolute magnitude is small, and hence which are virtually free of the Malmquist bias. New data are presented on the mean absolute-magnitude of the brightest individual red and blue supergiant stars in very nearby galaxies, calibrated relative to the Cepheids. The results are used to calibrate the maximum absolute blue magnitude for two well-observed Type I supernovae (SNe I). The velocity-relative distance diagram for 16 SNe I with known maximum apparent blue magnitudes is then calibrated using distances for IC 4182 and NGC 4214, with the result that the global Hubble constant equals 50 + or - 7 km per second per megaparsec. The result is compared with the known age of globular clusters in the Galaxy to show that the cosmological and the evolutionary time scales now closely agree.

Sandage, A.↗

NASA NTRS1982

Rate constant and possible pressure dependence of the reaction OH + HO2

The technique of laser-induced fluorescence is used to measure steady-state OH concentrations in the photolysis of water vapor at 184.9 nm and 298 K, with O2 added in trace amounts. He or Ar is present at total pressures in the range 75-730 torr. The results are used in deriving the rate-constant ratio of k1 to k5 to the 1/2 power, where k1 and k5 are the rate constants for the reactions OH + HO2 = H2O + O2 and HO2 + HO2 = O2, respectively. When available values of k5 are used, the results give k1 = (1.2 + or - 0.4) x 10 to the -10 cu cm/s at 1-atm pressure, with evidence of a decline of k1 at lower pressures. No water-vapor effect on k1 is observed.

Demore, W. B.↗

NASA NTRS1981

Study of the response of stratospheric ozone to perturbations in the solar constant and solar UV flux

A one-dimensional radiative-convective photochemical model has been used to examine the response of stratospheric and total ozone to perturbations in the solar flux. The model considers a detailed chemical reaction mechanism; vertical transport is parameterized through eddy diffusion coefficients. The temperature profile is calculated using a radiative transfer model for both time-dependent and steady-state cases. Results are discussed for the following types of perturbations: a 5% increase in the solar UV flux in the wavelength range 175-300 nm, a 5% increase in the solar constant, and an annual 6.6% variation in the solar constant associated with the variation in the earth-sun distance.

Natarajan, M.↗

NASA NTRS1982

Anharmonic properties of solids from measurements of the stress acoustic constant

The equations of elastic motion and their solutions are generalized in order to include nonzero homogeneous initial stresses and redefine the stress acoustic constants to include the effect of initial stress. In deriving the relationship between the stress acoustic constants and the strain-generalized Gruneisen parameters, implications in material anharmonicity and nonlinear thermoelasticity are discovered. It is found that the linear change in velocity obtained from these measurements is a nonlinear process resulting from anharmonicity in the interatomic potential. In addition, the thermal expansion coefficient can also be expressed in terms of linear combinations.

Cantrell, J. H., Jr.↗

NASA NTRS1982

Optical constants in the extreme ultraviolet and soft X-ray region

The nature of optical constants and their measurement by reflection or absorption techniques in the extreme ultraviolet and soft X-ray spectral region from 30 to 3000 eV is discussed with emphasis on mirror design. Sources of optical constant data are mentioned and reflectance measurements for SiC and Kanigen between 40 and 200 eV are reported.

Rife, J. C.↗