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At least 397 records · Page 22

Chemiluminescence Study on Thermal Degradation of Aircraft Tire Elastomers

Since the autoxidative process accounts in part for the degradation of rubber, including aircraft tires, it was felt that a study of the chemiluminescence from unsaturated elastomers could contribute significantly to an understanding of the degradation mechanism. The study revealed similarities in chemiluminescence behavior between four elastomers which were investigated, and it shows that similar oxidation mechanisms occur. Oxidative chemiluminescence was observed from purified samples of cis-1,4-polybutadiene, cis-1,4-polyisoprene, trans-polypentenamer, and 1,2-polybutadiene in an oxygen atmosphere at 25-150 C. The elastomer samples were placed in a 600 watt oven which is equipped with gas inlets for introducing any desired atmosphere. Chemiluminescence emission from the samples was focused with a two inch quartz lens onto the detector of a 12" photomultiplier which is connected to a photon counter. A strip-chart recorder, connected to the counter, permitted automatic data collection. Diagrams of the apparatus are included. The chemical reactions which occurred from the thermal decomposition of the polymer samples are described, and results (and tabulated data) are discussed.

Mendenhall, G. D.↗

Handbook for the estimation of microwave propagation effects: Link calculations for earth-space paths (path loss and noise estimation)

A single model for a standard of comparison for other models when dealing with rain attenuation problems in system design and experimentation is proposed. Refinements to the Global Rain Production Model are incorporated. Path loss and noise estimation procedures as the basic input to systems design for earth-to-space microwave links operating at frequencies from 1 to 300 GHz are provided. Topics covered include gaseous absorption, attenuation by rain, ionospheric and tropospheric scintillation, low elevation angle effects, radome attenuation, diversity schemes, link calculation, and receiver noise emission by atmospheric gases, rain, and antenna contributions.

Crane, R. K.↗

New CCIR papers on telecommunications for deep space research

The selection of preferred frequency bands for deep space telecommunications in the 20 to 120 GHz range is discussed. The performance of links between Earth stations and stations in deep space is affected by the atmosphere of the Earth. Attenuation and emission by the atmosphere generally limits deep space telecommunications to frequencies below 20 GHz. There are, however, certain frequency bands in the 20 to 120 GHz range where atmospheric attenuation is low enough to permit links between Earth stations and deep space stations. Additionally there are certain other bands in the 20 to 120 GHz range that would be particularly suitable for links between an Earth orbiting relay station and deep space stations.

Oldegroot, N. F.↗

Maser radiometer for cosmic background radiation anisotropy measurements

A maser amplifier was incorporated into a low noise radiometer designed to measure large-scale anisotropy in the 3 deg K microwave background radiation. To minimize emission by atmospheric water vapor and oxygen, the radiometer is flown in a small balloon to an altitude to 25 km. Three successful flights were made - two from Palestine, Texas and one from Sao Jose dos Campos, Brazil. Good sky coverage is important to the experiment. Data from the northern hemisphere flights has been edited and calibrated.

Fixsen, D. J.↗

LRIR observations of diurnal ozone variation in the mesosphere

The Limb Radiance Inversion Radiometer (LRIR) on the Nimbus 6 spacecraft obtained measurements of atmospheric infrared emission from which vertical profiles of temperature and ozone mixing ratio can be deduced. A three day sequence of data on either side of the evening terminator has been analyzed as a function of solar zenith angle (35 deg to 105 deg) and pressure level (2 mb to .1 mb). The response of the ozone field to solar flux extinction, temperature variability, and nighttime recombination are readily detected.

Anderson, G. P.↗

Formation of oxides of nitrogen in monodisperse spray combustion of hydrocarbon fuels

Experimental results of exit plane NO/NO(x) emissions from atmospheric monodisperse fuel spray combustion are presented. Six different hydrocarbon fuels were studied: isopropanol, n-propanol, n-octane, iso-octane, n-heptane and methanol. The results indicate an optimum droplet size for minimizing NO/NO(x) production for all of the test fuels. At the optimum droplet diameter, reductions in NO/NO(x) relative to the NO(x) occurred at droplet diameters of 55 and 48 microns respectively, as compared to a 50-micron droplet size for isopropanol. The occurrence of the minimum NO(x) point at different droplet diameters for the different fuels appears to be governed by the extent of prevaporization of the fuel in the spray, and is consistent with theoretical calculations based on each fuel's physical properties. Estimates are also given for the behavior of heavy fuels and of polydisperse fuel sprays in shifting the minimum NO(x) point compared to a monodisperse situation.

Nizami, A. A.↗

Storm severity detection (RF)

Atmospheric electrical emissions occurring in association with Hurricane Alicia were observed by two crossed baseline phase linear interferometers. The sensors were located in San Antonio, Texas, and at Marshall Space Flight Center (MSFC), Huntsville, Alabama. An analysis of the data has indicated that the direction finding (DF) performance of the San Antonio site was extremely good while the DF performance at the MSFC site evidenced erratic behavior. A check of the data acquisition hardware revealed an intermitted problem in one of the radio receiver channels. Since the system has experienced several lightning strikes during the early spring of 1984, it was necessary to ship the entire rack of equipment back to SwRI for refurbishment. Analysis of the DF data from the interferometer site at San Antonio is being done. A limited subset of the MSFC data acquired during Hurricane Alicia has been found to be valid. These were data which satisfied the phase linearity criteria. Approximately 2,000 location estimates have been produced on the valid data. The results of the DF analysis and the location data are being correlated with the McIDAS data base at Marshall Space Flight Center, and with the radar summary data provided by the Hurricane Research Division using the National weather Service radar Facility at Galveston, Texas.

Johnson, R. L.↗

Investigation of forest canopy temperatures recorded by the thermal infrared multispectral scanner at H. J. Andrews Experimental Forest

Thermal Infrared Multispectral Scanner (TIMS) data were collected over the H. J. Andrews Experimental Forest in Western Oregon on July 29, 1983 at approximately 1:30 p.m., Pacific Standard Time. The relation of changes in canopy temperature to green leaf biomass levels in reforested clearcuts and old-growth forest was investigated. A digital data base was generated in order to isolate that portion of the thermal emission that could be attributed to surface properties other than the vegetation biomass component. The TIMS appears to be capable of detecting subtle differences in ERT as related to canopy closure and green lead biomass, however calibration techniques are needed to correct for emissivity and atmospheric effects.

Sader, Steven A.↗

The potential impact on atmospheric ozone and temperature of increasing trace gas concentrations

The response of the atmosphere to emissions of chlorofluorocarbons (CFCs) and other chlorocarbons, and to increasing concentrations of other radiatively active trace gases such as CO2, CH4, and N2O is calculated by a coupled chemical-radiative transport one-dimensional model. It is shown that significant reductions in the ozone concentration and in the temperature are expected in the upper stratosphere as a result of increasing concentrations of active chlorine produced by photodecomposition of the CFCs. The ozone content is expected to increase in the troposphere, as a consequence of increasing concentrations of methane and nitrogen oxides. Due to enhanced greenhouse effects, the Earth's surface should warm up by several degrees. The amplitude and even the sign of future changes in the ozone column are difficult to predict as they are strongly scenario-dependent. An early detection system to prevent noticeable ozone changes as a result of increasing concentrations of source gases should thus be based on a continuous monitoring of the ozone amount in the upper stratosphere rather than on measurements of the ozone column only. Measurements of NOx, Clx, and HOx are also required for unambiguous trend detection and interpretation.

Brasseur, G.↗

A reanalysis of rocket measurements of the ultraviolet dayglow

Rocket measurements of O I 989, 1304, 1356 A and N2 Lyman-Birge-Hopfield band emission in the midlatitude dayglow reported by Gentieu et al. (1979) and Eastes et al. (1985) are reexamined. MSIS-83 atomic oxygen densities, the 1304 and 1356 A excitation cross sections of Zipf and Erdman (1985), and SMM solar 1304 A irradiance measurements are consistent with the observed O I and N2 emission intensities. Atmosphere Explorer E (AE-E) measurements of the solar EUV irradiance near solar maximum are consistent with the 1980 rocket airglow data, but the solar EUV irradiance required to explain the 1978 airglow data is a factor of 1.5 larger than indicated by AE-E. Enhancement of the 1304 A excitation cross section due to radiative entrapment of cascade-feeding photons is much less than the factor of two predicted by the cascade model of Julienne and Davis (1976).

Link, R.↗

Mechanical testing of large cryogenic structures

The mechanical testing performed on the Cryogenic Limb Array Etalon Spectrometer (CLAES) instrument installed on the Upper Atmosphere Research Satellite is discussed. The CLAES determines temperatures and concentrations of stratospheric minor species as a function of altitude by measuring the atmospheric infrared emission spectra. CLAES is based on a telescope optical system and infrared spectrometer which are cooled with cryogens.

Newkirk, Roger↗

The cryogenic limb array etalon spectrometer (CLAES) on UARS - Experiment description and performance

The design and the performance of the cryogenic limb array spectrometer (CLAES) aboard the NASA Upper Atmosphere Research Satellite are discussed. CLAES measures altitude profiles of temperature, pressure, O3, H2O, CH4, N2O, NO, NO2, N2O5, HNO3, ClONO2, HCl, CFC 11, CFC 12, and aerosol absorption coefficients for atmospheric layer between 10 and 60 km. Examples of atmospheric spectral emission profiles for a number of constituents are presented as well as responsivity and noise parameters.

Roche, A. E.↗

Balloon-borne submillimeterwave stratospheric measurements

A new remote sensing instrument, the Submillimeterwave Limb Sounder, has been developed to simultaneously measure ClO, HCl, O3 and HO2 from high altitude balloon and aircraft platforms. The instrument is a double sideband heterodyne radiometer measuring atmospheric thermal emission spectra near 640 GHz from the Earth's limb. The instrument was flown in April and October, 1991 and in February, 1992 on high altitude balloon platforms over the southwestern United States.

Stachnik, R. A.↗

Altitude profile of aerosols on Mars from measurements of its thermal radiation on limb

Measurements of the thermal (range 7 - 13 micrometers) radiation of Mars with the high space resolution (approximately 2 km) were made by the TERMOSKAN experiment of the Phobos mission. Some of the results were published earlier but only the surface radiation was analyzed in detail. However some part of these measurements was made near the limb of the planet. The atmosphere gives an important input here in the planetary thermal radiation. Beyond the limb the atmosphere is the only source. The task of this work is to estimate some characteristics of the atmosphere using brightness profiles of the thermal radiation near the limb. An appropriate model of the temperature profile T(h) is necessary for such an analysis. A set of T(h) models (nominal, maximal and minimal) was defined using various sources including MARSGRAM, Viking-1 lander data, its theoretical considerations and boundary layer models. On the next step the possible input of the atmospheric gaseous emissions (wing of CO2 15 micrometer band) was estimated. It was found that even for the maximal T(h) this input is no more than a few percents of the measured radiation beyond the limb. Consequently the aerosols are responsible for almost all measured emission. The analysis of the observed profile showed that these aerosols have two components: (1) exponential with the scale height about 10 km and (2) some layered structure (two layers with maxima about 23 and 33 km consisted probably of ice).

Moroz, V. I.↗