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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS2024

Airborne lidar measurements of atmospheric CO 2 column concentrations to cloud tops made during the 2017 ASCENDS/ABoVE campaign

We measured the column-averaged atmospheric CO 2 mixing ratio (XCO 2 ) to a variety of cloud tops with an airborne pulsed multi-wavelength integrated path differential absorption (IPDA) lidar during NASA's 2017 ASCENDS/ABoVE airborne campaign. Measurements of height-resolved atmospheric backscatter profiles allow this lidar to retrieve XCO 2 to cloud tops, as well as to the ground, with accurate knowledge of the photon path length. We validated these measurements with those from an onboard in situ CO 2 sensor during spiral-down maneuvers. These lidar measurements were 2–3 times better than those from previous airborne campaigns due to our using a wavelength step-locked laser transmitter and a high-efficiency detector for this campaign. Precisions of 0.6 parts per million (ppm) were achieved for 10 s average measurements to mid-level clouds and 0.9 ppm to low-level clouds at the top of the planetary boundary layer. This study demonstrates the lidar's capability to fill in XCO 2 measurement gaps in cloudy regions and to help resolve the vertical and horizontal distributions of atmospheric CO 2 . Future airborne campaigns and spaceborne missions with this capability can be used to improve atmospheric transport modeling, flux estimation and carbon data assimilation.

Jianping Mao↗
NASA NTRSDate not supplied

A Simulated High CO 2 Spaceflight Environment Increases Plant Preference for Ammonium as a Nitrogen Source.

The growth of crops to sustain astronauts will be critical to long-duration spaceflight missions. Carbon dioxide (CO 2 ) concentrations are very high in spaceflight cabin environments, often 5-10X the CO 2 concentration on Earth 1 . It is therefore crucial to understand how plants respond to elevated CO 2 (eCO 2 ). Nitrogen (N) is important for plant survival, though the effects of eCO 2 on plant uptake of different N forms remain poorly understood. Shoot nitrate assimilation may be reduced at eCO 2 due to a decrease in available reducing power through increased carbon fixation and inhibition of photorespiration 2 , suggesting that eCO 2 may increase plant ammonium preference (Figure 1). A deeper understanding of changes in plant nitrogen form preference in response to eCO 2 will inform nutrient optimization for future space crop production and wastewater processing system design requirements 3 in addition to developing future eCO 2 climate-ready crops.

nitrogen↗
NASA NTRSDate not supplied

Anticipating Hazard Impacts through Capacity Building and Co-development

Improving forecast accuracy, extending lead time, understanding hazard susceptibility, and integrating exposure and vulnerability data to generate impact-based forecasts are critical in mitigating disaster impacts. These efforts enable anticipatory action through enhancing the efficacy of early warning systems to assess potential multi-dimensional hazard impacts. In response to this need, SERVIR has co-developed a series of hazard services providing vital information from national to regional scales. This poster showcases examples of geospatial services co-developed with partners through a capacity building approach, supporting the establishment of hazard early warning / early action systems. These services integrate multidimensional vulnerability and exposure data to comprehensively assess impacts. Furthermore, these services demonstrate how co-development and capacity building can advance the development of impact-based forecasts and multi-hazards services. By prioritizing collaboration, human insights, local knowledge, capacity building, and employing applied science approaches in geospatial service development, this work has helped create inclusive and customized solutions. These solutions are tailored to meet the needs of local communities and are readily adaptable into decision-making processes.

weather↗
NASA NTRS2021

Electrolytic Co-deposition Neutron Production Evaluation

Co-deposition electrochemical cells are a simple means to examine novel nuclear reactions. In this study, palladium and deuterium atoms were co-deposited on a cathode at stoichiometric densities, forming dendritic morphologies. Bubble detector neutron dosimeters were used to measure equivalent dose levels during electrolytic deposition. Standard configuration cells expected to produce excess neutrons were denoted as experimental cells and contained an electrolyte consisting of palladium(II) chloride, lithium chloride, and heavy water. The control cells used copper(II) chloride, lithium chloride, and heavy water electrolyte. Experimental and control cells were supplied current, increasing from 0.1 to 100.0 mA over a period of 20 days. For test days 9 through 20, the standard configuration experimental cells exhibited significantly higher average neutron radiation than the controls at a 99% confidence level. Alternative configurations involving more increasing current over a shortened time scale, substitutions of water in place of heavy water or potassium chloride for lithium chloride, as well as inclusion of depleted uranium near the cell cathodes all resulted in inconclusive evidence for promoting neutron production.

neutron↗
NASA NTRS1972

Hot CO on Mars

An attempt was made to measure the rotational temperature profiles and column density of the fourth positive bands of hot CO on Mars in the laboratory. Data were taken from Mariner 6 and 7 observations. Experimental results indicate that due to high rotational temperatures and the dependence of that temperature on incident electron energy, the CO density in the fourth positive emission intensities cannot be determined. It was also determined that a wavelength resolution of 0.01 mm is needed to determine the profiles. The present Mariner has a resolution of only 0.75.

Mumma, M. J.↗
NASA NTRS1972

Mariner 6 and 7 ultraviolet spectrometer experiment - Implications of CO2/+/, CO, and O airglow.

The Mariner 6 and 7 UV spectrometer experiments observed intense emissions from CO, O, and CO2(+) in the Martian airglow. Analysis shows that they are excited predominantly by the absorption of solar EUV photons by CO2 and constitute a major energy-loss mechanism for the thermosphere. Models of the thermospheric temperature profile and the airglow layer that demonstrate the effects of neutral chemistry and ionospheric composition are developed. With their aid, the observed CO Cameron-band emission scale height of 19 (plus or minus 4.5) km is shown to suggest an exospheric temperature of 315 (plus or minus 75) K. Consideration of other data suggests a 'best' value of about 350 K. Within the uncertainties in the excitation efficiencies and in the thermospheric cooling mechanisms, the observations are consistent with the measured electron density. There is no indication in the data that the ionosphere is modified by the solar wind below 200 km.

Stewart, A. I.↗
NASA NTRS1973

The reactions of HO2 with CO and NO and the reaction of O(1D) with H2O

HO2 radicals were generated by the photolysis of N2O at 2139 A in the presence of excess H2O or H2 and smaller amounts of CO and O2. The O(1D) atoms produced from the photolysis of N2O to give HO radicals or H2 to give HO + H. With H2O two HO radicals are produced for each O(1D) removed low pressures (i.e. approximately 20 torr H2O), but the HO yield drops as the pressure is raised. This drop is attributed to the insertion reaction: O(1D) + H2O + M yields H2O2 +M. The HO radicals generated can react with either CO or H2 to produce H atoms which then add to O2 to produce HO2. Two reactions are given for the reactions of the HO radicals, in the absence of NO.

Simonaitis, R.↗
NASA NTRS1973

On the interstellar CO/+//CO abundance ratio.

A search at high sensitivity for interstellar absorption in the 4250-A line of CO(+) yields negative results toward 14 stars, despite the pervasive presence of large amounts of CO in the interstellar gas. This result is in accord with theory, but still lacks by a large factor sufficient sensitivity to test any details of the theory.

Hobbs, L. M.↗
NASA NTRS1973

On the dipole moment of CO/+/.

Results of self-consistent field calculations on neutral CO, its positive ion, and on neutral CN to verify an earlier estimate of the dipole moment of CO(+) in its ground super 2 Sigma state. Based on the above-mentioned calculations, direct evidence is obtained that the dipole moment (relative to the center of mass) is approximately 2.5 plus or minus 0.5 C, as previously determined by Kopelman and Klemperer (1962).

Certain, P. R.↗
NASA NTRS1973

Co-60 in lunar samples.

Results obtained for Co-60 in lunar soils and rocks of different depths are discussed. These results are compared to a production calculation based on the work of Lingenfelter et al. (1972). The measurement of Co-60 activities can give information about the present-day equilibrium neutron flux in the lunar regolith. The most important quantity which can be derived from these data is the absolute present-day lunar neutron production rate.

Wahlen, M.↗
NASA NTRS1974

Quadrupole moment of CO, N2, and NO/+/

Evaluation of quadrupole moments obtained for CO, N2, and NO(+) with multiconfiguration self-consistent-field wave functions chosen by the optimized valence configuration (OVC) approach of Wahl and Das (1972). The quadrupole moments thus obtained are compared with both experimental and Hartree-Fock values. The Hartree-Fock results are found to be not very accurate for N2, especially if vibrational averages over vibrational levels greater than 1 or 2 are to be taken. The agreement between the OVC quadrupole moment and the experimental values is found to be best for CO.

Billingsley, F. P., II↗
NASA NTRS1974

A new upper limit for an atmosphere of CO2, CO on Mercury

High-resolution infrared spectra of Mercury (1.9-2.7 microns, resolution limit 0.134 wavelength/cm) obtained with the original 'Connes' interferometer at the Steward Observatory 90-inch telescope have provided a very sensitive test for the possible presence of a CO2, CO atmosphere. An improved upper limit of 0.12 cm-atm has been set for CO2, and a new upper limit of 0.05 cm-atm has been set for CO. Upper limits of similar magnitude can be established for CH4 and NH3. From the separation of the Mercury signal into reflected sunlight and thermal emission, we determine that the reflectivity decreases toward longer wavelengths and has a value of about 0.06 at 2.25 microns. Implications for the possible evolution of an atmosphere on Mercury are discussed.

Fink, U.↗
NASA NTRS1974

Line Co-57 gamma rays - New diagnostic of supernova structure

The nuclear gamma-ray lines emitted when Co-57 decays to Fe-57 should be detectable for several years following Galactic supernovae, and the time structure of their intensity relative to those emitted following the Ni-56 and Co-56 decays can reveal the structure of the exploding star. An analysis of a simplified analytic model is presented as an example.

Clayton, D. D.↗
NASA NTRS1974

Partial equilibrium model for predicting concentration of CO in combustion

A simple kinetic model, based upon the concept of partial equilibrium, is developed for predicting carbon monoxide concentrations in such steady-flow hydrocarbon-air combustion systems as gas-turbine combustors. The only two kinetic constraints used in the model are on the rate of change of the total number of gaseous particles in the system, and on the rate of change of the CO concentration. The accuracy of the model is verified by comparison with experimental results obtained by burning kerosene with air in a 130,000 Btu/hr atmospheric-pressure steady-flow burner. Burnt-gas cooling rates of 1,000,000 K/sec, about the magnitude encountered in the dilution zone of gas-turbine combustors, were obtained with a compact water-cooled heat exchanger. Good agreement between measured CO concentrations and the values predicted by the partial-equilibrium model was obtained.

Morr, A. R.↗
NASA NTRS1975

High temperature chemical kinetic study of the H2-CO-CO2-NO reaction system

An experimental study of the kinetics of the H2-CO-CO2-NO reaction system was made behind incident shock waves at temperatures of 2460 and 2950 K. The overall rate of the reaction was measured by monitoring radiation from the CO + O yields CO2 + h upoilon reaction. Correlation of these data with a detailed reaction mechanism showed that the high-temperature rate of the reaction N + OH yields NO + H can be described by the low-temperature (320 K) rate coefficient. Catalytic dissociation of molecular hydrogen was an important reaction under the tests conditions.

Jachimowski, C. J.↗
NASA NTRS1974

The C-12/C-13 ratio in stellar atmospheres. II - CN and CO in alpha Orionis

The isotopic abundance ratio C-12/C-13 for the M supergiant alpha Orionis is derived from photoelectric high-resolution scans of the CN 2-0 red system and high-resolution interferometric spectra of the CO second-overtone bands. The two molecules yield consistent results and the final value for the C-12/C-13 ratio is 7.0 plus or minus 1.5. Rationale is offered for the causes contributing to an earlier suggestion that C-12/C-13 ratios from CO and CN were in disagreement.

Lambert, D. L.↗